光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
"JF IwXQbJ3v_ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
W:f )#' =`}|hI 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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IH=%%AS 9Z2aFW9 目录
sN[<{;K4 1. Introduction and Basic Principles
4[r:DM|8 1.1 Historical Development
q/7T-"q/G 1.2 The Electron Mean Free Path
4}Os>M{k 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
ayf;'1 1.4 Experimental Aspects
0}_1ZU 1.5 Very High Resolution
Kv5 !cll5 1.6 The Theory of Photoemission
FGMYpapc~ 1.6.1 Core-Level Photoemission
l>Zp#+I- 1.6.2 Valence-State Photoemission
I*+*Wf 1.6.3 Three-Step and One-Step Considerations
}z-)!8vF 1.7 Deviations from the Simple Theory of Photoemission
g{?{N References
)Zyw^KN^ jA3Ir;a 2. Core Levels and Final States
a,t]> z95 2.1 Core-Level Binding Energies in Atoms and Molecules
&C/,~pJ1S 2.1.1 The Equivalent-Core Approximation
A{hST~s 2.1.2 Chemical Shifts
.GDY
J9vi 2.2 Core-Level Binding Energies in Solids
vf<Tq 2.2.1 The Born-Haber Cycle in Insulators
x5yZ+`Gc 2.2.2 Theory of Binding Energies
<~5$<L4 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
)Vy}oFT\ 2.3 Core Polarization
@:u2{>Yl 2.4 Final-State Multiplets in Rare-Earth Valence Bands
P-N+ 2.5 Vibrational Side Bands
44h z, 2.6 Core Levels of Adsorbed Molecules
?P2d
9b 2.7 Quantitative Chemical Analysis from Core-Level Intensities
&2Cu"O'.i References
O;;vz+ j D7N` %A8 3. Charge-Excitation Final States: Satellites
0 KWi<G1 3.1 Copper Dihalides; 3d Transition Metal Compounds
%X\rP, 3.1.1 Characterization of a Satellite
'$CJZ`nt 3.1.2 Analysis of Charge-Transfer Satellites
8+~|!)a 3.1.3 Non-local Screening
L_YY, 3.2 The 6-eV Satellite in Nickel
aQfrDM<*XS 3.2.1 Resonance Photoemission
~u80v h' 3.2.2 Satellites in Other Metals
HuL9' M 3.3 The Gunnarsson-Sch6nhammer Theory
( /_Z^m9 3.4 Photoemission Signals and Narrow Bands in Metals
u/74E0$S References
<+7-^o_ !P* z= 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
SJI+$L\' 4.1 Theory
Xn8r3Nb$A 4.1.1 General
F;dUqXUu 4.1.2 Core-Line Shape
h3L{zOff 4.1.3 Intrinsic Plasmons
DU[vLe|Z 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
0 Pa\:^/6 4.1.5 The Total Photoelectron Spectrum
\5^GUT 4.2 Experimental Results
y>m=A41:g 4.2.1 The Core Line Without Plasmons
rsvGf7C 4.2.2 Core-Level Spectra Including Plasmoas
K5q9u-7 4.2.3 Valence-Band Spectra of the Simple Metals
(A8X|Y 4.2.4 Simple Metals: A General Comment
}q@Jh* 4.3 The Background Correction
yn5yQ; References
2f@gR9T v.I>B3bEg 5. Valence Orbitals in Simple Molecules and Insulating Solids
{wp"zaa 5.1 UPS Spectra of Monatomic Gases
e?~6HP^%. 5.2 Photoelectron Spectra of Diatomic Molecules
E MKv)5MH 5.3 Binding Energy of the H2 Molecule
\lpR+zaF 5.4 Hydrides Isoelectronic with Noble Gases
s5ddGiZnBT Neon (Ne)
(f|3(u'e? Hydrogen Fluoride (HF)
$q;dsW,8 Water (H2O)
k
GzosUt Ammonia (NH3)
w;Na9tR Methane (CH4)
[Y]\sF;J 5.5 Spectra of the Alkali HMides
x+7jJ=F 5.6 Transition Metal Dihalides
A#j'JA>_ 5.7 Hydrocarbons
+V6N/{^5 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
_/5mgn<GK 5.7.2 Linear Polymers
/A;!g5Y 5.8 Insulating Solids with Valence d Electrons
"(rG5z3P 5.8.1 The NiO Problem
"+V.Yue`R 5.8.2 Mort Insulation
pTlNJ!U> 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
[MKL>\U 5.8.4Band Structures of Transition Metal Compounds
$fA%_T_P'P 5.9 High—Temperature Superconductors
<M|kOi 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
@9^ozgg 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
X4U$#uI{ 5.9.3 The Superconducting Gap
O=PyXOf 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
o4CgtqRs 5.9.5 Core—Level Shifts
lclSzC9 5.10 The Fermi Liquid and the Luttinger Liquid
)xuvY3BPB? 5.11 Adsorbed Molecules
14p <0BG 5.11.1 Outline
Ojf.D6nY 5.11.2 CO on Metal Surfaces
g2v0! References
@<O
Bt d Ul@yXtj 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
EI*B( 6.1 Theory of Photoemission:A Summary of the Three-Step Model
N%\!eHxy 6.2 Discussion of the Photocurrent
dk9'C 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
("k.5$ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
\ueo^p]_? 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
T8,?\7)S9 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
W"_")V=QBz 6.3.1 Band Structure Regime
xFt[:G`\}u 6.3.2 XPS Regime
c1?_L( 6.3.3 Surface Emission
E
hROd 6.3.4 One-Step Calculations
p] V 6.4 Thermal Effects
%(,Kj
~0 6.5 Dipole Selection Rules for Direct Optical Transitions
;{79d8/= References
#%xzy@` wtCz%!OYB 7.Band Structtire and Angular-Resolved Photoelectron Spectra
>'^Tp7\ 7.1 Free-Electron Final—State Model
a'zf8id 7.2 Methods Employing Calculated Band Structures
oZkjg3 7.3 Methods for the Absolute Determination of the Crystal Momentum
A&OU;j] 7.3.1 Triangulation or Energy Coincidence Method
+wU9d8W 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
]CD 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
|#);^z_ 7.3.4 The Surface Emission Method and Electron Damping
0Z{f!MOh 7.3.5 The Very-Low-Energy Electron Diffraction Method
?H\K]; 7.3.6 The Fermi Surface Method
RG9YA&1ce 7.3.7 Intensities and Their Use in Band-Structure Determinations
}]ak6'|[ 7.3.8 Summary
"/e:V-W
7.4 Experimental Band Structures
)A}u)PH4O 7.4.1 One- and Two-Dimensional Systems
x roo_ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
XrY\ot`,D 7..4.3UPS Band Structures and XPS Density of States
KErQCBeJ 7.5 A Comment
WleE$ , References
*UVo>; r%*,pN7O 8.Surface States, Surface Effects
@7Oqp- 8.1 Theoretical Considerations
E)l0`83~^ 8.2 Experimental Results on Surface States
YL_M=h>P 8.3 Quantum-Well States
'%.:97 8.4 Surface Core-Level Shifts
8X,dVX5LT References
#"J8]3\F xx`xDD 9.Inverse Photoelectron Spectroscopy
}&+b\RE 9.1 Surface States
:C*7DS 9.2 Bulk Band Structures
/UP&TyZ 9.3 Adsorbed Molecules
DlHt#Ob7 References
)YE3n-~7{ + niz(] 10. Spin-Polarized Photoelectron Spectroscopy
cn62:p]5 10.1 General Description
s9R#rwIc 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
"]1 !<M6\i 10.3 Magnetic Dichroism
-?_#Yttu References
&\8qN_` 7>#?-, B 11. Photoelectron Diffraction
I!FIV^}Z( 11.1 Examples
eD4D<\* 11.2 Substrate Photoelectron Diffraction
'MLp*3djF, 11.3 Adsorbate Photoelectron Diffraction
$T.u Iq 11.4 Fermi Surface Scans
|$*1!pL-QP References
w;@NYMK) |]--sUx: Appendix
*$K_Tii A.1 Table of Binding Energies
U($bR|%D A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
!&'GWQY{( A.3 Compilation of Work Functions
UoAHy%Y<% References
Q&j-a;L Index