光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
`;#I_R_K p0j-$*F 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
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iU~p 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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0+"P1/ 3|.KEJC" 目录
QD*(wj 1. Introduction and Basic Principles
ekO*(vQ~ 1.1 Historical Development
?[S{kMb2 1.2 The Electron Mean Free Path
HZzdelo 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
"=XRonQZ 1.4 Experimental Aspects
>`+-Yi$(\ 1.5 Very High Resolution
px.]m- 1.6 The Theory of Photoemission
qAR}D~ t 1.6.1 Core-Level Photoemission
t^@4n&Dg 1.6.2 Valence-State Photoemission
HH,G3~EBF 1.6.3 Three-Step and One-Step Considerations
qVmG"et'J 1.7 Deviations from the Simple Theory of Photoemission
%#b+ =J References
AJ-~F>gn #ui7YUR=2 2. Core Levels and Final States
<=7^D 2.1 Core-Level Binding Energies in Atoms and Molecules
t!}?nw%$ 2.1.1 The Equivalent-Core Approximation
n{r_Xa 2.1.2 Chemical Shifts
K>fY9`Whm 2.2 Core-Level Binding Energies in Solids
OX/}j_8E^( 2.2.1 The Born-Haber Cycle in Insulators
[P"R+$"
2.2.2 Theory of Binding Energies
.6#Y-iJqc 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
"M5&&\uT 2.3 Core Polarization
s7TV@Y) 2.4 Final-State Multiplets in Rare-Earth Valence Bands
EL-1o02- 2.5 Vibrational Side Bands
cE0Kvqe` 2.6 Core Levels of Adsorbed Molecules
@ 6{U*vs 2.7 Quantitative Chemical Analysis from Core-Level Intensities
;yK:.Vg References
9Fm><,0'u #3act)m 3. Charge-Excitation Final States: Satellites
za@`,Yq 3.1 Copper Dihalides; 3d Transition Metal Compounds
3xz{[ 5<p 3.1.1 Characterization of a Satellite
cYMlcwS 3.1.2 Analysis of Charge-Transfer Satellites
b?FTwjV+# 3.1.3 Non-local Screening
(~FLG I 3.2 The 6-eV Satellite in Nickel
_jCjq 3.2.1 Resonance Photoemission
(J^2|9r 3.2.2 Satellites in Other Metals
-KG3_k E 3.3 The Gunnarsson-Sch6nhammer Theory
:X;AmLf`2u 3.4 Photoemission Signals and Narrow Bands in Metals
U
i ~*] References
SRx `m,535 /K]<7 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
)#l,RJ( 4.1 Theory
" |l-NUe 4.1.1 General
I*^3 Z 4.1.2 Core-Line Shape
*T'>-nm]
4.1.3 Intrinsic Plasmons
L'Fy\K\ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
/N&)r wc 4.1.5 The Total Photoelectron Spectrum
<C9_5Ce~ 4.2 Experimental Results
Hc{0O7 4.2.1 The Core Line Without Plasmons
)gR !G]Y 4.2.2 Core-Level Spectra Including Plasmoas
?"[h P=3J 4.2.3 Valence-Band Spectra of the Simple Metals
va/$dD9 4.2.4 Simple Metals: A General Comment
7}<057Xn' 4.3 The Background Correction
9}2E+ References
4X &\/X 4W''j[Y/ 5. Valence Orbitals in Simple Molecules and Insulating Solids
Ih.6"ISK} 5.1 UPS Spectra of Monatomic Gases
a jCx"J 5.2 Photoelectron Spectra of Diatomic Molecules
;9hi2_luV 5.3 Binding Energy of the H2 Molecule
C%csQ m 5.4 Hydrides Isoelectronic with Noble Gases
v*7lJNN. Neon (Ne)
H `V3oS~} Hydrogen Fluoride (HF)
Ibd
na9z7 Water (H2O)
5/O;&[l Yy Ammonia (NH3)
TVP.)% Methane (CH4)
Vnv9<=R 5.5 Spectra of the Alkali HMides
Ge>%?\ 5.6 Transition Metal Dihalides
3S'juHTe 5.7 Hydrocarbons
@{Q[M3l 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
[1Yx#t 5.7.2 Linear Polymers
H0YxPk) 5.8 Insulating Solids with Valence d Electrons
;_lEu" - 5.8.1 The NiO Problem
zW_V)UNe 5.8.2 Mort Insulation
{g>k-. 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
{<HL}m@kQ 5.8.4Band Structures of Transition Metal Compounds
,HxsU,xiG 5.9 High—Temperature Superconductors
Jn>7MuG 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
>k?/'R 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
btK| U 5.9.3 The Superconducting Gap
.f V-puE 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
jy] hP?QG 5.9.5 Core—Level Shifts
i~dW)7 5.10 The Fermi Liquid and the Luttinger Liquid
l0 H,TT~2 5.11 Adsorbed Molecules
%7PprN0> 5.11.1 Outline
;u'mSJI' 5.11.2 CO on Metal Surfaces
l+.E' References
s9<fPv0w Ne<"o]_M 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
tj ,*-).4% 6.1 Theory of Photoemission:A Summary of the Three-Step Model
@83h/Wcxd 6.2 Discussion of the Photocurrent
:4"SJ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
U/2g N
H 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
IPU'M*|Q 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
7 N?x29 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
Oph4&Ip[w 6.3.1 Band Structure Regime
fn zj@_{| 6.3.2 XPS Regime
)*I=>v.Jq 6.3.3 Surface Emission
X3DXEeBEL 6.3.4 One-Step Calculations
E/<[G? 6.4 Thermal Effects
K2TO,J3 E 6.5 Dipole Selection Rules for Direct Optical Transitions
hv'~S References
,# 1ke /(w:XTO< 7.Band Structtire and Angular-Resolved Photoelectron Spectra
^j?\_r'j 7.1 Free-Electron Final—State Model
EOrWax@k$} 7.2 Methods Employing Calculated Band Structures
w0Fi~:b 7.3 Methods for the Absolute Determination of the Crystal Momentum
<R7*00 7.3.1 Triangulation or Energy Coincidence Method
:".:Wd 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
Q/6T?{\U7 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
UAT46 7.3.4 The Surface Emission Method and Electron Damping
J'4{+Q_pa 7.3.5 The Very-Low-Energy Electron Diffraction Method
^lT$D8 7.3.6 The Fermi Surface Method
2B_6un];W 7.3.7 Intensities and Their Use in Band-Structure Determinations
^CTgo,uf6H 7.3.8 Summary
TR rO- 7.4 Experimental Band Structures
~ X8U@f
7.4.1 One- and Two-Dimensional Systems
owTW_V 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
rm>;B
*; 7..4.3UPS Band Structures and XPS Density of States
Eo\#*Cv* 7.5 A Comment
pr\yc References
y6'Fi(2yw YH^_d3A; 8.Surface States, Surface Effects
sJX/YGHt 8.1 Theoretical Considerations
j?1\E9&4-Q 8.2 Experimental Results on Surface States
Z9ciS";L 8.3 Quantum-Well States
$"T1W=;j9 8.4 Surface Core-Level Shifts
g*ES[JJH& References
D5)qmu iYA06~d 9.Inverse Photoelectron Spectroscopy
cD8.rRyD 9.1 Surface States
fcb:LPk; 9.2 Bulk Band Structures
&-+qB
>SK> 9.3 Adsorbed Molecules
N10'./c K References
N{`-&8q;K +&tY&dQQB 10. Spin-Polarized Photoelectron Spectroscopy
it\{#rb=4 10.1 General Description
P"_x/C(]@J 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
BD,JBu] 10.3 Magnetic Dichroism
z-uJ+SA References
_%!C;`3Y {$>*~.Wu 11. Photoelectron Diffraction
rx'},[b]3 11.1 Examples
<"/Y`/ 11.2 Substrate Photoelectron Diffraction
+H_Jr'/ 11.3 Adsorbate Photoelectron Diffraction
F&;g<
SD 11.4 Fermi Surface Scans
a@zKi; References
nG$*[7<0u BgD;"GD*W Appendix
TclZdk]%T A.1 Table of Binding Energies
8nQlmWpJ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
Gp$[u4-6M6 A.3 Compilation of Work Functions
~*Ve>4 References
eg)=^b Index