光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
3X Y"s" U2`:' 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
5xc e1[ d\-*Fmp(S 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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7Lj E!X>C^ 目录
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+>T@MH 1. Introduction and Basic Principles
|zRrGQYm 1.1 Historical Development
Q)E3)), 1.2 The Electron Mean Free Path
6# bTlmcg 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
n:a~=^IV 1.4 Experimental Aspects
A#`$#CO 1.5 Very High Resolution
Swf%WuDj 1.6 The Theory of Photoemission
`\##M= 1.6.1 Core-Level Photoemission
+L=Xc^ 1.6.2 Valence-State Photoemission
Ro{xprE1 1.6.3 Three-Step and One-Step Considerations
;Mmu} 1.7 Deviations from the Simple Theory of Photoemission
jcC"vr'u| References
%V1j M E#d~.#uH 2. Core Levels and Final States
*|q{(KX 2.1 Core-Level Binding Energies in Atoms and Molecules
mCn:{G8+ 2.1.1 The Equivalent-Core Approximation
,5U[#6^ 2.1.2 Chemical Shifts
k"=*' 2.2 Core-Level Binding Energies in Solids
I\Y N! 2.2.1 The Born-Haber Cycle in Insulators
]*MVC/R, 2.2.2 Theory of Binding Energies
p/eaO{6 6 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
t!xdKX& } 2.3 Core Polarization
4YY!oDN: 2.4 Final-State Multiplets in Rare-Earth Valence Bands
GfSD%" 2.5 Vibrational Side Bands
IPn!iv) 2.6 Core Levels of Adsorbed Molecules
w3VgGc~ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
X!{K`~DRX References
"1\GU1x W9}
,f 3. Charge-Excitation Final States: Satellites
$[Ut])4
~ 3.1 Copper Dihalides; 3d Transition Metal Compounds
r(>812^\ 3.1.1 Characterization of a Satellite
!Mgo~h"]# 3.1.2 Analysis of Charge-Transfer Satellites
qHheF%[\5 3.1.3 Non-local Screening
GwA\>qXw 3.2 The 6-eV Satellite in Nickel
#I MaN% 3.2.1 Resonance Photoemission
: &nF> 3.2.2 Satellites in Other Metals
|Ch,C 3.3 The Gunnarsson-Sch6nhammer Theory
com4@NK 3.4 Photoemission Signals and Narrow Bands in Metals
l['p^-I References
Q(Yn8t <H#0pFB 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
0$b4\.0>~ 4.1 Theory
E 6MeM'sx 4.1.1 General
V60"j( 4.1.2 Core-Line Shape
MtF^}/0w!` 4.1.3 Intrinsic Plasmons
,o0Kev z 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
0t(c84o5 4.1.5 The Total Photoelectron Spectrum
unqUs08 4.2 Experimental Results
] ZP!y 4.2.1 The Core Line Without Plasmons
]a.^F 4.2.2 Core-Level Spectra Including Plasmoas
3mopTzs) 4.2.3 Valence-Band Spectra of the Simple Metals
KSS]% 66Y 4.2.4 Simple Metals: A General Comment
Y~!A"$ 4.3 The Background Correction
g'w"U9tjO References
RX_f[ 1R yE8DdP 5. Valence Orbitals in Simple Molecules and Insulating Solids
AEx VKy 5.1 UPS Spectra of Monatomic Gases
m6^#pqSL 5.2 Photoelectron Spectra of Diatomic Molecules
d@$bPQQ$, 5.3 Binding Energy of the H2 Molecule
+Q"~2_q5/; 5.4 Hydrides Isoelectronic with Noble Gases
h-O;5.m-P Neon (Ne)
!Ea9
fe Hydrogen Fluoride (HF)
O#):*II`9 Water (H2O)
av5a2r0W1 Ammonia (NH3)
y<m[9FC} Methane (CH4)
z`$c4p6G6 5.5 Spectra of the Alkali HMides
VR1[-OE
5.6 Transition Metal Dihalides
H2Z
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O0
Uh 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
$B<:SuV# 5.7.2 Linear Polymers
0WKS 5.8 Insulating Solids with Valence d Electrons
tux0}|[^' 5.8.1 The NiO Problem
?WqaT) l~ 5.8.2 Mort Insulation
;!=i|"PG 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Ahba1\,N$ 5.8.4Band Structures of Transition Metal Compounds
sV5") /~ 5.9 High—Temperature Superconductors
? EHheZ{ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
F#)bGi 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
fI<d&5&g 5.9.3 The Superconducting Gap
JKrS;J^97v 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
z$d<ep{6 5.9.5 Core—Level Shifts
&Ruq8n< 5.10 The Fermi Liquid and the Luttinger Liquid
Nmt~1.J 5.11 Adsorbed Molecules
XR[=W(m} 5.11.1 Outline
h<>yzr3fN 5.11.2 CO on Metal Surfaces
'+vmC*-I( References
@OFxnF` xs Pt 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
{,*vMQ<^ 6.1 Theory of Photoemission:A Summary of the Three-Step Model
-])=\n!= 6.2 Discussion of the Photocurrent
Q (q&(/ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
IoK/ 2Gp 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
-r3
s{HO 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
djw\%00 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
%yjD<2J; 6.3.1 Band Structure Regime
v@M^ukk'} 6.3.2 XPS Regime
zA.0Sm 6.3.3 Surface Emission
wsH _pF 6.3.4 One-Step Calculations
1kUlQ*[<| 6.4 Thermal Effects
&dK!+ 6.5 Dipole Selection Rules for Direct Optical Transitions
79d(UG'O References
,p(&G_ $)8,dS 7.Band Structtire and Angular-Resolved Photoelectron Spectra
<Q- m & 7.1 Free-Electron Final—State Model
1 JIU5u) 7.2 Methods Employing Calculated Band Structures
+w?R4Sxjn 7.3 Methods for the Absolute Determination of the Crystal Momentum
tk=S4/VWv 7.3.1 Triangulation or Energy Coincidence Method
:Y1;= W 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
Kdp($L9r 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
&(32s! qH 7.3.4 The Surface Emission Method and Electron Damping
W-&V:S{< 7.3.5 The Very-Low-Energy Electron Diffraction Method
XGC\6?L~ 7.3.6 The Fermi Surface Method
Vq{3:QBR 7.3.7 Intensities and Their Use in Band-Structure Determinations
3b]M\F9 7.3.8 Summary
"&4r!2A 7.4 Experimental Band Structures
Av5:/c.B 7.4.1 One- and Two-Dimensional Systems
t8xXGWk0 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
NT5'U 7..4.3UPS Band Structures and XPS Density of States
02*qf:kTnA 7.5 A Comment
0{8L^
jB/ References
!d!u{1Y& kL0K[O 8.Surface States, Surface Effects
{N/%%O.b 8.1 Theoretical Considerations
|rZMcl/ 8.2 Experimental Results on Surface States
E0&d*BI2 8.3 Quantum-Well States
6},[HpXRc4 8.4 Surface Core-Level Shifts
Nf3UVK8LtS References
Q%d1n*;+ NY^0$h 9.Inverse Photoelectron Spectroscopy
bGgpPV 9.1 Surface States
CPRVSN0b{4 9.2 Bulk Band Structures
ykPiZK 9.3 Adsorbed Molecules
&g^*ep~|# References
dpNERc5 F N=WU<
5 10. Spin-Polarized Photoelectron Spectroscopy
P+|L6w*|[ 10.1 General Description
)=29Hm" 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
A(
vdlj 10.3 Magnetic Dichroism
Pn[oo_)s References
MsP6C)dz foQo`}"5 11. Photoelectron Diffraction
\y=oZk4 11.1 Examples
\I523$a 11.2 Substrate Photoelectron Diffraction
9CeR^/i 11.3 Adsorbate Photoelectron Diffraction
hp9U 11.4 Fermi Surface Scans
xSK#ovH2 References
Kob,}NgqZ mOn_#2=KF Appendix
\'*M
}G A.1 Table of Binding Energies
(A6~mi r! A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
/kkUEo+ A.3 Compilation of Work Functions
$Emu*' References
@y`xFPB Index