光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
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作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
p{mxk)A ^ 4u3Q 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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目录
d8Q_6(Ar| 1. Introduction and Basic Principles
$\YLmG 1.1 Historical Development
,cGwtt( 1.2 The Electron Mean Free Path
&rl]$Mtt 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
"!%w9 1.4 Experimental Aspects
veYsctK~ 1.5 Very High Resolution
aBqe+FXp4 1.6 The Theory of Photoemission
l5\B2 +}7 1.6.1 Core-Level Photoemission
CX&yjT6` 1.6.2 Valence-State Photoemission
nLFx/5sL 1.6.3 Three-Step and One-Step Considerations
*j_fG$10g 1.7 Deviations from the Simple Theory of Photoemission
BNL8hK`D References
"oE^R?m !7IT~pO` 2. Core Levels and Final States
q
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%!ER @&1f& 2.1.1 The Equivalent-Core Approximation
5{R#h : 2.1.2 Chemical Shifts
b*'=W"%\ 2.2 Core-Level Binding Energies in Solids
_V_8p)% 2.2.1 The Born-Haber Cycle in Insulators
5UrXVdP 2.2.2 Theory of Binding Energies
fG8}= xH_& 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
4pfix1F g 2.3 Core Polarization
5C Y@R 2.4 Final-State Multiplets in Rare-Earth Valence Bands
X%4uShM 2.5 Vibrational Side Bands
c:?#zX 2.6 Core Levels of Adsorbed Molecules
\J,- <wF 2.7 Quantitative Chemical Analysis from Core-Level Intensities
|"Xi%CQ2 References
c{m
;"ZCFS Z!]U&Ax`Z 3. Charge-Excitation Final States: Satellites
0_,3/EWa 3.1 Copper Dihalides; 3d Transition Metal Compounds
!
kOl$!X4 3.1.1 Characterization of a Satellite
r?5@Etpg 3.1.2 Analysis of Charge-Transfer Satellites
dVsAX( 3.1.3 Non-local Screening
9Th32}H 3.2 The 6-eV Satellite in Nickel
/c_kj2& ]9 3.2.1 Resonance Photoemission
i">z8?qF 3.2.2 Satellites in Other Metals
4P O%qO 3.3 The Gunnarsson-Sch6nhammer Theory
e~t}z_>F 3.4 Photoemission Signals and Narrow Bands in Metals
}QWTPRn References
K+h9bI/Sf 7kX7\[zN 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
Zv1Bju*y 4.1 Theory
Kbz7 4.1.1 General
z~}StCH( 4.1.2 Core-Line Shape
|z(Ws 4.1.3 Intrinsic Plasmons
aCUV[CPw 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
qOcG|UgF 4.1.5 The Total Photoelectron Spectrum
OU)p)Y_z 4.2 Experimental Results
YL9t3] 4.2.1 The Core Line Without Plasmons
p(x1D]#Z[ 4.2.2 Core-Level Spectra Including Plasmoas
&-8-xw#. 4.2.3 Valence-Band Spectra of the Simple Metals
os(Jr!p_= 4.2.4 Simple Metals: A General Comment
I7G\X#,iz 4.3 The Background Correction
H%01&u References
vHI"C % d5sGkR`( 5. Valence Orbitals in Simple Molecules and Insulating Solids
!0. 5 5.1 UPS Spectra of Monatomic Gases
?(,5eg 5.2 Photoelectron Spectra of Diatomic Molecules
&aevR^f+ 5.3 Binding Energy of the H2 Molecule
f1]AfH# 5.4 Hydrides Isoelectronic with Noble Gases
XY+aunLf
Neon (Ne)
N}l]Ilm$34 Hydrogen Fluoride (HF)
xPfnyAo?%z Water (H2O)
l9ifUhe Ammonia (NH3)
llZ"uTK\M Methane (CH4)
bW
86Iw 5.5 Spectra of the Alkali HMides
$Va]vC8? 5.6 Transition Metal Dihalides
:_~PU$%0 5.7 Hydrocarbons
4M0v1`k 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
G7_"^r%c9; 5.7.2 Linear Polymers
2,XqslB) 5.8 Insulating Solids with Valence d Electrons
o.
V0iS] 5.8.1 The NiO Problem
Z'>eT) 5.8.2 Mort Insulation
/_k hFw 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
/[0 /8f6 5.8.4Band Structures of Transition Metal Compounds
!(ux.T0 5.9 High—Temperature Superconductors
]!tYrSM! 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
Za:BJ: 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
}%>$}4 , 5.9.3 The Superconducting Gap
+sR *d 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
#Lxj
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|Z7bd^ 5.10 The Fermi Liquid and the Luttinger Liquid
L$TKO,T 5.11 Adsorbed Molecules
vn%U;} 5.11.1 Outline
XM@-Y&c$A 5.11.2 CO on Metal Surfaces
yz2oS|0 ' References
li_pM!dWU_ $NGtxZp 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
l LD)i J1 6.1 Theory of Photoemission:A Summary of the Three-Step Model
0p>:rU~ 6.2 Discussion of the Photocurrent
^0ZKHR(}e 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
Ay"2W%([` 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
<1g 1hqK3 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
#`#aSqGmc 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
7Yw\%}UL 6.3.1 Band Structure Regime
9}qfdbI 6.3.2 XPS Regime
<j8&u/Za~' 6.3.3 Surface Emission
G}dOx}kT 6.3.4 One-Step Calculations
dI0>m:RBz 6.4 Thermal Effects
dT@SO 6.5 Dipole Selection Rules for Direct Optical Transitions
Zz)oMw References
In9|n^=H@ norc!?L 7.Band Structtire and Angular-Resolved Photoelectron Spectra
Hj4w
i| 7.1 Free-Electron Final—State Model
x{`<);CQ 7.2 Methods Employing Calculated Band Structures
nhXp_Z9 7.3 Methods for the Absolute Determination of the Crystal Momentum
v!RB(T3 7.3.1 Triangulation or Energy Coincidence Method
QWW7I.9r 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
>/HU' 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
69I.*[ 7.3.4 The Surface Emission Method and Electron Damping
vkd<l&zD 7.3.5 The Very-Low-Energy Electron Diffraction Method
<#x%A0 7.3.6 The Fermi Surface Method
>yT@?!/Q>' 7.3.7 Intensities and Their Use in Band-Structure Determinations
>*i8RqU 7.3.8 Summary
9Or4`JOO 7.4 Experimental Band Structures
OD/P*CQ_ 7.4.1 One- and Two-Dimensional Systems
M Xt + 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
PN^1 7..4.3UPS Band Structures and XPS Density of States
R
EH&kcn 7.5 A Comment
dt0E0i References
}`/n2 nIqY}?? 8.Surface States, Surface Effects
H"RF[bX( 8.1 Theoretical Considerations
xEZVsz 8.2 Experimental Results on Surface States
b;;Kxi:7$} 8.3 Quantum-Well States
k-DB~-L 8.4 Surface Core-Level Shifts
{6y.%ysU References
yJ`1},^ RdVis|7o 9.Inverse Photoelectron Spectroscopy
dj&m 9.1 Surface States
^`r|3c0 9.2 Bulk Band Structures
6p]R)K>wS 9.3 Adsorbed Molecules
@?cXa: tX References
~Ow23N AFB 7s z 10. Spin-Polarized Photoelectron Spectroscopy
*0@;
kD=
10.1 General Description
A8Z?[,Mq! 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
E?h2e~ ,] 10.3 Magnetic Dichroism
,,#rv-* References
lGHu@(n< H6\ x.J^, 11. Photoelectron Diffraction
{*Wwu
f. 11.1 Examples
+:Q/<^Z 11.2 Substrate Photoelectron Diffraction
5b4V/d*
' 11.3 Adsorbate Photoelectron Diffraction
6V6g{6W,/ 11.4 Fermi Surface Scans
,~?A.
5 References
YGpp:8pen a;owG/\p Appendix
+P)[|y +e A.1 Table of Binding Energies
$JSC+o(q3# A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
`iayh A.3 Compilation of Work Functions
'xXqEwi4 References
Bsk2&17z Index