光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
CpC6vA.R k:CSH{ s5{ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
YtY.,H; /P/::$ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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P!~B07y 3E:+DF-Z\ 目录
)-S;j)(+ 1. Introduction and Basic Principles
8 Tm/gzx 1.1 Historical Development
%YI !{ 1.2 The Electron Mean Free Path
B \>W 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
Y~I6ee,\ 1.4 Experimental Aspects
t2&} 1.5 Very High Resolution
6G>bZ+ 1.6 The Theory of Photoemission
"
{Nw K 1.6.1 Core-Level Photoemission
zK&J2P` 1.6.2 Valence-State Photoemission
1xMD
)V: 1.6.3 Three-Step and One-Step Considerations
mW @Z1Plxs 1.7 Deviations from the Simple Theory of Photoemission
[`=:uUf3 References
2T}FX4' Z n]e2 2. Core Levels and Final States
a|@1RH>7H 2.1 Core-Level Binding Energies in Atoms and Molecules
WvHy}1W 2.1.1 The Equivalent-Core Approximation
<^B!.zQ 2.1.2 Chemical Shifts
JL&ni]m 2.2 Core-Level Binding Energies in Solids
dF0:'y 2.2.1 The Born-Haber Cycle in Insulators
+ZeK,Y+Xy 2.2.2 Theory of Binding Energies
nokMS 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
}7/Ob)O 2.3 Core Polarization
[NguQ]B. 2.4 Final-State Multiplets in Rare-Earth Valence Bands
)\,hc$<=m 2.5 Vibrational Side Bands
'2c4
4F)i 2.6 Core Levels of Adsorbed Molecules
]e]hA@4 2.7 Quantitative Chemical Analysis from Core-Level Intensities
5b%zpx0Y References
z;[Z'_B Rj{D#5 3. Charge-Excitation Final States: Satellites
yy$7{9! 3.1 Copper Dihalides; 3d Transition Metal Compounds
/R)(u@jk 3.1.1 Characterization of a Satellite
p?eQN
Y 3.1.2 Analysis of Charge-Transfer Satellites
S:xG:[N@ 3.1.3 Non-local Screening
5 }F6s 3.2 The 6-eV Satellite in Nickel
PVUNi: h 3.2.1 Resonance Photoemission
QzA/HP a 3.2.2 Satellites in Other Metals
h*?/[XY 3.3 The Gunnarsson-Sch6nhammer Theory
4p_@f^v~QH 3.4 Photoemission Signals and Narrow Bands in Metals
[[d@P%X& References
O,!4
W\s 8??%H7~ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
kR|(hA,$N 4.1 Theory
Wy,Tf*[ 4.1.1 General
vCtag]H2@ 4.1.2 Core-Line Shape
Y([vma>U] 4.1.3 Intrinsic Plasmons
]mmL8%B@_ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
YfOO]{x,X 4.1.5 The Total Photoelectron Spectrum
jYJfo< 4.2 Experimental Results
U2VnACCUZs 4.2.1 The Core Line Without Plasmons
[:\8Ug8 4.2.2 Core-Level Spectra Including Plasmoas
&y=~:1&f 4.2.3 Valence-Band Spectra of the Simple Metals
L[9]Ez$2+ 4.2.4 Simple Metals: A General Comment
OQZ\/~o 5 4.3 The Background Correction
5T;,wQ< References
Cn(0ID+3f WL5!H.q 5. Valence Orbitals in Simple Molecules and Insulating Solids
S)d_A 5.1 UPS Spectra of Monatomic Gases
~",,&>#[K 5.2 Photoelectron Spectra of Diatomic Molecules
WgQ6EV` 5.3 Binding Energy of the H2 Molecule
za@`,Yq 5.4 Hydrides Isoelectronic with Noble Gases
^YG.eT6iG Neon (Ne)
cYMlcwS Hydrogen Fluoride (HF)
b?FTwjV+# Water (H2O)
(~FLG I Ammonia (NH3)
r)SwV!b Methane (CH4)
=1Mh%/y 5.5 Spectra of the Alkali HMides
9K
F`9Y 5.6 Transition Metal Dihalides
1p9+c~4l: 5.7 Hydrocarbons
l+1GA0'JP 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
p%6j2;D 5.7.2 Linear Polymers
Z*(lg$A9M 5.8 Insulating Solids with Valence d Electrons
&D 4Ci_6k 5.8.1 The NiO Problem
+#! !
'XP 5.8.2 Mort Insulation
wFJ?u?b0Q 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
ij=}3;L_! 5.8.4Band Structures of Transition Metal Compounds
0jN?5j 5.9 High—Temperature Superconductors
Z[{ :
` 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
8L7ZWw
d 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
cCH2=v4hU 5.9.3 The Superconducting Gap
=a.avOZ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
I5J9,j 5.9.5 Core—Level Shifts
R_2JP C 5.10 The Fermi Liquid and the Luttinger Liquid
s$ 2@ |; 5.11 Adsorbed Molecules
Qm X(s 5.11.1 Outline
~y(-j[ 5.11.2 CO on Metal Surfaces
L4'FL?~I References
IL]VY1'# yS[Z%]bvU 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
P]G`Y>#$r 6.1 Theory of Photoemission:A Summary of the Three-Step Model
DEw_dOJ( 6.2 Discussion of the Photocurrent
8f<[Bu ze 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
S:En9E 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
V3u[{^^f 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
zU9G:jH 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
6Q._zk 6.3.1 Band Structure Regime
|[VtYV _{ 6.3.2 XPS Regime
&&;ol}W 6.3.3 Surface Emission
yw%5W=< 6.3.4 One-Step Calculations
|&t 2jD( 6.4 Thermal Effects
xNh#= 6__9 6.5 Dipole Selection Rules for Direct Optical Transitions
Z;{3RWV References
I~$LIdzw t4H@ZvAH0 7.Band Structtire and Angular-Resolved Photoelectron Spectra
YpT x1c- 7.1 Free-Electron Final—State Model
Tej-mr3P 7.2 Methods Employing Calculated Band Structures
lFNf/j^Z 7.3 Methods for the Absolute Determination of the Crystal Momentum
:_q 7.3.1 Triangulation or Energy Coincidence Method
s}d1 k 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
KGclo-, 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
l*|^mx^Q 7.3.4 The Surface Emission Method and Electron Damping
"3*Chc 7.3.5 The Very-Low-Energy Electron Diffraction Method
Xh/i5}5 t 7.3.6 The Fermi Surface Method
j3bTa|UdT 7.3.7 Intensities and Their Use in Band-Structure Determinations
64^dy V,; 7.3.8 Summary
wR?M2*ri 7.4 Experimental Band Structures
h7-!q@ 7.4.1 One- and Two-Dimensional Systems
lMX 2O2 o 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
$C UmRi{T 7..4.3UPS Band Structures and XPS Density of States
$S Q8,Y, 7.5 A Comment
6s833Tmb&r References
G"=tQ$ZU ,x?H]a) 8.Surface States, Surface Effects
_$me. 8.1 Theoretical Considerations
eiJO;%fl>l 8.2 Experimental Results on Surface States
3:i4DBp,i 8.3 Quantum-Well States
s7CoUd2 8.4 Surface Core-Level Shifts
|#x;}_>7 References
Rla4XN=mf 66?!"w 9.Inverse Photoelectron Spectroscopy
{6v|d{V+e 9.1 Surface States
kyQ%qBv ^ 9.2 Bulk Band Structures
k[l+~5ix 9.3 Adsorbed Molecules
)""i"/Mn References
${#5$U+kI aXyu%<@k 10. Spin-Polarized Photoelectron Spectroscopy
BYEqTwhT& 10.1 General Description
AF1";duA 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
,|_ewye 10.3 Magnetic Dichroism
ObIi$uJX References
FDaHsiI: %Yg;s'F>#q 11. Photoelectron Diffraction
mf'N4y% 11.1 Examples
<0T4MR7 11.2 Substrate Photoelectron Diffraction
;^:9huN 11.3 Adsorbate Photoelectron Diffraction
p3:x\P<| 11.4 Fermi Surface Scans
.9Bimhc6K References
:4h4vp< GA{>=Q_~ Appendix
v#.FK:u} A.1 Table of Binding Energies
xDu11W+g A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
kL^;^!Nt A.3 Compilation of Work Functions
H*3f8A&@s References
d3T|N\(DL Index