光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
1dFa@<5 y4@gGC= 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
)6{<
i5nJ\ t9FDU 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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n9%]-s\Hn _qn?2u3mnR 目录
=E(#YCx 1. Introduction and Basic Principles
RRADg^}l|" 1.1 Historical Development
|;+qld[4z 1.2 The Electron Mean Free Path
BcQEG *N 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
03=5Nof1 1.4 Experimental Aspects
TVaA>]Fv 1.5 Very High Resolution
?cKZ_c 1.6 The Theory of Photoemission
9sSN<7 1.6.1 Core-Level Photoemission
+r]zs^' 1.6.2 Valence-State Photoemission
/c` ^iPb 1.6.3 Three-Step and One-Step Considerations
,zhJY ?sk 1.7 Deviations from the Simple Theory of Photoemission
5\bJR0I@ References
bFY~oa%C rh!;|xB|+ 2. Core Levels and Final States
DkDoA;m 2.1 Core-Level Binding Energies in Atoms and Molecules
P(,?#+]- 2.1.1 The Equivalent-Core Approximation
PT'MNH 2.1.2 Chemical Shifts
:@eHX& 2.2 Core-Level Binding Energies in Solids
:ofBzTNwZ 2.2.1 The Born-Haber Cycle in Insulators
j.m(ltGh 2.2.2 Theory of Binding Energies
aJhxc<"e 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
***a2Z/( 2.3 Core Polarization
IXpc,l ` 2.4 Final-State Multiplets in Rare-Earth Valence Bands
8|@9{ 2.5 Vibrational Side Bands
NBYH;h P 2.6 Core Levels of Adsorbed Molecules
yVX8e I 2.7 Quantitative Chemical Analysis from Core-Level Intensities
iafE5b) References
d$t40+v ~g6 3qs 3. Charge-Excitation Final States: Satellites
MHU74//fe 3.1 Copper Dihalides; 3d Transition Metal Compounds
E{?au]y$J 3.1.1 Characterization of a Satellite
a0=WfeT 3.1.2 Analysis of Charge-Transfer Satellites
MSw$_d 3.1.3 Non-local Screening
-C-yQ.>\T# 3.2 The 6-eV Satellite in Nickel
:YP # 3.2.1 Resonance Photoemission
dOFD5}_ 3.2.2 Satellites in Other Metals
6gH{R$7L= 3.3 The Gunnarsson-Sch6nhammer Theory
0hY{<^"Y 3.4 Photoemission Signals and Narrow Bands in Metals
^7^N}x@ References
,ho3 ~q+hV+fa> 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
Ts.wh>` 4.1 Theory
l(;Kij 4.1.1 General
_n;;][]S 4.1.2 Core-Line Shape
l+*&:Q/ 4.1.3 Intrinsic Plasmons
|'d>JT: 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
pO7Zs 4.1.5 The Total Photoelectron Spectrum
i,IB!x 4.2 Experimental Results
:Dt~e| 4.2.1 The Core Line Without Plasmons
g[H',)A) 4.2.2 Core-Level Spectra Including Plasmoas
oGa^/:6L 4.2.3 Valence-Band Spectra of the Simple Metals
30>3 !Xqa 4.2.4 Simple Metals: A General Comment
#P<N^[m 4.3 The Background Correction
Q GZyL)Q References
83%)/_& y5r4+2B 5. Valence Orbitals in Simple Molecules and Insulating Solids
^r6!l. 5.1 UPS Spectra of Monatomic Gases
En{`@JsM 5.2 Photoelectron Spectra of Diatomic Molecules
TaE~s 5.3 Binding Energy of the H2 Molecule
_>+8og/%@ 5.4 Hydrides Isoelectronic with Noble Gases
nKa$1RMO Neon (Ne)
V#REjsf,t- Hydrogen Fluoride (HF)
]:>,A@7 Water (H2O)
EU7|,>a Ammonia (NH3)
M(x$xAiD Methane (CH4)
Lk\P7w{ 5.5 Spectra of the Alkali HMides
Ae]sGU|?' 5.6 Transition Metal Dihalides
L){iA-k;Ec 5.7 Hydrocarbons
w| `h[/, 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
0:w"M<80 5.7.2 Linear Polymers
'k;rH!R 5.8 Insulating Solids with Valence d Electrons
U_x )#,4 5.8.1 The NiO Problem
Ar*^;/ 5.8.2 Mort Insulation
4}+/F}TbJ5 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Wbr+KX8) 5.8.4Band Structures of Transition Metal Compounds
CI353-` 5.9 High—Temperature Superconductors
v~QHMg 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
}>)[<;M>% 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
8>hwK )av 5.9.3 The Superconducting Gap
@)o^uU T 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
^8.]d~j 5.9.5 Core—Level Shifts
>B]'fUt5a 5.10 The Fermi Liquid and the Luttinger Liquid
I:K"'R^ 5.11 Adsorbed Molecules
^[:p|U2mA 5.11.1 Outline
!;?+>R)h 5.11.2 CO on Metal Surfaces
cufH?Xg< References
M5gWD==uP S<'[%ihx 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
,) J~ ,^f6 6.1 Theory of Photoemission:A Summary of the Three-Step Model
$Y69@s %f 6.2 Discussion of the Photocurrent
;>n,:355L 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
pe^u$YE 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
94B\5I} 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
UQ{L{H 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
:q#Xq;Wp 6.3.1 Band Structure Regime
`BlI@6th 6.3.2 XPS Regime
9eH$XYy 6.3.3 Surface Emission
0u\GO; 6.3.4 One-Step Calculations
n2iJ%_zp 6.4 Thermal Effects
JvY}-}?c 6.5 Dipole Selection Rules for Direct Optical Transitions
dqN5]Sb2B References
~l)-wNqR4r &Z`#cMR{H 7.Band Structtire and Angular-Resolved Photoelectron Spectra
}GeSu|m( 7.1 Free-Electron Final—State Model
^]TVo\,N 7.2 Methods Employing Calculated Band Structures
8F'x=lIO 7.3 Methods for the Absolute Determination of the Crystal Momentum
I:mr}mv=i 7.3.1 Triangulation or Energy Coincidence Method
Hy^N!rBxfO 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
17`1SGZ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
ZIQ
[bE7 7.3.4 The Surface Emission Method and Electron Damping
#{?qNl8F*J 7.3.5 The Very-Low-Energy Electron Diffraction Method
=3L;Z[^9 7.3.6 The Fermi Surface Method
]*AR,0N& 7.3.7 Intensities and Their Use in Band-Structure Determinations
?#fu.YE\ 7.3.8 Summary
zG(\+4GE! 7.4 Experimental Band Structures
1fpQLaT 7.4.1 One- and Two-Dimensional Systems
V,cBk 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Evedc*z~P 7..4.3UPS Band Structures and XPS Density of States
q^Y-}=w 7.5 A Comment
*{L)dW+: References
s,]z[qB#$ ME*LHr, 8.Surface States, Surface Effects
g"}%2~Urf 8.1 Theoretical Considerations
k7T`bYv 8.2 Experimental Results on Surface States
"hsb8- 8.3 Quantum-Well States
%^ !,t:d 8.4 Surface Core-Level Shifts
K~R`%r_ References
R^Y
<RI )v.=jup[ 9.Inverse Photoelectron Spectroscopy
d>mo~ 9.1 Surface States
EwvoQ$#jv 9.2 Bulk Band Structures
c}2jmwq
9.3 Adsorbed Molecules
]GW]dM References
ivN&HAxI@ t:'Mh9h7u 10. Spin-Polarized Photoelectron Spectroscopy
C$XU%5qi 10.1 General Description
sM `DL 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
;EP:o%r 10.3 Magnetic Dichroism
iMDM1}b References
ZZzMO6US0 .nx2";oi 11. Photoelectron Diffraction
2*^j 11.1 Examples
{+Rog/;S' 11.2 Substrate Photoelectron Diffraction
|l]XpWV 11.3 Adsorbate Photoelectron Diffraction
^f4s"T 11.4 Fermi Surface Scans
k@k&}N0{ References
rE.;g^4p 8|l\EVV6 Appendix
paCV!tP A.1 Table of Binding Energies
P*3BB>FO A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
1cpiHZa A.3 Compilation of Work Functions
.uMn0PE References
0tT(W^ho g Index