光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
/c3A> {RFpTh7f: 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
tow0/Jt Sx{vZS3 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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+OEO 目录
~)Z{ Yj9)S 1. Introduction and Basic Principles
&&Ruy(&]I 1.1 Historical Development
tQz =_;jy 1.2 The Electron Mean Free Path
3ZRi@=kWz 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
}pk)\^/w/ 1.4 Experimental Aspects
n.+%eYM< 1.5 Very High Resolution
m~`d<RM/ 1.6 The Theory of Photoemission
jI})\5<R 1.6.1 Core-Level Photoemission
:&*Y
Io 1.6.2 Valence-State Photoemission
/SDN7M]m! 1.6.3 Three-Step and One-Step Considerations
J^t-p U 1.7 Deviations from the Simple Theory of Photoemission
-E,
d)O`;$ References
V`*N2ztSL ^e*Tg& 2. Core Levels and Final States
MR$R# 2.1 Core-Level Binding Energies in Atoms and Molecules
88%7 2.1.1 The Equivalent-Core Approximation
FKhmg&+> 2.1.2 Chemical Shifts
7K"{}: 2.2 Core-Level Binding Energies in Solids
@~t^zI1 2.2.1 The Born-Haber Cycle in Insulators
VRe7Q0 2.2.2 Theory of Binding Energies
(9g L 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
qfJi[8". 2.3 Core Polarization
9g%1^$R 2.4 Final-State Multiplets in Rare-Earth Valence Bands
aMaICM 2.5 Vibrational Side Bands
]B8`b 2.6 Core Levels of Adsorbed Molecules
3<Qe'd
^ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
AT@m_d References
l|WdJn
o
i_/A,5TF 3. Charge-Excitation Final States: Satellites
wm1`<r^M. 3.1 Copper Dihalides; 3d Transition Metal Compounds
Y~ku?/"6T 3.1.1 Characterization of a Satellite
]O}TK^% 3.1.2 Analysis of Charge-Transfer Satellites
"cJ))v-' 3.1.3 Non-local Screening
>9-$E?Mt 3.2 The 6-eV Satellite in Nickel
T'VZ=l[ 3.2.1 Resonance Photoemission
$7J9Yzp?L 3.2.2 Satellites in Other Metals
dJvT2s.t[ 3.3 The Gunnarsson-Sch6nhammer Theory
\#)|6w- 3.4 Photoemission Signals and Narrow Bands in Metals
"AN*2)e4 References
<V[Qs3uo( ANIx0*Yl( 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
,"6Bw|s 4.1 Theory
HL8onNq 4.1.1 General
<Zb~tYp 4.1.2 Core-Line Shape
CGyw '0S 4.1.3 Intrinsic Plasmons
Sj=x.Tr\ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
V47z;oMXct 4.1.5 The Total Photoelectron Spectrum
xxnvz 4.2 Experimental Results
4F[4H\>' 4.2.1 The Core Line Without Plasmons
B/Jz$D 4.2.2 Core-Level Spectra Including Plasmoas
"Zh3, 4.2.3 Valence-Band Spectra of the Simple Metals
<b
JF&, 4.2.4 Simple Metals: A General Comment
_?VMSu 4.3 The Background Correction
CjRU3
(Q References
io&FW!J. }Gvu!a#R 5. Valence Orbitals in Simple Molecules and Insulating Solids
}dv$^4
*n 5.1 UPS Spectra of Monatomic Gases
+ *xi&|% 5.2 Photoelectron Spectra of Diatomic Molecules
.ei5+?V<i 5.3 Binding Energy of the H2 Molecule
u;
]4ydp 5.4 Hydrides Isoelectronic with Noble Gases
` x|=vu- Neon (Ne)
zf4\V F Hydrogen Fluoride (HF)
1]&FB{l Water (H2O)
a,ff8Qm Ammonia (NH3)
o;[?b'\[d Methane (CH4)
U ;%cp 5.5 Spectra of the Alkali HMides
If>bE!_BO 5.6 Transition Metal Dihalides
Uf}u`"$F 5.7 Hydrocarbons
4UxxmREx; 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
C@o8C%o 5.7.2 Linear Polymers
o;kxu(>yL' 5.8 Insulating Solids with Valence d Electrons
e 48N[p 5.8.1 The NiO Problem
[_BQ%7DU 5.8.2 Mort Insulation
?zk#}Ex1 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
=&K8~
5.8.4Band Structures of Transition Metal Compounds
urbSprdF 5.9 High—Temperature Superconductors
7:C_{\( 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
dug^o c1
5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
drwD3jx0xv 5.9.3 The Superconducting Gap
S+ 3lX7 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
d1qvS@ 5.9.5 Core—Level Shifts
ljP<WD 5.10 The Fermi Liquid and the Luttinger Liquid
` n#Db 5.11 Adsorbed Molecules
pw.K,?kYr 5.11.1 Outline
I/B *iW^ 5.11.2 CO on Metal Surfaces
31GqWN`>$ References
w}qLI4 A8X3|<n= 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
~ K/_51O' 6.1 Theory of Photoemission:A Summary of the Three-Step Model
Ur9L8EdC 6.2 Discussion of the Photocurrent
I7
= 4%)A 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
Tlm::S
6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
11iV{ h 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
1/3<u:: 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
hLICu[LC? 6.3.1 Band Structure Regime
kXroFLrY 6.3.2 XPS Regime
Z mc" 6.3.3 Surface Emission
HO_!/4hrU 6.3.4 One-Step Calculations
G' '9eV$ 6.4 Thermal Effects
*x-@}WY$U 6.5 Dipole Selection Rules for Direct Optical Transitions
z -c1,GOD References
Qv
WvS9] B,fVNpqo 7.Band Structtire and Angular-Resolved Photoelectron Spectra
ipe8U1Sc 7.1 Free-Electron Final—State Model
a@S{A5j 7.2 Methods Employing Calculated Band Structures
Bra}HjHO 7.3 Methods for the Absolute Determination of the Crystal Momentum
A2.GNk 7.3.1 Triangulation or Energy Coincidence Method
XI+GWNAmJ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
%"Ia]0 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
` 7P%muY. 7.3.4 The Surface Emission Method and Electron Damping
eg1Mdg\a 7.3.5 The Very-Low-Energy Electron Diffraction Method
%-KgR 7.3.6 The Fermi Surface Method
%x-`Y[ 7.3.7 Intensities and Their Use in Band-Structure Determinations
Ea)=K'Pz 7.3.8 Summary
Cq -URih 7.4 Experimental Band Structures
6rMXv0) 7.4.1 One- and Two-Dimensional Systems
M%YxhuT0 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
,4j^lgJ 7..4.3UPS Band Structures and XPS Density of States
D(WdI 7.5 A Comment
2~l +2.. References
MCAWn
H +bGO"* 8.Surface States, Surface Effects
&`IJ55Z-) 8.1 Theoretical Considerations
.lAPlJOO 8.2 Experimental Results on Surface States
25j?0P"& 8.3 Quantum-Well States
jmG)p|6 8.4 Surface Core-Level Shifts
I|l5e2j References
e>m+@4*sn 7_R[=t 9.Inverse Photoelectron Spectroscopy
zZW5M^z8 9.1 Surface States
"%YVAaN 9.2 Bulk Band Structures
ceuEsQ} 9.3 Adsorbed Molecules
u2S8DuJ References
*nK4XgD UX'q64F! 10. Spin-Polarized Photoelectron Spectroscopy
mM r$~^P: 10.1 General Description
?kK3%uJy& 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
8!{
}WLwb 10.3 Magnetic Dichroism
|\Q2L;4C References
vq+4so
)/S t`Rbn{ 11. Photoelectron Diffraction
h$XoR0 11.1 Examples
DX^8w?t 11.2 Substrate Photoelectron Diffraction
nvCp-Z$ 11.3 Adsorbate Photoelectron Diffraction
;jJ4H+8 11.4 Fermi Surface Scans
P]iJ"d]+X References
8!b>[Nsc CTe!jMZ= Appendix
-Q/wW4dE= A.1 Table of Binding Energies
::_bEmk A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
icQQLSU5 A.3 Compilation of Work Functions
1gnLKf c References
d)3jkHYEjj Index