光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
Co`O{|NS}! uL`6}0 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
_," -25a 'rWu}#Nb 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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{R`,iWV Yc5{M*w 目录
\SA"DT 1. Introduction and Basic Principles
^;on 1.1 Historical Development
n%N|?!rB 1.2 The Electron Mean Free Path
hN(sz 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
/$]#L% 1.4 Experimental Aspects
Ww(($e! 1.5 Very High Resolution
Jptzc:~B 1.6 The Theory of Photoemission
=_(i#}"A 1.6.1 Core-Level Photoemission
kzZdYiC 1.6.2 Valence-State Photoemission
*{3&?pxx 1.6.3 Three-Step and One-Step Considerations
M\%LB}4M 1.7 Deviations from the Simple Theory of Photoemission
P F#X8+&J References
EN
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5f.G^A: _X 2. Core Levels and Final States
1_chO?&,I 2.1 Core-Level Binding Energies in Atoms and Molecules
y^M~zOe 2.1.1 The Equivalent-Core Approximation
'A#`,^]uLF 2.1.2 Chemical Shifts
z:Sr@!DZ 2.2 Core-Level Binding Energies in Solids
Z0fl]3p 2.2.1 The Born-Haber Cycle in Insulators
M$|r8%z1 2.2.2 Theory of Binding Energies
^F5Q(A 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
f-Yp`lnn.d 2.3 Core Polarization
["5Z=4 2.4 Final-State Multiplets in Rare-Earth Valence Bands
v
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)s @}|` 2.6 Core Levels of Adsorbed Molecules
6[q<%wA 2.7 Quantitative Chemical Analysis from Core-Level Intensities
D{b*,F:&@) References
aSu6SU BQ&G7V 3. Charge-Excitation Final States: Satellites
IU
f1N+-z 3.1 Copper Dihalides; 3d Transition Metal Compounds
?]JTrv"zp 3.1.1 Characterization of a Satellite
v% mAU3M 3.1.2 Analysis of Charge-Transfer Satellites
]{tnNr>mv 3.1.3 Non-local Screening
Vl91I+Ev 3.2 The 6-eV Satellite in Nickel
z(-j%? 3.2.1 Resonance Photoemission
3*N-@;[>b 3.2.2 Satellites in Other Metals
w!~%v
#
3.3 The Gunnarsson-Sch6nhammer Theory
=(!&8U9 3.4 Photoemission Signals and Narrow Bands in Metals
+
?z=,') References
(:JX;<- UIhU[f] 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
+`;YK7o 4.1 Theory
y">_$ 4.1.1 General
!/1aot^( 4.1.2 Core-Line Shape
Mq!vu! 4.1.3 Intrinsic Plasmons
Qktj 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
g;N)K3\2 4.1.5 The Total Photoelectron Spectrum
*aE/\b 4.2 Experimental Results
Im7t8XCG 4.2.1 The Core Line Without Plasmons
^lF'KW$ 4.2.2 Core-Level Spectra Including Plasmoas
%'}zr>tx: 4.2.3 Valence-Band Spectra of the Simple Metals
J>H$4t#HX 4.2.4 Simple Metals: A General Comment
.XD.'S 4.3 The Background Correction
HnDz4eD References
x,f=J4yco 6qCRM *V 5. Valence Orbitals in Simple Molecules and Insulating Solids
^A4bsoW 5.1 UPS Spectra of Monatomic Gases
%kod31X3< 5.2 Photoelectron Spectra of Diatomic Molecules
g{t)I0xm 5.3 Binding Energy of the H2 Molecule
zz4TJ(' 5.4 Hydrides Isoelectronic with Noble Gases
J%_m`? Neon (Ne)
'<Nhq_u{ Hydrogen Fluoride (HF)
4|?y
[j6 Water (H2O)
Ec44JD Ammonia (NH3)
n^H Kf^] Methane (CH4)
P;A9t #\ 5.5 Spectra of the Alkali HMides
{F Ir|R& 5.6 Transition Metal Dihalides
K>!+5A$6i 5.7 Hydrocarbons
F&ud|X=m 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
0^5*@vt 5.7.2 Linear Polymers
av}Giz 5.8 Insulating Solids with Valence d Electrons
q 9cN2|: 5.8.1 The NiO Problem
S;!l"1[; 5.8.2 Mort Insulation
\!+sL JP 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
sZ-A~X@g 5.8.4Band Structures of Transition Metal Compounds
[?dsS$Y3 5.9 High—Temperature Superconductors
29W~<E8K- 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
5Op|="W. 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
7W)*IJ 5.9.3 The Superconducting Gap
PRR]DEz 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
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5.9.5 Core—Level Shifts
hkifd4# 5.10 The Fermi Liquid and the Luttinger Liquid
`R9}.?7 5.11 Adsorbed Molecules
)SX2%&N 5.11.1 Outline
\yQs[l%J 5.11.2 CO on Metal Surfaces
K2'Il[ References
EAPLe{qw:q +,"O#`sy< 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
K\bA[5+N 6.1 Theory of Photoemission:A Summary of the Three-Step Model
ws^ 7J/8 6.2 Discussion of the Photocurrent
X&s@S5=r] 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
!Zr 9t|_ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
XL10W ^ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
/h.hFM/ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
~>j5z&:& 6.3.1 Band Structure Regime
1FkS$ j8: 6.3.2 XPS Regime
~d9R:t1 6.3.3 Surface Emission
M,uQ8SZA[ 6.3.4 One-Step Calculations
%%7~<=rk 6.4 Thermal Effects
^lI>&I&1 6.5 Dipole Selection Rules for Direct Optical Transitions
VL[} References
&jbZL5 h(<2{%j 7.Band Structtire and Angular-Resolved Photoelectron Spectra
WbIf)\ 7.1 Free-Electron Final—State Model
JemB[ 7.2 Methods Employing Calculated Band Structures
,V>7eQt? 7.3 Methods for the Absolute Determination of the Crystal Momentum
4!l%@R>O2 7.3.1 Triangulation or Energy Coincidence Method
vv F: 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
u0s25 JY.% 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
D|8Pe{` 7.3.4 The Surface Emission Method and Electron Damping
w~}*MsB 7.3.5 The Very-Low-Energy Electron Diffraction Method
xE0'eC5n^ 7.3.6 The Fermi Surface Method
lD K<gd 7.3.7 Intensities and Their Use in Band-Structure Determinations
54^2=bp 7.3.8 Summary
zfm-vU 7.4 Experimental Band Structures
x%$as; 7.4.1 One- and Two-Dimensional Systems
;7
F'xz" 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
z:Q4E|IX 7..4.3UPS Band Structures and XPS Density of States
x2 _?B[z 7.5 A Comment
n[`KhRN References
d i;Fj &3_S+.JO 8.Surface States, Surface Effects
J+]W*?m 8.1 Theoretical Considerations
:JI&ngWK 8.2 Experimental Results on Surface States
9_/dj"5 8.3 Quantum-Well States
k~|5TO 8.4 Surface Core-Level Shifts
~4}'R_ References
=Felo8+ C"JFN(f 9.Inverse Photoelectron Spectroscopy
EPn0ZwnS:M 9.1 Surface States
/W @k: 9.2 Bulk Band Structures
)LRso>iOO 9.3 Adsorbed Molecules
M{ References
Y \oz9tf8
[<!4 a 10. Spin-Polarized Photoelectron Spectroscopy
D'UYHc{ 10.1 General Description
gA/8Df\G:l 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
s6F^z\6 10.3 Magnetic Dichroism
0DR:qw References
Zf [#~4 d8V)eZYXy~ 11. Photoelectron Diffraction
6.0/asN} 11.1 Examples
nUy2)CL[L 11.2 Substrate Photoelectron Diffraction
'
Akt5q 11.3 Adsorbate Photoelectron Diffraction
`{
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~V:@4P References
^~65M/ 5m(V(@a3 Appendix
?A\[EI^ A.1 Table of Binding Energies
w<54mGMOLr A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
o$[alh;c+W A.3 Compilation of Work Functions
YS|Ve*t(L= References
q<2b,w== Index