光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
@!Pq"/ eD/?$@y 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
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b{8zo 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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qzH97<M}T R{WG>c 目录
%>s y`c 1. Introduction and Basic Principles
T|=8jt, 1.1 Historical Development
0 8U:{LL 1.2 The Electron Mean Free Path
R"tLu/S n 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
)i?wBxq'MA 1.4 Experimental Aspects
6Y=$7%z 1.5 Very High Resolution
4~
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i\3`?d 1.6.1 Core-Level Photoemission
SAqX[c 1.6.2 Valence-State Photoemission
N_T;&wibO 1.6.3 Three-Step and One-Step Considerations
&^Xm4r%u_ 1.7 Deviations from the Simple Theory of Photoemission
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> if<o References
68D.Li )cvC9gt 2. Core Levels and Final States
J4JKAv~3 2.1 Core-Level Binding Energies in Atoms and Molecules
Aw5yvQ>]e 2.1.1 The Equivalent-Core Approximation
7y60-6r 2.1.2 Chemical Shifts
-yC},tK 2.2 Core-Level Binding Energies in Solids
hxv/285B 2.2.1 The Born-Haber Cycle in Insulators
.NPai4V' 2.2.2 Theory of Binding Energies
jKtbGVZ7r 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
9\dC8 2.3 Core Polarization
;MO
%)) 2.4 Final-State Multiplets in Rare-Earth Valence Bands
kmuF*0Bjk 2.5 Vibrational Side Bands
Xl}>mbB 2.6 Core Levels of Adsorbed Molecules
Dl7#h,GTc< 2.7 Quantitative Chemical Analysis from Core-Level Intensities
K/08F|]a References
Bt.WRRpAB .<tb*6rX> 3. Charge-Excitation Final States: Satellites
(l$bA_F\ 3.1 Copper Dihalides; 3d Transition Metal Compounds
2AdV=n6Z 3.1.1 Characterization of a Satellite
T%:}/@ 3.1.2 Analysis of Charge-Transfer Satellites
1_F2{n:yp 3.1.3 Non-local Screening
yDHH05Yl 3.2 The 6-eV Satellite in Nickel
l.&6| 3.2.1 Resonance Photoemission
O6m}#?Ai/@ 3.2.2 Satellites in Other Metals
z S^:Ng5 3.3 The Gunnarsson-Sch6nhammer Theory
M,7v}[Tbl 3.4 Photoemission Signals and Narrow Bands in Metals
p^^<BjkQ References
+.zriiF]i Bf8 #&]O 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
tQ*5[F,fm 4.1 Theory
)K%AbKn 4.1.1 General
zHyM@*Gf( 4.1.2 Core-Line Shape
] @IzJz"R 4.1.3 Intrinsic Plasmons
Of-l<Ks\ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
&'i>5Y 4.1.5 The Total Photoelectron Spectrum
&t`l,]PQ=6 4.2 Experimental Results
w%`7,du| 4.2.1 The Core Line Without Plasmons
?*Jv&f# 4.2.2 Core-Level Spectra Including Plasmoas
Es)Kw3^a 4.2.3 Valence-Band Spectra of the Simple Metals
Z~v.!j0 4.2.4 Simple Metals: A General Comment
g"F vD_ 4.3 The Background Correction
sN;xHTY References
HD$W\P A5z5e#
,u 5. Valence Orbitals in Simple Molecules and Insulating Solids
0<fN<iR` 5.1 UPS Spectra of Monatomic Gases
GsxrqIaD 5.2 Photoelectron Spectra of Diatomic Molecules
l+RBe<Mq 5.3 Binding Energy of the H2 Molecule
Z+E@B>D7A^ 5.4 Hydrides Isoelectronic with Noble Gases
TVQ9"C Neon (Ne)
LKTIwb> Hydrogen Fluoride (HF)
XB^o>/|@S Water (H2O)
)%gigQZ+ Ammonia (NH3)
>DPC}@Wl Methane (CH4)
m{;2! 5.5 Spectra of the Alkali HMides
}c^`!9 5.6 Transition Metal Dihalides
%r?Y!=0 5.7 Hydrocarbons
}H\wed]F/ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
A-qdTJP 5.7.2 Linear Polymers
gm(`SC?a 5.8 Insulating Solids with Valence d Electrons
oBpHmMzA 5.8.1 The NiO Problem
pFx7URZA 5.8.2 Mort Insulation
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D$o|l]\ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
3Oy?_a$ 5.8.4Band Structures of Transition Metal Compounds
Nxp7/Nn3 5.9 High—Temperature Superconductors
~4<xTP\* 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
lEh; MJ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
Etj@wy/E 5.9.3 The Superconducting Gap
( hp 52Vse 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
JN,4#, 5.9.5 Core—Level Shifts
&Y4S[- 5.10 The Fermi Liquid and the Luttinger Liquid
$TGE 5.11 Adsorbed Molecules
`$Z:j;F 5.11.1 Outline
Se{}OG) 5.11.2 CO on Metal Surfaces
i]Njn k References
Y({&}\o s#hIzt 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
p
D-k<8| 6.1 Theory of Photoemission:A Summary of the Three-Step Model
j
Jt"= 6.2 Discussion of the Photocurrent
3MH9%*w'0 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
EyO=M~nsS 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
5<^$9(' 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
~=67#&(R 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
ltK\)L 6.3.1 Band Structure Regime
HRn
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K&3,J7&& 6.3.3 Surface Emission
OX-t#R` 6.3.4 One-Step Calculations
_)XQb1] 6.4 Thermal Effects
IOhJL'r 6.5 Dipole Selection Rules for Direct Optical Transitions
F>RL&i References
6Cfu19Dx I&vD >a5# 7.Band Structtire and Angular-Resolved Photoelectron Spectra
_3~/Z{z8 7.1 Free-Electron Final—State Model
C>wOoXjt 7.2 Methods Employing Calculated Band Structures
'{*{ 7.3 Methods for the Absolute Determination of the Crystal Momentum
D~P3~^ 7.3.1 Triangulation or Energy Coincidence Method
Xt}
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3CcCcZ9I 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
Gj!9#on$7R 7.3.4 The Surface Emission Method and Electron Damping
VokIc&!Uz 7.3.5 The Very-Low-Energy Electron Diffraction Method
>>bsr#aJ 7.3.6 The Fermi Surface Method
=S+*=j A 7.3.7 Intensities and Their Use in Band-Structure Determinations
oN({X/P2j 7.3.8 Summary
v]{F.N 7.4 Experimental Band Structures
VW&EdrR,S 7.4.1 One- and Two-Dimensional Systems
6Ft?9
B(F: 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
}$%j} F{ 7..4.3UPS Band Structures and XPS Density of States
M$YU_RPl+ 7.5 A Comment
Ec'Hlsgh&T References
n#$sLXVy h@AKfE!\~ 8.Surface States, Surface Effects
;YN`E 8.1 Theoretical Considerations
zbY2gq@? 8.2 Experimental Results on Surface States
3V uoDmG 8.3 Quantum-Well States
#z6[8B 8.4 Surface Core-Level Shifts
aW=c.Q. References
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!x X<8?># 9.Inverse Photoelectron Spectroscopy
m#K)%0 9.1 Surface States
u:]c 9.2 Bulk Band Structures
I-Q@v` 9.3 Adsorbed Molecules
:Oiz|b( References
cV$an (fA>@5n 10. Spin-Polarized Photoelectron Spectroscopy
epN!+(v 10.1 General Description
qPQ6`rD\ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
+P! ibHfP 10.3 Magnetic Dichroism
VdL*"i References
)d~{gPr. /Fk]>|* 11. Photoelectron Diffraction
o|kiwr}Y 11.1 Examples
!\<
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- f?8O6e 11.3 Adsorbate Photoelectron Diffraction
Zh 11.4 Fermi Surface Scans
22OfbwCb
References
_^/k I=[Ir8}; Appendix
4%B0H> A.1 Table of Binding Energies
4bs<j A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
s5/u>d A.3 Compilation of Work Functions
J8'1 ~$6 References
LwlO)|E Index