光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
|xTf:@hgHf }xl
@:Qo 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
[1Dg_>lz _J51:pi 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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89B1\ff &/7AW(? 目录
N~-N Q 1. Introduction and Basic Principles
-IR9^) 1.1 Historical Development
)>)_>[ 1.2 The Electron Mean Free Path
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{?s 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
3ySP*J5 1.4 Experimental Aspects
%aX<p{EY 1.5 Very High Resolution
7oPBe1P,K+ 1.6 The Theory of Photoemission
?o h3t 1.6.1 Core-Level Photoemission
A$RN7# 1.6.2 Valence-State Photoemission
Q:]F* p2 1.6.3 Three-Step and One-Step Considerations
!U$ %Jz 1.7 Deviations from the Simple Theory of Photoemission
63QSYn,t References
Q1Z;vzQfg K<b -|t9f 2. Core Levels and Final States
~ e[)]b3 2.1 Core-Level Binding Energies in Atoms and Molecules
U~SK 'R 2.1.1 The Equivalent-Core Approximation
$-VW)~Sl 2.1.2 Chemical Shifts
,vQkvuz 2.2 Core-Level Binding Energies in Solids
#(@dN+ 2.2.1 The Born-Haber Cycle in Insulators
RIUJ20PfYQ 2.2.2 Theory of Binding Energies
(jkjj7a 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
17G7r\iNYq 2.3 Core Polarization
Dyp'a 2.4 Final-State Multiplets in Rare-Earth Valence Bands
0Bn$C,- 2.5 Vibrational Side Bands
f #414ja 2.6 Core Levels of Adsorbed Molecules
0[0</"K%1m 2.7 Quantitative Chemical Analysis from Core-Level Intensities
Z94D<X" References
=5_8f {S\cpCI` 3. Charge-Excitation Final States: Satellites
T7n;Bf 3.1 Copper Dihalides; 3d Transition Metal Compounds
knypSgk_ 3.1.1 Characterization of a Satellite
t09,X 3.1.2 Analysis of Charge-Transfer Satellites
$cH'9W}3K 3.1.3 Non-local Screening
l\5qa_{z 3.2 The 6-eV Satellite in Nickel
}6eWdm!B 3.2.1 Resonance Photoemission
3Nw9o6` U 3.2.2 Satellites in Other Metals
iD@2_m) 3.3 The Gunnarsson-Sch6nhammer Theory
f7XmVCz1 3.4 Photoemission Signals and Narrow Bands in Metals
*D]/V U References
G:'-|h 0;e>kz3o 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
d OqwF
iO 4.1 Theory
q{c6DCc ]\ 4.1.1 General
hvGb9 4.1.2 Core-Line Shape
0_Etm83Wq6 4.1.3 Intrinsic Plasmons
f&^K>Jt1@# 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
l4u`R(!n5 4.1.5 The Total Photoelectron Spectrum
av
wU)6L 4.2 Experimental Results
qX:54$t 4.2.1 The Core Line Without Plasmons
@q5!3Nz 4.2.2 Core-Level Spectra Including Plasmoas
E](Ood 4.2.3 Valence-Band Spectra of the Simple Metals
Old5E& 4.2.4 Simple Metals: A General Comment
\I#2Mq? 4.3 The Background Correction
[ OMcSd|nf References
yS7[=S ^`=Z=C$fj 5. Valence Orbitals in Simple Molecules and Insulating Solids
?mRU9VY 5.1 UPS Spectra of Monatomic Gases
" S#0QH%5 5.2 Photoelectron Spectra of Diatomic Molecules
~mK9S^[ 5.3 Binding Energy of the H2 Molecule
i/oaKpPN 5.4 Hydrides Isoelectronic with Noble Gases
ngEjbCV+ Neon (Ne)
L ! yl^c Hydrogen Fluoride (HF)
F:IG3 @ Water (H2O)
V'^s5 Ammonia (NH3)
5Z6$90!k Methane (CH4)
YG?W8)T 5.5 Spectra of the Alkali HMides
sxnj`z 5.6 Transition Metal Dihalides
rN$_(%m_N 5.7 Hydrocarbons
Hc^b}A y7 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
qN+ ngk,: 5.7.2 Linear Polymers
wp.<}=|u 5.8 Insulating Solids with Valence d Electrons
,+,""t 5.8.1 The NiO Problem
#12PO q 5.8.2 Mort Insulation
+n^$4f 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Lc+wS@ 5.8.4Band Structures of Transition Metal Compounds
K!HSQ,AC 5.9 High—Temperature Superconductors
gGe `w 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
W?F+QmD 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
292e0cE 5.9.3 The Superconducting Gap
lXW.G 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
q+e'=0BHd: 5.9.5 Core—Level Shifts
~+QfP:G 5.10 The Fermi Liquid and the Luttinger Liquid
O)`R)MQ) 5.11 Adsorbed Molecules
6BLw 4m=h 5.11.1 Outline
/jeurCQ8#u 5.11.2 CO on Metal Surfaces
1/6 G&RB References
Po(9BRd7 [)#,~L3 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
h+CTi6-p 6.1 Theory of Photoemission:A Summary of the Three-Step Model
LJfd{R1y+ 6.2 Discussion of the Photocurrent
>UZfi u 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
#{UM4~|: 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
PRWS[2[yk 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
vDv:3qN7( 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
(6>8Dt 9[ 6.3.1 Band Structure Regime
hqD]^P>l1 6.3.2 XPS Regime
FuLP{]Y+AM 6.3.3 Surface Emission
. sgV 6.3.4 One-Step Calculations
,~JxYh 6.4 Thermal Effects
Kt;h'? 6.5 Dipole Selection Rules for Direct Optical Transitions
K\5@yqy5 References
K.",=\53 \;.\g6zX 7.Band Structtire and Angular-Resolved Photoelectron Spectra
68+9^ 7.1 Free-Electron Final—State Model
$3W[fC 7.2 Methods Employing Calculated Band Structures
tO)mKN+
( 7.3 Methods for the Absolute Determination of the Crystal Momentum
+/-#yfn!TR 7.3.1 Triangulation or Energy Coincidence Method
,N?~je. 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
%m t|Dl 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
}R;.~F 7.3.4 The Surface Emission Method and Electron Damping
bQrH8) 7.3.5 The Very-Low-Energy Electron Diffraction Method
0}PW<lU- 7.3.6 The Fermi Surface Method
GTeFDm;T^ 7.3.7 Intensities and Their Use in Band-Structure Determinations
M0S}-eXc5 7.3.8 Summary
!G90oW 7.4 Experimental Band Structures
o;D87E6Z 7.4.1 One- and Two-Dimensional Systems
5 nkx8JJ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
q+>{@tP9 7..4.3UPS Band Structures and XPS Density of States
cuB~A8H#} 7.5 A Comment
|Eu_K` References
m`}!
dBi 0;#%KC, 8.Surface States, Surface Effects
?76Wg:: 8.1 Theoretical Considerations
8&IsZPq%l 8.2 Experimental Results on Surface States
=%%\b_\L 8.3 Quantum-Well States
^}8(o 8.4 Surface Core-Level Shifts
I_6?Q^_uZ References
`kpX}cKK} (/a2#iW 9.Inverse Photoelectron Spectroscopy
68[3
/ 9.1 Surface States
Q&opnvN 9.2 Bulk Band Structures
1y2D]h /' 9.3 Adsorbed Molecules
_[<R<&jG References
j#f+0 w-C~
Ik 10. Spin-Polarized Photoelectron Spectroscopy
GLp2
?fon 10.1 General Description
ryB^$Kh,, 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
o8-BTq8 10.3 Magnetic Dichroism
r/$+'~apTk References
9TIyY`2! 6iVjAxR 11. Photoelectron Diffraction
.{1G"(z 11.1 Examples
:2pd2 S 11.2 Substrate Photoelectron Diffraction
&=Gz[1
L 11.3 Adsorbate Photoelectron Diffraction
WS/^WxRY 11.4 Fermi Surface Scans
2?u>A3^R References
5|my}.TR J*o :RnB Appendix
cv=nGFx6 A.1 Table of Binding Energies
%0fF_OU A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
1P.
W 34 A.3 Compilation of Work Functions
MUhC6s\F References
m2E$[g Index