光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
3:Z(tM&-O ]NFDE-Jz] 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
r]HLO'<] ]LSa(7>EU 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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_ZS<zQ' }?fa+FQGp 目录
yPQ{tS*t 1. Introduction and Basic Principles
FwW%@Y 1.1 Historical Development
4l$8lYi 1.2 The Electron Mean Free Path
w
x,; 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
CIaabn
1.4 Experimental Aspects
rk. UW 1.5 Very High Resolution
!k s<VJh 1.6 The Theory of Photoemission
,o}[q92@w 1.6.1 Core-Level Photoemission
~IqT> 1.6.2 Valence-State Photoemission
zcZw} 1.6.3 Three-Step and One-Step Considerations
]cA~%$c89s 1.7 Deviations from the Simple Theory of Photoemission
=VY4y]V References
3\WES! =0f8W=d:Vr 2. Core Levels and Final States
AQV3ZVP 2.1 Core-Level Binding Energies in Atoms and Molecules
yv:NH|,/y 2.1.1 The Equivalent-Core Approximation
BuvBSLC~ 2.1.2 Chemical Shifts
7J;.T%4l 2.2 Core-Level Binding Energies in Solids
)?xt=9Lh 2.2.1 The Born-Haber Cycle in Insulators
|1<Z3\+_/ 2.2.2 Theory of Binding Energies
0[i]PgIH
2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
cq=R 2.3 Core Polarization
lLDHx3+ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
C {,d4KG 2.5 Vibrational Side Bands
)Z _i[1V 2.6 Core Levels of Adsorbed Molecules
b
gDDys 2.7 Quantitative Chemical Analysis from Core-Level Intensities
3PEs$m9e References
WcJ{}V9 Grub1=6l 3. Charge-Excitation Final States: Satellites
vOj$-A--qU 3.1 Copper Dihalides; 3d Transition Metal Compounds
Hb$q}1+y 3.1.1 Characterization of a Satellite
<qy+@t 3.1.2 Analysis of Charge-Transfer Satellites
:_H88/?RR 3.1.3 Non-local Screening
DVS7N_cx2o 3.2 The 6-eV Satellite in Nickel
jCl[!L5/1 3.2.1 Resonance Photoemission
x!jhWX 3.2.2 Satellites in Other Metals
A^Zs?<C- 3.3 The Gunnarsson-Sch6nhammer Theory
.)GVb<w 3.4 Photoemission Signals and Narrow Bands in Metals
"D/ fB%h` References
fE:2MW!)* x('yBf 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
(j/O=$mJ 4.1 Theory
S- H3UND" 4.1.1 General
pqr"x2=. 4.1.2 Core-Line Shape
#.='dSj 4.1.3 Intrinsic Plasmons
MDq @:t 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
P}I*SV0 4.1.5 The Total Photoelectron Spectrum
=ht@7z8QM 4.2 Experimental Results
?7+2i\L 4.2.1 The Core Line Without Plasmons
:Rn9rdX 4.2.2 Core-Level Spectra Including Plasmoas
QM]^@2rK2 4.2.3 Valence-Band Spectra of the Simple Metals
X , 4.2.4 Simple Metals: A General Comment
Uoe?5Of(* 4.3 The Background Correction
Z4!3I@yZ References
5eLPn ~h/U ;Da 5. Valence Orbitals in Simple Molecules and Insulating Solids
4jW{IGW 5.1 UPS Spectra of Monatomic Gases
nr^p H. 5.2 Photoelectron Spectra of Diatomic Molecules
r__M1
!3 5.3 Binding Energy of the H2 Molecule
f,#xicSB* 5.4 Hydrides Isoelectronic with Noble Gases
a=O!\J Neon (Ne)
Pla EI p Hydrogen Fluoride (HF)
GND[f} Water (H2O)
@RP|?Xc{? Ammonia (NH3)
dB5DJ:$W$ Methane (CH4)
T,fz/5w 5.5 Spectra of the Alkali HMides
r:cUAe7# 5.6 Transition Metal Dihalides
_6' g]4 5.7 Hydrocarbons
D4|_?O3|m 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
'zb7:[[7% 5.7.2 Linear Polymers
k
y98/6 5.8 Insulating Solids with Valence d Electrons
7,zARWB!? 5.8.1 The NiO Problem
* y B-N;I 5.8.2 Mort Insulation
kYAvzuGRb 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
rBf?kDt6l 5.8.4Band Structures of Transition Metal Compounds
D/WS 5.9 High—Temperature Superconductors
Fk(5y) 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
L7- nPH 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
?zEF?LJoK 5.9.3 The Superconducting Gap
#<o#kJL 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
7E95"B&w 5.9.5 Core—Level Shifts
H.L@]~AyL 5.10 The Fermi Liquid and the Luttinger Liquid
{E/TC% 5.11 Adsorbed Molecules
FScQS.qF 5.11.1 Outline
:m\KQ1sq 5.11.2 CO on Metal Surfaces
1 GdD References
]YP?bP,: |@BN+o;`Om 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
q~n2VU4L* 6.1 Theory of Photoemission:A Summary of the Three-Step Model
"ivqh{ , 6.2 Discussion of the Photocurrent
v,&2!Zv 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
8=~>B@' 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
4B`Rz1QBy 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
U\ued=H 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
zTLn*? 6.3.1 Band Structure Regime
+$t%L 6.3.2 XPS Regime
ja/[PHq" 6.3.3 Surface Emission
T8-$[
2 6.3.4 One-Step Calculations
~<aB-.d 6.4 Thermal Effects
u$#7W>R 6.5 Dipole Selection Rules for Direct Optical Transitions
&iZYBa References
1'
m
$_ +0Gep}&z. 7.Band Structtire and Angular-Resolved Photoelectron Spectra
Pc'?p 7.1 Free-Electron Final—State Model
ydQS"]\g 7.2 Methods Employing Calculated Band Structures
p0K;m% 7.3 Methods for the Absolute Determination of the Crystal Momentum
m+vEs,W. 7.3.1 Triangulation or Energy Coincidence Method
cAS_?"V
a 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
b U NYTF{ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
=]e^8;e9 7.3.4 The Surface Emission Method and Electron Damping
y6}):| 7.3.5 The Very-Low-Energy Electron Diffraction Method
lWvd"Vlt 7.3.6 The Fermi Surface Method
gf?^yP ;V 7.3.7 Intensities and Their Use in Band-Structure Determinations
5>)jNtZ 7.3.8 Summary
7h1gU 7.4 Experimental Band Structures
NrcCUZ .:N 7.4.1 One- and Two-Dimensional Systems
pm\X*t}L 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
<q\)
o_tH 7..4.3UPS Band Structures and XPS Density of States
)/"7$2Aoy 7.5 A Comment
|`wsKr' References
sv"mba.J Kdu\`c-lB 8.Surface States, Surface Effects
yipD5,TC 8.1 Theoretical Considerations
@88i/ Z_ 8.2 Experimental Results on Surface States
a}fClI-u 8.3 Quantum-Well States
sG2 3[t8 8.4 Surface Core-Level Shifts
X vMG09 References
/T[ICd2J C+XZDY(=Z 9.Inverse Photoelectron Spectroscopy
493i*j5r)l 9.1 Surface States
bK\WdG\; 9.2 Bulk Band Structures
DWQQ615i 9.3 Adsorbed Molecules
e oSM@Isu References
@BUqQ9q: I^(#\vRW 10. Spin-Polarized Photoelectron Spectroscopy
}Y`<(V5: 10.1 General Description
2F@)nh 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
*Ne&SXg 10.3 Magnetic Dichroism
g ypq`F References
8G&+ GA.bRN2CI2 11. Photoelectron Diffraction
n~u3 11.1 Examples
I0+wczW,^ 11.2 Substrate Photoelectron Diffraction
PlH`(n# 11.3 Adsorbate Photoelectron Diffraction
F*t_lN5{ 11.4 Fermi Surface Scans
ir:~*| References
y*h1W4:^- l/zC##1+. Appendix
bDBO+qA A.1 Table of Binding Energies
W#I:j: p A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
@[tV_Z%,b A.3 Compilation of Work Functions
5;8B!%b References
<3=qLm Index