光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
PjriAlxD nN!/ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
?0_Bs4O\ H\7#$ HB 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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'f0*~Wq| S-{3'D[Nj 目录
dIiQ^M 1. Introduction and Basic Principles
`p`)D6 1.1 Historical Development
ssVO+
T 1.2 The Electron Mean Free Path
u^H: z0 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
l]Ozy@
Ib 1.4 Experimental Aspects
?n o.hf 1.5 Very High Resolution
:#8#tLv 1.6 The Theory of Photoemission
@i`*i@g 1.6.1 Core-Level Photoemission
B WdR~|2 1.6.2 Valence-State Photoemission
?o'!(3`L 1.6.3 Three-Step and One-Step Considerations
lWj{pyZ 1.7 Deviations from the Simple Theory of Photoemission
1 FTxbw@ References
dKyJ.p t}LV[bj1u 2. Core Levels and Final States
s'\PU1{ 2.1 Core-Level Binding Energies in Atoms and Molecules
*B"p:F7J| 2.1.1 The Equivalent-Core Approximation
v;.7-9c* 2.1.2 Chemical Shifts
s)Bl1\Q 2.2 Core-Level Binding Energies in Solids
jt|e?1:vF 2.2.1 The Born-Haber Cycle in Insulators
EVc
Ees 2.2.2 Theory of Binding Energies
gf/$M[H! 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
/mLOh2T 2.3 Core Polarization
1U[8OM{$ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
{KJ !rT 2.5 Vibrational Side Bands
f\+MnZ4[Qj 2.6 Core Levels of Adsorbed Molecules
E!.>*`)?. 2.7 Quantitative Chemical Analysis from Core-Level Intensities
rUjK1A{V References
SP][xdN7 f\CJ |tKX 3. Charge-Excitation Final States: Satellites
ER0nrTlB< 3.1 Copper Dihalides; 3d Transition Metal Compounds
M\5aJ:cQ+ 3.1.1 Characterization of a Satellite
L&3Ak}sh 3.1.2 Analysis of Charge-Transfer Satellites
_l$V| 3.1.3 Non-local Screening
Y;3DU1MG0 3.2 The 6-eV Satellite in Nickel
r 7w1~z 3.2.1 Resonance Photoemission
QDCu 3.2.2 Satellites in Other Metals
-r%4,4 3.3 The Gunnarsson-Sch6nhammer Theory
JWhi*je 3.4 Photoemission Signals and Narrow Bands in Metals
9W3zcL8 References
;=goIsk{Q -*8 |J; 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
?+-uF} 4.1 Theory
Ua^#.K 4.1.1 General
MY>mP 4.1.2 Core-Line Shape
8,\toT7 4.1.3 Intrinsic Plasmons
r}k2n s9 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
??&Q"6Oe 4.1.5 The Total Photoelectron Spectrum
,B|~V 3)( 4.2 Experimental Results
jd<`W 4.2.1 The Core Line Without Plasmons
"
`rkp= 4.2.2 Core-Level Spectra Including Plasmoas
V8`o71p 4.2.3 Valence-Band Spectra of the Simple Metals
Bw^*6P^l 4.2.4 Simple Metals: A General Comment
$X1T!i[.X 4.3 The Background Correction
)}QtK+Rq References
IC&>PwXb G9'Wo.$ t 5. Valence Orbitals in Simple Molecules and Insulating Solids
Jq0aDf
f 5.1 UPS Spectra of Monatomic Gases
13
`Or(>U 5.2 Photoelectron Spectra of Diatomic Molecules
A1Tk6i<F1 5.3 Binding Energy of the H2 Molecule
"G. L)oD 5.4 Hydrides Isoelectronic with Noble Gases
d:08@~# Neon (Ne)
eUMOV]h Hydrogen Fluoride (HF)
f'
|JLhs Water (H2O)
%M"rc4Xd Ammonia (NH3)
v@_}R_pX Methane (CH4)
u#9 H 5.5 Spectra of the Alkali HMides
cXM4+pa=% 5.6 Transition Metal Dihalides
$['_m~
2 5.7 Hydrocarbons
wrw4Uxq 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
m-V_J`9" 5.7.2 Linear Polymers
S ]_iobWK 5.8 Insulating Solids with Valence d Electrons
OV<'v%_& 5.8.1 The NiO Problem
M<h2+0(il 5.8.2 Mort Insulation
a3t[Tk; 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
;2Aqztp 5.8.4Band Structures of Transition Metal Compounds
[D/q
5.9 High—Temperature Superconductors
;+ : C 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
sfb)iH|sW 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
Zb> UY8 5.9.3 The Superconducting Gap
4%k{vo5i 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
#0OW0:Q 5.9.5 Core—Level Shifts
tzH~[n, 5.10 The Fermi Liquid and the Luttinger Liquid
l/WQqT 5.11 Adsorbed Molecules
! @EZ 5.11.1 Outline
mn5y]:;` 5.11.2 CO on Metal Surfaces
TsiI5'tx References
90Rz#qrI* Y!!w*G9b 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
2G=prS`s 6.1 Theory of Photoemission:A Summary of the Three-Step Model
ck0K^o v 6.2 Discussion of the Photocurrent
W(~7e?fO 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
6uNWL `v 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
bF_SD\/ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
pZeJ$3@vk 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
[S Jx\Os 6.3.1 Band Structure Regime
Y52f8qQq 6.3.2 XPS Regime
94uAt&&b( 6.3.3 Surface Emission
}
O:Y?Wq^ 6.3.4 One-Step Calculations
EV=/'f[++ 6.4 Thermal Effects
JU>F&g/| 6.5 Dipole Selection Rules for Direct Optical Transitions
zDakl*
References
tk]>\}% t4Q&^AC 7.Band Structtire and Angular-Resolved Photoelectron Spectra
0Y|"Bo9k 7.1 Free-Electron Final—State Model
<V}
ec1 7.2 Methods Employing Calculated Band Structures
l~mC$>f 7.3 Methods for the Absolute Determination of the Crystal Momentum
86 $88`/2 7.3.1 Triangulation or Energy Coincidence Method
5t=7- 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
V -X*e 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
7XM:4whw 7.3.4 The Surface Emission Method and Electron Damping
-l(G"]tRB 7.3.5 The Very-Low-Energy Electron Diffraction Method
$[S)A0O 7.3.6 The Fermi Surface Method
3Gk\3iU! 7.3.7 Intensities and Their Use in Band-Structure Determinations
o5h*sQ9 7.3.8 Summary
h#:_GNuF 7.4 Experimental Band Structures
lf`" (:./ 7.4.1 One- and Two-Dimensional Systems
dbe\ YE 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
kleE\8_ 7..4.3UPS Band Structures and XPS Density of States
IuV7~w 7.5 A Comment
_P}wO8 References
{JGXdp:SB 7T69tQZ< 8.Surface States, Surface Effects
;Q.'u 8.1 Theoretical Considerations
QgF2f/;! 8.2 Experimental Results on Surface States
u{J\X$] 8.3 Quantum-Well States
f%[0}.wp 8.4 Surface Core-Level Shifts
}5b,u6 References
rbw~Ml0 /mK."5-cm 9.Inverse Photoelectron Spectroscopy
RKb{QAK!v 9.1 Surface States
)\PPIY>iP 9.2 Bulk Band Structures
8"=E0(m 9.3 Adsorbed Molecules
52P^0<Wq References
Y@ l>4q") 8-5g6qAS 10. Spin-Polarized Photoelectron Spectroscopy
{3@"}Eh 10.1 General Description
n_9Wrx328 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
vp|.x |@ 10.3 Magnetic Dichroism
,R$U(,>_0 References
tBjMm8lgb c&"OhzzJK' 11. Photoelectron Diffraction
hd>_K*oH 11.1 Examples
49!(Sa_]j 11.2 Substrate Photoelectron Diffraction
,>3b|-C- 11.3 Adsorbate Photoelectron Diffraction
p!/ *(TT 11.4 Fermi Surface Scans
eW\C@>Ke References
w,zm$s ^ ecdM+kP Appendix
F9J9zs*, A.1 Table of Binding Energies
M2Zk1Z A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
jBr3Ay@< A.3 Compilation of Work Functions
k
& 6$S9 References
=`EVg>+^ Index