光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
`HW:^T \iU] s\{). 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
mJC3@V
s 9s` /~ a@ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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f@t4(i YQgNv` l} 目录
c8A`<-\MfB 1. Introduction and Basic Principles
N[Sb#w`[/ 1.1 Historical Development
LdTdQ,s< 1.2 The Electron Mean Free Path
Cd]/ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
1;&;5 1.4 Experimental Aspects
'r+PH*Mr 1.5 Very High Resolution
|dmh 1.6 The Theory of Photoemission
+.Bmkim 1.6.1 Core-Level Photoemission
9"sDm}5% 1.6.2 Valence-State Photoemission
.Q&rfH3 1.6.3 Three-Step and One-Step Considerations
LJQJ\bT? 1.7 Deviations from the Simple Theory of Photoemission
(j&A",^^S References
V 0{tap} Yck~xt&] 2. Core Levels and Final States
8Fq_i-u 2.1 Core-Level Binding Energies in Atoms and Molecules
<]G${y*; 2.1.1 The Equivalent-Core Approximation
u&]vd / 2.1.2 Chemical Shifts
K`k'}(vj 2.2 Core-Level Binding Energies in Solids
"T6# 2.2.1 The Born-Haber Cycle in Insulators
SH8/0g? 2.2.2 Theory of Binding Energies
fgF;&(b 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
.px:e)iW 2.3 Core Polarization
~]uZy=P? 5 2.4 Final-State Multiplets in Rare-Earth Valence Bands
x5Zrz<Y$w 2.5 Vibrational Side Bands
^_>!B) 2.6 Core Levels of Adsorbed Molecules
0ys~2Y!eH 2.7 Quantitative Chemical Analysis from Core-Level Intensities
nr\q7 References
SEF6B45}1 @Doyt{|T 3. Charge-Excitation Final States: Satellites
Z=+03 3.1 Copper Dihalides; 3d Transition Metal Compounds
ii4B?E 3.1.1 Characterization of a Satellite
IA*KaX2S< 3.1.2 Analysis of Charge-Transfer Satellites
?o[L7JI 3.1.3 Non-local Screening
%_gho 3.2 The 6-eV Satellite in Nickel
S~F` 3.2.1 Resonance Photoemission
p!W[X%`) 3.2.2 Satellites in Other Metals
4]XI"-M^D 3.3 The Gunnarsson-Sch6nhammer Theory
:q+N&j'3 3.4 Photoemission Signals and Narrow Bands in Metals
>nnY:7m References
w+AuMc #a9_~\s 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
$v27]"] 4.1 Theory
3/goCg 4.1.1 General
k#)Ad*t 4.1.2 Core-Line Shape
&%F@O<: 4.1.3 Intrinsic Plasmons
8cVzFFQP 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
V@ :20m 4.1.5 The Total Photoelectron Spectrum
8+'C_t/0i 4.2 Experimental Results
z,f=}t[.Y 4.2.1 The Core Line Without Plasmons
cT'w= 4.2.2 Core-Level Spectra Including Plasmoas
P-Su5F 4.2.3 Valence-Band Spectra of the Simple Metals
E{Vo'!LY 4.2.4 Simple Metals: A General Comment
SUdm 0y 4.3 The Background Correction
J|QiH< References
<94G uJow7-FD 5. Valence Orbitals in Simple Molecules and Insulating Solids
U;^[$Aq 5.1 UPS Spectra of Monatomic Gases
f7<pEGb 5.2 Photoelectron Spectra of Diatomic Molecules
pSAR/':eg 5.3 Binding Energy of the H2 Molecule
B~gV'(9g 5.4 Hydrides Isoelectronic with Noble Gases
mLwY]2T" Neon (Ne)
sQ1jrkm Hydrogen Fluoride (HF)
eaZQ2 Water (H2O)
Nhf~PO({& Ammonia (NH3)
l";'6;g Methane (CH4)
+m$5a
YX 5.5 Spectra of the Alkali HMides
jBtj+TL8 5.6 Transition Metal Dihalides
iI?{"}BZ 5.7 Hydrocarbons
.p@N:)W6 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
3<(q } 5.7.2 Linear Polymers
;j}yB 5.8 Insulating Solids with Valence d Electrons
VcgBLkIF 5.8.1 The NiO Problem
:@. ; 5.8.2 Mort Insulation
'3,\@4 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
g`,AaWlF 5.8.4Band Structures of Transition Metal Compounds
+]!lS7nsW 5.9 High—Temperature Superconductors
Ka-p& Uv1< 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
/g.]RY+u|x 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
c{3rl;Cs 5.9.3 The Superconducting Gap
4\2V9F{s 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
dbF M,"^ 5.9.5 Core—Level Shifts
_
Jc2&(; 5.10 The Fermi Liquid and the Luttinger Liquid
vK$^y^ 5.11 Adsorbed Molecules
wD9a#AgEd 5.11.1 Outline
\C|cp|A*& 5.11.2 CO on Metal Surfaces
#Ob]]!y References
8k!6b\Imz Wk7WK` >i 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
:d'
5O8 6.1 Theory of Photoemission:A Summary of the Three-Step Model
9K"JYJ
q2 6.2 Discussion of the Photocurrent
n9UKcN- 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
u?0d[mC 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
80hme+e 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
<@#PF$! 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
o'=VZT9 6.3.1 Band Structure Regime
Oh!(@ 6.3.2 XPS Regime
pj{\T?( 6.3.3 Surface Emission
pB01J<@m 6.3.4 One-Step Calculations
9]yW_]P 6.4 Thermal Effects
Fr:5$,At7- 6.5 Dipole Selection Rules for Direct Optical Transitions
=nRuY' References
u<Xog$esu .ER 98 7.Band Structtire and Angular-Resolved Photoelectron Spectra
%'ZN`XftG 7.1 Free-Electron Final—State Model
VXKT\9g3A 7.2 Methods Employing Calculated Band Structures
ujzW|HW^v 7.3 Methods for the Absolute Determination of the Crystal Momentum
1/iE`Si 7.3.1 Triangulation or Energy Coincidence Method
3N4.$#>#9@ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
46XN3r 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
Pv){sYUh 7.3.4 The Surface Emission Method and Electron Damping
Fb_S&! 7.3.5 The Very-Low-Energy Electron Diffraction Method
PZOKrW 7.3.6 The Fermi Surface Method
v 81rfB5 7.3.7 Intensities and Their Use in Band-Structure Determinations
F[E?A95W 7.3.8 Summary
^Kq|ID
AP 7.4 Experimental Band Structures
;e{5)@h$ 7.4.1 One- and Two-Dimensional Systems
ef]B9J~h 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
fE25(wCz7 7..4.3UPS Band Structures and XPS Density of States
}T(z4P3 7.5 A Comment
SG'JE}jzO References
uP|FJLY %+tV/7|F 8.Surface States, Surface Effects
v\A.Tyy 8.1 Theoretical Considerations
%a8&W 8.2 Experimental Results on Surface States
r6Nm!Bq7 8.3 Quantum-Well States
G[yI*/E; 8.4 Surface Core-Level Shifts
[]}N References
`wO}Hz U{#xW 9.Inverse Photoelectron Spectroscopy
b X,Siz:F 9.1 Surface States
N}QFGX 9.2 Bulk Band Structures
O|z%DkH[ 9.3 Adsorbed Molecules
x)viY5vjH References
=ApY9` `,#!C`E 9 10. Spin-Polarized Photoelectron Spectroscopy
+{-]P\oc 10.1 General Description
%$9bce-fcG 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
w|Qd` 10.3 Magnetic Dichroism
U^$E'Q-VK References
n0fR u`SNV =/Juh7[C 11. Photoelectron Diffraction
|63Y
>U" 11.1 Examples
;Bs^iL 11.2 Substrate Photoelectron Diffraction
3|eUy_d3 11.3 Adsorbate Photoelectron Diffraction
Fd8hGj1 11.4 Fermi Surface Scans
KwFXB References
DY3:#X`4 p;->hn~D'5 Appendix
lB:l)!]||= A.1 Table of Binding Energies
!J^tg2M8: A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
pVG>A&4 A.3 Compilation of Work Functions
p24.bLr References
O
E|+R4M Index