光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
PTA;a0A J[YA1 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
G#5Cyu<r! cZ|D!1% 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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Qat%<;P2 -c<<A.X 目录
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1. Introduction and Basic Principles
jm RYL(" 1.1 Historical Development
L)8 +/+ 1.2 The Electron Mean Free Path
dtA- 4Ndm 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
f*XF"@ZQV 1.4 Experimental Aspects
-J[zJ4z# 1.5 Very High Resolution
\^Y#"zXo1 1.6 The Theory of Photoemission
`Kym{og 1.6.1 Core-Level Photoemission
<kLY1EILM 1.6.2 Valence-State Photoemission
F1M@$S, 1.6.3 Three-Step and One-Step Considerations
~pzaX8! 1.7 Deviations from the Simple Theory of Photoemission
%T'?7^\> References
W U<#_by
g 4bAgbx-^ 2. Core Levels and Final States
m*i~Vjxj-m 2.1 Core-Level Binding Energies in Atoms and Molecules
++&F5'?g 2.1.1 The Equivalent-Core Approximation
dC( 6s=4 2.1.2 Chemical Shifts
Lj~lfO 2.2 Core-Level Binding Energies in Solids
"b1_vA]03 2.2.1 The Born-Haber Cycle in Insulators
"VT5WFj 2.2.2 Theory of Binding Energies
Ne^#5 T 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
2CmeO&(Qf* 2.3 Core Polarization
T{)!>) 2.4 Final-State Multiplets in Rare-Earth Valence Bands
vnN_csJ#^ 2.5 Vibrational Side Bands
LL[+QcH 2.6 Core Levels of Adsorbed Molecules
!?l 23(d 2.7 Quantitative Chemical Analysis from Core-Level Intensities
nn=JM7e\9 References
aLsGden| dt5gQ9(B 3. Charge-Excitation Final States: Satellites
E_H1X'|qS4 3.1 Copper Dihalides; 3d Transition Metal Compounds
htF&VeIte 3.1.1 Characterization of a Satellite
8vT:icl 3.1.2 Analysis of Charge-Transfer Satellites
ko5\*!|:lj 3.1.3 Non-local Screening
iEU(1?m2- 3.2 The 6-eV Satellite in Nickel
+?.,pq n<= 3.2.1 Resonance Photoemission
1B1d>V$* 3.2.2 Satellites in Other Metals
;m5M:Z" 3.3 The Gunnarsson-Sch6nhammer Theory
[=9R5.)c 3.4 Photoemission Signals and Narrow Bands in Metals
':>B%k References
,h>w % ScTqnY$v 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
K&X'^|en 4.1 Theory
<]9MgfAe
4.1.1 General
HAiUFO/R 4.1.2 Core-Line Shape
.U1dcL6 4.1.3 Intrinsic Plasmons
S:}s |![p 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
D~y]d 4.1.5 The Total Photoelectron Spectrum
,S5#Kka~a 4.2 Experimental Results
7d<v\=J} 4.2.1 The Core Line Without Plasmons
/Mk)H
d 4.2.2 Core-Level Spectra Including Plasmoas
{c1qC zM4 4.2.3 Valence-Band Spectra of the Simple Metals
~H$XSNPi 4.2.4 Simple Metals: A General Comment
FjydEV 4.3 The Background Correction
[yyV`& References
]lo1Kw UQ8x#(`ak 5. Valence Orbitals in Simple Molecules and Insulating Solids
iWCV(! 5.1 UPS Spectra of Monatomic Gases
jgstx3 5.2 Photoelectron Spectra of Diatomic Molecules
35>}$1?-6 5.3 Binding Energy of the H2 Molecule
G<z)Ydh_ 5.4 Hydrides Isoelectronic with Noble Gases
WAa?$"U2 Neon (Ne)
Gw./qu-W Hydrogen Fluoride (HF)
9,W-KM Water (H2O)
l+6\U6_)B Ammonia (NH3)
n1t(ns| Methane (CH4)
X2`>@GR/> 5.5 Spectra of the Alkali HMides
p4t)Z#0 5.6 Transition Metal Dihalides
1FJ[_l 5.7 Hydrocarbons
d.AjH9 jg 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
r83~o/T@ 5.7.2 Linear Polymers
jE#8&P~ 5.8 Insulating Solids with Valence d Electrons
2UF94 5.8.1 The NiO Problem
gp HwiFc 5.8.2 Mort Insulation
!_) ^bRd 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
;N\?]{ L 5.8.4Band Structures of Transition Metal Compounds
C6w{"[Wv=X 5.9 High—Temperature Superconductors
m'tk#C 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
kKM%
5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
'EV *-_k 5.9.3 The Superconducting Gap
?U08A{ c 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
2[po~}2-0 5.9.5 Core—Level Shifts
u`@f~QP0 5.10 The Fermi Liquid and the Luttinger Liquid
r%pFq1/'! 5.11 Adsorbed Molecules
m;f?}z_\$ 5.11.1 Outline
}yw;L(3 5.11.2 CO on Metal Surfaces
fZ}Y(TG/ References
6# ";W2 ^4pKsO3ul 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
JF%=Bc $C 6.1 Theory of Photoemission:A Summary of the Three-Step Model
#<Nvy9 6.2 Discussion of the Photocurrent
c)MR+'d\WO 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
lmKq xs4 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
*\KvcRMGUa 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
vQmackY 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
]A$^ l, 6.3.1 Band Structure Regime
%8CT -mQ 6.3.2 XPS Regime
w"agn}CK 6.3.3 Surface Emission
noNF;zT 6.3.4 One-Step Calculations
6BU0hV 6.4 Thermal Effects
U?fN3 6.5 Dipole Selection Rules for Direct Optical Transitions
XYHCggy References
uuYH6bw*d Pgw%SMEp 7.Band Structtire and Angular-Resolved Photoelectron Spectra
*C@[5#CA2z 7.1 Free-Electron Final—State Model
QeeC2 7.2 Methods Employing Calculated Band Structures
%}MA5 t]o 7.3 Methods for the Absolute Determination of the Crystal Momentum
Cxk$"_ 7.3.1 Triangulation or Energy Coincidence Method
zLw h6^?Y 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
bq3fiT9 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
(Ef2
w[' 7.3.4 The Surface Emission Method and Electron Damping
Dg>'5`& 7.3.5 The Very-Low-Energy Electron Diffraction Method
SXBQ 7.3.6 The Fermi Surface Method
FK@ f' 7.3.7 Intensities and Their Use in Band-Structure Determinations
O/Mz?$8J 7.3.8 Summary
Md>f 7.4 Experimental Band Structures
>[XOMKgQ]( 7.4.1 One- and Two-Dimensional Systems
?$J7%I@ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
oBj>9I; 7..4.3UPS Band Structures and XPS Density of States
Ukx/jNyYv 7.5 A Comment
sh
!~T<yy References
o7Cnyy#: )-.Cne;n 8.Surface States, Surface Effects
HTUYvU*- 8.1 Theoretical Considerations
BK(pJNBh 8.2 Experimental Results on Surface States
UN *dU 8.3 Quantum-Well States
hINnb7o 8.4 Surface Core-Level Shifts
+e0dV_T_> References
E+m]aYu" ^p"4)6p-W 9.Inverse Photoelectron Spectroscopy
]Z.<c$ 9.1 Surface States
e7XsyL'|p 9.2 Bulk Band Structures
S2'`|uI 9.3 Adsorbed Molecules
mmrW`~- References
Sv7>IVC?@ wRXn9 10. Spin-Polarized Photoelectron Spectroscopy
2fkIdy#n@ 10.1 General Description
I~p8#<4#b 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
jiA5oX^g 10.3 Magnetic Dichroism
cg(QjH" References
_HWHQF7 CB*` 11. Photoelectron Diffraction
1<LC8?wt 11.1 Examples
'2|1%NSW9 11.2 Substrate Photoelectron Diffraction
pu/m8
11.3 Adsorbate Photoelectron Diffraction
.k# N7[q= 11.4 Fermi Surface Scans
";wyNpb( References
CrnB{Z4L *.kj]BoO Appendix
]j& FbP)3 A.1 Table of Binding Energies
KY4d+~2 A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
r?64!VS; A.3 Compilation of Work Functions
{E!$ xY8 References
3C277nx Index