光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
w}k B6o] 'JZ_ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
e'~ Q@_D B,y3]
g6u 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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i4 x[Q&k[xV 目录
SIv[9G6 1. Introduction and Basic Principles
kI+b <$:D 1.1 Historical Development
V9{B}5KC
1.2 The Electron Mean Free Path
sU%"azc 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
AM/lbMr 1.4 Experimental Aspects
\+]O*Bm&`8 1.5 Very High Resolution
@:gl:mc 1.6 The Theory of Photoemission
*k6$ 1.6.1 Core-Level Photoemission
rWe
8D/oc 1.6.2 Valence-State Photoemission
=t.F2'<[Z 1.6.3 Three-Step and One-Step Considerations
J/7u7_ 1.7 Deviations from the Simple Theory of Photoemission
#pa\2d| References
cYD1~JX. i
tW~d 2. Core Levels and Final States
9|a)sb7/ 2.1 Core-Level Binding Energies in Atoms and Molecules
8A_TIyh? 2.1.1 The Equivalent-Core Approximation
uXNp!tY 2.1.2 Chemical Shifts
OR~G Ov| 2.2 Core-Level Binding Energies in Solids
k4mTZ}6E 2.2.1 The Born-Haber Cycle in Insulators
]+,nA R 2.2.2 Theory of Binding Energies
?>TbTfmR 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
P^;WB*V 2.3 Core Polarization
k>-'AWH^v 2.4 Final-State Multiplets in Rare-Earth Valence Bands
05 g?jV 2.5 Vibrational Side Bands
>I:9'"` 2.6 Core Levels of Adsorbed Molecules
@`2ozi~lO 2.7 Quantitative Chemical Analysis from Core-Level Intensities
cJV!>0ua References
4ioNA/E .m'N7`VB 3. Charge-Excitation Final States: Satellites
]E..43 3.1 Copper Dihalides; 3d Transition Metal Compounds
KM@`YV_"g 3.1.1 Characterization of a Satellite
{4)5]62>u 3.1.2 Analysis of Charge-Transfer Satellites
J\GKqt;5@ 3.1.3 Non-local Screening
TP^\e_k 3.2 The 6-eV Satellite in Nickel
)w@y(;WJ 3.2.1 Resonance Photoemission
x"!#_0TT} 3.2.2 Satellites in Other Metals
%9.bu|`KK 3.3 The Gunnarsson-Sch6nhammer Theory
5Wl,J _<F 3.4 Photoemission Signals and Narrow Bands in Metals
I')x]edU References
lDH_ Y]bM M'vXyb%$1 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
jaNH](V 4.1 Theory
yOM
-;h 4.1.1 General
;pCG9 4.1.2 Core-Line Shape
9XY|V<} 4.1.3 Intrinsic Plasmons
=mAGD*NKu 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
E.Pje@d 4.1.5 The Total Photoelectron Spectrum
{AtfK>D 4.2 Experimental Results
@US '{hO1p 4.2.1 The Core Line Without Plasmons
tUn&z?7bF 4.2.2 Core-Level Spectra Including Plasmoas
eb(m8vLR 4.2.3 Valence-Band Spectra of the Simple Metals
ap{{(y&R 4.2.4 Simple Metals: A General Comment
[)bz6\d[ 4.3 The Background Correction
bsD'\ References
s}<)BRZi 0n7HkDo 5. Valence Orbitals in Simple Molecules and Insulating Solids
8L@UB6b\ 5.1 UPS Spectra of Monatomic Gases
}]Qmt5'NI 5.2 Photoelectron Spectra of Diatomic Molecules
WMRYT"J?N] 5.3 Binding Energy of the H2 Molecule
kKNk2!z`M 5.4 Hydrides Isoelectronic with Noble Gases
>n#g9v K Neon (Ne)
ByC1I.B` Hydrogen Fluoride (HF)
hE9'F(87a Water (H2O)
8o%E&Jg: Ammonia (NH3)
upZYv~Sa Methane (CH4)
)3+xsn v 5.5 Spectra of the Alkali HMides
?BXP}] 5.6 Transition Metal Dihalides
l6yB_M 5.7 Hydrocarbons
~x9 W{B] 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
k-;.0!D^ 5.7.2 Linear Polymers
AW]("pt 5.8 Insulating Solids with Valence d Electrons
+D6-m 5.8.1 The NiO Problem
z[_R"+ 5.8.2 Mort Insulation
s}z(|IrH 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
^?81.b|qb 5.8.4Band Structures of Transition Metal Compounds
CvgPIrl 5.9 High—Temperature Superconductors
F<H`8*q9 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
WX+< 4j 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
EXv\FUzo 5.9.3 The Superconducting Gap
2M!+gk=+ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
w;z@py 5.9.5 Core—Level Shifts
}:K\)Pd 5.10 The Fermi Liquid and the Luttinger Liquid
N8u_=b{X 5.11 Adsorbed Molecules
Q'>_59 5.11.1 Outline
:XNK-A W 5.11.2 CO on Metal Surfaces
6:8EZ'y References
7H/!rx 1gf/#+$\ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
mkKRC; 6.1 Theory of Photoemission:A Summary of the Three-Step Model
!W(/Y9g# 6.2 Discussion of the Photocurrent
&h_d|8 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
dw=Xjyk?h 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
@$K![]oD 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
Oi+Qy[y2 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
c"oQ/x 6.3.1 Band Structure Regime
nvm1.}=Cnd 6.3.2 XPS Regime
~2;&pZ$ 6.3.3 Surface Emission
1o"y%*" 6.3.4 One-Step Calculations
GN}9$: 6.4 Thermal Effects
q[Sp|C6x 6.5 Dipole Selection Rules for Direct Optical Transitions
PaU@T! v References
s/k )w3XN A_V 7.Band Structtire and Angular-Resolved Photoelectron Spectra
XPR:_ 7.1 Free-Electron Final—State Model
+c~O0U1 7.2 Methods Employing Calculated Band Structures
:7 s#5b 7.3 Methods for the Absolute Determination of the Crystal Momentum
PW~cqo B71 7.3.1 Triangulation or Energy Coincidence Method
Q>#)LHX 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
6c;?`C 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
}lrfO_ 7.3.4 The Surface Emission Method and Electron Damping
*NX*/(Q 7.3.5 The Very-Low-Energy Electron Diffraction Method
)%nt61P\W 7.3.6 The Fermi Surface Method
y.TdWnXx 7.3.7 Intensities and Their Use in Band-Structure Determinations
tZ*f~yW 7.3.8 Summary
X(0:zb,#G* 7.4 Experimental Band Structures
PLY-,Q&' 7.4.1 One- and Two-Dimensional Systems
&T|UAM. 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
'/]fZ| 7..4.3UPS Band Structures and XPS Density of States
=~(L JPo6 7.5 A Comment
ijR*5#5h References
} SWA|x "pKGUM 8.Surface States, Surface Effects
]h`E4B 8.1 Theoretical Considerations
&6~ncQWu 8.2 Experimental Results on Surface States
tjc5>T[Es8 8.3 Quantum-Well States
~
33@H 8.4 Surface Core-Level Shifts
SFm.<^6 References
qH}62DP3 b;t}7.V'% 9.Inverse Photoelectron Spectroscopy
O!@KM; 9.1 Surface States
rE'
%MiIK 9.2 Bulk Band Structures
1)c=15^ 9.3 Adsorbed Molecules
y:(C=*^<t References
A16- NnSI)*%' 10. Spin-Polarized Photoelectron Spectroscopy
o<eWg 10.1 General Description
El8.D3 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
.k?hb]2N 10.3 Magnetic Dichroism
]#Z$jq{, References
ZLFdnC@ C[/Uy 11. Photoelectron Diffraction
/:c,v- 11.1 Examples
1.cUolnr 11.2 Substrate Photoelectron Diffraction
5{x[EXE' 11.3 Adsorbate Photoelectron Diffraction
SieV%T0t1 11.4 Fermi Surface Scans
w7]p9B References
k)4lX|}Vm |^&2zyUj/ Appendix
4OESsN$O A.1 Table of Binding Energies
.L5T4) A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
p<^/T,&I A.3 Compilation of Work Functions
@#O| References
dA!fv`,6- Index