光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
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*cw2 7qk61YBLz 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
0c{N) Xw%z#6l 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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!>tXib]: ,-b9:]{L 目录
Rg6>6.fk* 1. Introduction and Basic Principles
38#(ruv 1.1 Historical Development
dM') <lF 1.2 The Electron Mean Free Path
)mEF_ & 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
4c% :?H@2 1.4 Experimental Aspects
S4_Y^ 1.5 Very High Resolution
U:>O6" 1.6 The Theory of Photoemission
1/m/Iw@ 1.6.1 Core-Level Photoemission
r,}Zc W+ 1.6.2 Valence-State Photoemission
_,}Ye,(^= 1.6.3 Three-Step and One-Step Considerations
n RGH58 1.7 Deviations from the Simple Theory of Photoemission
$Z j. References
-[F^~Gv|; 1a<,/N}}t 2. Core Levels and Final States
vV|egmw01 2.1 Core-Level Binding Energies in Atoms and Molecules
c"~TH.,d 2.1.1 The Equivalent-Core Approximation
3FdoADe{{ 2.1.2 Chemical Shifts
$=bN=hE 2.2 Core-Level Binding Energies in Solids
xQ[YQ!l 2.2.1 The Born-Haber Cycle in Insulators
VltWY'\Wu; 2.2.2 Theory of Binding Energies
j@DyWm/7 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
u4"+u"{d 2.3 Core Polarization
Z-Uq89[HZ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
Cfj*[i4 2.5 Vibrational Side Bands
K!9=e7|P 2.6 Core Levels of Adsorbed Molecules
J+zqu 2.7 Quantitative Chemical Analysis from Core-Level Intensities
}vi%pfrB References
~`BOzP fZZ!kea[ 3. Charge-Excitation Final States: Satellites
aX|`G]PhdI 3.1 Copper Dihalides; 3d Transition Metal Compounds
X;1q1X)K 3.1.1 Characterization of a Satellite
xv2;h4{< 3.1.2 Analysis of Charge-Transfer Satellites
_EY:vv 3.1.3 Non-local Screening
HCu1vjU(] 3.2 The 6-eV Satellite in Nickel
rQWft r^ 3.2.1 Resonance Photoemission
7+ysE 3.2.2 Satellites in Other Metals
\u*,~J)z 3.3 The Gunnarsson-Sch6nhammer Theory
%~h'#S2X( 3.4 Photoemission Signals and Narrow Bands in Metals
S HvML References
+)Ty^;+[1 IP >An8+ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
eQc!@*:8U 4.1 Theory
L}9@kjW 4.1.1 General
fSTEZH 4.1.2 Core-Line Shape
\)v.dQ! 4.1.3 Intrinsic Plasmons
;gc2vDMv 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
R%Z} J R. 4.1.5 The Total Photoelectron Spectrum
&Ls0!dWC 4.2 Experimental Results
o{
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@|^Ch+%@ 4.2.2 Core-Level Spectra Including Plasmoas
%ry>p(-pC( 4.2.3 Valence-Band Spectra of the Simple Metals
8RK\B%UW 4.2.4 Simple Metals: A General Comment
`i{ :mio 4.3 The Background Correction
6?74l; References
b,'./{c0 :eO]65N 5. Valence Orbitals in Simple Molecules and Insulating Solids
:G-1VtE n 5.1 UPS Spectra of Monatomic Gases
QZ`<+"a0 5.2 Photoelectron Spectra of Diatomic Molecules
*be+x RY 5.3 Binding Energy of the H2 Molecule
E|6|m8 5.4 Hydrides Isoelectronic with Noble Gases
Oe#k| Neon (Ne)
Vs"Z9p$U Hydrogen Fluoride (HF)
qM`SN4C Water (H2O)
C
}[u[) Ammonia (NH3)
ZDb`]c4( Methane (CH4)
(lm/S_U$ 5.5 Spectra of the Alkali HMides
XyI w5
9 5.6 Transition Metal Dihalides
QSLDA` 5.7 Hydrocarbons
)dV.A IQ+ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
h"'f~KM9a> 5.7.2 Linear Polymers
*dTw$T# 5.8 Insulating Solids with Valence d Electrons
vxgm0ZOMN 5.8.1 The NiO Problem
`+gF|o9 5.8.2 Mort Insulation
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_TaI 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
md_Ld
/ 5.8.4Band Structures of Transition Metal Compounds
F7hQNQu: 5.9 High—Temperature Superconductors
)CB?gW 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
"6}+|!"$ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
2.[qcs3zl 5.9.3 The Superconducting Gap
&>/nYvuq - 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
!F8
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lN&GfPP6 5.10 The Fermi Liquid and the Luttinger Liquid
^?A+`1- 5.11 Adsorbed Molecules
94R+S-|P 5.11.1 Outline
l>]M^=,&7 5.11.2 CO on Metal Surfaces
J0oR]eT} References
9+/|sU\.% CuGk?i 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
iO@wqbg$6 6.1 Theory of Photoemission:A Summary of the Three-Step Model
^T[#rNkeL 6.2 Discussion of the Photocurrent
W6PGv1iaW> 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
W)_B(;$] 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
"gO5dZ\0 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
]+Vcu zq/ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
`7j,njCX. 6.3.1 Band Structure Regime
'71btd1 6.3.2 XPS Regime
83h3C EQ 6.3.3 Surface Emission
$@xkKe" 6.3.4 One-Step Calculations
pxF!<nN1, 6.4 Thermal Effects
yx-"YV}5 6.5 Dipole Selection Rules for Direct Optical Transitions
3k/MigT References
#7>CLjI |RmBa'.)z 7.Band Structtire and Angular-Resolved Photoelectron Spectra
I,[EL{fz 7.1 Free-Electron Final—State Model
K?>&Mr 7.2 Methods Employing Calculated Band Structures
b-Hn=e _ 7.3 Methods for the Absolute Determination of the Crystal Momentum
&td#m"wI 7.3.1 Triangulation or Energy Coincidence Method
O^GX Fz^ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
<ZiO[dEV 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
_H,RcpyJ 7.3.4 The Surface Emission Method and Electron Damping
1K`A.J:Uy 7.3.5 The Very-Low-Energy Electron Diffraction Method
H1]\B: 7.3.6 The Fermi Surface Method
fwEi//1 7.3.7 Intensities and Their Use in Band-Structure Determinations
%F~
dmA#: 7.3.8 Summary
*O;N"jf
7.4 Experimental Band Structures
K+\hv~+@ 7.4.1 One- and Two-Dimensional Systems
p5KNqqZZ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
_=] FJhO 7..4.3UPS Band Structures and XPS Density of States
.EdV36$n 7.5 A Comment
8M|Q^VeT,1 References
l.BNe)1!22 I?"5i8E 8.Surface States, Surface Effects
6yb<4@LOb 8.1 Theoretical Considerations
UO wNcY 8.2 Experimental Results on Surface States
sF$m?/Kt 8.3 Quantum-Well States
*E]\l+]J 8.4 Surface Core-Level Shifts
cMv3` $ References
^kq! /c3r krA))cP 9.Inverse Photoelectron Spectroscopy
1<83MO; 9.1 Surface States
a|NU)mgEI 9.2 Bulk Band Structures
Go|65Z\`7M 9.3 Adsorbed Molecules
&u8c!;y$b References
,zFN3NLtA lg1D>=(mY 10. Spin-Polarized Photoelectron Spectroscopy
| QA8"&r 10.1 General Description
if'4MDl 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
b<n)`; 10.3 Magnetic Dichroism
m%&B4E#3T References
+[ zo2lBx C#Jj;Gd 11. Photoelectron Diffraction
9:>K!@ 11.1 Examples
rx/6x(3 11.2 Substrate Photoelectron Diffraction
m5Kx}H~ 11.3 Adsorbate Photoelectron Diffraction
[7V]=] p 11.4 Fermi Surface Scans
3[0:,^a References
.p`'^$X^ r.^&%D Appendix
ZTZE_[ A.1 Table of Binding Energies
0h#M)Ft A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
ui1m+ A.3 Compilation of Work Functions
\Hd B References
9[D7N Index