光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
v)!C
Dpw <*vWcCS1 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
\nKpJ9! hE9UWa.Q> 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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S+LS!b jkrv2 `" 目录
;r1.Uz( 1. Introduction and Basic Principles
W,53|9b@ 1.1 Historical Development
xV}ybRKV 1.2 The Electron Mean Free Path
7/UdE:~]*= 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
0c,)T1NG > 1.4 Experimental Aspects
Vlka+$4! 1.5 Very High Resolution
(TF;+FRW 1.6 The Theory of Photoemission
yf/c 1.6.1 Core-Level Photoemission
m|%L[h1 1.6.2 Valence-State Photoemission
5{.g~3" 1.6.3 Three-Step and One-Step Considerations
>~vZ+YO 1.7 Deviations from the Simple Theory of Photoemission
4_i6qu(4 References
zNo(|;19 ]CnqPLqL 2. Core Levels and Final States
EYaX@|) 2.1 Core-Level Binding Energies in Atoms and Molecules
A
$GiO 2.1.1 The Equivalent-Core Approximation
8K;wX%_, 2.1.2 Chemical Shifts
G^6\ OOSy 2.2 Core-Level Binding Energies in Solids
`SN?4;N0 2.2.1 The Born-Haber Cycle in Insulators
8A,="YIt 2.2.2 Theory of Binding Energies
AgU 7U/yk 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
J=OWXL!<a 2.3 Core Polarization
-|/kg7IO\ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
-gzY~a 2.5 Vibrational Side Bands
|E7)s;}D 2.6 Core Levels of Adsorbed Molecules
d=$1Z.] 2.7 Quantitative Chemical Analysis from Core-Level Intensities
M,WC+")Z= References
yrgb6)]nm@ /qeSR3WC 3. Charge-Excitation Final States: Satellites
`(dRb 3.1 Copper Dihalides; 3d Transition Metal Compounds
t%'0uB#v1 3.1.1 Characterization of a Satellite
M9J^;3Lrh 3.1.2 Analysis of Charge-Transfer Satellites
Ozo)} 3.1.3 Non-local Screening
f|cF[&wo 3.2 The 6-eV Satellite in Nickel
zB@@Gs> 3.2.1 Resonance Photoemission
BGSqfr1F 3.2.2 Satellites in Other Metals
D,)^l@UP 3.3 The Gunnarsson-Sch6nhammer Theory
xdV $dDCT 3.4 Photoemission Signals and Narrow Bands in Metals
{R{Io| References
LqOjVQxz \~{b;$N} 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
S^/:O.X)c, 4.1 Theory
{zj<nu 4.1.1 General
zr1,A#BV 4.1.2 Core-Line Shape
X"z!52*3] 4.1.3 Intrinsic Plasmons
;^cc-bLvF 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
P: 3%#d~q 4.1.5 The Total Photoelectron Spectrum
50Kv4a" 4.2 Experimental Results
uJX(s6["= 4.2.1 The Core Line Without Plasmons
320g!r 4.2.2 Core-Level Spectra Including Plasmoas
UB7H`)C} 4.2.3 Valence-Band Spectra of the Simple Metals
Pp9nilb_( 4.2.4 Simple Metals: A General Comment
Pqc+p E 4.3 The Background Correction
(9X>E+0E References
~H+W[r} SyWLPh 5. Valence Orbitals in Simple Molecules and Insulating Solids
x.:k0;%Q 5.1 UPS Spectra of Monatomic Gases
(q|EC; 5.2 Photoelectron Spectra of Diatomic Molecules
C $r]]MSj 5.3 Binding Energy of the H2 Molecule
U if61)+!i 5.4 Hydrides Isoelectronic with Noble Gases
0
3/<A ^ Neon (Ne)
$sTvXf:g Hydrogen Fluoride (HF)
^9zFAY.| Water (H2O)
RgQ;fYS Ammonia (NH3)
a|s64+ Methane (CH4)
V(LE4P1 5.5 Spectra of the Alkali HMides
w' gKE'c 5.6 Transition Metal Dihalides
iOO1\9{@ 5.7 Hydrocarbons
ji~P?5(: 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
0k7kmDW 5.7.2 Linear Polymers
y,OwO4+y\ 5.8 Insulating Solids with Valence d Electrons
PM
A61g 5.8.1 The NiO Problem
V,W":&!x 5.8.2 Mort Insulation
WV8?zB1 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
O(Tdn;1 5.8.4Band Structures of Transition Metal Compounds
nYF *f 5.9 High—Temperature Superconductors
.bT|:Q~@{ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
Oy `2ccQ# 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
*Pmk1h2 5.9.3 The Superconducting Gap
-UhGacw 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
ONkHHyT 5.9.5 Core—Level Shifts
Wxxnc#;lv 5.10 The Fermi Liquid and the Luttinger Liquid
8UANB]@Y} 5.11 Adsorbed Molecules
5jYZ+OB 5.11.1 Outline
<X{hW^??) 5.11.2 CO on Metal Surfaces
p7YfOUo
k References
Gw;[maM!%` /h!Y/\ kI 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
Owa]ax5 6.1 Theory of Photoemission:A Summary of the Three-Step Model
c_33.i"I} 6.2 Discussion of the Photocurrent
Yiq8>| 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
G \S >H 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
6a=Y_fma 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
%](H?'H 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
~D9VjXfL) 6.3.1 Band Structure Regime
*Y@)t*
-a 6.3.2 XPS Regime
)/:&i<Q: 6.3.3 Surface Emission
=:!$'q: 6.3.4 One-Step Calculations
V=C@ocyZ 6.4 Thermal Effects
^uy2qO4Yw 6.5 Dipole Selection Rules for Direct Optical Transitions
mN9Uyz5G References
t[.wx.y&0 y+C.2 ca 7.Band Structtire and Angular-Resolved Photoelectron Spectra
p=U/l#xO 7.1 Free-Electron Final—State Model
A|D]e)/6+B 7.2 Methods Employing Calculated Band Structures
N9M''H*VS 7.3 Methods for the Absolute Determination of the Crystal Momentum
iSZiJ4AUq 7.3.1 Triangulation or Energy Coincidence Method
DB^"iof 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
^rDT+ x 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
9J$8=UuxWG 7.3.4 The Surface Emission Method and Electron Damping
Jhyb{i8RR 7.3.5 The Very-Low-Energy Electron Diffraction Method
0> 6;,pd" 7.3.6 The Fermi Surface Method
x 7;Zwd 7.3.7 Intensities and Their Use in Band-Structure Determinations
QqC4g] 7.3.8 Summary
DM-8azq $ 7.4 Experimental Band Structures
7sQw&yUL) 7.4.1 One- and Two-Dimensional Systems
% 1+\N 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
XQ{G) 7..4.3UPS Band Structures and XPS Density of States
]vPa
A 7.5 A Comment
mh#dnxeR References
_`bH$ 6G<t1?_yD 8.Surface States, Surface Effects
4@wH4H8 8.1 Theoretical Considerations
.=VtMi$n 8.2 Experimental Results on Surface States
.3B3Z&vr 8.3 Quantum-Well States
^Fl6-|^~ 8.4 Surface Core-Level Shifts
myVV5#{ References
9\/T #EP WJ{hta 9.Inverse Photoelectron Spectroscopy
oH/4opV 9.1 Surface States
Ch1+YZG 9.2 Bulk Band Structures
[U]ouh) 9.3 Adsorbed Molecules
[3s p References
Vs1j9P|G #L{+V?
10. Spin-Polarized Photoelectron Spectroscopy
!*0\Yi,6 10.1 General Description
Y=oj0(Q* 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
Sv7_-#SW<( 10.3 Magnetic Dichroism
x*~a{M,h References
\;?=h N
F[v/S 11. Photoelectron Diffraction
w>IYrSaa> 11.1 Examples
brkR,(#L3 11.2 Substrate Photoelectron Diffraction
LiyEF&_u 11.3 Adsorbate Photoelectron Diffraction
uhuwQS=X 11.4 Fermi Surface Scans
3&D;V;ON}_ References
FTy`#*7Ul !OJ@
=y`i Appendix
-$(,&qyk A.1 Table of Binding Energies
[mSK!Y@u A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
ob A.3 Compilation of Work Functions
y&0&K4aa References
o|7]8K= Index