光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
U 7.k Yu DqT<bNR1*; 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
`MCiybl,&P Yj1|]i5b 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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9D+k71"+ Qy0w'L/@ 目录
`DF49YP"~ 1. Introduction and Basic Principles
Hp04apM: 1.1 Historical Development
d}zh.O5P!
1.2 The Electron Mean Free Path
_wK.n.,S~ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
u+r!;-0i 1.4 Experimental Aspects
wR@>U.XT@ 1.5 Very High Resolution
Q&xH 1.6 The Theory of Photoemission
&H%/.4la 1.6.1 Core-Level Photoemission
qvSYrnpn 1.6.2 Valence-State Photoemission
;W|NG3_y 1.6.3 Three-Step and One-Step Considerations
cJaA*sg 1.7 Deviations from the Simple Theory of Photoemission
pT->qQ3; References
'k[qx} ];hqI O#nM 2. Core Levels and Final States
+4_, , I 2.1 Core-Level Binding Energies in Atoms and Molecules
M,_
$s, 2.1.1 The Equivalent-Core Approximation
sdZ$3oE. 2.1.2 Chemical Shifts
2I [zV7 @t 2.2 Core-Level Binding Energies in Solids
P0}{xq'k9v 2.2.1 The Born-Haber Cycle in Insulators
?LmeZ}K 2.2.2 Theory of Binding Energies
F-wAQ: 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
olv?$]
2.3 Core Polarization
nK :YbLdK, 2.4 Final-State Multiplets in Rare-Earth Valence Bands
vvv'!\'# 2.5 Vibrational Side Bands
'~&W'='b; 2.6 Core Levels of Adsorbed Molecules
&L$9Ii 2.7 Quantitative Chemical Analysis from Core-Level Intensities
P.XT1)qo* References
4F|79U # 4T(d9y 3. Charge-Excitation Final States: Satellites
$ ubU" 3.1 Copper Dihalides; 3d Transition Metal Compounds
F1stRZ1ZI 3.1.1 Characterization of a Satellite
&]o-ZZX 3.1.2 Analysis of Charge-Transfer Satellites
Bk~C$'x4 3.1.3 Non-local Screening
'G l~P><e 3.2 The 6-eV Satellite in Nickel
W+!UVUpW 3.2.1 Resonance Photoemission
XqmB%g( 3.2.2 Satellites in Other Metals
'JMW.;Lh?X 3.3 The Gunnarsson-Sch6nhammer Theory
g=$U&Hgs 3.4 Photoemission Signals and Narrow Bands in Metals
g77M5(ME References
6/S.sj~ o@zxzZWg 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
9y*] {IY 4.1 Theory
d j\Z}[ 4.1.1 General
FSA%,b;U 4.1.2 Core-Line Shape
w-pgtO|Us 4.1.3 Intrinsic Plasmons
EcB
!bf 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
d-_V*rYU 4.1.5 The Total Photoelectron Spectrum
nUP, Yd 4.2 Experimental Results
CVa>5vt 4.2.1 The Core Line Without Plasmons
q-<DYVG+ 4.2.2 Core-Level Spectra Including Plasmoas
&|Duc} t 4.2.3 Valence-Band Spectra of the Simple Metals
6i[Ts0H%<! 4.2.4 Simple Metals: A General Comment
!.,wg'\P 4.3 The Background Correction
88osWo6rG References
pz
/[${X C K7([>2 5. Valence Orbitals in Simple Molecules and Insulating Solids
(NvjX})eh 5.1 UPS Spectra of Monatomic Gases
N x&/p$d 5.2 Photoelectron Spectra of Diatomic Molecules
=:s`C,l.4 5.3 Binding Energy of the H2 Molecule
hi[nUG(OI 5.4 Hydrides Isoelectronic with Noble Gases
%LMpErZO Neon (Ne)
&" t~d}Rg Hydrogen Fluoride (HF)
!#)t<9]fv Water (H2O)
1p.c6[9- Ammonia (NH3)
eT".psRiC Methane (CH4)
GP%V(HhN 5.5 Spectra of the Alkali HMides
w1)TnGT 5.6 Transition Metal Dihalides
&!CVF 5.7 Hydrocarbons
t`H1]`c? 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
9S|sTf 5.7.2 Linear Polymers
TF/NA\0c$ 5.8 Insulating Solids with Valence d Electrons
O% T?+1E 5.8.1 The NiO Problem
o%?)};o 5.8.2 Mort Insulation
.kBkYK8*t 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
*lSu=dk+ 5.8.4Band Structures of Transition Metal Compounds
(+|+ELfqW 5.9 High—Temperature Superconductors
py'vD3Q 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
\l:R]:w;ZI 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
;-Yvi,sS+ 5.9.3 The Superconducting Gap
z^QrIl/<c2 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
jhm3:;Z 5.9.5 Core—Level Shifts
ez'NHodwk2 5.10 The Fermi Liquid and the Luttinger Liquid
#<*.{"T 5.11 Adsorbed Molecules
[ey#
,&T 5.11.1 Outline
@A1f#Ed< 5.11.2 CO on Metal Surfaces
[~{F(Le References
:8)Jnh\5 ?wB_fDb} 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
a* cWj}u 6.1 Theory of Photoemission:A Summary of the Three-Step Model
i=Qy?aU? 6.2 Discussion of the Photocurrent
WoZU} T- 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
|!PL"]? 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
{ ^dq7! 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
f7_(C0d 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
h vYRAQR: 6.3.1 Band Structure Regime
?kO.>o 6.3.2 XPS Regime
@
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-MTk9<qnT 6.3.4 One-Step Calculations
>N |?>M* 6.4 Thermal Effects
{nKw<F2 6.5 Dipole Selection Rules for Direct Optical Transitions
zIrOMh References
DJ"PP5d iM<$
n2t 7.Band Structtire and Angular-Resolved Photoelectron Spectra
hQ@k|3=Re 7.1 Free-Electron Final—State Model
w.x&3aG 7.2 Methods Employing Calculated Band Structures
Q-oDmjU 7.3 Methods for the Absolute Determination of the Crystal Momentum
%/Wk+r9uu 7.3.1 Triangulation or Energy Coincidence Method
(fF8)4l 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
UOZ+&DL,L 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
]:gW+6w"C 7.3.4 The Surface Emission Method and Electron Damping
sQ}|Lu9hZ 7.3.5 The Very-Low-Energy Electron Diffraction Method
8 MO-QO 7.3.6 The Fermi Surface Method
KmNnW1T 7.3.7 Intensities and Their Use in Band-Structure Determinations
PB@IPnB- 7.3.8 Summary
L/ 7AGR|;C 7.4 Experimental Band Structures
t%Jk3W/f 7.4.1 One- and Two-Dimensional Systems
,'s}g,L 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
SI!A?34 7..4.3UPS Band Structures and XPS Density of States
gQPw+0w 7.5 A Comment
`D77CC]vU References
4QA~@pBX^{ o`iA& 8.Surface States, Surface Effects
Lk !)G'42 8.1 Theoretical Considerations
J#$U<`j*G 8.2 Experimental Results on Surface States
8%,#TMOg 8.3 Quantum-Well States
L?h?LZnq 8.4 Surface Core-Level Shifts
&4:R(]| References
`q36`Wn Z5vdH5?!r 9.Inverse Photoelectron Spectroscopy
}nlS&gew^ 9.1 Surface States
}MQ:n8
9.2 Bulk Band Structures
=de'Yy:\- 9.3 Adsorbed Molecules
)$!b`u References
kO\ O$J^S I0+6p8, 10. Spin-Polarized Photoelectron Spectroscopy
to?! qxn 10.1 General Description
^VXhv9\>B 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
@-sWXz*W 10.3 Magnetic Dichroism
c& ;@i$X( References
ooVs8T2 xxur4@p! 11. Photoelectron Diffraction
FaeKDbLJr 11.1 Examples
R;!,(l 11.2 Substrate Photoelectron Diffraction
{32m&a 11.3 Adsorbate Photoelectron Diffraction
/
dJz?0 11.4 Fermi Surface Scans
Or? )Nlg6x References
*6?mZ*GYY N
(4H}2 Appendix
8._uwA<[ A.1 Table of Binding Energies
Cx2#
0$ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
-Rpra0o.
C A.3 Compilation of Work Functions
LFax$CZc References
e{E\YEc
Index