光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
Jo%`N#jG isU7nlc! 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
--S1p0 X#;n Gq)5 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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0.pZlv DIsK+1 目录
{ XI 0KiE 1. Introduction and Basic Principles
}j+Af["W? 1.1 Historical Development
g`7C1&U*T 1.2 The Electron Mean Free Path
VtP^fM^{ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
[j3-a4Wu 1.4 Experimental Aspects
{oXU)9vj 1.5 Very High Resolution
T]er_n 1.6 The Theory of Photoemission
J&P{7a 1.6.1 Core-Level Photoemission
3o_)x 1.6.2 Valence-State Photoemission
@euH[< 1.6.3 Three-Step and One-Step Considerations
GtuA94=!V& 1.7 Deviations from the Simple Theory of Photoemission
|Do+=Gr$t@ References
(M0"I1g|w >m$jJlAv8 2. Core Levels and Final States
HZASIsl 2.1 Core-Level Binding Energies in Atoms and Molecules
<QuIX A 2.1.1 The Equivalent-Core Approximation
L/J1; 2.1.2 Chemical Shifts
34*73WxK 2.2 Core-Level Binding Energies in Solids
}Z/[ " 2.2.1 The Born-Haber Cycle in Insulators
UC
e{V ]T 2.2.2 Theory of Binding Energies
Ob ~7w[n3 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
\T'.b93~B 2.3 Core Polarization
&9+]{jXF 2.4 Final-State Multiplets in Rare-Earth Valence Bands
H^Mfj!S 2.5 Vibrational Side Bands
xNrPj8V<Y 2.6 Core Levels of Adsorbed Molecules
2Kkm-#p7 2.7 Quantitative Chemical Analysis from Core-Level Intensities
-gQtw%
`x References
N!PPL"5z @:dn\{Zsea 3. Charge-Excitation Final States: Satellites
Gye84C2E= 3.1 Copper Dihalides; 3d Transition Metal Compounds
aM7e?.rU 3.1.1 Characterization of a Satellite
SD/=e3 3.1.2 Analysis of Charge-Transfer Satellites
]8n*f o2# 3.1.3 Non-local Screening
@=7[ KM b 3.2 The 6-eV Satellite in Nickel
f};RtRo2 3.2.1 Resonance Photoemission
(U{,D1? 3.2.2 Satellites in Other Metals
R7o'V* d 3.3 The Gunnarsson-Sch6nhammer Theory
]/9@^D}& 3.4 Photoemission Signals and Narrow Bands in Metals
YujR}=B!/ References
"[QQ(]={ -lY,lC>{ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
-Qy@-s $ 4.1 Theory
a
Xn:hn~O 4.1.1 General
k/Z]zZC 4.1.2 Core-Line Shape
}WA= 4.1.3 Intrinsic Plasmons
[+F6C 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
(+CNs 4.1.5 The Total Photoelectron Spectrum
{e+}jZ[L 4.2 Experimental Results
_v#Vf*# 4.2.1 The Core Line Without Plasmons
/n2qW.qJ> 4.2.2 Core-Level Spectra Including Plasmoas
&wX568o 4.2.3 Valence-Band Spectra of the Simple Metals
%A3ci[$g 4.2.4 Simple Metals: A General Comment
ynZp|'b?< 4.3 The Background Correction
q)l1tC72 References
Zv0'OX~8i j].=,M<dxE 5. Valence Orbitals in Simple Molecules and Insulating Solids
MpVZL29) 5.1 UPS Spectra of Monatomic Gases
%p(X*mVX 5.2 Photoelectron Spectra of Diatomic Molecules
@CtnV| 5.3 Binding Energy of the H2 Molecule
&s(mbpV 5.4 Hydrides Isoelectronic with Noble Gases
s$JO3-) Neon (Ne)
w)Xn MyD(P Hydrogen Fluoride (HF)
_ea|E 8 Water (H2O)
!C;$5(k Ammonia (NH3)
cCx_tGR" Methane (CH4)
*`_2uBz 5.5 Spectra of the Alkali HMides
S l`F` 5.6 Transition Metal Dihalides
Kr'Yz! 5.7 Hydrocarbons
Hmx
Y{KB 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
K0{
,*>C 5.7.2 Linear Polymers
NY
GWA4L 5.8 Insulating Solids with Valence d Electrons
]PlLy:( 5.8.1 The NiO Problem
7<*,O&![| 5.8.2 Mort Insulation
*7w,o?l 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
K8JshFIe 5.8.4Band Structures of Transition Metal Compounds
g5;Ig 5.9 High—Temperature Superconductors
w.(?O; 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
;lQ>>[* 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
M1q_gHA 5.9.3 The Superconducting Gap
ydTd.` 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
7.*Mmx~]= 5.9.5 Core—Level Shifts
d3]<'B:nb 5.10 The Fermi Liquid and the Luttinger Liquid
z?Cez*.h> 5.11 Adsorbed Molecules
6VtN4c.Q 5.11.1 Outline
YmwXA e: 5.11.2 CO on Metal Surfaces
rh DiIO_ References
,YBe|3 FOAXm4" 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
%l3f . 6.1 Theory of Photoemission:A Summary of the Three-Step Model
/?1^&a 6.2 Discussion of the Photocurrent
_/J`v`}G 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
[NK&s:wMk 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
d/[kky} 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
i~LY 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
IAJ+n0U 6.3.1 Band Structure Regime
cAn_:^ 6.3.2 XPS Regime
^x2@KMKXZ 6.3.3 Surface Emission
oL7F^34; 6.3.4 One-Step Calculations
P
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(e#f 6.5 Dipole Selection Rules for Direct Optical Transitions
L1kAAR References
XG E.*aI }LY)FT4n 7.Band Structtire and Angular-Resolved Photoelectron Spectra
%R<xe.X 7.1 Free-Electron Final—State Model
XM) 7.2 Methods Employing Calculated Band Structures
`PT'Lakf;3 7.3 Methods for the Absolute Determination of the Crystal Momentum
; Kh!OBZFo 7.3.1 Triangulation or Energy Coincidence Method
WFTwFm6 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
8 q> 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
L+CPT 7.3.4 The Surface Emission Method and Electron Damping
9w6 uoM 7.3.5 The Very-Low-Energy Electron Diffraction Method
Wjli(sT#- 7.3.6 The Fermi Surface Method
VV/aec8 7.3.7 Intensities and Their Use in Band-Structure Determinations
=z4J[8bb 7.3.8 Summary
Mzw:c# 7.4 Experimental Band Structures
{mB!mbr
7.4.1 One- and Two-Dimensional Systems
Y(Y#H$w 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Svdmg D! 7..4.3UPS Band Structures and XPS Density of States
89m9iJ= 7.5 A Comment
M[C)b\ References
%Iiu#- 'B t)mc~M9w 8.Surface States, Surface Effects
iZ4"@G:, 8.1 Theoretical Considerations
Z^J7r&\V 8.2 Experimental Results on Surface States
m%b#B>J,n 8.3 Quantum-Well States
!gcea?I 8.4 Surface Core-Level Shifts
ZcN#jnb0/ References
rN,T}M=2 7gx?LI_e 9.Inverse Photoelectron Spectroscopy
a+j"8tHu$ 9.1 Surface States
dl(!{tZ# 9.2 Bulk Band Structures
0]zMb^wo 9.3 Adsorbed Molecules
lx7]rkWo|a References
4HpKKhv" L#S|2L_hC 10. Spin-Polarized Photoelectron Spectroscopy
j@{ B 8 10.1 General Description
X6BOB? 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
OlgM7Vrl 10.3 Magnetic Dichroism
!;K zR& References
ijDXh y !="8ok+ 11. Photoelectron Diffraction
D=SjCmG 11.1 Examples
K)^8 :nt 11.2 Substrate Photoelectron Diffraction
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