光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
=l2 @'Y Q
$o9^b
Z 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
>WO;q tM@%EO 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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=WF@S1 %eF=;q 目录
hRKJKQ@7 1. Introduction and Basic Principles
Q_/UC#I8 1.1 Historical Development
DM6(8df( 1.2 The Electron Mean Free Path
9XUYy2{G 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
r,|}^u8` 1.4 Experimental Aspects
,*Wh{) 1.5 Very High Resolution
;|= 5)KE 1.6 The Theory of Photoemission
Qt"jU+Zoy 1.6.1 Core-Level Photoemission
~A/vP- 1.6.2 Valence-State Photoemission
Yk{4 3yw 1.6.3 Three-Step and One-Step Considerations
1=_?Wg: 1.7 Deviations from the Simple Theory of Photoemission
{niV63$m References
T*k{^=6"! (CAVOed 2. Core Levels and Final States
`j2|aX
%Z* 2.1 Core-Level Binding Energies in Atoms and Molecules
CC6]AM(i 2.1.1 The Equivalent-Core Approximation
/L`qOr2E 2.1.2 Chemical Shifts
*ax&}AHK[/ 2.2 Core-Level Binding Energies in Solids
abe5 As r 2.2.1 The Born-Haber Cycle in Insulators
^~B#r# 2.2.2 Theory of Binding Energies
q.hpnE~#lh 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
c8l\1ce?7 2.3 Core Polarization
nKwOSGPQt 2.4 Final-State Multiplets in Rare-Earth Valence Bands
}P!:0w3 2.5 Vibrational Side Bands
Yg!fEopLb 2.6 Core Levels of Adsorbed Molecules
Ux);~P`/o 2.7 Quantitative Chemical Analysis from Core-Level Intensities
OS~Z@'Eg References
;Uypv|xX |Ntretz`\ 3. Charge-Excitation Final States: Satellites
.4z_ohe 3.1 Copper Dihalides; 3d Transition Metal Compounds
+s+E!= s 3.1.1 Characterization of a Satellite
[2!?pVI 3.1.2 Analysis of Charge-Transfer Satellites
{- &wV 3.1.3 Non-local Screening
>U:.5Tch'V 3.2 The 6-eV Satellite in Nickel
;k1VY
Ie} 3.2.1 Resonance Photoemission
=dQ46@ 3.2.2 Satellites in Other Metals
^x >R #.R 3.3 The Gunnarsson-Sch6nhammer Theory
/KgP<2p 3.4 Photoemission Signals and Narrow Bands in Metals
cW{ Bsr
References
[r1\FF@v, E_xCRfw_i] 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
P#KTlH 4.1 Theory
GQ9H>Ssz 4.1.1 General
x50ZwV&j 4.1.2 Core-Line Shape
Nk\/lK\ 4.1.3 Intrinsic Plasmons
meD?<g4n~" 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
s=&x%0f% 4.1.5 The Total Photoelectron Spectrum
k
_Bz@^J 4.2 Experimental Results
.P!pC 4.2.1 The Core Line Without Plasmons
DoEN`K\U 4.2.2 Core-Level Spectra Including Plasmoas
>{h/4T@ 4.2.3 Valence-Band Spectra of the Simple Metals
Ap(>mUs!i 4.2.4 Simple Metals: A General Comment
Eye.#~ 4.3 The Background Correction
dEoW8 M# References
>s%m\"|oh OYIH**? 5. Valence Orbitals in Simple Molecules and Insulating Solids
O=}jg0k 5.1 UPS Spectra of Monatomic Gases
'oM&Ar$ 5.2 Photoelectron Spectra of Diatomic Molecules
^,fMs: 5.3 Binding Energy of the H2 Molecule
/n 1H;~f] 5.4 Hydrides Isoelectronic with Noble Gases
$2v{4WP7G Neon (Ne)
*edhJUT Hydrogen Fluoride (HF)
JW=P}h Water (H2O)
Z&Z=24q_ Ammonia (NH3)
D7,{p2<2T Methane (CH4)
d+6-ten 5.5 Spectra of the Alkali HMides
,6T3:qkkvF 5.6 Transition Metal Dihalides
k
3oR: 5.7 Hydrocarbons
$s9YU" 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
Xa=oEG 5.7.2 Linear Polymers
FJ
V!B& 5.8 Insulating Solids with Valence d Electrons
R|t.JoP9 5.8.1 The NiO Problem
iFB {a?BE 5.8.2 Mort Insulation
5m a(~5 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
IaYy5Rw 5.8.4Band Structures of Transition Metal Compounds
I(0 *cWO 5.9 High—Temperature Superconductors
OR-fC 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
FP h1 }qS 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
9d >AnTf&H 5.9.3 The Superconducting Gap
,g bQqoLV 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
`BKV/Xl 5.9.5 Core—Level Shifts
J*r%b+ 5.10 The Fermi Liquid and the Luttinger Liquid
v^Pjvv = 5.11 Adsorbed Molecules
uY$BZEuAZ 5.11.1 Outline
&/]g@^h9 5.11.2 CO on Metal Surfaces
C1SCV^# References
*gL-v]V jf~-;2 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
KIHr% 6.1 Theory of Photoemission:A Summary of the Three-Step Model
5(&'/U^ 6.2 Discussion of the Photocurrent
<lHVch"(^$ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
q5ja \ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
YhFd0A?] 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
l]__!X 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
rh 7%<xb> 6.3.1 Band Structure Regime
nv2p&-e+ 6.3.2 XPS Regime
1usLCG>w{ 6.3.3 Surface Emission
$]S*(K3U~ 6.3.4 One-Step Calculations
T!Eyq,] 6.4 Thermal Effects
tU>?j1 6.5 Dipole Selection Rules for Direct Optical Transitions
yM*f}S/
( References
!p|d[ ;*409P 7.Band Structtire and Angular-Resolved Photoelectron Spectra
4 .d~u@= 7.1 Free-Electron Final—State Model
OykYXFv* 7.2 Methods Employing Calculated Band Structures
s^Rig[ 7.3 Methods for the Absolute Determination of the Crystal Momentum
?'r=>'6D 7.3.1 Triangulation or Energy Coincidence Method
HmZ* 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
a+ lGN 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
kF29~ 7.3.4 The Surface Emission Method and Electron Damping
"3X~BdH&J 7.3.5 The Very-Low-Energy Electron Diffraction Method
;dE'# Kb 7.3.6 The Fermi Surface Method
M7g6m 7.3.7 Intensities and Their Use in Band-Structure Determinations
%[H|3 7.3.8 Summary
^OnZ9?C{R 7.4 Experimental Band Structures
Ym5ji$!2 7.4.1 One- and Two-Dimensional Systems
&5o ln@YL 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
r*XEne 7..4.3UPS Band Structures and XPS Density of States
E|l qlS7 7.5 A Comment
pLea 4 References
'n4$dv%q ;{hE]jReH 8.Surface States, Surface Effects
2qxede 8.1 Theoretical Considerations
AI\|8[kf0 8.2 Experimental Results on Surface States
bAZx*qE= 8.3 Quantum-Well States
nN$aZSb` 8.4 Surface Core-Level Shifts
2u?k;"]V References
97SOa.@ ym.:I@b?6 9.Inverse Photoelectron Spectroscopy
xY94v 9.1 Surface States
)=@SA`J 9.2 Bulk Band Structures
pGdo:L? 9.3 Adsorbed Molecules
rf]'VJg#3 References
TZYz`l+v $PE{}`#g 10. Spin-Polarized Photoelectron Spectroscopy
sxFkpf_h 10.1 General Description
2{fPQQ;# 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
~s4o1^6L 10.3 Magnetic Dichroism
}10ZPaHjl+ References
nYbI =_- W2W4w 11. Photoelectron Diffraction
;;? Zd 11.1 Examples
G~N$bF^R) 11.2 Substrate Photoelectron Diffraction
1DT}_0{0Q 11.3 Adsorbate Photoelectron Diffraction
=!{
E!3>*D 11.4 Fermi Surface Scans
|VxO ,[~ References
9qXKHro LOf)D7T Appendix
(D1$ & A.1 Table of Binding Energies
$++SF)G1]_ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
NT&skrzW A.3 Compilation of Work Functions
%e|.a)78 References
>hsvRX\_` Index