光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
{kB `>VS \y
Hen|% 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
|!z2oO 8}p8r|d!ls 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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OmMX$YID C9tb \?# 目录
('k<XOi 1. Introduction and Basic Principles
$Rtgr{ {;" 1.1 Historical Development
!|{IVm/J 1.2 The Electron Mean Free Path
'"YYj$>
' 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
n~0z_;5 1.4 Experimental Aspects
@uleyB 1.5 Very High Resolution
T.&7sbE_ 1.6 The Theory of Photoemission
mO rWJ~= 1.6.1 Core-Level Photoemission
#B}?Zg 1.6.2 Valence-State Photoemission
{eZ{] 1.6.3 Three-Step and One-Step Considerations
C0)Z6 1.7 Deviations from the Simple Theory of Photoemission
+a)E|(cN References
GuQRn 3Kq`<B~% 2. Core Levels and Final States
1JS2SxF 2.1 Core-Level Binding Energies in Atoms and Molecules
TR vZ 2.1.1 The Equivalent-Core Approximation
Q4'C;<\@(Q 2.1.2 Chemical Shifts
?Hz2-Cn 2.2 Core-Level Binding Energies in Solids
UGKaOol. 2.2.1 The Born-Haber Cycle in Insulators
]?l{j 2.2.2 Theory of Binding Energies
y.a]r7 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
59 2;W-y 2.3 Core Polarization
x1[?5n6 2.4 Final-State Multiplets in Rare-Earth Valence Bands
#;r]/)> 2.5 Vibrational Side Bands
2Oc$+St~8 2.6 Core Levels of Adsorbed Molecules
Y*YFB|f? 2.7 Quantitative Chemical Analysis from Core-Level Intensities
X T>('qy References
HMQI&Lh=U oVO.@M# 3. Charge-Excitation Final States: Satellites
j'rS&BIG 3.1 Copper Dihalides; 3d Transition Metal Compounds
K'b*A$5o 3.1.1 Characterization of a Satellite
U@lV
3.1.2 Analysis of Charge-Transfer Satellites
>IvBUM[Rt 3.1.3 Non-local Screening
RVM&4#E 3.2 The 6-eV Satellite in Nickel
tai Vk4 3.2.1 Resonance Photoemission
`u'dh{,gE 3.2.2 Satellites in Other Metals
#gZ|T
M/h 3.3 The Gunnarsson-Sch6nhammer Theory
H
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e-6w8*!i References
&w\I<J`T -;c 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
%vqT#+x 4.1 Theory
C7"HQQ 4.1.1 General
.Ao0;:;(2- 4.1.2 Core-Line Shape
!vqC+o>@ 4.1.3 Intrinsic Plasmons
LsTffIP 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
s@@1
*VQ 4.1.5 The Total Photoelectron Spectrum
R{}qK r 4.2 Experimental Results
]|oJ)5P 4.2.1 The Core Line Without Plasmons
I48VNX 4.2.2 Core-Level Spectra Including Plasmoas
J\`^:tcG 4.2.3 Valence-Band Spectra of the Simple Metals
mUXk9X%n 4.2.4 Simple Metals: A General Comment
Gp2!xKgm 4.3 The Background Correction
x7ATI[b[ References
=4NqjSH zQfkMa. 5. Valence Orbitals in Simple Molecules and Insulating Solids
NB)t7/Us 5.1 UPS Spectra of Monatomic Gases
szq+@2: 5.2 Photoelectron Spectra of Diatomic Molecules
@p!Q1-] = 5.3 Binding Energy of the H2 Molecule
Z7#7N wy4 5.4 Hydrides Isoelectronic with Noble Gases
78Y@OL_$ Neon (Ne)
gY5l.& Hydrogen Fluoride (HF)
%J P!{mqj Water (H2O)
"sbBe73 m Ammonia (NH3)
>;lKLGJrd> Methane (CH4)
L(o#4YH}>J 5.5 Spectra of the Alkali HMides
9M2f!kJP$ 5.6 Transition Metal Dihalides
^#SBpLw 5.7 Hydrocarbons
{*xBm# 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
W<'<'z5 5.7.2 Linear Polymers
qo;)X0N 5.8 Insulating Solids with Valence d Electrons
Mtp%co )f 5.8.1 The NiO Problem
P;U@y"s 5.8.2 Mort Insulation
F=Y S^ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
)x\z@g 5.8.4Band Structures of Transition Metal Compounds
g9V.13k 5.9 High—Temperature Superconductors
z,Xk\@ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
/tC9G@Hl 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
lX;mhJj! 5.9.3 The Superconducting Gap
qei$<j'b 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
OlGR<X 5.9.5 Core—Level Shifts
tgN92Q.i6T 5.10 The Fermi Liquid and the Luttinger Liquid
Auac>')&Q 5.11 Adsorbed Molecules
n2'|.y}Um: 5.11.1 Outline
h6QWH 5.11.2 CO on Metal Surfaces
6VR[)T% References
n7iE8SK|k &o.iUk 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
-Bv12ymLG 6.1 Theory of Photoemission:A Summary of the Three-Step Model
d]7*mzw^j 6.2 Discussion of the Photocurrent
Mq+<mX7 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
BjZ>hhs!* 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
%$9:e
J? 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
otnV-7)@ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
(#u{ U= 6.3.1 Band Structure Regime
w%u5< 6.3.2 XPS Regime
-1m vhR~ 6.3.3 Surface Emission
# #>a&, 6.3.4 One-Step Calculations
3+ asP&n 6.4 Thermal Effects
[4gjC
6.5 Dipole Selection Rules for Direct Optical Transitions
<7RfBR.9 References
_LLshV3 uBRw>"c_*8 7.Band Structtire and Angular-Resolved Photoelectron Spectra
Q\WXi 7.1 Free-Electron Final—State Model
~d+O/:=K_ 7.2 Methods Employing Calculated Band Structures
A$m<@%Sz 7.3 Methods for the Absolute Determination of the Crystal Momentum
~XQ$aRl& 7.3.1 Triangulation or Energy Coincidence Method
5"2@NL 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
LDX y}hm) 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
,;3:pr 7.3.4 The Surface Emission Method and Electron Damping
g RU-g 7.3.5 The Very-Low-Energy Electron Diffraction Method
G5umeqYC 7.3.6 The Fermi Surface Method
1.dX)^\ 7.3.7 Intensities and Their Use in Band-Structure Determinations
dqz1xQ1 7.3.8 Summary
BvJ\x) 7.4 Experimental Band Structures
~2 Oc
K 7.4.1 One- and Two-Dimensional Systems
k+txb? 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
3N3*`?5c< 7..4.3UPS Band Structures and XPS Density of States
Ij,Yuo 7.5 A Comment
B$`d&7I;D References
!PI0oh [oJ& J>U' 8.Surface States, Surface Effects
?\d5;%YSr 8.1 Theoretical Considerations
d~/xGB`< 8.2 Experimental Results on Surface States
d'q&Lq 8.3 Quantum-Well States
'A1E^rl]= 8.4 Surface Core-Level Shifts
PHQcstW References
i&pMF O ChVY
Vx( 9.Inverse Photoelectron Spectroscopy
<G}m # 9.1 Surface States
d3(+ztmG! 9.2 Bulk Band Structures
!xH,y 9.3 Adsorbed Molecules
{[lx!QF 8& References
2_I+mQ x3_,nl 10. Spin-Polarized Photoelectron Spectroscopy
pKYLAt+^> 10.1 General Description
*NF&Y 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
%0 qc@4 10.3 Magnetic Dichroism
s)Gb!-`` References
!8Y3V/)NU YpiRF+G
11. Photoelectron Diffraction
Uv'uqt 11.1 Examples
wvX"D0eVn 11.2 Substrate Photoelectron Diffraction
ec#_olG% 11.3 Adsorbate Photoelectron Diffraction
$'y1Po'2 11.4 Fermi Surface Scans
Z{
%Uw;d References
Q>V?w gZ I,w^?o Appendix
P2 |}*h5( A.1 Table of Binding Energies
E4hq} A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
'%:5axg?] A.3 Compilation of Work Functions
O2$!'!hz References
dZ-Ny_@& Index