光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
.!6ufaf$ i;dr(c/ft 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
i-ogeR? >LLz G 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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H%yyT 目录
A|a\pL` @ 1. Introduction and Basic Principles
Tf[]vqa`G 1.1 Historical Development
s~63JDy"E 1.2 The Electron Mean Free Path
n&V(c&C 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
1Gqtd^*; 1.4 Experimental Aspects
QB@*/Le 1.5 Very High Resolution
C3<3 1.6 The Theory of Photoemission
!EW]:u 1.6.1 Core-Level Photoemission
R1m18GHQ 1.6.2 Valence-State Photoemission
,`Mlo 1.6.3 Three-Step and One-Step Considerations
9,>M/_8> 1.7 Deviations from the Simple Theory of Photoemission
Wex4>J<`/ References
x
p$0J<2 "yz@LV1 2. Core Levels and Final States
r-0
7!A 2.1 Core-Level Binding Energies in Atoms and Molecules
4{Ak| 2.1.1 The Equivalent-Core Approximation
%FRkvqV* 2.1.2 Chemical Shifts
AP~!YwLW 2.2 Core-Level Binding Energies in Solids
Pb`sn5; 2.2.1 The Born-Haber Cycle in Insulators
"bO] 2.2.2 Theory of Binding Energies
e,4G:V'NX 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
gI%n(eY 2.3 Core Polarization
D"WkD j"M 2.4 Final-State Multiplets in Rare-Earth Valence Bands
Bl1I "B 2.5 Vibrational Side Bands
%B?5l^W@ 2.6 Core Levels of Adsorbed Molecules
qqAsh]Z 2.7 Quantitative Chemical Analysis from Core-Level Intensities
J+4uUf/d! References
lGz0K5P{ @Uu\x~3y 3. Charge-Excitation Final States: Satellites
E:tUbWVp 3.1 Copper Dihalides; 3d Transition Metal Compounds
N1-LM9S 3.1.1 Characterization of a Satellite
j)0R*_-B[ 3.1.2 Analysis of Charge-Transfer Satellites
?t"PawBWE 3.1.3 Non-local Screening
bpILiC 3.2 The 6-eV Satellite in Nickel
7/yd@#$X 3.2.1 Resonance Photoemission
;|%r!!#-t 3.2.2 Satellites in Other Metals
Qp54(` 3.3 The Gunnarsson-Sch6nhammer Theory
{!S/8o"] 3.4 Photoemission Signals and Narrow Bands in Metals
!K2[S
J References
7wnzef?) D0P% .r"v 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
lyPXlt 4.1 Theory
i_@RWka< 4.1.1 General
GwV FD% 4.1.2 Core-Line Shape
pWp2{G^XB 4.1.3 Intrinsic Plasmons
R}VL UL$ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
D^~gq`/) 4.1.5 The Total Photoelectron Spectrum
5zGj,y>u 4.2 Experimental Results
R;yAqr29 4.2.1 The Core Line Without Plasmons
7AiCQWf9 4.2.2 Core-Level Spectra Including Plasmoas
pSP_cYa#(# 4.2.3 Valence-Band Spectra of the Simple Metals
bi[l , 4.2.4 Simple Metals: A General Comment
Ed-gYL^< 4.3 The Background Correction
ZL>V9UWN References
rifxr4c[X> C"{on% 5. Valence Orbitals in Simple Molecules and Insulating Solids
6b|`[t 5.1 UPS Spectra of Monatomic Gases
&1{k^>oz 5.2 Photoelectron Spectra of Diatomic Molecules
$Da^z[8e 5.3 Binding Energy of the H2 Molecule
THp `!l 5.4 Hydrides Isoelectronic with Noble Gases
yd~fC:_ ] Neon (Ne)
B@=<'/S\7 Hydrogen Fluoride (HF)
E0Djo'64 Water (H2O)
6~S0t1/t? Ammonia (NH3)
d/&|%Z
r Methane (CH4)
B,>Fh X>h 5.5 Spectra of the Alkali HMides
{+:XVT_+ 5.6 Transition Metal Dihalides
;`B35K 5.7 Hydrocarbons
"Zk6B"o) 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
c5R{Sl 5.7.2 Linear Polymers
q9!9OcN2 5.8 Insulating Solids with Valence d Electrons
~'MWtDe:Z8 5.8.1 The NiO Problem
C":\L>Ax 5.8.2 Mort Insulation
`[CJtd2\ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
'qJ-eQ7e 5.8.4Band Structures of Transition Metal Compounds
ArYF\7P 5.9 High—Temperature Superconductors
s>\g03= 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
pG6-.F; 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
!&lPdEc@T 5.9.3 The Superconducting Gap
Ak Tw?v' 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
PuaosMn(9 5.9.5 Core—Level Shifts
;l ()3; 5.10 The Fermi Liquid and the Luttinger Liquid
0Q >|s_ 5.11 Adsorbed Molecules
_vH!0@QFU 5.11.1 Outline
!@{[I:5 5.11.2 CO on Metal Surfaces
3L?a4,Q"k} References
a7\L-T+ C4tl4df9 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
PEEY;x 6.1 Theory of Photoemission:A Summary of the Three-Step Model
AFTed?( 6.2 Discussion of the Photocurrent
"ru1 ;I
6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
_KVB~loT 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
[Z\1"m 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
sVd_O[ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
I%919 6.3.1 Band Structure Regime
%k
#Nu 6.3.2 XPS Regime
%E"/]!}3 6.3.3 Surface Emission
vXyo 6.3.4 One-Step Calculations
TSSt@xQ+ 6.4 Thermal Effects
Q+(:n)G_6E 6.5 Dipole Selection Rules for Direct Optical Transitions
tq[",&K References
lO> 7`2x=F /kU@S 7.Band Structtire and Angular-Resolved Photoelectron Spectra
Y&f[2+?2NK 7.1 Free-Electron Final—State Model
[;?{BB 7.2 Methods Employing Calculated Band Structures
So%1RY{) 7.3 Methods for the Absolute Determination of the Crystal Momentum
J 7;n;Mx 7.3.1 Triangulation or Energy Coincidence Method
/%9p9$kFot 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
ptyDv 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
jnzz~: 7.3.4 The Surface Emission Method and Electron Damping
w9<FX>@ 7.3.5 The Very-Low-Energy Electron Diffraction Method
!9 LAXM 7.3.6 The Fermi Surface Method
t0H=NUP8 7.3.7 Intensities and Their Use in Band-Structure Determinations
+1jqCW 7.3.8 Summary
h$ iyclX 7.4 Experimental Band Structures
_8pkejg 7.4.1 One- and Two-Dimensional Systems
TL{pc=eBo 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
1=5'R/k 7..4.3UPS Band Structures and XPS Density of States
sk6|_ 7.5 A Comment
yn":!4U1 References
"rDzrz [I<'E
LX 8.Surface States, Surface Effects
q\y# 8.1 Theoretical Considerations
T>Rf?%o 8.2 Experimental Results on Surface States
1qKxg 8.3 Quantum-Well States
sFM>gG 8.4 Surface Core-Level Shifts
1fhK{9# References
f9XO9N,hE: h9w^7MbO 9.Inverse Photoelectron Spectroscopy
)7"DR+;: 9.1 Surface States
Y1_6\zpA 9.2 Bulk Band Structures
h8= MVh(I 9.3 Adsorbed Molecules
VueQP| References
$CwTNm? pkV\D 10. Spin-Polarized Photoelectron Spectroscopy
27YLg c 10.1 General Description
4U
a~*58 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
GlgORy=> 10.3 Magnetic Dichroism
vua1iN1 References
p C2c(4 )tI2?YIR 11. Photoelectron Diffraction
OK2/k_jXN' 11.1 Examples
9q)nNX<$) 11.2 Substrate Photoelectron Diffraction
q{Ta?|x# 11.3 Adsorbate Photoelectron Diffraction
]V769B9 11.4 Fermi Surface Scans
A"<)(M+kG References
dYew7 iMeRQYW Appendix
])ALAAIc- A.1 Table of Binding Energies
-k[tFBlw A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
Or#+E2%1E A.3 Compilation of Work Functions
Gp3nR<+ References
k5%0wHpk = Index