光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
Z3u""oM/ Y/:Q|HnXQ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
I?:+~q}lZr hj#+8= 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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><Mbea=U+ LcQ\?]w`] 目录
onS{ 1. Introduction and Basic Principles
+wf& L 1.1 Historical Development
RIVN>G[;L 1.2 The Electron Mean Free Path
DrVbx 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
XN 0RT>@ 1.4 Experimental Aspects
|'l* $ 1.5 Very High Resolution
TTw~.x, 1.6 The Theory of Photoemission
="[+6X 1.6.1 Core-Level Photoemission
0,i+ 1.6.2 Valence-State Photoemission
Y9(i}uTi 1.6.3 Three-Step and One-Step Considerations
1J!tcj1( 1.7 Deviations from the Simple Theory of Photoemission
hzf}_1 References
Z!5m'yZO Zqe[2() 2. Core Levels and Final States
^Qb!k/$3y 2.1 Core-Level Binding Energies in Atoms and Molecules
Pq_ApUZa 2.1.1 The Equivalent-Core Approximation
|RbUmuj 2.1.2 Chemical Shifts
_o=`-iy9 2.2 Core-Level Binding Energies in Solids
4j=@}!TBt 2.2.1 The Born-Haber Cycle in Insulators
X|QX1dl 2.2.2 Theory of Binding Energies
5x L,~" 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
f"}14V 2.3 Core Polarization
iz|9a|k6x 2.4 Final-State Multiplets in Rare-Earth Valence Bands
^
8Nr %NJ 2.5 Vibrational Side Bands
A<G ; 2.6 Core Levels of Adsorbed Molecules
P$#}-15?|_ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
=<tJAoVV References
=_~'G^`tu ]MH
\3g; 3. Charge-Excitation Final States: Satellites
(^OC%pc 3.1 Copper Dihalides; 3d Transition Metal Compounds
'5+, lRu 3.1.1 Characterization of a Satellite
;{)@ghD 3.1.2 Analysis of Charge-Transfer Satellites
P)o[p( 3.1.3 Non-local Screening
OKNs (H 3.2 The 6-eV Satellite in Nickel
looPO:bo^ 3.2.1 Resonance Photoemission
h"%,eW|^ 3.2.2 Satellites in Other Metals
S
g_?.XZc[ 3.3 The Gunnarsson-Sch6nhammer Theory
]r{#268 3.4 Photoemission Signals and Narrow Bands in Metals
[>QsMUvak References
:r|P?;t( b*%WAVt2T 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
[}g5Z=l 4.1 Theory
0eu$oel- 4.1.1 General
:$@zX]?M 4.1.2 Core-Line Shape
:~YyHX 4.1.3 Intrinsic Plasmons
7}HA_@[ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
@RG3*3( 4.1.5 The Total Photoelectron Spectrum
OsuSx^} 4.2 Experimental Results
6b5{ 4.2.1 The Core Line Without Plasmons
K Qy\l+\gM 4.2.2 Core-Level Spectra Including Plasmoas
a/xCl
:=8q 4.2.3 Valence-Band Spectra of the Simple Metals
*g_>eNpXD 4.2.4 Simple Metals: A General Comment
!P3tTL!*L 4.3 The Background Correction
G}OrpPP References
6(;[ov1 Q0cf] 5. Valence Orbitals in Simple Molecules and Insulating Solids
6Yi,%# 5.1 UPS Spectra of Monatomic Gases
_rWXcK3cjr 5.2 Photoelectron Spectra of Diatomic Molecules
wB0WR 5.3 Binding Energy of the H2 Molecule
P6Ol+SI#m 5.4 Hydrides Isoelectronic with Noble Gases
J'oz P^N Neon (Ne)
tj Bv{ Hydrogen Fluoride (HF)
PzG:M7 Water (H2O)
<L[)P{jn?p Ammonia (NH3)
+hYmL
Sq Methane (CH4)
[+2^n7R 5.5 Spectra of the Alkali HMides
fN/KXdAy& 5.6 Transition Metal Dihalides
.oOt(K+ 5.7 Hydrocarbons
R(#;yn 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
/IR5[67 5.7.2 Linear Polymers
8&AorYw[ 5.8 Insulating Solids with Valence d Electrons
kxiyF$
9 5.8.1 The NiO Problem
I(eR3d: 5.8.2 Mort Insulation
JC-yiORVr 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Gf$>!zXr 5.8.4Band Structures of Transition Metal Compounds
S 2` ;7 5.9 High—Temperature Superconductors
V'#u_`x"D) 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
cnO4NUDv 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
oieLh"$ 5.9.3 The Superconducting Gap
NWX%0PGZ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
{nWtNyJpS 5.9.5 Core—Level Shifts
ph. :~n>z 5.10 The Fermi Liquid and the Luttinger Liquid
0md{e`'q: 5.11 Adsorbed Molecules
*8HxJ+[,[ 5.11.1 Outline
?~9X:~6\ 5.11.2 CO on Metal Surfaces
KPK!'4,cu References
P =Gb 0L-g'^nn 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
PhL5EYn 6.1 Theory of Photoemission:A Summary of the Three-Step Model
;^SgV 6.2 Discussion of the Photocurrent
'4S@:.D` 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
-Q8`p 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
DdW8~yI& 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
rW .0_* 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
?n~j2-[< 6.3.1 Band Structure Regime
/9gMcn9EB 6.3.2 XPS Regime
e 2&i 6.3.3 Surface Emission
/R?uxhV 6.3.4 One-Step Calculations
y9mZQq 6.4 Thermal Effects
66;O 3g' 6.5 Dipole Selection Rules for Direct Optical Transitions
Q|r1. References
_Xe< JJvq +OP' / 7.Band Structtire and Angular-Resolved Photoelectron Spectra
%Q01EjRes 7.1 Free-Electron Final—State Model
?XrTZ{5' 7.2 Methods Employing Calculated Band Structures
vCr$miZ 7.3 Methods for the Absolute Determination of the Crystal Momentum
)^xmy6k 7.3.1 Triangulation or Energy Coincidence Method
5Wjp_^!e
7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
;hp; Rd 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
tV%\Jk), 7.3.4 The Surface Emission Method and Electron Damping
~UFsi VpL 7.3.5 The Very-Low-Energy Electron Diffraction Method
wYM{x!D 7.3.6 The Fermi Surface Method
Hc3/`.nt 7.3.7 Intensities and Their Use in Band-Structure Determinations
iIRigW 7.3.8 Summary
"Vy\- ^ 7.4 Experimental Band Structures
G*V
7*KC 7.4.1 One- and Two-Dimensional Systems
dRC+|^rSC 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
'S>Jps@ 7..4.3UPS Band Structures and XPS Density of States
1z!Lk*C) 7.5 A Comment
WJ,ON-v References
gW%(_H mX o?\Pw9Y 8.Surface States, Surface Effects
6d6SP)|j 8.1 Theoretical Considerations
/d;l: 8.2 Experimental Results on Surface States
6YbSzx`?k 8.3 Quantum-Well States
>eI(M $ 8.4 Surface Core-Level Shifts
Ue%5
:Sdr References
pm|]GkM (CwaOm{g 9.Inverse Photoelectron Spectroscopy
1EB`6_>y 9.1 Surface States
J]e&z5c 9.2 Bulk Band Structures
EwsJa3
` 9.3 Adsorbed Molecules
w=5qth7 References
~d]7 Cl *?\Nioii 10. Spin-Polarized Photoelectron Spectroscopy
AG%aH=TKp 10.1 General Description
$'w l{D" 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
c7 -j 10.3 Magnetic Dichroism
> ^}z References
p5ihuV, $tJJ
>" 11. Photoelectron Diffraction
^%.<(:k[L 11.1 Examples
DO;
2)ZQ% 11.2 Substrate Photoelectron Diffraction
w0SgF/"@ 11.3 Adsorbate Photoelectron Diffraction
2sH5<5G' 11.4 Fermi Surface Scans
$cedO'] References
S{06bLXU" 1:8: yFV Appendix
;o=mL_[ A.1 Table of Binding Energies
it@s(1EO# A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
#(G&%I A|; A.3 Compilation of Work Functions
Q2uE_w`B References
1-fz564 Index