光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
6^vMJ82U O>Vb7`z0< 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
Z'P>sV %nTgrgS(= 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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0P 7~2b4"& 目录
j4ARGkK5B 1. Introduction and Basic Principles
k3[%pS 1.1 Historical Development
y;)j 1.2 The Electron Mean Free Path
ax]Pa*C} 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
*}pl 1.4 Experimental Aspects
MZyzc{c, 1.5 Very High Resolution
wA+QUN3#n 1.6 The Theory of Photoemission
Hm>M}MF3 1.6.1 Core-Level Photoemission
or?@Ti; 1.6.2 Valence-State Photoemission
#J1vN]g 1.6.3 Three-Step and One-Step Considerations
)20jZm* 1.7 Deviations from the Simple Theory of Photoemission
*hhPCYOm References
I<v1S ]SqLF!S(= 2. Core Levels and Final States
tE i-0J 2.1 Core-Level Binding Energies in Atoms and Molecules
*SW.K{{ 2.1.1 The Equivalent-Core Approximation
cR/-FR 2.1.2 Chemical Shifts
OLThi[Yn 2.2 Core-Level Binding Energies in Solids
B0_[bQoc1 2.2.1 The Born-Haber Cycle in Insulators
&+@~;p5F 2.2.2 Theory of Binding Energies
]bjXbbHd 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
k<aKT?Ek> 2.3 Core Polarization
,/d
R 2.4 Final-State Multiplets in Rare-Earth Valence Bands
lzJ[ `i. 2.5 Vibrational Side Bands
>zYO1.~ 2.6 Core Levels of Adsorbed Molecules
]}KoW?M 2.7 Quantitative Chemical Analysis from Core-Level Intensities
5H (CP References
YL(7l|^! 2E
V
M*^A 3. Charge-Excitation Final States: Satellites
S,9}p1 3.1 Copper Dihalides; 3d Transition Metal Compounds
LaI( 3.1.1 Characterization of a Satellite
_/@VV5Mq 3.1.2 Analysis of Charge-Transfer Satellites
H3$~S ' 3.1.3 Non-local Screening
4 1w*<{Lk 3.2 The 6-eV Satellite in Nickel
ZG=B'4W 3.2.1 Resonance Photoemission
28 h3Ayw4 3.2.2 Satellites in Other Metals
KC+C?]~M 3.3 The Gunnarsson-Sch6nhammer Theory
/i$-ws- 3.4 Photoemission Signals and Narrow Bands in Metals
K+3dwQo References
c$X0C&m mcbr3P 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
m!{}Y]FZn 4.1 Theory
ls5s}X 4.1.1 General
AJ0qq 4.1.2 Core-Line Shape
q+A^JjzT 4.1.3 Intrinsic Plasmons
OYcf+p"<\ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
3Uzb]D~u 4.1.5 The Total Photoelectron Spectrum
n5nV461U 4.2 Experimental Results
G~,K$z/-l 4.2.1 The Core Line Without Plasmons
2h<{~; 4.2.2 Core-Level Spectra Including Plasmoas
4nC`DJ;V 4.2.3 Valence-Band Spectra of the Simple Metals
TTg>g~t` 4.2.4 Simple Metals: A General Comment
)_*<uSl 4.3 The Background Correction
aE[>^~Lv} References
9fk@C /$ JNQiCK,)}M 5. Valence Orbitals in Simple Molecules and Insulating Solids
5k0r{^#M 5.1 UPS Spectra of Monatomic Gases
]dZ8]I<$C 5.2 Photoelectron Spectra of Diatomic Molecules
;aZ$qgN*Y 5.3 Binding Energy of the H2 Molecule
s%tPGjMq 5.4 Hydrides Isoelectronic with Noble Gases
E0K'|* Neon (Ne)
Ql1HaC/5)- Hydrogen Fluoride (HF)
E)eRi"a46 Water (H2O)
<+MNv#1:w Ammonia (NH3)
yY,O=yOjq Methane (CH4)
D`nW9i7 5.5 Spectra of the Alkali HMides
txF)R[dZK 5.6 Transition Metal Dihalides
Kjbz\~ 5.7 Hydrocarbons
l djypEa} 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
1<hj3 5.7.2 Linear Polymers
PJC[#>} 5.8 Insulating Solids with Valence d Electrons
Z]$RO 5.8.1 The NiO Problem
K".\QF,: 5.8.2 Mort Insulation
V=<OV]0 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
/*5t@_0fe 5.8.4Band Structures of Transition Metal Compounds
yNY *Fl! 5.9 High—Temperature Superconductors
3"28=)o 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
>KjyxJ7 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
#UR4I2t* 5.9.3 The Superconducting Gap
(!h%)
_?.l 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
-4P2 2 5.9.5 Core—Level Shifts
\3P.G S{l 5.10 The Fermi Liquid and the Luttinger Liquid
Vp = 5.11 Adsorbed Molecules
zWiMl.[ 5.11.1 Outline
P;%4Imq3 5.11.2 CO on Metal Surfaces
?Ji.bnfK References
3kxI'0&T :t
&ib}v 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
__U;fH{c 6.1 Theory of Photoemission:A Summary of the Three-Step Model
x:TBZh?@$ 6.2 Discussion of the Photocurrent
3y!yz3E 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
xPa>-N=* 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
m5HP56a 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
3nfw:. 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
f
=H,BQ 6.3.1 Band Structure Regime
NTRw:' 6.3.2 XPS Regime
5t6!K?} 6.3.3 Surface Emission
]=A=VH& 6.3.4 One-Step Calculations
JTcK\t8 6.4 Thermal Effects
zV)Ob0M7U 6.5 Dipole Selection Rules for Direct Optical Transitions
?!H<V@a References
<v<TsEI &]VCZQL 7.Band Structtire and Angular-Resolved Photoelectron Spectra
ygm4A j> 7.1 Free-Electron Final—State Model
te?R(& 7.2 Methods Employing Calculated Band Structures
r>+Hwj0> 7.3 Methods for the Absolute Determination of the Crystal Momentum
'</ 7.3.1 Triangulation or Energy Coincidence Method
"65@8xt== 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
D:Zpls. 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
MF>1u% 7.3.4 The Surface Emission Method and Electron Damping
#4h_(Y 7.3.5 The Very-Low-Energy Electron Diffraction Method
:[gM 5G 7.3.6 The Fermi Surface Method
Q1qf'u 7.3.7 Intensities and Their Use in Band-Structure Determinations
-#]?3*NO 7.3.8 Summary
WeGT} 7.4 Experimental Band Structures
4;;F(yk8 7.4.1 One- and Two-Dimensional Systems
~8'4/wh+8 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
OZ?4"1$.t 7..4.3UPS Band Structures and XPS Density of States
J-g#zs 7.5 A Comment
Ya] qo] References
}+U} [G y}jX/Ln 8.Surface States, Surface Effects
zGFo-C 8.1 Theoretical Considerations
?' H);ou-p 8.2 Experimental Results on Surface States
DJ"O`qNV3 8.3 Quantum-Well States
2#Fc4RR;
8.4 Surface Core-Level Shifts
;$W/le"Xr References
aK'`yuN DKL< "#.7 9.Inverse Photoelectron Spectroscopy
;u LD_1% 9.1 Surface States
)L#C1DP# 9.2 Bulk Band Structures
Wt+aW 9.3 Adsorbed Molecules
R4,j References
hx$-d}W{ )f4D2c&VE 10. Spin-Polarized Photoelectron Spectroscopy
gO-C[j/ 10.1 General Description
TRG(W^<F 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
!pI)i*V| 10.3 Magnetic Dichroism
Xz5 aTJ& References
CQfrAk4mu {HeIY2 11. Photoelectron Diffraction
}Jt( H 11.1 Examples
HxJKS*H; 11.2 Substrate Photoelectron Diffraction
=%AFn9q 11.3 Adsorbate Photoelectron Diffraction
k))*Sg 11.4 Fermi Surface Scans
$NP5Z0v7 References
b7>^w<ki R}4o{l6 Appendix
Mn+;3qo{6 A.1 Table of Binding Energies
VAf~,T]Ww A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
+M%i3A A.3 Compilation of Work Functions
.:,RoK1 References
:bMCmY Index