光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
a%-P^M;a2 ZR3x;$I~4 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
Xja l6e)[ >o\[?QvP 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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G}tq'#]E{z ?D#]g[6 9's/~T 目录
Sdc;jK 9d! 1. Introduction and Basic Principles
4=H/-v'& 1.1 Historical Development
.&ynS 1.2 The Electron Mean Free Path
-4JdKO 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
=sP6 1.4 Experimental Aspects
EiY i<Z_S 1.5 Very High Resolution
]FLuiC 1.6 The Theory of Photoemission
2'"$Y' 1.6.1 Core-Level Photoemission
t/,k{5lX 1.6.2 Valence-State Photoemission
>9f-zv(n 1.6.3 Three-Step and One-Step Considerations
JF >mybB 1.7 Deviations from the Simple Theory of Photoemission
wovWEtVBU References
a#=GLB_P( w+cI0lj 2. Core Levels and Final States
V(3udB@K 2.1 Core-Level Binding Energies in Atoms and Molecules
* xs8/? 2.1.1 The Equivalent-Core Approximation
{Ex0mw)T 2.1.2 Chemical Shifts
|52VHW8c 2.2 Core-Level Binding Energies in Solids
$S$%avRX 2.2.1 The Born-Haber Cycle in Insulators
G!uQ|<( 2.2.2 Theory of Binding Energies
'}c0:,5 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
bQk5R._got 2.3 Core Polarization
AZ5c^c) 2.4 Final-State Multiplets in Rare-Earth Valence Bands
E'LkoyI 2.5 Vibrational Side Bands
#jV6w=I 2.6 Core Levels of Adsorbed Molecules
T7YzO,b/
2.7 Quantitative Chemical Analysis from Core-Level Intensities
{M]m cRB( References
$Q|66/S^ au8bEw&W 3. Charge-Excitation Final States: Satellites
MB\vgKY 3.1 Copper Dihalides; 3d Transition Metal Compounds
M`umfw T 3.1.1 Characterization of a Satellite
=,I,K=+_x 3.1.2 Analysis of Charge-Transfer Satellites
LiJ;A* 3.1.3 Non-local Screening
LX
j Tqp' 3.2 The 6-eV Satellite in Nickel
Zx<s-J4o=w 3.2.1 Resonance Photoemission
K/Axojo 3.2.2 Satellites in Other Metals
K:P gkc 3.3 The Gunnarsson-Sch6nhammer Theory
yPm)r2Ck 3.4 Photoemission Signals and Narrow Bands in Metals
8T
6jM+ h References
A20_a;V C,-V>bx g 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
E/_=0t 4.1 Theory
?S!lX[#v 4.1.1 General
lN 1 T\ 4.1.2 Core-Line Shape
BZsw(l4/0' 4.1.3 Intrinsic Plasmons
A1\;6W: 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
FFH-Kw, 4.1.5 The Total Photoelectron Spectrum
}?>30+42: 4.2 Experimental Results
e)\s0# 4.2.1 The Core Line Without Plasmons
4MRHz{`wa 4.2.2 Core-Level Spectra Including Plasmoas
%Q}#x 4.2.3 Valence-Band Spectra of the Simple Metals
g}' "&Y 4.2.4 Simple Metals: A General Comment
2N(c&Dzkh` 4.3 The Background Correction
>'Nrvy%&0 References
a&ZH ,[+gE\z{{u 5. Valence Orbitals in Simple Molecules and Insulating Solids
~&k1P:#R 5.1 UPS Spectra of Monatomic Gases
ep[7#\}5 5.2 Photoelectron Spectra of Diatomic Molecules
R^dAwt`.D 5.3 Binding Energy of the H2 Molecule
rM pb 5.4 Hydrides Isoelectronic with Noble Gases
`-Gs*#(/ Neon (Ne)
p%J,af Hydrogen Fluoride (HF)
?mRU9VY Water (H2O)
" S#0QH%5 Ammonia (NH3)
a+zE`uY
Methane (CH4)
u&bo32fc 5.5 Spectra of the Alkali HMides
LUKdu&M 5.6 Transition Metal Dihalides
|)pT"` 5.7 Hydrocarbons
!=cW+=1 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
{:od=\*R 5.7.2 Linear Polymers
9+=U&* 5.8 Insulating Solids with Valence d Electrons
~b8U#'KD 5.8.1 The NiO Problem
d'^jekh 5.8.2 Mort Insulation
3j<]
W 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
4<Bj;1*4 5.8.4Band Structures of Transition Metal Compounds
v.\1-Q? 5.9 High—Temperature Superconductors
<J {VTk ~ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
8*4X%a=Of 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
h{J2CWJ 5.9.3 The Superconducting Gap
wC <!,tB(8 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
"]5]"F 4] 5.9.5 Core—Level Shifts
SMqJMirR 5.10 The Fermi Liquid and the Luttinger Liquid
-UPdgZ_Vxz 5.11 Adsorbed Molecules
69r<Z 5.11.1 Outline
398}a!XM 5.11.2 CO on Metal Surfaces
aQ]C`9k References
7qgHH p |53Zg"! 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
E;D9S 6.1 Theory of Photoemission:A Summary of the Three-Step Model
~;il{ym 6.2 Discussion of the Photocurrent
cL< 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
6/.-V1*O 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
OPBnU@=R 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
U`IDZ{g 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
*8,]fBUq 6.3.1 Band Structure Regime
8WZM}3x$f{ 6.3.2 XPS Regime
d1``}naNw 6.3.3 Surface Emission
0z_e3H{P27 6.3.4 One-Step Calculations
e<9IwS!/ 6.4 Thermal Effects
)@\= pE.H 6.5 Dipole Selection Rules for Direct Optical Transitions
& 2>W=h References
jUI'F4.5x- HeNg<5v%Y 7.Band Structtire and Angular-Resolved Photoelectron Spectra
EF qWnz 7.1 Free-Electron Final—State Model
[[Qu|?KEa 7.2 Methods Employing Calculated Band Structures
wC`])z}bT 7.3 Methods for the Absolute Determination of the Crystal Momentum
^yu0Veypy 7.3.1 Triangulation or Energy Coincidence Method
jzdK''CHi 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
x<~ pqq8] 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
m:)v>v u 7.3.4 The Surface Emission Method and Electron Damping
%W+*)u72( 7.3.5 The Very-Low-Energy Electron Diffraction Method
@iS(P u 7.3.6 The Fermi Surface Method
yFH)PQ_ 7.3.7 Intensities and Their Use in Band-Structure Determinations
u!
x9O8y 7.3.8 Summary
vtv|H 7.4 Experimental Band Structures
kDS4 t?Ig 7.4.1 One- and Two-Dimensional Systems
"qIO,\3T 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
yO]Vex5) 7..4.3UPS Band Structures and XPS Density of States
%'%ej^s-R 7.5 A Comment
go@UE2qw References
5|9,S (@pE 8.Surface States, Surface Effects
/3L1Un* 8.1 Theoretical Considerations
Ym8G=KA 8.2 Experimental Results on Surface States
r-9P&*1 8.3 Quantum-Well States
@F+4
NL-'P 8.4 Surface Core-Level Shifts
T7'njaLec References
imZi7o m5v9:5{ 9.Inverse Photoelectron Spectroscopy
ltO:./6v 9.1 Surface States
UMma|9l(i 9.2 Bulk Band Structures
_b&Mrd 9.3 Adsorbed Molecules
nz3j";d References
}f+If{ | -e*^| 10. Spin-Polarized Photoelectron Spectroscopy
*}-X
'_ 10.1 General Description
m$NBG w 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
|ITp$_S 10.3 Magnetic Dichroism
p&>*bF, References
hJ (Q^Z N&]v\MjI62 11. Photoelectron Diffraction
kn^RS1m 11.1 Examples
rh5R kiF~ 11.2 Substrate Photoelectron Diffraction
E5~HH($b 11.3 Adsorbate Photoelectron Diffraction
JN .\{ Y 11.4 Fermi Surface Scans
'nz;|6uC References
0~iC#lHO }/nbv;) Appendix
&na#ES$X, A.1 Table of Binding Energies
%g5TU 6WP A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
j&6,%s-M`a A.3 Compilation of Work Functions
D^baXp8 References
Kyt.[" p Index