光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
cjY@Ot*i$ aL)$b 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
rw*M&qg!z h AAU ecx 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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&FFIu 目录
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1. Introduction and Basic Principles
1^sb T[%R 1.1 Historical Development
lk o3]A3 1.2 The Electron Mean Free Path
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mW\\kA> 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
%*p^$5L< 1.4 Experimental Aspects
Nuq(4Yf1W 1.5 Very High Resolution
*h])mqhB 1.6 The Theory of Photoemission
$QffrU' 1.6.1 Core-Level Photoemission
pXNtN5@FQ 1.6.2 Valence-State Photoemission
lb95!.av+I 1.6.3 Three-Step and One-Step Considerations
FvA|1c 1.7 Deviations from the Simple Theory of Photoemission
40+fGRyOL References
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2. Core Levels and Final States
dcP88!#5- 2.1 Core-Level Binding Energies in Atoms and Molecules
m9I(TOw 2.1.1 The Equivalent-Core Approximation
8E-Ip>{> 2.1.2 Chemical Shifts
APOea 2.2 Core-Level Binding Energies in Solids
U,d2DAvt 2.2.1 The Born-Haber Cycle in Insulators
-s33m]a; 2.2.2 Theory of Binding Energies
:SdIU36 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
oE 5;|x3 2.3 Core Polarization
PbQE{&D# 2.4 Final-State Multiplets in Rare-Earth Valence Bands
'Ye]eL,I\ 2.5 Vibrational Side Bands
8(uw0~GO 2.6 Core Levels of Adsorbed Molecules
(I!1sE!?1 2.7 Quantitative Chemical Analysis from Core-Level Intensities
8z0Hx References
u{pTva w4aiI2KFq 3. Charge-Excitation Final States: Satellites
k3/4Bt G/ 3.1 Copper Dihalides; 3d Transition Metal Compounds
7s!AHyZ 3.1.1 Characterization of a Satellite
WQTendS 3.1.2 Analysis of Charge-Transfer Satellites
A` =]RJ 3.1.3 Non-local Screening
bsMC#xT 3.2 The 6-eV Satellite in Nickel
nE^wxtY 3.2.1 Resonance Photoemission
Ho>p ^p 3.2.2 Satellites in Other Metals
~6MMErSj 3.3 The Gunnarsson-Sch6nhammer Theory
iPz1eUj 3.4 Photoemission Signals and Narrow Bands in Metals
JqQ3C}z References
[ns&Y0Y`t '&/(oJ;O~ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
% hNn%Oy:E 4.1 Theory
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4.1.1 General
*:(1K%g 4.1.2 Core-Line Shape
{ .cB>L 4.1.3 Intrinsic Plasmons
[KD}U-(Wg 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
?3n=m%W,J* 4.1.5 The Total Photoelectron Spectrum
Fz{o-4 4.2 Experimental Results
s^obJl3 4.2.1 The Core Line Without Plasmons
}@3$)L%n_u 4.2.2 Core-Level Spectra Including Plasmoas
<%he
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2k%Bl+I 4.3 The Background Correction
vsjM3= References
*P&OxVz y B1W>s8& 5. Valence Orbitals in Simple Molecules and Insulating Solids
VN?<[#ij 5.1 UPS Spectra of Monatomic Gases
J&( 5.2 Photoelectron Spectra of Diatomic Molecules
qmQFHC_ 5.3 Binding Energy of the H2 Molecule
}1l}- w`F 5.4 Hydrides Isoelectronic with Noble Gases
0H;"5 Neon (Ne)
byp.V_a}/ Hydrogen Fluoride (HF)
#cR57=M} Water (H2O)
'Dnq+ Ammonia (NH3)
='KPT1dW* Methane (CH4)
TeOFAIU 5.5 Spectra of the Alkali HMides
UzXDi#Ky 5.6 Transition Metal Dihalides
4GEjW4E 5.7 Hydrocarbons
<<i=+ed8eP 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
t!NrB X 5.7.2 Linear Polymers
<Wp`[S]r 5.8 Insulating Solids with Valence d Electrons
Mf!owpW
T 5.8.1 The NiO Problem
XA=|]5C 5.8.2 Mort Insulation
q=T<^Tk#e 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
?SBh^/zf 5.8.4Band Structures of Transition Metal Compounds
g]:..W7 5.9 High—Temperature Superconductors
R65;oJh 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
^XtHF|%0T 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
$[WN[J 5.9.3 The Superconducting Gap
cKaL K#~ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
7MR:X#2v> 5.9.5 Core—Level Shifts
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