光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
u [Dz~ =tQ^t4_ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
\.K4tY+V V*j1[d 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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o8c5~fG1 /Dj-@7.C/ 目录
t`Lh(` 1. Introduction and Basic Principles
k^Qd%;bdF 1.1 Historical Development
5lrjM^E| 1.2 The Electron Mean Free Path
~v|NC([( 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
*&O4b3R 1.4 Experimental Aspects
.8]buM5_G 1.5 Very High Resolution
hq*"S-N 1.6 The Theory of Photoemission
%*a%F~Ss 1.6.1 Core-Level Photoemission
';zS0Yk 1.6.2 Valence-State Photoemission
hn[lhC 1.6.3 Three-Step and One-Step Considerations
6R#.AD\
1.7 Deviations from the Simple Theory of Photoemission
*|({(aZ References
.
ytxe!O a%*W(
4=Y 2. Core Levels and Final States
hEMS 2.1 Core-Level Binding Energies in Atoms and Molecules
1<D^+FC4b, 2.1.1 The Equivalent-Core Approximation
,R[<+!RS 2.1.2 Chemical Shifts
2OZ<t@\OY 2.2 Core-Level Binding Energies in Solids
'BX
U' 2.2.1 The Born-Haber Cycle in Insulators
+N2R'Phv 2.2.2 Theory of Binding Energies
GV8`.3DBOF 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
&|I{ju_ 2.3 Core Polarization
]=G dAW 2.4 Final-State Multiplets in Rare-Earth Valence Bands
4WXr~?Vq9 2.5 Vibrational Side Bands
o7kQ&w 2.6 Core Levels of Adsorbed Molecules
AYsiaSTRqW 2.7 Quantitative Chemical Analysis from Core-Level Intensities
Fp~0 ^ References
OICH:(t_ UFGUP]J> 3. Charge-Excitation Final States: Satellites
G]RFGwGt 3.1 Copper Dihalides; 3d Transition Metal Compounds
d$B+xW 3.1.1 Characterization of a Satellite
&xE+PfX 3.1.2 Analysis of Charge-Transfer Satellites
#3}!Q0 3.1.3 Non-local Screening
~tZy-1 3.2 The 6-eV Satellite in Nickel
v9MliD' 3.2.1 Resonance Photoemission
YJB/*SV^ 3.2.2 Satellites in Other Metals
"sJ@_lp 3.3 The Gunnarsson-Sch6nhammer Theory
%@^9(xTE 3.4 Photoemission Signals and Narrow Bands in Metals
![ @i+hl References
F5
7Kr5X I/_,24[ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
L*zfZ& 4.1 Theory
S.|%dz 4.1.1 General
H,Yrk(O- 4.1.2 Core-Line Shape
CZ.HQc 4.1.3 Intrinsic Plasmons
HE@P< 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
iJb-F*_y 4.1.5 The Total Photoelectron Spectrum
%9b TfX" 4.2 Experimental Results
C *]XQ1F4 4.2.1 The Core Line Without Plasmons
`teaE7^Wm 4.2.2 Core-Level Spectra Including Plasmoas
oH1]-Nl$ 4.2.3 Valence-Band Spectra of the Simple Metals
JlE b 4.2.4 Simple Metals: A General Comment
?P"j5 4.3 The Background Correction
1O+$"5H References
j$Vtd& ^w*&7.Z 5. Valence Orbitals in Simple Molecules and Insulating Solids
N4w&g- 5.1 UPS Spectra of Monatomic Gases
G5*_ 5.2 Photoelectron Spectra of Diatomic Molecules
cv9-ZOxJ 5.3 Binding Energy of the H2 Molecule
CO{AC~ 5.4 Hydrides Isoelectronic with Noble Gases
1?{w~cF} Neon (Ne)
]69z-; Hydrogen Fluoride (HF)
no9=K4h` Water (H2O)
pykRi#[UrX Ammonia (NH3)
ALt^@|!d Methane (CH4)
XL`i9kV? 5.5 Spectra of the Alkali HMides
S#l)|c_~ 5.6 Transition Metal Dihalides
AME<V-5 5.7 Hydrocarbons
i+~H~k}"X 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
`3L?x8g 5.7.2 Linear Polymers
!Q{~f;L 5.8 Insulating Solids with Valence d Electrons
LsaRw-4.c 5.8.1 The NiO Problem
E[M.q;rM 5.8.2 Mort Insulation
ew1bb K> 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
LEA^o"NW. 5.8.4Band Structures of Transition Metal Compounds
3$PGLM 5.9 High—Temperature Superconductors
7%yP5c
B 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
|3=tF"h 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
@pV&{Vp 5.9.3 The Superconducting Gap
iJzW3%E 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
|VmQ 5.9.5 Core—Level Shifts
cWp5pGIzfp 5.10 The Fermi Liquid and the Luttinger Liquid
Vm%0436wOY 5.11 Adsorbed Molecules
Z(hRwIOF 5.11.1 Outline
;k8U5=6a 5.11.2 CO on Metal Surfaces
lQ| i
Ws References
Kbcr-89Gv~ &W?
hCr 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
'/@i}
digf 6.1 Theory of Photoemission:A Summary of the Three-Step Model
4H hQzVM{ 6.2 Discussion of the Photocurrent
6mC% zXR5 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
/igbn 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
s`o_ER 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
0ae}!LO 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
*.zC 9Y, 6.3.1 Band Structure Regime
dgW/5g 6.3.2 XPS Regime
5<Y-?23 6.3.3 Surface Emission
ya'OI P ` 6.3.4 One-Step Calculations
T@j@IEGH
6.4 Thermal Effects
PZhpp" 6.5 Dipole Selection Rules for Direct Optical Transitions
T4x[
\v5d References
O],]\M{GL ef]60OtP 7.Band Structtire and Angular-Resolved Photoelectron Spectra
-4t!k
Aw` 7.1 Free-Electron Final—State Model
rB.LG'GG] 7.2 Methods Employing Calculated Band Structures
V,>uM
>$ 7.3 Methods for the Absolute Determination of the Crystal Momentum
HKYJgx 7.3.1 Triangulation or Energy Coincidence Method
%$zX a%A 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
z+X DN: 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
kcZz WG|n 7.3.4 The Surface Emission Method and Electron Damping
S3&lkN5 7.3.5 The Very-Low-Energy Electron Diffraction Method
*!L
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k>!A~gfP~ 7.3.7 Intensities and Their Use in Band-Structure Determinations
T<~?7-O" 7.3.8 Summary
Hb@PQcj 7.4 Experimental Band Structures
_A=Pr_kN 7.4.1 One- and Two-Dimensional Systems
6F08$,%Y 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
);*#s~R 7..4.3UPS Band Structures and XPS Density of States
A9ru]|? 7.5 A Comment
0uS6F8x@ References
OM#eJ,MH<) n]snD1?KX 8.Surface States, Surface Effects
8aa`0X/6 8.1 Theoretical Considerations
fz`\-"f] 8.2 Experimental Results on Surface States
hV[= 8.3 Quantum-Well States
jHBP:c 8.4 Surface Core-Level Shifts
8B|B[,` References
}XIUz| lwp(Pq 9.Inverse Photoelectron Spectroscopy
QHbjZJ
N 9.1 Surface States
SD=9fh0l 9.2 Bulk Band Structures
+BkmI\ 9.3 Adsorbed Molecules
LLW
xzu!< References
jt4c*0z Fq#; 10. Spin-Polarized Photoelectron Spectroscopy
+<\.z* 10.1 General Description
F!~o J 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
~+bS D<!b 10.3 Magnetic Dichroism
h . R bdG References
yZqX[U wsyAq'%L 11. Photoelectron Diffraction
3NxwQ,~ 11.1 Examples
&l2C-( 11.2 Substrate Photoelectron Diffraction
!;COFR 11.3 Adsorbate Photoelectron Diffraction
6@cT;=W;xj 11.4 Fermi Surface Scans
fv?vfI+m References
KImazS^ ad'C&^o5 Appendix
.lIkJQ3d A.1 Table of Binding Energies
+N>&b% A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
zIh`Vw ,t0 A.3 Compilation of Work Functions
<jHo2U8/"s References
E>3(ff& Index