光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
hfEGkaV._3 #wC4$y<> 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
g1&GX(4[ \;P Bx & 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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4AP<mo @<alWBS 目录
Nk^#Sa? 1. Introduction and Basic Principles
56TUh_ 1.1 Historical Development
%kVpW&
~ 1.2 The Electron Mean Free Path
g00XZ0@ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
\J1Jn~ 1.4 Experimental Aspects
OM,uR3, 1.5 Very High Resolution
"]JS,g {m 1.6 The Theory of Photoemission
/D~z}\k 1.6.1 Core-Level Photoemission
{H0B"i 1.6.2 Valence-State Photoemission
(U|W=@8` 1.6.3 Three-Step and One-Step Considerations
C9bf1ddCW& 1.7 Deviations from the Simple Theory of Photoemission
xY_/CR[, References
DoImWNLo h?$4\^/ 2. Core Levels and Final States
N2~DxVJ5cT 2.1 Core-Level Binding Energies in Atoms and Molecules
/B1NcRS 2.1.1 The Equivalent-Core Approximation
lT$A;7[ 2.1.2 Chemical Shifts
1}V_:~7 2.2 Core-Level Binding Energies in Solids
MNJ$/l)h 2.2.1 The Born-Haber Cycle in Insulators
pLk?<y 2.2.2 Theory of Binding Energies
q$H'u[KQ06 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
n{UB^-}5 2.3 Core Polarization
:r#FI".qx 2.4 Final-State Multiplets in Rare-Earth Valence Bands
\UK 9 2.5 Vibrational Side Bands
(( t8 2.6 Core Levels of Adsorbed Molecules
X0
%k`3 2.7 Quantitative Chemical Analysis from Core-Level Intensities
'z+8;g.ekO References
]1p&*xX:Bj Kb4u)~S: 3. Charge-Excitation Final States: Satellites
&LYU#$sj 3.1 Copper Dihalides; 3d Transition Metal Compounds
Iy`Zh@"~ 3.1.1 Characterization of a Satellite
rGq~e|.O3 3.1.2 Analysis of Charge-Transfer Satellites
\mv7"TM 3.1.3 Non-local Screening
~0worI? 3.2 The 6-eV Satellite in Nickel
.s,hl(w, 3.2.1 Resonance Photoemission
w3yI;P 3.2.2 Satellites in Other Metals
<4(rY9 3.3 The Gunnarsson-Sch6nhammer Theory
t|%iW%m4 3.4 Photoemission Signals and Narrow Bands in Metals
lm@<i4%$F References
j7uiZU;3Rx v( (fRX.` 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
rY($+O@a< 4.1 Theory
`Jz"rh-M 4.1.1 General
@^%zh 4.1.2 Core-Line Shape
?M\3n5; 4.1.3 Intrinsic Plasmons
P_i2yhpK 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
vp-)$f& 4.1.5 The Total Photoelectron Spectrum
-bKli<C 4.2 Experimental Results
+hKQha!* 4.2.1 The Core Line Without Plasmons
\.Q"fd?a_D 4.2.2 Core-Level Spectra Including Plasmoas
Oja)J-QXb 4.2.3 Valence-Band Spectra of the Simple Metals
m qtl0P0 4.2.4 Simple Metals: A General Comment
[Ma&=2h 4.3 The Background Correction
|QxDjL<&t4 References
~fQ#-ekzqk #nn2odR 5. Valence Orbitals in Simple Molecules and Insulating Solids
kGX`y.-[ 5.1 UPS Spectra of Monatomic Gases
5H?`a7q N 5.2 Photoelectron Spectra of Diatomic Molecules
"1`c^ 5.3 Binding Energy of the H2 Molecule
&.Yh_ 5.4 Hydrides Isoelectronic with Noble Gases
|\Qr
cf Neon (Ne)
G|X1c}zAL Hydrogen Fluoride (HF)
ly6?jVJ Water (H2O)
uKtrG,/ p Ammonia (NH3)
dkRJ^~ Methane (CH4)
xOD;pRZQ
5.5 Spectra of the Alkali HMides
0UlaB
sv 5.6 Transition Metal Dihalides
,/JrQWgD 5.7 Hydrocarbons
K+Ehj(eF 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
v)J6}H}e 5.7.2 Linear Polymers
~vaV=}) 5.8 Insulating Solids with Valence d Electrons
\+S~N:@><k 5.8.1 The NiO Problem
lusINILc 5.8.2 Mort Insulation
Z/56JYt!~ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Bz!ddAvlK 5.8.4Band Structures of Transition Metal Compounds
TvMY\e 5.9 High—Temperature Superconductors
J%D'Xlb 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
O,: en t| 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
2{**bArV 5.9.3 The Superconducting Gap
`^(6{p ? 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
TZPWMCN4 5.9.5 Core—Level Shifts
I@ }:} 8t 5.10 The Fermi Liquid and the Luttinger Liquid
Z]oa+W+ 5.11 Adsorbed Molecules
0B1*N_.L@ 5.11.1 Outline
QT\S>} 5.11.2 CO on Metal Surfaces
ZYrd;9zB References
/3rt]h" ':F{st>&H 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
)"|g&= 6.1 Theory of Photoemission:A Summary of the Three-Step Model
?$F:S%eH 6.2 Discussion of the Photocurrent
S1 %{/w 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
"YHe]R>3s 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
<E6]8SQE 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
z`5+BL,|ND 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
GVn7#0x 6.3.1 Band Structure Regime
nN/v7^^ 6.3.2 XPS Regime
op&,& 6.3.3 Surface Emission
=4+UX*&i?. 6.3.4 One-Step Calculations
)!p=0&z@{ 6.4 Thermal Effects
=F8uuYX%m 6.5 Dipole Selection Rules for Direct Optical Transitions
(/Z~0hA[Q References
L=4?vs "uqa~R{ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
t3v*P6 7.1 Free-Electron Final—State Model
`Z]a6@w~ 7.2 Methods Employing Calculated Band Structures
xg\M9&J 7.3 Methods for the Absolute Determination of the Crystal Momentum
k`2 K?9\ 7.3.1 Triangulation or Energy Coincidence Method
EmG`ga)s 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
+;U}SR< 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
+z;xl-*[ 7.3.4 The Surface Emission Method and Electron Damping
`=b*g24z[N 7.3.5 The Very-Low-Energy Electron Diffraction Method
Yca9G?^\v 7.3.6 The Fermi Surface Method
,LWM}L 7.3.7 Intensities and Their Use in Band-Structure Determinations
Vg6?a 7.3.8 Summary
q.~.1
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=<O{ 7.4.1 One- and Two-Dimensional Systems
u =#LY$ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
=5I1[p; 7..4.3UPS Band Structures and XPS Density of States
RE!MX>sOEq 7.5 A Comment
&g.w~KWa References
E=sBcb/v DV*8Mkzg 8.Surface States, Surface Effects
6SlE>b9tA 8.1 Theoretical Considerations
=EsKFt" 8.2 Experimental Results on Surface States
p5c'gziR 8.3 Quantum-Well States
X&
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ldanM>5 References
(.
1<.PZp) J
A4'e@ 9.Inverse Photoelectron Spectroscopy
/Eh\07p 9.1 Surface States
BAdHGwomh 9.2 Bulk Band Structures
0MrtJNF]_O 9.3 Adsorbed Molecules
k;;?3)! References
JR'Q Th:z )|uPCZdLZ 10. Spin-Polarized Photoelectron Spectroscopy
dGP*bMCT 10.1 General Description
=u${2= 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
QVn!60[lj 10.3 Magnetic Dichroism
/M v\~vg$1 References
T*-*U/ 4x e:+sA.N 11. Photoelectron Diffraction
</:f-J%U/ 11.1 Examples
>OZ+k(saL 11.2 Substrate Photoelectron Diffraction
,^:Zf|V 11.3 Adsorbate Photoelectron Diffraction
V4/P 11.4 Fermi Surface Scans
7$,["cJX References
DtXXfp@; w v9s{I{P Appendix
h7[VXE A.1 Table of Binding Energies
1K09iB A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
1fViW^l_ A.3 Compilation of Work Functions
JWlH(-U4| References
>`'#4!}G5j Index