光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
pbLGe' ^npJUa 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
!h: Q jg_n 7 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
,S!w'0k|n Gx'TkU=
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jO8k6<l u|fXP)>. 目录
z<&m*0WYA 1. Introduction and Basic Principles
A5nO= 1.1 Historical Development
f*fE}; 1.2 The Electron Mean Free Path
Cq\I''~8 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
!p[`IWZ 1.4 Experimental Aspects
>|*yh~ 1.5 Very High Resolution
W^3;F1 1.6 The Theory of Photoemission
][7p+IsB 1.6.1 Core-Level Photoemission
?WFh',`: 1.6.2 Valence-State Photoemission
|W7rr1]~S 1.6.3 Three-Step and One-Step Considerations
cdTsRS;E 1.7 Deviations from the Simple Theory of Photoemission
s'u(B]E References
(
u`W!{1\ YRcps0Dx9 2. Core Levels and Final States
fn}UBzED\ 2.1 Core-Level Binding Energies in Atoms and Molecules
hfrnxeM#~ 2.1.1 The Equivalent-Core Approximation
o6L9UdT 2.1.2 Chemical Shifts
zp4W'8
2.2 Core-Level Binding Energies in Solids
L
CSeOR 2.2.1 The Born-Haber Cycle in Insulators
(OmH~lSO. 2.2.2 Theory of Binding Energies
YZE.@Rz 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
H{(]9{ 2.3 Core Polarization
2R.2D'4)` 2.4 Final-State Multiplets in Rare-Earth Valence Bands
>M;u*Go`QO 2.5 Vibrational Side Bands
lA;a 2.6 Core Levels of Adsorbed Molecules
xf,5R9g/ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
aGoE,5 References
.p&Yr%~ .}`hCt08 3. Charge-Excitation Final States: Satellites
#T3h}= 3.1 Copper Dihalides; 3d Transition Metal Compounds
ziEz.Wn" 3.1.1 Characterization of a Satellite
^^Jnv{) 3.1.2 Analysis of Charge-Transfer Satellites
+j[oE I`e 3.1.3 Non-local Screening
la^
DjHA$ 3.2 The 6-eV Satellite in Nickel
nH[+n `{o 3.2.1 Resonance Photoemission
g,kzQ}_ 3.2.2 Satellites in Other Metals
)^O-X.1 3.3 The Gunnarsson-Sch6nhammer Theory
%fjuG 3.4 Photoemission Signals and Narrow Bands in Metals
q/gB<p9 References
{`"#yl6" `-UJ /{ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
-?a<qa?$ 4.1 Theory
- u3e5gW 4.1.1 General
csQfic 4.1.2 Core-Line Shape
LE=k 4.1.3 Intrinsic Plasmons
ma& To= 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
K%j&/T j1 4.1.5 The Total Photoelectron Spectrum
buMqF-j 4.2 Experimental Results
_GoVx=t
4.2.1 The Core Line Without Plasmons
7;}l\VXHm 4.2.2 Core-Level Spectra Including Plasmoas
1np^(['ih 4.2.3 Valence-Band Spectra of the Simple Metals
#AViM_u 4.2.4 Simple Metals: A General Comment
Tpr tE.mP 4.3 The Background Correction
lmCZ8 j(FF References
XcfKx@l b=[?b+ 5. Valence Orbitals in Simple Molecules and Insulating Solids
@QEqB_W 5.1 UPS Spectra of Monatomic Gases
2+"r~#K* 5.2 Photoelectron Spectra of Diatomic Molecules
lWZuXb,G 5.3 Binding Energy of the H2 Molecule
Y)I8eU{Wl( 5.4 Hydrides Isoelectronic with Noble Gases
cO#oH2} Neon (Ne)
)Y]/^1hx Hydrogen Fluoride (HF)
/VTM 9)u Water (H2O)
+cB&Mi5 Ammonia (NH3)
&tI#T)SSs Methane (CH4)
\h{r;#g 5.5 Spectra of the Alkali HMides
`,>wC+} 5.6 Transition Metal Dihalides
7C,T&g
1: 5.7 Hydrocarbons
v."Dnl 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
>'=MH2; 5.7.2 Linear Polymers
9'~-U 5.8 Insulating Solids with Valence d Electrons
cma*Dc 5.8.1 The NiO Problem
!u;>Wyd W 5.8.2 Mort Insulation
kCP$I732 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
eE8ULtO 5.8.4Band Structures of Transition Metal Compounds
'cd N3i( 5.9 High—Temperature Superconductors
%i0\1hhV< 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
<:;^'x>! 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
)R)a@op 5.9.3 The Superconducting Gap
9IZu$- 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
,/Cq
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]$iN#d|ZU 5.10 The Fermi Liquid and the Luttinger Liquid
h
y-cG%f 5.11 Adsorbed Molecules
LXfCmc9|Z 5.11.1 Outline
{1lO 5.11.2 CO on Metal Surfaces
~oD8Rnf References
)@g;j> `$5UHa2/ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
f@V3\Z/6E 6.1 Theory of Photoemission:A Summary of the Three-Step Model
G*8GGWB^a 6.2 Discussion of the Photocurrent
~P f5ORoe 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
":;@Hnb/ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
HK=[U9 o? 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
A}VYb:u/ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
hkL5HzWn 6.3.1 Band Structure Regime
$17
su') 6.3.2 XPS Regime
pw020}` 6.3.3 Surface Emission
uQCo6"e 6.3.4 One-Step Calculations
|;vi*u 6.4 Thermal Effects
O/Y)&VG7 6.5 Dipole Selection Rules for Direct Optical Transitions
e 9$C#D>D References
x^= M6;: M#jN-ix 7.Band Structtire and Angular-Resolved Photoelectron Spectra
h8 @ 7.1 Free-Electron Final—State Model
kJK,6mN 7.2 Methods Employing Calculated Band Structures
SAv<& 7.3 Methods for the Absolute Determination of the Crystal Momentum
d+L#t 7.3.1 Triangulation or Energy Coincidence Method
34AP(3w 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
8\ha@&p 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
?/#}ZZK^ 7.3.4 The Surface Emission Method and Electron Damping
7S^""*Q^ 7.3.5 The Very-Low-Energy Electron Diffraction Method
'` CspY 7.3.6 The Fermi Surface Method
P>QpvSd_# 7.3.7 Intensities and Their Use in Band-Structure Determinations
@1RP/y% 7.3.8 Summary
-e@! 7.4 Experimental Band Structures
dKhA$f~ 7.4.1 One- and Two-Dimensional Systems
JC;^--0(z 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
OyG"1F 7..4.3UPS Band Structures and XPS Density of States
h1"zV6U 7.5 A Comment
8nNsrat References
CC >=UF <eN R8(P 8.Surface States, Surface Effects
Uu p(6`7 8.1 Theoretical Considerations
&Vk; VM`5 8.2 Experimental Results on Surface States
]gb= 8.3 Quantum-Well States
B0UJq./` 8.4 Surface Core-Level Shifts
gQWd&)'muf References
2(YPz|~W JcO08n 9.Inverse Photoelectron Spectroscopy
|1=
!;.# 9.1 Surface States
"dh:-x6 9.2 Bulk Band Structures
q!,zq 9.3 Adsorbed Molecules
d.<~&.-$ References
4/>Our 5 748CD{KxW 10. Spin-Polarized Photoelectron Spectroscopy
QP I+y8N= 10.1 General Description
WgR4Ix^L# 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
S5=Udd" 10.3 Magnetic Dichroism
|01?w | References
dWRrG-' ^C^*,V3 11. Photoelectron Diffraction
(X[2TT3j! 11.1 Examples
$A\m>*@ 11.2 Substrate Photoelectron Diffraction
@]CF&: P A 11.3 Adsorbate Photoelectron Diffraction
< a rZbM 11.4 Fermi Surface Scans
!E\[SjY@J References
eARk
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0y* Appendix
WT3gNNx| A.1 Table of Binding Energies
S9sR# A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
w2gf&Lc\ A.3 Compilation of Work Functions
|VH!)vD References
&R-H"kK? Index