光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
>J.Qm0TY( Sc$gnUYD{ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
Dzo{PstM% ,E%1Uq" 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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X R4 )z 5!tb$p#z 目录
D@#0 dDT 1. Introduction and Basic Principles
#^Ys{ 1.1 Historical Development
>jv\Qh 1.2 The Electron Mean Free Path
"@4ghot t 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
u %'y_C3 1.4 Experimental Aspects
_$8{;1$T? 1.5 Very High Resolution
J,RDTXqn 1.6 The Theory of Photoemission
l^ARW
E 1.6.1 Core-Level Photoemission
ln fm0 1.6.2 Valence-State Photoemission
-/zp&*0gcx 1.6.3 Three-Step and One-Step Considerations
`%oIRuYG]j 1.7 Deviations from the Simple Theory of Photoemission
inZi3@h)T References
C w%BZ xHHV=M2l(s 2. Core Levels and Final States
6ga5^6W 2.1 Core-Level Binding Energies in Atoms and Molecules
T(JuL<PB 2.1.1 The Equivalent-Core Approximation
<~N%W#z/ 2.1.2 Chemical Shifts
yQ'eu;+] 2.2 Core-Level Binding Energies in Solids
Lbsr_*4t 2.2.1 The Born-Haber Cycle in Insulators
t-!m
vx9Z 2.2.2 Theory of Binding Energies
7lwTZ*rnY 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
BB63xEx 2.3 Core Polarization
wYjQV?, 2.4 Final-State Multiplets in Rare-Earth Valence Bands
qcYNtEs*c 2.5 Vibrational Side Bands
+qhnP$vIe 2.6 Core Levels of Adsorbed Molecules
7-X/>v 2.7 Quantitative Chemical Analysis from Core-Level Intensities
H'Ln
P>@n# References
gM#jA8gz nS.2C>A 3. Charge-Excitation Final States: Satellites
)km7tA
0a 3.1 Copper Dihalides; 3d Transition Metal Compounds
'PpZ/ry$ 3.1.1 Characterization of a Satellite
k1#5nYN. 3.1.2 Analysis of Charge-Transfer Satellites
Ny^'IUu 3.1.3 Non-local Screening
{OCJ(^8i 3.2 The 6-eV Satellite in Nickel
lufeieW 3.2.1 Resonance Photoemission
;%WdvnW 3.2.2 Satellites in Other Metals
tFiR!f) 3.3 The Gunnarsson-Sch6nhammer Theory
1Cv#nhmp 3.4 Photoemission Signals and Narrow Bands in Metals
T9?54r References
IC/Q /&(1JqzlB 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
&{ ZSE^ 4.1 Theory
pv&^D,H, 4.1.1 General
DvYwCgLR 4.1.2 Core-Line Shape
3fp> 4;ym' 4.1.3 Intrinsic Plasmons
HxIoA 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
3cixQzb}u 4.1.5 The Total Photoelectron Spectrum
nvt$F%+ 4.2 Experimental Results
TF\sP8>V 4.2.1 The Core Line Without Plasmons
W Y:s
gG 4.2.2 Core-Level Spectra Including Plasmoas
"r. . 4.2.3 Valence-Band Spectra of the Simple Metals
:6D0j 4.2.4 Simple Metals: A General Comment
8teJ*sz 4.3 The Background Correction
;&
|qSa' References
a+Ab]m8` *ik/p 5. Valence Orbitals in Simple Molecules and Insulating Solids
,{8v4b- 5.1 UPS Spectra of Monatomic Gases
Kam]Mn' 5.2 Photoelectron Spectra of Diatomic Molecules
mxp Y&Y 5.3 Binding Energy of the H2 Molecule
'$[Di'*; 5.4 Hydrides Isoelectronic with Noble Gases
")%r}:0 Neon (Ne)
/2XW Hydrogen Fluoride (HF)
=9$mbn
r Water (H2O)
cDeZMsV Ammonia (NH3)
[zh"x#AyI Methane (CH4)
R=M!e<' 5.5 Spectra of the Alkali HMides
"hPCQp`Tj 5.6 Transition Metal Dihalides
lhO2'#]i 5.7 Hydrocarbons
3m=2x5{L 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
7ZsA5%s=, 5.7.2 Linear Polymers
[/$N!2'5 5.8 Insulating Solids with Valence d Electrons
,{KCY[}| 5.8.1 The NiO Problem
$r79n- 5.8.2 Mort Insulation
N4wA#\- 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
1bSD,;$sQ 5.8.4Band Structures of Transition Metal Compounds
9M'DC^x*T 5.9 High—Temperature Superconductors
,@.EpbB 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
Mu2`ODe] 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
J@]k%h 5.9.3 The Superconducting Gap
B4Lx{uno 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
W&C-/O,m
5.9.5 Core—Level Shifts
Cj^{9'0 5.10 The Fermi Liquid and the Luttinger Liquid
2d`c! 5.11 Adsorbed Molecules
3Aj*\e0t 5.11.1 Outline
c!wtf,F 5.11.2 CO on Metal Surfaces
%Q~CB7ILK References
}ZzLs/v%X c-8!#~M( 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
@cv{rr 6.1 Theory of Photoemission:A Summary of the Three-Step Model
RH[+1z8 6.2 Discussion of the Photocurrent
2"&)W dm 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
f*fE}; 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
Cq\I''~8 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
!p[`IWZ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
>|*yh~ 6.3.1 Band Structure Regime
W^3;F1 6.3.2 XPS Regime
][7p+IsB 6.3.3 Surface Emission
?WFh',`: 6.3.4 One-Step Calculations
|W7rr1]~S 6.4 Thermal Effects
cdTsRS;E 6.5 Dipole Selection Rules for Direct Optical Transitions
s'u(B]E References
(
u`W!{1\ YRcps0Dx9 7.Band Structtire and Angular-Resolved Photoelectron Spectra
fn}UBzED\ 7.1 Free-Electron Final—State Model
hfrnxeM#~ 7.2 Methods Employing Calculated Band Structures
o6L9UdT 7.3 Methods for the Absolute Determination of the Crystal Momentum
zp4W'8
7.3.1 Triangulation or Energy Coincidence Method
L
CSeOR 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
_MfD 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
r;m`9,RW 7.3.4 The Surface Emission Method and Electron Damping
H{(]9{ 7.3.5 The Very-Low-Energy Electron Diffraction Method
2R.2D'4)` 7.3.6 The Fermi Surface Method
>M;u*Go`QO 7.3.7 Intensities and Their Use in Band-Structure Determinations
lA;a 7.3.8 Summary
xf,5R9g/ 7.4 Experimental Band Structures
+ WDq=S 7.4.1 One- and Two-Dimensional Systems
i::\Z$L";i 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
%b}gDWs 7..4.3UPS Band Structures and XPS Density of States
s;1h-Oq( 7.5 A Comment
d,cN( References
WsOi,oG@ 9|WV~ 8.Surface States, Surface Effects
B0Xl+JIR# 8.1 Theoretical Considerations
Wa'sZ# 8.2 Experimental Results on Surface States
{9 PR()_ 8.3 Quantum-Well States
*fc-gAj 8.4 Surface Core-Level Shifts
JPx7EEkZR4 References
ZafboqsDL I+;-p]~ 9.Inverse Photoelectron Spectroscopy
ra6o>lI(, 9.1 Surface States
K_/B?h 9.2 Bulk Band Structures
- u3e5gW 9.3 Adsorbed Molecules
csQfic References
LE=k ma& To= 10. Spin-Polarized Photoelectron Spectroscopy
K%j&/T j1 10.1 General Description
acW'$@y9?N 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
d&(_|xq# 10.3 Magnetic Dichroism
.tXtcf/ References
1np^(['ih #AViM_u 11. Photoelectron Diffraction
Tpr tE.mP 11.1 Examples
lmCZ8 j(FF 11.2 Substrate Photoelectron Diffraction
XcfKx@l 11.3 Adsorbate Photoelectron Diffraction
SUtf[6 11.4 Fermi Surface Scans
`\Unpp\I References
[_6 &N. Mi7y&~, Appendix
3f76kl(& A.1 Table of Binding Energies
=XY]x A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
GdmmrfXB A.3 Compilation of Work Functions
;/8 {N0 References
;%!m<S|%k Index