光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
4x7(50hp# YXCltME 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
ZrY#B8 k(LZ,WSR 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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O/g|E47 PWeCk2 xH 目录
ZK:dhwer 1. Introduction and Basic Principles
hojP3 [ 1.1 Historical Development
5=/&[= 1.2 The Electron Mean Free Path
F6>K FU8 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
s18o,Zs' 1.4 Experimental Aspects
\H<gKZquR 1.5 Very High Resolution
Q{%2Npvq 1.6 The Theory of Photoemission
)Z6bMAb0'N 1.6.1 Core-Level Photoemission
AI
KLJvte 1.6.2 Valence-State Photoemission
}/tT=G]91 1.6.3 Three-Step and One-Step Considerations
oh*Hzb 1.7 Deviations from the Simple Theory of Photoemission
d4ANh+}X"_ References
B
~u9"SR. x_za
R}WI 2. Core Levels and Final States
&gF*p 2.1 Core-Level Binding Energies in Atoms and Molecules
G!]%xFwYa 2.1.1 The Equivalent-Core Approximation
-s~6FrKy 2.1.2 Chemical Shifts
b#ga 2.2 Core-Level Binding Energies in Solids
%8c
<C 2.2.1 The Born-Haber Cycle in Insulators
rP4v_?Zg+ 2.2.2 Theory of Binding Energies
6P,vGmR 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
j,<3[ 2.3 Core Polarization
y 98v 2.4 Final-State Multiplets in Rare-Earth Valence Bands
EQQ/E!N8l 2.5 Vibrational Side Bands
/<[S> ;!kr 2.6 Core Levels of Adsorbed Molecules
'I$-h<W 2.7 Quantitative Chemical Analysis from Core-Level Intensities
5x$/.U
References
9Z?P/
o 5L ]TV\\ 3. Charge-Excitation Final States: Satellites
DI9hy/T( 3.1 Copper Dihalides; 3d Transition Metal Compounds
q/T(s 3.1.1 Characterization of a Satellite
BdWRm= 3.1.2 Analysis of Charge-Transfer Satellites
$;O-1# ] 3.1.3 Non-local Screening
_N`'R.va 3.2 The 6-eV Satellite in Nickel
:LE0_ . 3.2.1 Resonance Photoemission
Q?"o.T'; 3.2.2 Satellites in Other Metals
)"( ojh 3.3 The Gunnarsson-Sch6nhammer Theory
|gXtP- 3.4 Photoemission Signals and Narrow Bands in Metals
E`E$ }iLs References
$}&r.=J". (CUrFZT$ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
-Iq
W@|N 4.1 Theory
R$>]7-N} 4.1.1 General
* SAYli+@ 4.1.2 Core-Line Shape
ZtzSG@f 4.1.3 Intrinsic Plasmons
48}L!m @ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
'K|Jg.2 4.1.5 The Total Photoelectron Spectrum
+SM&_b 4.2 Experimental Results
Z|78>0SAt 4.2.1 The Core Line Without Plasmons
( I<]@7> 4.2.2 Core-Level Spectra Including Plasmoas
:+ASZE. 4.2.3 Valence-Band Spectra of the Simple Metals
0 QzUcr)3+ 4.2.4 Simple Metals: A General Comment
z@70{* 4.3 The Background Correction
Tbf@qid e References
hMcSB8 ? O
&/9wi>!q 5. Valence Orbitals in Simple Molecules and Insulating Solids
s,5SWdb\v 5.1 UPS Spectra of Monatomic Gases
^{ Kj{M22 5.2 Photoelectron Spectra of Diatomic Molecules
0<g;g%
5.3 Binding Energy of the H2 Molecule
S7|6dwQ& 5.4 Hydrides Isoelectronic with Noble Gases
4Sj;38F
.1 Neon (Ne)
O"'.n5>:` Hydrogen Fluoride (HF)
f82$_1s^ Water (H2O)
W|~Jl7hs8Q Ammonia (NH3)
|_<'qh Methane (CH4)
gzHMZ/31 5.5 Spectra of the Alkali HMides
)^Ha?;TS 5.6 Transition Metal Dihalides
*.'9 eC0s 5.7 Hydrocarbons
UJ\[^/t 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
C(=$0FIR 5.7.2 Linear Polymers
]'L#'"@ 5.8 Insulating Solids with Valence d Electrons
8|-j]
5.8.1 The NiO Problem
XwZ~pY ~ 5.8.2 Mort Insulation
$q"/q*ys 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Lg;b17 5.8.4Band Structures of Transition Metal Compounds
UxGr+q 5.9 High—Temperature Superconductors
0n FEPMO 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
%1Ex{H hb 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
p3m!Iota 5.9.3 The Superconducting Gap
xgdS]Sz 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
0r4,27w 5.9.5 Core—Level Shifts
|E&
Fe8 5.10 The Fermi Liquid and the Luttinger Liquid
7@[HRr 5.11 Adsorbed Molecules
xH,D
bAC; 5.11.1 Outline
YsX&]4vzm 5.11.2 CO on Metal Surfaces
k`j>lhH References
%VV\biO] 'ycr/E&m{ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
">8]Oi;g 6.1 Theory of Photoemission:A Summary of the Three-Step Model
2
}9of[ 6.2 Discussion of the Photocurrent
kiah,7V/ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
3 s @6pI 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
U@;W^Mt 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
:,<G6"i 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
sIVVF#0}] 6.3.1 Band Structure Regime
cWNZ +Q8Y 6.3.2 XPS Regime
4qd =]i 6.3.3 Surface Emission
&-S;.} 6.3.4 One-Step Calculations
=up!lg^M 6.4 Thermal Effects
b]-~{' + 6.5 Dipole Selection Rules for Direct Optical Transitions
gI~4A, References
@Cnn8Y&' 8!R +wy 7.Band Structtire and Angular-Resolved Photoelectron Spectra
{r.KY 7.1 Free-Electron Final—State Model
nV[0O8p2Md 7.2 Methods Employing Calculated Band Structures
"e3T;M+ 7.3 Methods for the Absolute Determination of the Crystal Momentum
^|b ]E 7.3.1 Triangulation or Energy Coincidence Method
3Y;<Q>roT 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
jfLkp>2E' 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
TO,XN\{y 7.3.4 The Surface Emission Method and Electron Damping
bOB<m4 7.3.5 The Very-Low-Energy Electron Diffraction Method
"k;j@ 7.3.6 The Fermi Surface Method
IIZu&iZo\ 7.3.7 Intensities and Their Use in Band-Structure Determinations
*mvDh9v 7.3.8 Summary
35;UE2d)< 7.4 Experimental Band Structures
_mEW]9Sp 7.4.1 One- and Two-Dimensional Systems
n?UFFi+a 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
D2,2Yy5y 7..4.3UPS Band Structures and XPS Density of States
JU6PBY~C' 7.5 A Comment
=7e|e6 References
!R
b -T,/S^ 8.Surface States, Surface Effects
I^u$H& 8.1 Theoretical Considerations
~ z< &vQ= 8.2 Experimental Results on Surface States
%(P\"hE' 8.3 Quantum-Well States
71RG1, 8.4 Surface Core-Level Shifts
M0B6v}^H References
?k 4|;DD ,k9@%{4 l 9.Inverse Photoelectron Spectroscopy
&8!~H<S 9.1 Surface States
Ar;uq7c,G 9.2 Bulk Band Structures
>qqI6@h]c 9.3 Adsorbed Molecules
@5[9iY References
GKk>;X- w !5@PJ)~U 10. Spin-Polarized Photoelectron Spectroscopy
8E/wUN,Lxj 10.1 General Description
hja;d1yH 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
<[oPh(!V 10.3 Magnetic Dichroism
\{GBaMwG~ References
x;w^&<hQ\ $-=QT X 11. Photoelectron Diffraction
+,g"8&> 11.1 Examples
=V[ey 11.2 Substrate Photoelectron Diffraction
l%f&vOcd 11.3 Adsorbate Photoelectron Diffraction
I,nW~;OV0 11.4 Fermi Surface Scans
nt5x[xa References
aFbIJm=! Li? _P5+a Appendix
.{=|N8*py8 A.1 Table of Binding Energies
CyWMr/' A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
|_}
LMkU) A.3 Compilation of Work Functions
l>kREfHq!{ References
6m\MYay Index