光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
)/OIzbA3# "^
dMCS@ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
k{|>!(Ax YbZ?["S& 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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.;,,{; H3iYE~^# 目录
d5{RIM| 1. Introduction and Basic Principles
u'T>Y1I 1.1 Historical Development
'b >3:& 1.2 The Electron Mean Free Path
7[R`52pP 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
).Iifu|ks 1.4 Experimental Aspects
5dX0C 1.5 Very High Resolution
w=ufJRj 1.6 The Theory of Photoemission
*`Ge8?qC 1.6.1 Core-Level Photoemission
hX-^h2eV 1.6.2 Valence-State Photoemission
'fzJw 1.6.3 Three-Step and One-Step Considerations
dww4o~hO 1.7 Deviations from the Simple Theory of Photoemission
$t5>1G1j7 References
N?A}WW# W55kR.X6M 2. Core Levels and Final States
PBL=P+ 2.1 Core-Level Binding Energies in Atoms and Molecules
~~p )_ 2.1.1 The Equivalent-Core Approximation
/P/0\3TCi 2.1.2 Chemical Shifts
G#E8xA"{/ 2.2 Core-Level Binding Energies in Solids
!SLfAFcS 2.2.1 The Born-Haber Cycle in Insulators
cb. -AlqQ 2.2.2 Theory of Binding Energies
=4!m]*y 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
^0(D2:E 2.3 Core Polarization
Dv^M/z2&[ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
e%9zY{ABR% 2.5 Vibrational Side Bands
"0z4mQ}>N 2.6 Core Levels of Adsorbed Molecules
CSNz8
y 2.7 Quantitative Chemical Analysis from Core-Level Intensities
X@A8~kj1 References
e%7#e%1s iUqD>OV 3. Charge-Excitation Final States: Satellites
T7Ju7_q} 3.1 Copper Dihalides; 3d Transition Metal Compounds
D_`~$QB`, 3.1.1 Characterization of a Satellite
%hz5) 3.1.2 Analysis of Charge-Transfer Satellites
8ddBQfCY 3.1.3 Non-local Screening
}p8iq 3.2 The 6-eV Satellite in Nickel
I}}>M# 3.2.1 Resonance Photoemission
Cw5B
p9 3.2.2 Satellites in Other Metals
4:s,e<Tc4v 3.3 The Gunnarsson-Sch6nhammer Theory
ZlcEeG 3.4 Photoemission Signals and Narrow Bands in Metals
a:1$i dj References
8@FgvWC >I+p;V$@ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
'Awd:Aed5 4.1 Theory
QUz4 Kt 4.1.1 General
_ZK*p+u% 4.1.2 Core-Line Shape
8\?H`NN 4.1.3 Intrinsic Plasmons
wkJ@#jD*[ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
X LY>}r 4.1.5 The Total Photoelectron Spectrum
4`+R
|"4 4.2 Experimental Results
cCG!X%9 4.2.1 The Core Line Without Plasmons
N{a=CaYi+ 4.2.2 Core-Level Spectra Including Plasmoas
b<E78B+Aax 4.2.3 Valence-Band Spectra of the Simple Metals
&IG*;$c! 4.2.4 Simple Metals: A General Comment
dTwYDV}: 4.3 The Background Correction
xd4~[n\hm References
wS|hc+1 2LCOB&-Ww 5. Valence Orbitals in Simple Molecules and Insulating Solids
}YU\}T-P 5.1 UPS Spectra of Monatomic Gases
J)H*tzg 5.2 Photoelectron Spectra of Diatomic Molecules
-O $!sFmY 5.3 Binding Energy of the H2 Molecule
@F|pKf:M+ 5.4 Hydrides Isoelectronic with Noble Gases
F84<='K Neon (Ne)
j:HIcCp Hydrogen Fluoride (HF)
xo!2GPD. Water (H2O)
(L W2S;- Ammonia (NH3)
"z*?#&?, Methane (CH4)
rX?%{M,xFw 5.5 Spectra of the Alkali HMides
c+##!_[9 5.6 Transition Metal Dihalides
VMu?mqEa 5.7 Hydrocarbons
UhU"[^YO 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
=8Z-ORW51 5.7.2 Linear Polymers
#9HX"<5
5.8 Insulating Solids with Valence d Electrons
-6e^`c6{ 5.8.1 The NiO Problem
{m_y< 5.8.2 Mort Insulation
7T(&DOGZ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
S>s+ nqcP 5.8.4Band Structures of Transition Metal Compounds
zu,Yuq 5.9 High—Temperature Superconductors
e?KzT5j: 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
Ns\};j?TU* 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
}>b@=5O 5.9.3 The Superconducting Gap
p?4,YV|# 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
CsjrQ-#9yn 5.9.5 Core—Level Shifts
_9<Mo;C 5.10 The Fermi Liquid and the Luttinger Liquid
Q&w"!N 5.11 Adsorbed Molecules
,}l|_GGj 5.11.1 Outline
@z`eqG,'] 5.11.2 CO on Metal Surfaces
9&Z+K'$= References
z0|-OCmL " z -tL 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
O;0VKNn[' 6.1 Theory of Photoemission:A Summary of the Three-Step Model
_]L]_Bh 6.2 Discussion of the Photocurrent
R_ )PbFw 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
V \/Qik{h 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
3XDuo|( 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
7zowvE?# 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
4rpry@1 6.3.1 Band Structure Regime
"1UpoF'w 6.3.2 XPS Regime
\:2z!\iP` 6.3.3 Surface Emission
@c).&7 6.3.4 One-Step Calculations
G[{Av5g mx 6.4 Thermal Effects
CQ7NQ^3k 6.5 Dipole Selection Rules for Direct Optical Transitions
eWr6@ References
6d3YLb4M$i J.]`l\ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
b)r;a5"<5 7.1 Free-Electron Final—State Model
n"@){:{4? 7.2 Methods Employing Calculated Band Structures
Ny2bMj.o 7.3 Methods for the Absolute Determination of the Crystal Momentum
3jHE,5m 7.3.1 Triangulation or Energy Coincidence Method
uXb}oUC 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
8TTj<T!N 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
$"?$r 7.3.4 The Surface Emission Method and Electron Damping
gJ>#HEkMB 7.3.5 The Very-Low-Energy Electron Diffraction Method
U(%6ny 7.3.6 The Fermi Surface Method
HmHM#~5(` 7.3.7 Intensities and Their Use in Band-Structure Determinations
d<w]>T5VW 7.3.8 Summary
9~y:K$NO 7.4 Experimental Band Structures
$lAdh 7.4.1 One- and Two-Dimensional Systems
3#eAXIW[ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
v@{VQVx 7..4.3UPS Band Structures and XPS Density of States
ScmwHid:\ 7.5 A Comment
??("0U References
Q% ^_<u hDc2T 8.Surface States, Surface Effects
'lOQb) 8.1 Theoretical Considerations
n Q{~D5y,, 8.2 Experimental Results on Surface States
bH!_0+$P 8.3 Quantum-Well States
mE&SAm5#d 8.4 Surface Core-Level Shifts
J|VDZ# c7 References
\[%_ :9eq !/X>k{ 9.Inverse Photoelectron Spectroscopy
dV-6 l6 9.1 Surface States
PH'n`D# 9.2 Bulk Band Structures
+RnWeBXAT 9.3 Adsorbed Molecules
6P)D M References
*^CN2tm ~yA^6[a = 10. Spin-Polarized Photoelectron Spectroscopy
Bj\Us$cZ 10.1 General Description
"~Zdv}^xS 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
AoK;6je`K^ 10.3 Magnetic Dichroism
:)FNhx3 References
</R@)_' *:`fgaIDa 11. Photoelectron Diffraction
L@f&71 11.1 Examples
F*-'8~T 11.2 Substrate Photoelectron Diffraction
-
b` 11.3 Adsorbate Photoelectron Diffraction
Q5_ ,`r` 11.4 Fermi Surface Scans
lA`-" References
`G=+qti ==trl#kQ%% Appendix
yh).1Q-D A.1 Table of Binding Energies
I*/:rb A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
%ofq A.3 Compilation of Work Functions
Nz%pl! References
'Zqt~5=5 Index