光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
OL]^4m ?2VY^7N[ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
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:e6em 8tWOVLquJ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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[ 目录
\^iPU 27H 1. Introduction and Basic Principles
27*u^N*z@ 1.1 Historical Development
vS-k0g; 1.2 The Electron Mean Free Path
d%?+q0j 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
=>Y b~r71 1.4 Experimental Aspects
xwa5dtcng 1.5 Very High Resolution
&eV& +j 1.6 The Theory of Photoemission
ryzz!0l 1.6.1 Core-Level Photoemission
]gYnw;W$ 1.6.2 Valence-State Photoemission
v8"plx=3 1.6.3 Three-Step and One-Step Considerations
5uMh#dm^ 1.7 Deviations from the Simple Theory of Photoemission
X3#/|> References
FR9<$ F)/}Q[o8 2. Core Levels and Final States
Z~{0XG\Y 2.1 Core-Level Binding Energies in Atoms and Molecules
~dfc 2.1.1 The Equivalent-Core Approximation
jC1mui|Y^ 2.1.2 Chemical Shifts
x[7jm"Pz 2.2 Core-Level Binding Energies in Solids
<}-[9fW 2.2.1 The Born-Haber Cycle in Insulators
!=@Lyt)_b 2.2.2 Theory of Binding Energies
e2Sm.H ' 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
zVe@`gc 2.3 Core Polarization
zCKZv|j6 2.4 Final-State Multiplets in Rare-Earth Valence Bands
z]ZhvH7- 2.5 Vibrational Side Bands
([zt}uf 2.6 Core Levels of Adsorbed Molecules
pv&:N,p 2.7 Quantitative Chemical Analysis from Core-Level Intensities
}^WQNdws56 References
oK&LYlU 98h,VuKVaB 3. Charge-Excitation Final States: Satellites
obRR)) 3.1 Copper Dihalides; 3d Transition Metal Compounds
jr{C/B} 3.1.1 Characterization of a Satellite
WyVFhAuU 3.1.2 Analysis of Charge-Transfer Satellites
Tx?,]c,(u 3.1.3 Non-local Screening
pfgFHNH: 3.2 The 6-eV Satellite in Nickel
/]_T 3.2.1 Resonance Photoemission
*@=in7*c 3.2.2 Satellites in Other Metals
mh]'/C_*<w 3.3 The Gunnarsson-Sch6nhammer Theory
o^;$-O!/ 3.4 Photoemission Signals and Narrow Bands in Metals
g1VdP[Y# References
S?n k9T+ K^`3Bg 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
1VK?Svnd 4.1 Theory
ZB GLwe 4.1.1 General
Pcut#8?
4.1.2 Core-Line Shape
{]<l|qK 4.1.3 Intrinsic Plasmons
IRNL(9H 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
XVAyuuTg\ 4.1.5 The Total Photoelectron Spectrum
o9G%KO&;D, 4.2 Experimental Results
q%TWtQS 4.2.1 The Core Line Without Plasmons
&=H{ 36i@ 4.2.2 Core-Level Spectra Including Plasmoas
S!<YVQq 4.2.3 Valence-Band Spectra of the Simple Metals
#pP4\n-~hU 4.2.4 Simple Metals: A General Comment
jW*|Mu>2 4.3 The Background Correction
?|'+5$ References
;vvO#3DWM !"/]<OQ 5. Valence Orbitals in Simple Molecules and Insulating Solids
=3OK3| 5.1 UPS Spectra of Monatomic Gases
7l> |G,[c 5.2 Photoelectron Spectra of Diatomic Molecules
qPZ'n=+ 5.3 Binding Energy of the H2 Molecule
dt(~)*~R 5.4 Hydrides Isoelectronic with Noble Gases
K:
g_M Neon (Ne)
D-e0q)RSU Hydrogen Fluoride (HF)
=LV7K8FSd Water (H2O)
=; Gw=m( Ammonia (NH3)
J#vIzQ Methane (CH4)
occ^bq 5.5 Spectra of the Alkali HMides
sm5\> L3V 5.6 Transition Metal Dihalides
)I'?]p< 5.7 Hydrocarbons
0 3fCn" 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
,gGIkl& 5.7.2 Linear Polymers
S[,! 5.8 Insulating Solids with Valence d Electrons
MTo<COp($ 5.8.1 The NiO Problem
Z"PPXv-<jY 5.8.2 Mort Insulation
k`JP 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
B.CUk. 5.8.4Band Structures of Transition Metal Compounds
Pe6}y 5.9 High—Temperature Superconductors
!E!i`yF 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
y\Kr@;q0w 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
^Gt&c_gH 5.9.3 The Superconducting Gap
w>Iw&US
5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
Qd;P?W6 5.9.5 Core—Level Shifts
XWN
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f =@'F= 5.11 Adsorbed Molecules
zWKnkIit, 5.11.1 Outline
Ix@rn 5.11.2 CO on Metal Surfaces
[xzgk[>5 References
MyB&mC7Es FY_.Vp 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
T<(1)N1H` 6.1 Theory of Photoemission:A Summary of the Three-Step Model
/aS= vjs 6.2 Discussion of the Photocurrent
Klfg:q:j+b 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
l?pF?({ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
-4ry)isYx 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
YoyJnl.?u 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
>KHR;W 03 6.3.1 Band Structure Regime
MCOiB<L6 6.3.2 XPS Regime
abiZ"?( 6.3.3 Surface Emission
hkV;(Fr&z 6.3.4 One-Step Calculations
&_Kb;UVRj 6.4 Thermal Effects
y4*i
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su;u_rc, References
U-Ia$b-5! -^sW{s0Rc 7.Band Structtire and Angular-Resolved Photoelectron Spectra
X[/>{rK 7.1 Free-Electron Final—State Model
d: D`rpcC 7.2 Methods Employing Calculated Band Structures
gGF]Dq 7.3 Methods for the Absolute Determination of the Crystal Momentum
iUSP+iC, 7.3.1 Triangulation or Energy Coincidence Method
biAI*t 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
ZrY#B8 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
k(LZ,WSR 7.3.4 The Surface Emission Method and Electron Damping
Gl8D
GELl; 7.3.5 The Very-Low-Energy Electron Diffraction Method
4=/5 7.3.6 The Fermi Surface Method
<xM$^r) 7.3.7 Intensities and Their Use in Band-Structure Determinations
t8X$M;$ 7.3.8 Summary
o6`4y^Q{/ 7.4 Experimental Band Structures
3m3ljy 7.4.1 One- and Two-Dimensional Systems
m$<LO%<~p 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
.EeXq}a[ 7..4.3UPS Band Structures and XPS Density of States
{UqS q 7.5 A Comment
hojP3 [ References
5=/&[= F6>K FU8 8.Surface States, Surface Effects
PPoQNW 8.1 Theoretical Considerations
\H<gKZquR 8.2 Experimental Results on Surface States
WP7RX|7 8.3 Quantum-Well States
'Cv,:Q 8.4 Surface Core-Level Shifts
+m?;,JGt References
=&+]>g{T oh*Hzb 9.Inverse Photoelectron Spectroscopy
HI iMq'H^ 9.1 Surface States
Br/qOO:n$} 9.2 Bulk Band Structures
\s_lB~"P!3 9.3 Adsorbed Molecules
&gF*p References
be&5vl vTnrSNdSE 10. Spin-Polarized Photoelectron Spectroscopy
b#ga 10.1 General Description
%8c
<C 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
758`lfz=_ 10.3 Magnetic Dichroism
5mzOr4*0 References
W,sU5sjA s|er+-' 11. Photoelectron Diffraction
/<[S> ;!kr 11.1 Examples
'I$-h<W 11.2 Substrate Photoelectron Diffraction
5x$/.U
11.3 Adsorbate Photoelectron Diffraction
9Z?P/
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)m8ve)l References
R Lnsy, {
'A`ram Appendix
Z_b^K^4 A.1 Table of Binding Energies
/zt9;^e A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
C]@v60I
A.3 Compilation of Work Functions
dA,irb I0W References
Q6>7{\8l Index