光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
G;t<dJ8 ;VCFDE{K= 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
y}U'8*, (1er?4 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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)Rk(gd i+I.>L/S 目录
sKiy1Ww 1. Introduction and Basic Principles
"Gqas bX 1.1 Historical Development
n~w[ajC/ 1.2 The Electron Mean Free Path
4T)`%Oo<} 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
<Z]j89wzDZ 1.4 Experimental Aspects
`N}'5{I 1.5 Very High Resolution
Z>1yLt@ls 1.6 The Theory of Photoemission
1)N# 1.6.1 Core-Level Photoemission
|P9)*~\5 1.6.2 Valence-State Photoemission
)r*F.m{&: 1.6.3 Three-Step and One-Step Considerations
tg/!=g 1.7 Deviations from the Simple Theory of Photoemission
0!:%Ge_ References
T0@<u a{ByU% 2. Core Levels and Final States
]wbV1Y" 2.1 Core-Level Binding Energies in Atoms and Molecules
cUi6 On1C 2.1.1 The Equivalent-Core Approximation
VeFfkg4 2.1.2 Chemical Shifts
6(A"5B=\ 2.2 Core-Level Binding Energies in Solids
R>[G6LOG 2.2.1 The Born-Haber Cycle in Insulators
q8e] {sT'! 2.2.2 Theory of Binding Energies
[Q8vS ;. 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
li')U 2.3 Core Polarization
##]
` 2.4 Final-State Multiplets in Rare-Earth Valence Bands
E%Ysyk 2.5 Vibrational Side Bands
{ueDwnZ 2.6 Core Levels of Adsorbed Molecules
U?:?NC=1{ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
!Xq5r8] References
raP9rEs Qq.Ja%Zq 3. Charge-Excitation Final States: Satellites
d.U"lP/)D 3.1 Copper Dihalides; 3d Transition Metal Compounds
;t.)A3 PL 3.1.1 Characterization of a Satellite
J?&%fI 3.1.2 Analysis of Charge-Transfer Satellites
UD2l!)rW 3.1.3 Non-local Screening
2 XjH1 3.2 The 6-eV Satellite in Nickel
gHWsKE
% 3.2.1 Resonance Photoemission
P!&yYR\ 3.2.2 Satellites in Other Metals
`,c~M 3.3 The Gunnarsson-Sch6nhammer Theory
H,!yG5yF 3.4 Photoemission Signals and Narrow Bands in Metals
U'} [:h~) References
ZtI@$ An ~!Rf5QA85 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
&D7Mv5i0@ 4.1 Theory
-BrJ5]T>* 4.1.1 General
l>7?B2^<E 4.1.2 Core-Line Shape
)b|xzj @ 4.1.3 Intrinsic Plasmons
/EZ - 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
`my\59T 4.1.5 The Total Photoelectron Spectrum
ge{%B~x 4.2 Experimental Results
w(odgD 4.2.1 The Core Line Without Plasmons
kL -f@CD 4.2.2 Core-Level Spectra Including Plasmoas
HNX/#?3 4.2.3 Valence-Band Spectra of the Simple Metals
4"+v:t)z6{ 4.2.4 Simple Metals: A General Comment
<Um 5w1 4.3 The Background Correction
6ZC~q=my References
GRgpy 7 z+Ngt' ! 5. Valence Orbitals in Simple Molecules and Insulating Solids
gYw=Z_z 5.1 UPS Spectra of Monatomic Gases
1=jwJv.^/ 5.2 Photoelectron Spectra of Diatomic Molecules
'^:q|h 5.3 Binding Energy of the H2 Molecule
XE:bYzH 5.4 Hydrides Isoelectronic with Noble Gases
55Ye7P-d Neon (Ne)
h7}P5z0F Hydrogen Fluoride (HF)
S"Ag7i Water (H2O)
#4& <d.aw' Ammonia (NH3)
sFRQFX0XoY Methane (CH4)
~/Kqkhq+c 5.5 Spectra of the Alkali HMides
Lyjp 5.6 Transition Metal Dihalides
","to 5.7 Hydrocarbons
Rap_1o9#\ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
Q2t>E(S 5.7.2 Linear Polymers
&WVRh=R 5.8 Insulating Solids with Valence d Electrons
tHH @[E+h 5.8.1 The NiO Problem
v*@R U 5.8.2 Mort Insulation
8H{9 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
04!akPP< 5.8.4Band Structures of Transition Metal Compounds
fjy2\J! 5.9 High—Temperature Superconductors
`n%8y I% 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
8ao>]5Rs3 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
{MmK:C 5.9.3 The Superconducting Gap
SKSI\]Cc 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
J/A UOInh 5.9.5 Core—Level Shifts
+?C7(-U> 5.10 The Fermi Liquid and the Luttinger Liquid
2D{`AJ 5.11 Adsorbed Molecules
2,'%G\QT 5.11.1 Outline
n'<F'1SWv 5.11.2 CO on Metal Surfaces
l]geQl:7`r References
m^1'aO_;q J<ZG&m362p 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
' n "n; 6.1 Theory of Photoemission:A Summary of the Three-Step Model
;-{'d8 6.2 Discussion of the Photocurrent
I- WR6s= 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
-Rr Qv( 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
MZ<BCRB 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
PWN$x`h g[ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
ID$%4jl 6.3.1 Band Structure Regime
#}nDX4jI 6.3.2 XPS Regime
Wg=4`&F^ 6.3.3 Surface Emission
}LdeU:E4 6.3.4 One-Step Calculations
Qr*7bE(a 6.4 Thermal Effects
[hKt4]R 6.5 Dipole Selection Rules for Direct Optical Transitions
:.F;LF& References
jH]?vpP xayd_RB 9 7.Band Structtire and Angular-Resolved Photoelectron Spectra
oJor
]QY K 7.1 Free-Electron Final—State Model
A!aki}aT~ 7.2 Methods Employing Calculated Band Structures
p!p:LSk"/b 7.3 Methods for the Absolute Determination of the Crystal Momentum
[O^mG
9 7.3.1 Triangulation or Energy Coincidence Method
"5$2b>_UE 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
N/eFwv.Er 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
e4Jx%v?_P 7.3.4 The Surface Emission Method and Electron Damping
#w]@yL]|is 7.3.5 The Very-Low-Energy Electron Diffraction Method
FK`M+ j 7.3.6 The Fermi Surface Method
?8@EBPpC 7.3.7 Intensities and Their Use in Band-Structure Determinations
*d,Z?S/ 7.3.8 Summary
vo]$[Cp|4 7.4 Experimental Band Structures
P#ot$@1v 7.4.1 One- and Two-Dimensional Systems
?89_2W 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
2vX!j!_ 7..4.3UPS Band Structures and XPS Density of States
iig@$
i# 7.5 A Comment
fk?(mxx" References
`>skcvkm \kVi&X=q: 8.Surface States, Surface Effects
$|!@$A j 8.1 Theoretical Considerations
u75(\<{ 8.2 Experimental Results on Surface States
E|omC_h 8.3 Quantum-Well States
@N+6qO} 8.4 Surface Core-Level Shifts
5TVA1 References
[[VB'Rs y,vrMWDy 9.Inverse Photoelectron Spectroscopy
.
I#dR* 9.1 Surface States
PitDk
1T 9.2 Bulk Band Structures
hYU4%"X 9.3 Adsorbed Molecules
R{SN.% {; References
RI-)Qx&!f s
N|7 10. Spin-Polarized Photoelectron Spectroscopy
" 2J2za 10.1 General Description
\tZZn~ex 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
W)m\q}]FYz 10.3 Magnetic Dichroism
WxI_wRKx References
0N4+6k| @}iY(-V 11. Photoelectron Diffraction
jp P'{mc 11.1 Examples
b;Uqyc 11.2 Substrate Photoelectron Diffraction
qr_:zXsob_ 11.3 Adsorbate Photoelectron Diffraction
EiWsVic[ 11.4 Fermi Surface Scans
c:sk1I,d~^ References
a<mM
)[U )NL_))\ Appendix
4]%v%64U A.1 Table of Binding Energies
#a=~a=c(^ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
Ym/y2B( A.3 Compilation of Work Functions
f%5 s8) References
^h\Y. Index