光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
{1.t ZCMT o[W7'1O 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
n0:Y*Op F'DO46 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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JW ;DA E< u;m[, 目录
<taN3 1. Introduction and Basic Principles
1H{M0e 1.1 Historical Development
Z> jk\[ 1.2 The Electron Mean Free Path
,rT62w*e 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
M/XxiF 1.4 Experimental Aspects
vq|o}6Et 1.5 Very High Resolution
$bRakF1'S 1.6 The Theory of Photoemission
3>Ts7
wM 1.6.1 Core-Level Photoemission
B>}=x4-8 1.6.2 Valence-State Photoemission
;ZMm6o 1.6.3 Three-Step and One-Step Considerations
:<l(l\MC 1.7 Deviations from the Simple Theory of Photoemission
y#Je%tAe
2 References
%y{#fZHc ZtPq*/' 2. Core Levels and Final States
u6{=Z : 2.1 Core-Level Binding Energies in Atoms and Molecules
SnsOuC5Ah 2.1.1 The Equivalent-Core Approximation
vs-%J6}G 2.1.2 Chemical Shifts
,C%fA>?UF8 2.2 Core-Level Binding Energies in Solids
<RfPd+</ 2.2.1 The Born-Haber Cycle in Insulators
#;59THdtPk 2.2.2 Theory of Binding Energies
pBV_'A}ioh 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
c|8[$_2 2.3 Core Polarization
RM8p[lfX 2.4 Final-State Multiplets in Rare-Earth Valence Bands
AV\6K;~ 2.5 Vibrational Side Bands
$Cw>
z^}u 2.6 Core Levels of Adsorbed Molecules
eHUr!zH: 2.7 Quantitative Chemical Analysis from Core-Level Intensities
bM[!E 8dF References
6 KuB<od E_-3G<rt 3. Charge-Excitation Final States: Satellites
2JNO@ 3.1 Copper Dihalides; 3d Transition Metal Compounds
9~ 8 A> 3.1.1 Characterization of a Satellite
z DDvXz 3.1.2 Analysis of Charge-Transfer Satellites
Gzxq] Mg 3.1.3 Non-local Screening
bjvpYZC\5 3.2 The 6-eV Satellite in Nickel
Enu/Nj 2 3.2.1 Resonance Photoemission
q 65mR!) 3.2.2 Satellites in Other Metals
56 k89o 3.3 The Gunnarsson-Sch6nhammer Theory
ag Za+a 3.4 Photoemission Signals and Narrow Bands in Metals
*"4d6 References
dc[w` }}Gz3>?24= 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
OU&eswW 4.1 Theory
+L(0R&C 4.1.1 General
/[Oo*}Dc=F 4.1.2 Core-Line Shape
$89hkUuTu^ 4.1.3 Intrinsic Plasmons
zs!}P 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
+DMD
g. 4.1.5 The Total Photoelectron Spectrum
y5;l?v94 4.2 Experimental Results
X=O}k& 4.2.1 The Core Line Without Plasmons
d~B]s 4.2.2 Core-Level Spectra Including Plasmoas
?;1^8 c0 4.2.3 Valence-Band Spectra of the Simple Metals
o4I&?d7;" 4.2.4 Simple Metals: A General Comment
z8W@N8IqC 4.3 The Background Correction
LgN\%5f- References
] .Mr&@ wfr+- 5. Valence Orbitals in Simple Molecules and Insulating Solids
5fpBzn$ 5.1 UPS Spectra of Monatomic Gases
b'\a
4 5.2 Photoelectron Spectra of Diatomic Molecules
sU>!sxW 5.3 Binding Energy of the H2 Molecule
cR.[4rG' 5.4 Hydrides Isoelectronic with Noble Gases
e!cZW.B=`f Neon (Ne)
V\k?$} Hydrogen Fluoride (HF)
?@W=bJ8{ Water (H2O)
x|B$n} B Ammonia (NH3)
pAwmQS\W Methane (CH4)
!FwR7`i 5.5 Spectra of the Alkali HMides
iwb]mJUA 5.6 Transition Metal Dihalides
@Y2"=QVt 5.7 Hydrocarbons
n^OWz4 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
uM3F[p%V^ 5.7.2 Linear Polymers
mIu- 5.8 Insulating Solids with Valence d Electrons
1QHCX*_ 5.8.1 The NiO Problem
>
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\@]/ks=K 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
56!>}!8! 5.8.4Band Structures of Transition Metal Compounds
=*f>vrme 5.9 High—Temperature Superconductors
nv WTx4oy 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
('1k%`R% 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
/0 |niiI 5.9.3 The Superconducting Gap
AEx|<E0 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
PVBf' 5.9.5 Core—Level Shifts
=X6+}YQ" 5.10 The Fermi Liquid and the Luttinger Liquid
C:C9swik"5 5.11 Adsorbed Molecules
cZ$!_30N+ 5.11.1 Outline
rTJv>Jjld 5.11.2 CO on Metal Surfaces
ZSL:q%:. References
A/kRw'6 cI #2MjL 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
SZ+<0Y| 6.1 Theory of Photoemission:A Summary of the Three-Step Model
.:eNL]2%: 6.2 Discussion of the Photocurrent
~z''kH=e
6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
,,+ ~./) 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
Z
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_E({!t"` 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
:UuPy|> 6.3.1 Band Structure Regime
;1Kxqpz_i 6.3.2 XPS Regime
i*16kdI. 6.3.3 Surface Emission
5gpqN)|)[ 6.3.4 One-Step Calculations
F">>,Oc)U" 6.4 Thermal Effects
.HTX7mA3 6.5 Dipole Selection Rules for Direct Optical Transitions
t(SSrM] References
#A|~s;s>N USVM' ~p I 7.Band Structtire and Angular-Resolved Photoelectron Spectra
r30t`o12i 7.1 Free-Electron Final—State Model
ypxqW8Xe 7.2 Methods Employing Calculated Band Structures
(n{sp 7.3 Methods for the Absolute Determination of the Crystal Momentum
y]OW{5( 7.3.1 Triangulation or Energy Coincidence Method
\R&4Nu2F 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
Nkfu k 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
4uip!@$K 7.3.4 The Surface Emission Method and Electron Damping
YM9oVF- 7.3.5 The Very-Low-Energy Electron Diffraction Method
&dSw[C#f 7.3.6 The Fermi Surface Method
A@/DGrZX 7.3.7 Intensities and Their Use in Band-Structure Determinations
c"+N{$ vp 7.3.8 Summary
],r?]> 7.4 Experimental Band Structures
xNt 7.4.1 One- and Two-Dimensional Systems
x/$s:[0B# 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
[kqxC 7..4.3UPS Band Structures and XPS Density of States
*"E?n>b 7.5 A Comment
e=t?mDh#E References
5 Vm
|/ Vy
= fm 8.Surface States, Surface Effects
S3"js4a 8.1 Theoretical Considerations
;S+c<MSl 8.2 Experimental Results on Surface States
aE^tc'h~ 8.3 Quantum-Well States
Y[8w0ve-g 8.4 Surface Core-Level Shifts
Fz+0 h" References
nLq7J: ?U0iHg{ 9.Inverse Photoelectron Spectroscopy
T6f{'.w 9.1 Surface States
uh`@ qmu) 9.2 Bulk Band Structures
hoASrj{s 9.3 Adsorbed Molecules
JWG7QH References
JH!qGV1 o a,Ju 10. Spin-Polarized Photoelectron Spectroscopy
R<mLG $ 10.1 General Description
Y_`D5c: 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
d"78w-S 10.3 Magnetic Dichroism
h
Ia{s) References
8eP2B281 r
@~T}<I 11. Photoelectron Diffraction
6wzF6]@O 11.1 Examples
O?@1</r^ 11.2 Substrate Photoelectron Diffraction
{Ny\9r 11.3 Adsorbate Photoelectron Diffraction
1W;3pN 11.4 Fermi Surface Scans
jG{}b6 References
bxP> kP%W:4l0 Appendix
Kq`Luf A.1 Table of Binding Energies
7|6tH@4Ub A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
uqZLlP# A.3 Compilation of Work Functions
*MkhRLw\, References
t Zj6=# Index