光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
?()$imb* NDv_@V(D 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
_x ;fTW0 b=-LQkcZhK 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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qr~=S 82bOiN15 目录
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1. Introduction and Basic Principles
aAX(M=3 1.1 Historical Development
NgXV|) L 1.2 The Electron Mean Free Path
' Oe}Ja 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
!ufSO9eDx" 1.4 Experimental Aspects
;.g <u 1.5 Very High Resolution
Xw2tCRzD 1.6 The Theory of Photoemission
TT0~41&l 1.6.1 Core-Level Photoemission
~Uet)y< 1.6.2 Valence-State Photoemission
b&$sY!iU 1.6.3 Three-Step and One-Step Considerations
<RMrp@[ 1.7 Deviations from the Simple Theory of Photoemission
&xGcxFd References
!] -ET7 HAi'0%" 2. Core Levels and Final States
-'9sn/ 2.1 Core-Level Binding Energies in Atoms and Molecules
QE8aYPSFf 2.1.1 The Equivalent-Core Approximation
=!RlU)w 2.1.2 Chemical Shifts
XZk?aik}` 2.2 Core-Level Binding Energies in Solids
@9wug!, 2.2.1 The Born-Haber Cycle in Insulators
cG`R\$ 2.2.2 Theory of Binding Energies
/4f4H?A - 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
=
+=k(* 2.3 Core Polarization
nd 5w|83 2.4 Final-State Multiplets in Rare-Earth Valence Bands
G2{.Ew 2.5 Vibrational Side Bands
?l3PDorR 2.6 Core Levels of Adsorbed Molecules
u=5~^ 9 2.7 Quantitative Chemical Analysis from Core-Level Intensities
-X6[qLq References
r^$4]@Wn P}El#y#& 3. Charge-Excitation Final States: Satellites
?oc#$fcQ~ 3.1 Copper Dihalides; 3d Transition Metal Compounds
nDhD"rc 3.1.1 Characterization of a Satellite
-0{"QhdE% 3.1.2 Analysis of Charge-Transfer Satellites
$ 4&
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hu
G]kv3F: 3.2 The 6-eV Satellite in Nickel
BZP~m=kq 3.2.1 Resonance Photoemission
-PI_* 3.2.2 Satellites in Other Metals
=nmvG%.hd 3.3 The Gunnarsson-Sch6nhammer Theory
i8tH0w/(M 3.4 Photoemission Signals and Narrow Bands in Metals
o$=D`B References
?1f(@ `V;vvHP A 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
<~[A 4.1 Theory
HZ#<+~J 4.1.1 General
~?m vV`30& 4.1.2 Core-Line Shape
U# jbii6e 4.1.3 Intrinsic Plasmons
qOV6Kh) 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
z8ox#+l 4.1.5 The Total Photoelectron Spectrum
v/4Bt2J 4.2 Experimental Results
tyH*epanw 4.2.1 The Core Line Without Plasmons
5Z`9L|3d 4.2.2 Core-Level Spectra Including Plasmoas
P7||d@VW, 4.2.3 Valence-Band Spectra of the Simple Metals
"2}E ARa 4.2.4 Simple Metals: A General Comment
Lb'HM-d 4.3 The Background Correction
},2mIit( References
C>?`1d@ 6n
2LG 5. Valence Orbitals in Simple Molecules and Insulating Solids
UY_'F5X 5.1 UPS Spectra of Monatomic Gases
k lRS:\dW 5.2 Photoelectron Spectra of Diatomic Molecules
qx1}e 5.3 Binding Energy of the H2 Molecule
@"6dq;" 5.4 Hydrides Isoelectronic with Noble Gases
.[Z<r> Neon (Ne)
4mG?$kCN Hydrogen Fluoride (HF)
\s.c.c*eh; Water (H2O)
BtyBZ8P;e Ammonia (NH3)
IXmtjRv5 Methane (CH4)
)_bR"!Z 5.5 Spectra of the Alkali HMides
>l\?K8jL9 5.6 Transition Metal Dihalides
xJvM
l`2; 5.7 Hydrocarbons
!;YmLJk;hN 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
pN[G?A 5.7.2 Linear Polymers
)V}u}5 5.8 Insulating Solids with Valence d Electrons
fR=B/` 5.8.1 The NiO Problem
3MR4yw5v 5.8.2 Mort Insulation
KT)A{i 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
H$
!78/f 5.8.4Band Structures of Transition Metal Compounds
;+dB-g[ 5.9 High—Temperature Superconductors
f$lf(brQ: 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
USKa6<:{W 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
;_yp@.,\T 5.9.3 The Superconducting Gap
9`/\|t|V 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
t\hvhcbL 5.9.5 Core—Level Shifts
Bu ~N)^ 5.10 The Fermi Liquid and the Luttinger Liquid
7>g^OE f 5.11 Adsorbed Molecules
2BU%4IG 5.11.1 Outline
J~0_ 5.11.2 CO on Metal Surfaces
'g8~ uP References
A;t6duBDf/ [jD.l;jF 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
`&.]>H)N* 6.1 Theory of Photoemission:A Summary of the Three-Step Model
S$!)Uc\)A 6.2 Discussion of the Photocurrent
!H`! KBW 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
#6[7q6{4 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
!N4?>[E 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
A6APU><dm^ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
^K4#_H#" 6.3.1 Band Structure Regime
QMGMXa 6.3.2 XPS Regime
1D42+cy 6.3.3 Surface Emission
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