光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
mj{TqF M(jSv 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
sJw#^l n]r7} 2hM 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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% 目录
]wc'h>w 1. Introduction and Basic Principles
69p>?zn 1.1 Historical Development
VK[^v; 1.2 The Electron Mean Free Path
[K9l>O 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
`!K(P- yB? 1.4 Experimental Aspects
l*e*jA_>:7 1.5 Very High Resolution
jL<:N
8 1.6 The Theory of Photoemission
9h9 jS~h 1.6.1 Core-Level Photoemission
g\,pZ]0i 1.6.2 Valence-State Photoemission
&&nvv &a 1.6.3 Three-Step and One-Step Considerations
v1oq[+ 1.7 Deviations from the Simple Theory of Photoemission
7b_t%G" References
LkK%DY 0L S,(v4 2. Core Levels and Final States
RpOGY{[)[ 2.1 Core-Level Binding Energies in Atoms and Molecules
gp`$/ci 2.1.1 The Equivalent-Core Approximation
h.l^f>,/ 2.1.2 Chemical Shifts
'-N `u$3Y 2.2 Core-Level Binding Energies in Solids
6c$ so 2.2.1 The Born-Haber Cycle in Insulators
sn+g#v9e 2.2.2 Theory of Binding Energies
hs!a'E 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
anxgD?<+B 2.3 Core Polarization
G%jgr"]\z 2.4 Final-State Multiplets in Rare-Earth Valence Bands
TwH%P2)x 2.5 Vibrational Side Bands
A,Wwt
[Qw 2.6 Core Levels of Adsorbed Molecules
!ow:P8K? 2.7 Quantitative Chemical Analysis from Core-Level Intensities
>B!E 6ah References
|-a5|3 ="Zr. g~8 3. Charge-Excitation Final States: Satellites
p.A_,iE 3.1 Copper Dihalides; 3d Transition Metal Compounds
Vzn0; 3.1.1 Characterization of a Satellite
Qz=F
nR 3.1.2 Analysis of Charge-Transfer Satellites
($pN OGH 3.1.3 Non-local Screening
ywTt<;
3.2 The 6-eV Satellite in Nickel
Fku~'30 3.2.1 Resonance Photoemission
%UT5KYd!=N 3.2.2 Satellites in Other Metals
bA!n; 3.3 The Gunnarsson-Sch6nhammer Theory
zl^ %x1G 3.4 Photoemission Signals and Narrow Bands in Metals
Yd'Fhvo8 References
t~]n"zgovz #I8)|p?P 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
LM\ H%=*L 4.1 Theory
Oi%\'biM 4.1.1 General
b+Vfi9< 4.1.2 Core-Line Shape
c<bV3, 4.1.3 Intrinsic Plasmons
UTB]svC' 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
"{(|}Cds 4.1.5 The Total Photoelectron Spectrum
v3PtiKS 4.2 Experimental Results
js;p7wi 4.2.1 The Core Line Without Plasmons
)O\w'|$G 4.2.2 Core-Level Spectra Including Plasmoas
"jV:L 4.2.3 Valence-Band Spectra of the Simple Metals
@+Yql 4.2.4 Simple Metals: A General Comment
fGjYWw
4.3 The Background Correction
'5V}Z3zJ/ References
)Q= EmZbJz h K;9XJAf 5. Valence Orbitals in Simple Molecules and Insulating Solids
i<@"+~n~GK 5.1 UPS Spectra of Monatomic Gases
A0X'|4I 5.2 Photoelectron Spectra of Diatomic Molecules
*U>"_h T0 5.3 Binding Energy of the H2 Molecule
jV{?.0/h| 5.4 Hydrides Isoelectronic with Noble Gases
uDD{O~wF, Neon (Ne)
_|+}4 ap Hydrogen Fluoride (HF)
k;/K']4y Water (H2O)
"o_s=^U Ammonia (NH3)
E{s p Methane (CH4)
-&q@|h' 5.5 Spectra of the Alkali HMides
;>hRj! 5.6 Transition Metal Dihalides
@=_4i&]$ 5.7 Hydrocarbons
rebnV&- 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
3bYPi^ 5.7.2 Linear Polymers
pPL)!=o! 5.8 Insulating Solids with Valence d Electrons
m.F}9HI%hN 5.8.1 The NiO Problem
I+2#k\y 5.8.2 Mort Insulation
+MZsL7% 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
9*~bAgkWI 5.8.4Band Structures of Transition Metal Compounds
aa2 vk)~ 5.9 High—Temperature Superconductors
i4T=4q 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
5 EhOvt8 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
L a>fvm 5.9.3 The Superconducting Gap
.A6D&-&z 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
RN^<bt{_U 5.9.5 Core—Level Shifts
M.FY4~ 5.10 The Fermi Liquid and the Luttinger Liquid
Cv[_N%3[ 5.11 Adsorbed Molecules
*^y,Gg/ 5.11.1 Outline
B]2m(0Y>>v 5.11.2 CO on Metal Surfaces
<+y%k~(" References
l XpbAW cN% r\ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
i?wEd!=w 6.1 Theory of Photoemission:A Summary of the Three-Step Model
35Ro85j 6.2 Discussion of the Photocurrent
=kzuU1s 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
kB`
@M>[ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
~=GwNo_ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
[KQ#b 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
joz0D!-"# 6.3.1 Band Structure Regime
3</W}]$)p 6.3.2 XPS Regime
A"tE~m;"7 6.3.3 Surface Emission
Ab
#}BHI 6.3.4 One-Step Calculations
2Tp@;[!3 6.4 Thermal Effects
d`gKF 6.5 Dipole Selection Rules for Direct Optical Transitions
$UD$NSl References
LZtO Q__B) ?K\r-J!Y 7.Band Structtire and Angular-Resolved Photoelectron Spectra
t|urvoz 7.1 Free-Electron Final—State Model
C/?x`2' 7.2 Methods Employing Calculated Band Structures
bL`>#M_^ 7.3 Methods for the Absolute Determination of the Crystal Momentum
a B$x(8pP@ 7.3.1 Triangulation or Energy Coincidence Method
]z O6ESH 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
T)MX]T 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
VTUSM{TC 7.3.4 The Surface Emission Method and Electron Damping
B?%e-xV- 7.3.5 The Very-Low-Energy Electron Diffraction Method
dVMduo 7.3.6 The Fermi Surface Method
4A`U [r_>D 7.3.7 Intensities and Their Use in Band-Structure Determinations
`h%K8];<6f 7.3.8 Summary
d>gQgQ;g 7.4 Experimental Band Structures
CJjT-(a 7.4.1 One- and Two-Dimensional Systems
cYgd1 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
ToK=`0#LNK 7..4.3UPS Band Structures and XPS Density of States
z"nMR_TTu 7.5 A Comment
YEa<zhO8 References
z6*r<>Bf+b ;V?3Hwl 8.Surface States, Surface Effects
k4d;4D? 8.1 Theoretical Considerations
wP7
E8' 8.2 Experimental Results on Surface States
)[ QT?; 8.3 Quantum-Well States
DH7]TRCMZ) 8.4 Surface Core-Level Shifts
{[4.<|26 References
"!Qi$ ] cOf.z)kf6 9.Inverse Photoelectron Spectroscopy
W|Cs{rBc? 9.1 Surface States
uZTbJ3$$ 9.2 Bulk Band Structures
XU<XK9EA 9.3 Adsorbed Molecules
nx(jYXVT References
bt* :9DyABK=Cv 10. Spin-Polarized Photoelectron Spectroscopy
/PVx 10.1 General Description
Kv)Kn8df 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
:N!s@6 10.3 Magnetic Dichroism
SdF+b+P] References
:-_"[:t 5Z O]Ey@7 & 11. Photoelectron Diffraction
b")O#v. 11.1 Examples
4p7j"d5 11.2 Substrate Photoelectron Diffraction
Ei<m/v
11.3 Adsorbate Photoelectron Diffraction
T/0cPn0> 11.4 Fermi Surface Scans
:%gM
Xsb References
PWeWz(]0Z4 O=vD6@QI Appendix
Uw]o9 e0S A.1 Table of Binding Energies
r $[{sW A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
I s|_ A.3 Compilation of Work Functions
Ey.%:
O-Dv References
Scug
wSB Index