光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
BUdO:fr NiEz3ODSi 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
VeqB/QX mq}UUk@ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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y<~(}xsHh c(29JZ 目录
;1s;" 1. Introduction and Basic Principles
4`'Rm/) 1.1 Historical Development
N?8nlrDQ 1.2 The Electron Mean Free Path
-7XaS&.4 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
O$x +>^ 1.4 Experimental Aspects
$m-C6xC/ 1.5 Very High Resolution
lYS " 1.6 The Theory of Photoemission
aK(e%Ed t" 1.6.1 Core-Level Photoemission
>l=jJTJ;q 1.6.2 Valence-State Photoemission
P8H2v_)X& 1.6.3 Three-Step and One-Step Considerations
Q );}1'c 1.7 Deviations from the Simple Theory of Photoemission
A/&u/?*C References
O>I%O^ G^z>2P 2. Core Levels and Final States
Dw 5Ze 2.1 Core-Level Binding Energies in Atoms and Molecules
<WbO&;% 2.1.1 The Equivalent-Core Approximation
i-#D c(9 2.1.2 Chemical Shifts
VZe'6?# 2.2 Core-Level Binding Energies in Solids
%{UW!/ 2.2.1 The Born-Haber Cycle in Insulators
]ncK M?'O 2.2.2 Theory of Binding Energies
~]Av$S 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
/XA*:8~! 2.3 Core Polarization
\ [M4[Qlq 2.4 Final-State Multiplets in Rare-Earth Valence Bands
6(7dr?^eGT 2.5 Vibrational Side Bands
I~E&::, 2.6 Core Levels of Adsorbed Molecules
7<L!" 2VB 2.7 Quantitative Chemical Analysis from Core-Level Intensities
C!nbl+75 References
/1m+iM^V .Iz
JJp 3. Charge-Excitation Final States: Satellites
J9f]=1` 3.1 Copper Dihalides; 3d Transition Metal Compounds
<[T{q
|* 3.1.1 Characterization of a Satellite
BlM(Q/z 3.1.2 Analysis of Charge-Transfer Satellites
l)~$/#k 3.1.3 Non-local Screening
a1ps'^Qhh 3.2 The 6-eV Satellite in Nickel
(WP^}V5 3.2.1 Resonance Photoemission
{iCX?Sb 3.2.2 Satellites in Other Metals
0W_u"UY$c 3.3 The Gunnarsson-Sch6nhammer Theory
~0o>B$xJ 3.4 Photoemission Signals and Narrow Bands in Metals
ooCfr?E References
~$rSy|19 _;/+8= 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
c>! ^\ 4.1 Theory
|VjD. ]I 4.1.1 General
;>fM?ae5 4.1.2 Core-Line Shape
R:ecLbC 4.1.3 Intrinsic Plasmons
t0?tXe.B 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
(dx~lMI 4.1.5 The Total Photoelectron Spectrum
^; }Y ZBy 4.2 Experimental Results
{qU;>;( 4.2.1 The Core Line Without Plasmons
><.*5q 4.2.2 Core-Level Spectra Including Plasmoas
cBU3Q<^ 4.2.3 Valence-Band Spectra of the Simple Metals
ah(k!0PV 4.2.4 Simple Metals: A General Comment
cxFyN;7 4.3 The Background Correction
ccx0aC3@I References
S\GxLW@x ka{!' ^ 5. Valence Orbitals in Simple Molecules and Insulating Solids
I>6zX 5.1 UPS Spectra of Monatomic Gases
wbk$(P'gN 5.2 Photoelectron Spectra of Diatomic Molecules
s;[=B 5.3 Binding Energy of the H2 Molecule
w'y,$gtX/ 5.4 Hydrides Isoelectronic with Noble Gases
r%>7n,+o Neon (Ne)
:QHh;TIG=< Hydrogen Fluoride (HF)
1=z\,~b Water (H2O)
r^ ' Ammonia (NH3)
w4&\-S# Methane (CH4)
SLH;iqPT 5.5 Spectra of the Alkali HMides
1zCgPiAem 5.6 Transition Metal Dihalides
0Pt%(^ 5.7 Hydrocarbons
<^W5UU#Pg 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
vIZFI 5.7.2 Linear Polymers
0HQTe>! 5.8 Insulating Solids with Valence d Electrons
7h:EU7 5.8.1 The NiO Problem
u@`y/,PX 5.8.2 Mort Insulation
!kH 1| 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
jfam/LL{V 5.8.4Band Structures of Transition Metal Compounds
2E!Q5 l!j 5.9 High—Temperature Superconductors
KFaYn 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
Hq?dqg' %~ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
H:WuMw D4 5.9.3 The Superconducting Gap
aN6HO 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
xK5~9StP 5.9.5 Core—Level Shifts
N|
P?!G-= 5.10 The Fermi Liquid and the Luttinger Liquid
C}pQFL{B5 5.11 Adsorbed Molecules
w6-<HPW<S 5.11.1 Outline
[9F 5.11.2 CO on Metal Surfaces
s"2+H}u References
# $'H?lO ",Fvv
6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
*<h )q)HS 6.1 Theory of Photoemission:A Summary of the Three-Step Model
23a:q{R 6.2 Discussion of the Photocurrent
X+N8r^& 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
'e$8
IZm 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
m}>Q#IVZ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
D^U?!S&4~ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
u%=2g'+)_ 6.3.1 Band Structure Regime
Qv]rj]% 6.3.2 XPS Regime
KYl!Iw67d 6.3.3 Surface Emission
K*p3#iB 6.3.4 One-Step Calculations
[dqh-7 6.4 Thermal Effects
$ERiBALN: 6.5 Dipole Selection Rules for Direct Optical Transitions
H7meI9L References
b d C e5'U[bQm 7.Band Structtire and Angular-Resolved Photoelectron Spectra
<,U$Y> 7.1 Free-Electron Final—State Model
s3K!~v\L] 7.2 Methods Employing Calculated Band Structures
58eO|c( 7.3 Methods for the Absolute Determination of the Crystal Momentum
1xO-tIp/ 7.3.1 Triangulation or Energy Coincidence Method
.S* sGauM 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
c'5ls7?}O{ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
{.e^1qE 7.3.4 The Surface Emission Method and Electron Damping
PY&mLux% 7.3.5 The Very-Low-Energy Electron Diffraction Method
!;${2 Q 7.3.6 The Fermi Surface Method
eax"AmO 7.3.7 Intensities and Their Use in Band-Structure Determinations
"g!ek3w( 7.3.8 Summary
Az:A,;~+,! 7.4 Experimental Band Structures
EW+QVu@ 7.4.1 One- and Two-Dimensional Systems
o*oFCR]j 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
k<NxI\s8] 7..4.3UPS Band Structures and XPS Density of States
K}'?#a(aX= 7.5 A Comment
A\13*4:;l References
}KEr@h,N 8PWEQ<ev7> 8.Surface States, Surface Effects
%'S[f 8.1 Theoretical Considerations
upZf&4 I8 8.2 Experimental Results on Surface States
,/!^ZS* 8.3 Quantum-Well States
p\.IP2+c 8.4 Surface Core-Level Shifts
*9EW&Ek References
k^zU; s%RG_"l 9.Inverse Photoelectron Spectroscopy
Q8.LlE999 9.1 Surface States
bL+}n8B 9.2 Bulk Band Structures
Vjd>j; H 9.3 Adsorbed Molecules
da@W6Ov x References
`}rk1rl6 n9-WZsc1 10. Spin-Polarized Photoelectron Spectroscopy
iJCv+p_f 10.1 General Description
=F
%lx[9Ye 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
vUDMl Z 10.3 Magnetic Dichroism
-zI9E!24 References
#Jr4LQ@A9 6&
6|R3 11. Photoelectron Diffraction
6qWWfm/6 11.1 Examples
9`M7 -{ 11.2 Substrate Photoelectron Diffraction
sk
AF6n 11.3 Adsorbate Photoelectron Diffraction
X}g3[ 11.4 Fermi Surface Scans
1xSG(! References
h
9}x6t, (A "yE4rYK Appendix
\)ZCB7| A.1 Table of Binding Energies
77ztDQDtM A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
MV07RjeS A.3 Compilation of Work Functions
KKWvV4u References
IFhS(3YK[ Index