光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
i-W >|3a
9S 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
Rg* J} \dq!q=b\ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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BJL ~|lIC !q 目录
:eOR-}p' 1. Introduction and Basic Principles
u@=?#a$$ 1.1 Historical Development
9`"DFFSMS 1.2 The Electron Mean Free Path
4_LQ?U>$ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
}nud 1.4 Experimental Aspects
F9H~k"_ZJR 1.5 Very High Resolution
b2kWjg.4 1.6 The Theory of Photoemission
1f4bt6[ 1.6.1 Core-Level Photoemission
ksWSMxm 1.6.2 Valence-State Photoemission
6^#uLp> 1.6.3 Three-Step and One-Step Considerations
4;KWG}~[o 1.7 Deviations from the Simple Theory of Photoemission
ZPO|<uR References
4nkE IZ R$m`Z+/@ 2. Core Levels and Final States
$/_qE 2.1 Core-Level Binding Energies in Atoms and Molecules
.Q&rfH3 2.1.1 The Equivalent-Core Approximation
LJQJ\bT? 2.1.2 Chemical Shifts
(j&A",^^S 2.2 Core-Level Binding Energies in Solids
C3VLV&wF 2.2.1 The Born-Haber Cycle in Insulators
?Zz'|.l@ 2.2.2 Theory of Binding Energies
8Fq_i-u 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
<]G${y*; 2.3 Core Polarization
naNyGE7) 2.4 Final-State Multiplets in Rare-Earth Valence Bands
K`k'}(vj 2.5 Vibrational Side Bands
"T6# 2.6 Core Levels of Adsorbed Molecules
N.j
"S'(i 2.7 Quantitative Chemical Analysis from Core-Level Intensities
bAF )Bli References
.px:e)iW ~]uZy=P? 5 3. Charge-Excitation Final States: Satellites
?m;;D'1j 3.1 Copper Dihalides; 3d Transition Metal Compounds
$Ui&D
I 3.1.1 Characterization of a Satellite
|L:Cn J 3.1.2 Analysis of Charge-Transfer Satellites
]hTb@. 3.1.3 Non-local Screening
qpqokK 3.2 The 6-eV Satellite in Nickel
{CUk1+ 3.2.1 Resonance Photoemission
2t1I3yA'{z 3.2.2 Satellites in Other Metals
{G*QY%j^ 3.3 The Gunnarsson-Sch6nhammer Theory
H:S,\D?%2x 3.4 Photoemission Signals and Narrow Bands in Metals
Z1,gtl ? References
d^V$Z6*
] ?tYpc_p# 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
gPEqjj 4.1 Theory
;-@= 4.1.1 General
sR_xe}- 4.1.2 Core-Line Shape
8_we:
9A 4.1.3 Intrinsic Plasmons
R+=a`0_S 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
-50AX1h31: 4.1.5 The Total Photoelectron Spectrum
;IZ?19Q 4.2 Experimental Results
vR hnX 4.2.1 The Core Line Without Plasmons
kA#vByf`v 4.2.2 Core-Level Spectra Including Plasmoas
d"THt} 4.2.3 Valence-Band Spectra of the Simple Metals
6s xz_f 4.2.4 Simple Metals: A General Comment
&M"ouy Zo9 4.3 The Background Correction
O`W%Tr References
'ks{D(` F $yO 5. Valence Orbitals in Simple Molecules and Insulating Solids
fCUT[d +H 5.1 UPS Spectra of Monatomic Gases
2x}6\t 5.2 Photoelectron Spectra of Diatomic Molecules
,M6ZZ* ,e 5.3 Binding Energy of the H2 Molecule
($!KzxF3 5.4 Hydrides Isoelectronic with Noble Gases
]/dVRkZeAE Neon (Ne)
kE)!<1yy2 Hydrogen Fluoride (HF)
%c/^_. Water (H2O)
.BZVX=x Ammonia (NH3)
qfL-r,XS`F Methane (CH4)
pyB~M9Bp/ 5.5 Spectra of the Alkali HMides
VOgi7\ 5.6 Transition Metal Dihalides
M}F~_S0h 5.7 Hydrocarbons
4%ZM:/ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
Q/^A #l[ 5.7.2 Linear Polymers
pP/@ 5.8 Insulating Solids with Valence d Electrons
&Cro2|KZhG 5.8.1 The NiO Problem
| {P|. 5.8.2 Mort Insulation
iI?{"}BZ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
3<(q } 5.8.4Band Structures of Transition Metal Compounds
jNl/!l7B 5.9 High—Temperature Superconductors
\,xFg w4 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
&a)vdlZSE= 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
"S!3m9_# 5.9.3 The Superconducting Gap
G$JFuz)| 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
e>H:/24 5.9.5 Core—Level Shifts
-q>^ALf|@> 5.10 The Fermi Liquid and the Luttinger Liquid
:BZ0 7`9 5.11 Adsorbed Molecules
r6.N4eW.L 5.11.1 Outline
EESN\_{~. 5.11.2 CO on Metal Surfaces
^^?q$1k6r* References
\L]|-f(4 mP}#Ccji? 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
T~>#2N-Z 6.1 Theory of Photoemission:A Summary of the Three-Step Model
(.X]F_*sc 6.2 Discussion of the Photocurrent
4E3g,%9u 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
l\Ftr_Dk 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
]n
v( aM?d 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
t9
F=^)s 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
'ZHdV,dd 6.3.1 Band Structure Regime
ST',4Oph5 6.3.2 XPS Regime
v1.*IV5Y 6.3.3 Surface Emission
$RO$}! 6.3.4 One-Step Calculations
T1
MY X 6.4 Thermal Effects
M<`|CVl 6.5 Dipole Selection Rules for Direct Optical Transitions
?9KGnOVu References
5M){!8"S)# XW~bu2%{7" 7.Band Structtire and Angular-Resolved Photoelectron Spectra
*"9<TSU%m 7.1 Free-Electron Final—State Model
tFh|V
pB 7.2 Methods Employing Calculated Band Structures
Q< *8<Oo4g 7.3 Methods for the Absolute Determination of the Crystal Momentum
>P(`MSc 7.3.1 Triangulation or Energy Coincidence Method
N}Vn;29 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
y\PxR708 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
Re[:qLa] 7.3.4 The Surface Emission Method and Electron Damping
">90E^ 7.3.5 The Very-Low-Energy Electron Diffraction Method
P]6}\
]~ 7.3.6 The Fermi Surface Method
')TPF{\# 7.3.7 Intensities and Their Use in Band-Structure Determinations
wGLF%;rRe4 7.3.8 Summary
N6/T#UVns 7.4 Experimental Band Structures
yYTVXs`fVj 7.4.1 One- and Two-Dimensional Systems
JOfV]eCL 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
%}qbkkZ 7..4.3UPS Band Structures and XPS Density of States
`a4 $lyZ 7.5 A Comment
+;gsRhWk References
@.9I3E-= IgX4.]W5 8.Surface States, Surface Effects
'"xiS$b( 8.1 Theoretical Considerations
=3'(A14C= 8.2 Experimental Results on Surface States
Fdt}..H% 8.3 Quantum-Well States
ImkrV{,e 8.4 Surface Core-Level Shifts
j%tEZ"H References
"JhimgwvY =_-C%<4 9.Inverse Photoelectron Spectroscopy
5Pke8K 9.1 Surface States
l4T:d^Eb 9.2 Bulk Band Structures
kQIw/@WC 9.3 Adsorbed Molecules
9([6d.`~ References
P Jo ; B$*)X9 10. Spin-Polarized Photoelectron Spectroscopy
&3DK^|Lq 10.1 General Description
2C/%gcN > 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
>BoSw&T$Q 10.3 Magnetic Dichroism
.Ff_s References
DeQDH5X" 3H8Al 11. Photoelectron Diffraction
e}"wL g] 11.1 Examples
YoSQN/Z 11.2 Substrate Photoelectron Diffraction
L;)v&a7[P 11.3 Adsorbate Photoelectron Diffraction
=,:K) 11.4 Fermi Surface Scans
Bc
^4 T1 References
{bkGYx5.C (!</%^ZI Appendix
d*-Xuv A.1 Table of Binding Energies
h~UJCnzS A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
n|KKby.$ A.3 Compilation of Work Functions
F`&>NQb References
2d&^Sp&11 Index