光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
a
j13cC$ "74Rn"d5 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
^)%TQ. RK\$>KFE 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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L^%jR= SLi?E 目录
vNIQ1x5Za 1. Introduction and Basic Principles
T*bBw 1.1 Historical Development
nm{J 1.2 The Electron Mean Free Path
0NFYFd-50 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
LR:meCOI 1.4 Experimental Aspects
VPI;{0kh 1.5 Very High Resolution
w\`u|f;Aq 1.6 The Theory of Photoemission
4cQ|"sOzD 1.6.1 Core-Level Photoemission
V'm4DR#M 1.6.2 Valence-State Photoemission
1@6FV x 1.6.3 Three-Step and One-Step Considerations
Cj3C%W 1.7 Deviations from the Simple Theory of Photoemission
~Kll. References
]`H8r y2 \ Q E?.Fx 2. Core Levels and Final States
t{g7 :A 2.1 Core-Level Binding Energies in Atoms and Molecules
SMIr@*R 2.1.1 The Equivalent-Core Approximation
L>>Cx`ASi 2.1.2 Chemical Shifts
D)){"Q!b 2.2 Core-Level Binding Energies in Solids
0$1-5XY9 2.2.1 The Born-Haber Cycle in Insulators
U{|WN7Q:A 2.2.2 Theory of Binding Energies
gzd)7np B2 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
}N`m7PSf 2.3 Core Polarization
"inXHxqu/J 2.4 Final-State Multiplets in Rare-Earth Valence Bands
Izr_]% 2.5 Vibrational Side Bands
w^N3Ma 2.6 Core Levels of Adsorbed Molecules
2nkUvb%= 2.7 Quantitative Chemical Analysis from Core-Level Intensities
FNgC TO% References
"&{sE RYY @q<F_'7is 3. Charge-Excitation Final States: Satellites
n04lTME 3.1 Copper Dihalides; 3d Transition Metal Compounds
}35HKgqX 3.1.1 Characterization of a Satellite
T/Fj0' 3.1.2 Analysis of Charge-Transfer Satellites
1_V',0|`> 3.1.3 Non-local Screening
%5rC`9^ 3.2 The 6-eV Satellite in Nickel
0k):OVfm= 3.2.1 Resonance Photoemission
KoF_G[m 3.2.2 Satellites in Other Metals
H;k-@J 3.3 The Gunnarsson-Sch6nhammer Theory
&vHfuM` 3.4 Photoemission Signals and Narrow Bands in Metals
jTE~^ References
S :%SarhBD [)KLmL% 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
H=1Jq 4.1 Theory
y~-dQ7r 4.1.1 General
% >}{SS 4.1.2 Core-Line Shape
*r|)@K| 4.1.3 Intrinsic Plasmons
2GW.'\D 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
ML-?#jNa< 4.1.5 The Total Photoelectron Spectrum
CF0i72ul5 4.2 Experimental Results
]O1}q!s
4.2.1 The Core Line Without Plasmons
8AQ@?\Rc"2 4.2.2 Core-Level Spectra Including Plasmoas
vzPuk|q3 4.2.3 Valence-Band Spectra of the Simple Metals
ON
q =b I* 4.2.4 Simple Metals: A General Comment
FdFN4{<QZ 4.3 The Background Correction
tShyG!b References
VY]L<4BfGL gK+/wTQ% 5. Valence Orbitals in Simple Molecules and Insulating Solids
'%\FT-{ 5.1 UPS Spectra of Monatomic Gases
w</qUOx 5.2 Photoelectron Spectra of Diatomic Molecules
*p=a-s5- 5.3 Binding Energy of the H2 Molecule
lJ$j[Y 5.4 Hydrides Isoelectronic with Noble Gases
*CS2ndp Neon (Ne)
ux=0N]lc Hydrogen Fluoride (HF)
T2p;#)dP Water (H2O)
_DAj$$ Ru4 Ammonia (NH3)
}<KQ+ Methane (CH4)
8 bpYop7
L 5.5 Spectra of the Alkali HMides
A[6D40o 5.6 Transition Metal Dihalides
hH])0C 5.7 Hydrocarbons
lOJ3_8 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
E
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+:jx{*}jo 5.8 Insulating Solids with Valence d Electrons
C<u<:4^H 5.8.1 The NiO Problem
Pt^SlX^MM 5.8.2 Mort Insulation
uqFYa bU 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
y L|'K} 5.8.4Band Structures of Transition Metal Compounds
JK_(!
5.9 High—Temperature Superconductors
}V I}O{ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
O[RivHCY 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
@M_p3[c\ 5.9.3 The Superconducting Gap
DSX.84 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
OD~B2MpM> 5.9.5 Core—Level Shifts
.|Y&,?k|Y 5.10 The Fermi Liquid and the Luttinger Liquid
( {}Z
' 5.11 Adsorbed Molecules
&8R!`uh1 5.11.1 Outline
.lE7v -e 5.11.2 CO on Metal Surfaces
/@qnEP% References
f&ri=VJY\T 75?z" i 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
iB0#Z_ 6.1 Theory of Photoemission:A Summary of the Three-Step Model
I2G:jMPy 6.2 Discussion of the Photocurrent
zvAUF8'_ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
66 @#V 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
RP|/rd]-k 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
-H-:b7 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
roNRbA] 6.3.1 Band Structure Regime
3d81]!n 6.3.2 XPS Regime
X+LG Z4]D 6.3.3 Surface Emission
+2?=W1` 6.3.4 One-Step Calculations
qOM" ?av 6.4 Thermal Effects
6L}}3b h 6.5 Dipole Selection Rules for Direct Optical Transitions
7 S6@[-E References
`j)S7KN Fx6]x$3 7.Band Structtire and Angular-Resolved Photoelectron Spectra
O4lHR6M2 7.1 Free-Electron Final—State Model
E=eK(t(8 7.2 Methods Employing Calculated Band Structures
pN?geF~t| 7.3 Methods for the Absolute Determination of the Crystal Momentum
9qcA+gz:| 7.3.1 Triangulation or Energy Coincidence Method
{$H-7-O$ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
{a6cA=WTPd 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
M|DVFC 7.3.4 The Surface Emission Method and Electron Damping
+$y%H 7.3.5 The Very-Low-Energy Electron Diffraction Method
BWG*UjP
M 7.3.6 The Fermi Surface Method
qGVf!R 7.3.7 Intensities and Their Use in Band-Structure Determinations
%!X9>i> 7.3.8 Summary
6zR9(c:a~ 7.4 Experimental Band Structures
P~d&PhOe 7.4.1 One- and Two-Dimensional Systems
JVxGS{Z 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
QMAineO 7..4.3UPS Band Structures and XPS Density of States
d.Im{-S 7.5 A Comment
IF~E; References
R;l;;dC= R&MdwTa 8.Surface States, Surface Effects
bbe$6x wi 8.1 Theoretical Considerations
1r?hRJ:' 8.2 Experimental Results on Surface States
vmsrypm 8.3 Quantum-Well States
734f&2 8.4 Surface Core-Level Shifts
?_V&~?r References
b<bj5m4fz> s:ZYiZ- 9.Inverse Photoelectron Spectroscopy
Q}6!t$Vk 9.1 Surface States
@]F1J 9.2 Bulk Band Structures
j0`)m R} 9.3 Adsorbed Molecules
w 8BSY References
/?*GJN#
=`pH2SJT 10. Spin-Polarized Photoelectron Spectroscopy
I 6-.;)McO 10.1 General Description
9Rd&Jq^ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
0(|Yy/Yq 10.3 Magnetic Dichroism
o|G[/o2 References
B9(@. oT0TbZu% 11. Photoelectron Diffraction
?[VL
2dP0 11.1 Examples
OUFx M 11.2 Substrate Photoelectron Diffraction
@
Cd#\D| 11.3 Adsorbate Photoelectron Diffraction
q"9 2][} 11.4 Fermi Surface Scans
X 7R&>Pf References
%iR"eEE m-u0U Appendix
QCAoL.v A.1 Table of Binding Energies
i9koh3R\ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
/nWBo l, A.3 Compilation of Work Functions
*hvC0U@3 References
%5$)w;p.$' Index