光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
6!=q+sw/X -f?,%6(1 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
ItZ*$I1< 4]xD-sc 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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I-Am9\
e Dpt1 {rygIl{V 目录
YjPj#57+ 1. Introduction and Basic Principles
$j4/ohwTDY 1.1 Historical Development
~Ds3-#mMy 1.2 The Electron Mean Free Path
dkQP.Tj$i 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
`@So6%3Y| 1.4 Experimental Aspects
]v+yeGIK S 1.5 Very High Resolution
/38XaKc{6 1.6 The Theory of Photoemission
Qr-,J_ 1.6.1 Core-Level Photoemission
F8\JL % 1.6.2 Valence-State Photoemission
#TB
3|= 1.6.3 Three-Step and One-Step Considerations
Q4g69IE 1.7 Deviations from the Simple Theory of Photoemission
FB3}M)G>M References
MaF4lFmS E[FE-{B# 2. Core Levels and Final States
1`~.!yd8( 2.1 Core-Level Binding Energies in Atoms and Molecules
L3s"L.G 2.1.1 The Equivalent-Core Approximation
hK %FpGYA 2.1.2 Chemical Shifts
s+h}O}RV 2.2 Core-Level Binding Energies in Solids
Bt(nm>Ng 2.2.1 The Born-Haber Cycle in Insulators
uu/2C \n} 2.2.2 Theory of Binding Energies
AH:0h X6+ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
m<J:6^H@ 2.3 Core Polarization
\]3[Xw-$ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
E+$D$a 2.5 Vibrational Side Bands
~CHVU3 2.6 Core Levels of Adsorbed Molecules
0u
+_D8G 2.7 Quantitative Chemical Analysis from Core-Level Intensities
m@",Zr`f= References
gIKQip< lx> ."rW 3. Charge-Excitation Final States: Satellites
8KsPAK_ 3.1 Copper Dihalides; 3d Transition Metal Compounds
a/[)A _- 3.1.1 Characterization of a Satellite
vb9C 3.1.2 Analysis of Charge-Transfer Satellites
Xwd9-: 3.1.3 Non-local Screening
{=;<1PykLb 3.2 The 6-eV Satellite in Nickel
.d?LRf 3.2.1 Resonance Photoemission
r$Oa 3.2.2 Satellites in Other Metals
{W=5
J7 3.3 The Gunnarsson-Sch6nhammer Theory
1R7tnR@[u 3.4 Photoemission Signals and Narrow Bands in Metals
ju1B._48 References
VL|Z+3L @E>I<j,D 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
Mt@Ma ]! 4.1 Theory
/<"ok;Pu7 4.1.1 General
y~Mu~/s 4.1.2 Core-Line Shape
I^[[*Bh*C 4.1.3 Intrinsic Plasmons
v[)8 1uY 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
gJ^taUE 4.1.5 The Total Photoelectron Spectrum
%l!-rXp 4.2 Experimental Results
Y+5aT(6O 4.2.1 The Core Line Without Plasmons
o.s(=iG 4.2.2 Core-Level Spectra Including Plasmoas
ZX'3qW^D 4.2.3 Valence-Band Spectra of the Simple Metals
2WE01D9O 4.2.4 Simple Metals: A General Comment
M
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^z51f>C References
p =-~qBw w:mm@8N 5. Valence Orbitals in Simple Molecules and Insulating Solids
F^5\w-gLY 5.1 UPS Spectra of Monatomic Gases
hoLA*v2< 5.2 Photoelectron Spectra of Diatomic Molecules
'X`W+=T$ 5.3 Binding Energy of the H2 Molecule
lNTbd"}$: 5.4 Hydrides Isoelectronic with Noble Gases
*;U<b Neon (Ne)
-lR7
@S Hydrogen Fluoride (HF)
T 2Yc` + Water (H2O)
Z*=$n_
G Ammonia (NH3)
3rR1/\ Methane (CH4)
;s -@m< 5.5 Spectra of the Alkali HMides
}y vH)q 5.6 Transition Metal Dihalides
QlS_{XV 5.7 Hydrocarbons
DWN9_*{ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
9TwKd0AT$& 5.7.2 Linear Polymers
#WS>Z3AY 5.8 Insulating Solids with Valence d Electrons
EK&0Cn3z 5.8.1 The NiO Problem
wJ"]H!r0 5.8.2 Mort Insulation
6Cfsh<]b 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
!OMCsUZ 5.8.4Band Structures of Transition Metal Compounds
hE<Sm*HU 5.9 High—Temperature Superconductors
E()%IC/R 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
mA@!t>=oMq 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
KLG29G 5.9.3 The Superconducting Gap
d]MpE9@'v 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
C>SOd] 5.9.5 Core—Level Shifts
P'DcNMdw 5.10 The Fermi Liquid and the Luttinger Liquid
wuM'M<J@ 5.11 Adsorbed Molecules
_]{LjJ!M 5.11.1 Outline
/y6I I$AvM 5.11.2 CO on Metal Surfaces
Sh?eb References
T|0d2aa Ijk hV 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
H!>>|6OPF 6.1 Theory of Photoemission:A Summary of the Three-Step Model
~Yc!~Rz 6.2 Discussion of the Photocurrent
N(2M
w:} 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
&gUa^5'# 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
c2?VjuB0 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
kt=&mq/B 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
4YR{
* 6.3.1 Band Structure Regime
>0uj\5h)I] 6.3.2 XPS Regime
X5)(,036 6.3.3 Surface Emission
@;N(3| n7 6.3.4 One-Step Calculations
;cZp$
xb3 6.4 Thermal Effects
w'E?L`c 6.5 Dipole Selection Rules for Direct Optical Transitions
$cU7)vmK` References
rm-;Z< E VC]B} 7.Band Structtire and Angular-Resolved Photoelectron Spectra
e
m0 hTxb 7.1 Free-Electron Final—State Model
i0J`{PbI 7.2 Methods Employing Calculated Band Structures
B^/k`h6J 7.3 Methods for the Absolute Determination of the Crystal Momentum
*aFY+.;U` 7.3.1 Triangulation or Energy Coincidence Method
=LGSywWM9 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
gXM+N(M- 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
E+LQyvF[ 7.3.4 The Surface Emission Method and Electron Damping
uGm?e]7Hx< 7.3.5 The Very-Low-Energy Electron Diffraction Method
yqVoedN 7.3.6 The Fermi Surface Method
oZ ^,* 7.3.7 Intensities and Their Use in Band-Structure Determinations
X$6QQnyR 7.3.8 Summary
Y=g]\%-PB 7.4 Experimental Band Structures
fre5{=@ 7.4.1 One- and Two-Dimensional Systems
/lh1sHgD 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
=Y5m% ,Bq 7..4.3UPS Band Structures and XPS Density of States
Y*\N{6$2 7.5 A Comment
9NNXj^7 References
]>Gi_20*. I)s_f5' 8.Surface States, Surface Effects
TdT`Vf 8.1 Theoretical Considerations
x+;y0`oL 8.2 Experimental Results on Surface States
+l.LwA 8.3 Quantum-Well States
WglpWp) 8.4 Surface Core-Level Shifts
08D:2 z1z References
6(uZn= e9tb]sAG 9.Inverse Photoelectron Spectroscopy
vxLr034 9.1 Surface States
8n-Xt7z 9.2 Bulk Band Structures
K+XUC 9.3 Adsorbed Molecules
m7C!}l]9 References
K]G(u"' qxsHhyB_n; 10. Spin-Polarized Photoelectron Spectroscopy
PxGw5: 10.1 General Description
GZKYRPg 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
';c 6 10.3 Magnetic Dichroism
3bR%#G% References
R!lug;u# ICr.Gwe3_ 11. Photoelectron Diffraction
0:<Y@#L 11.1 Examples
EWgJ"WTF 11.2 Substrate Photoelectron Diffraction
wf &Jd:)4t 11.3 Adsorbate Photoelectron Diffraction
41s\^'^& 11.4 Fermi Surface Scans
9 wbQ$>G9 References
ZS;V?]\( C/#pK2xY Appendix
RqP_^tB A.1 Table of Binding Energies
yU4mS;GX A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
tf|;'Nc6 A.3 Compilation of Work Functions
[#RFdn< References
)0ydSz`B Index