光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
];\XA;aOl} L@`:mK+; 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
)3)x/WM (= Wu5H 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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r:H.VAD x$.0:jP/s 目录
YqYobL*q/ 1. Introduction and Basic Principles
9(hI%idq 1.1 Historical Development
*.!5327 1.2 The Electron Mean Free Path
-=)+)9~G 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
Ted!*HKlB 1.4 Experimental Aspects
R{q<V uN 1.5 Very High Resolution
SyIi*dH 1.6 The Theory of Photoemission
jRhRw; 1.6.1 Core-Level Photoemission
gQuU_dbXSB 1.6.2 Valence-State Photoemission
_C@<*L=Q 1.6.3 Three-Step and One-Step Considerations
cQ(,M 1.7 Deviations from the Simple Theory of Photoemission
bpdluWS+ ) References
LknV47vd SbH} cu8 2. Core Levels and Final States
o^Qy71Uj 2.1 Core-Level Binding Energies in Atoms and Molecules
i wI} 2.1.1 The Equivalent-Core Approximation
}ni@]k#q< 2.1.2 Chemical Shifts
j<}y( ~ 2.2 Core-Level Binding Energies in Solids
ORFi0gFbA 2.2.1 The Born-Haber Cycle in Insulators
n_4BNOZ~ 2.2.2 Theory of Binding Energies
60r0O5=|Fl 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
6o~g3{Ow 2.3 Core Polarization
C@ "l" 2.4 Final-State Multiplets in Rare-Earth Valence Bands
/`g~lww2O 2.5 Vibrational Side Bands
D{^CJ :n 2.6 Core Levels of Adsorbed Molecules
;TboS-Y 2.7 Quantitative Chemical Analysis from Core-Level Intensities
6<No_x |_ References
.B{:<;sa ?6 "B4%7b 3. Charge-Excitation Final States: Satellites
D'Uv7Mis 3.1 Copper Dihalides; 3d Transition Metal Compounds
;upYam" 3.1.1 Characterization of a Satellite
IY}{1[<N 3.1.2 Analysis of Charge-Transfer Satellites
h&z(;B!;y. 3.1.3 Non-local Screening
6&,9=(:J&R 3.2 The 6-eV Satellite in Nickel
=r^Pu| 3.2.1 Resonance Photoemission
A#nSK#wS61 3.2.2 Satellites in Other Metals
DS0:^TLI 3.3 The Gunnarsson-Sch6nhammer Theory
vUB*Qm]Y\ 3.4 Photoemission Signals and Narrow Bands in Metals
*OHaqe(* References
,{BF`5bn| a6hDw'8! 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
J1Oe`my 4.1 Theory
x{1S!A^ 4.1.1 General
8jz7t:0 4.1.2 Core-Line Shape
q6eD{/4a1 4.1.3 Intrinsic Plasmons
QaSRD/,M 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
+4V"&S|& 4.1.5 The Total Photoelectron Spectrum
E|x t\* 4.2 Experimental Results
e]D TK*W~ 4.2.1 The Core Line Without Plasmons
QQQN}!xPj 4.2.2 Core-Level Spectra Including Plasmoas
iy [W:<c7j 4.2.3 Valence-Band Spectra of the Simple Metals
]~\%ANoi 4.2.4 Simple Metals: A General Comment
n(j5dN>] 4.3 The Background Correction
bkIQ?cl<at References
tfPe-U 7:n OAN}% 5. Valence Orbitals in Simple Molecules and Insulating Solids
#f }ORA 5.1 UPS Spectra of Monatomic Gases
>!%+) 5.2 Photoelectron Spectra of Diatomic Molecules
53l !$#o 5.3 Binding Energy of the H2 Molecule
j "e]Ui 5.4 Hydrides Isoelectronic with Noble Gases
2xt$w% Neon (Ne)
}nMp.7b Hydrogen Fluoride (HF)
jB3Rue:+g Water (H2O)
D4PjE@D"H Ammonia (NH3)
ML:H\ Methane (CH4)
#*
Iyvx 5.5 Spectra of the Alkali HMides
}W
nvz;]B 5.6 Transition Metal Dihalides
8Wx7%@^O 5.7 Hydrocarbons
`bjPOA(g 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
[wM]w 5.7.2 Linear Polymers
;bkvdn} 5.8 Insulating Solids with Valence d Electrons
lj@ibA] 5.8.1 The NiO Problem
Y#rd'
8 5.8.2 Mort Insulation
R&MetQ~-{ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
0w?G&jjNtM 5.8.4Band Structures of Transition Metal Compounds
/C/I_S}H 5.9 High—Temperature Superconductors
YeVkX{y 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
EOG&Xa 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
LteZ7e 5.9.3 The Superconducting Gap
rl:D>t(:. 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
HA3d9` 5.9.5 Core—Level Shifts
7-4S'rq+ 5.10 The Fermi Liquid and the Luttinger Liquid
P@8S|#LpZ 5.11 Adsorbed Molecules
;f9a0V s 5.11.1 Outline
m-HBoN 5.11.2 CO on Metal Surfaces
V~S(cO[vj References
DB.)/(zWQ }PxPJ$o 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
KdLj1T 6.1 Theory of Photoemission:A Summary of the Three-Step Model
H1hADn 6.2 Discussion of the Photocurrent
<4jqF 4
W 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
f<*-; 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
.Tc?PmN 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
`0Xs!f 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
b2UqN]{ 6.3.1 Band Structure Regime
Ex4)R2c* 6.3.2 XPS Regime
3/EJ^C 6.3.3 Surface Emission
GUUd(xS{ 6.3.4 One-Step Calculations
;!pJ%p0Sc 6.4 Thermal Effects
l#rr--]; 6.5 Dipole Selection Rules for Direct Optical Transitions
`W'S'?$ References
q;9OqArq `WlQ<QEi 7.Band Structtire and Angular-Resolved Photoelectron Spectra
HKG8X=" 7.1 Free-Electron Final—State Model
&eWnS~hJ 7.2 Methods Employing Calculated Band Structures
VVHL@ 7.3 Methods for the Absolute Determination of the Crystal Momentum
j&"GE':Y 7.3.1 Triangulation or Energy Coincidence Method
=iE)vY,?"} 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
<&iLMb:% 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
$im6v 7.3.4 The Surface Emission Method and Electron Damping
3'6by!N,d 7.3.5 The Very-Low-Energy Electron Diffraction Method
VMJK9|JC[ 7.3.6 The Fermi Surface Method
8W}rSv+ 7.3.7 Intensities and Their Use in Band-Structure Determinations
cb%ML1c 7.3.8 Summary
o3a%u( 7.4 Experimental Band Structures
M`QK{$1p 7.4.1 One- and Two-Dimensional Systems
jYnP)xX; 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
|]tsf
/SA 7..4.3UPS Band Structures and XPS Density of States
|jyD@Q,4 7.5 A Comment
k;pU8y6Y References
##/ l vfOG(EkG.? 8.Surface States, Surface Effects
RKwuvVI 8.1 Theoretical Considerations
dW#?{n-H< 8.2 Experimental Results on Surface States
6yhRcvJ} 8.3 Quantum-Well States
Jek3K& 8.4 Surface Core-Level Shifts
8o[+>W References
/[UuHU5*R JwcC9
O 9.Inverse Photoelectron Spectroscopy
0<42\ya 9.1 Surface States
s5u 9.2 Bulk Band Structures
Sbjc8V ut 9.3 Adsorbed Molecules
_QiGrC References
CC XOxd Ls{]ohP 10. Spin-Polarized Photoelectron Spectroscopy
#E@X'jwu 10.1 General Description
K#a_7/!v/ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
JVh/<A 10.3 Magnetic Dichroism
c}D>.x|] References
&|c] U/_w `;z;=A* 11. Photoelectron Diffraction
xqzB=0 11.1 Examples
9~yp=JOV@ 11.2 Substrate Photoelectron Diffraction
y+P$}Nru 11.3 Adsorbate Photoelectron Diffraction
yI8
/m| 11.4 Fermi Surface Scans
Rmh u"N/q References
+M.!_2t$2 <<+Hs/ ] Appendix
`g:bvIV5x> A.1 Table of Binding Energies
m,#Us A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
K]yUPx A.3 Compilation of Work Functions
TPWqiA?3Cp References
"Sd2VSLg Index