光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
@kymL8"2w t,nB`g? 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
OSk9Eb4ld H:6$)# 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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Lb 9$& 目录
5Bo)j_Qo 1. Introduction and Basic Principles
v^'~-^s
1.1 Historical Development
c-d}E!C: 1.2 The Electron Mean Free Path
Xi.?9J`@ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
YvX I 1.4 Experimental Aspects
|e>-v 1.5 Very High Resolution
ak[)+_k_ 1.6 The Theory of Photoemission
EVsZ:Ra^k 1.6.1 Core-Level Photoemission
Nig-D>OS 1.6.2 Valence-State Photoemission
AF6'JxG7 1.6.3 Three-Step and One-Step Considerations
#J_i 5KmXJ 1.7 Deviations from the Simple Theory of Photoemission
Y2EN!{YU References
wP*Z/}Uum+ KHtY
+93 2. Core Levels and Final States
K-3 _4As 2.1 Core-Level Binding Energies in Atoms and Molecules
RSC-+c6 1 2.1.1 The Equivalent-Core Approximation
=d}3>YHS 2.1.2 Chemical Shifts
TZg7BLfy 2.2 Core-Level Binding Energies in Solids
$(U|JR@ 2.2.1 The Born-Haber Cycle in Insulators
$!Tw`O 2.2.2 Theory of Binding Energies
{,=,0NQKn 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
L8ke*O$ 2.3 Core Polarization
.2xkf@OP 2.4 Final-State Multiplets in Rare-Earth Valence Bands
l.$#IE 2.5 Vibrational Side Bands
L_,U*Jyo 2.6 Core Levels of Adsorbed Molecules
c^y 1s* 2.7 Quantitative Chemical Analysis from Core-Level Intensities
E3!twR*Aw References
,e2va7}3 CCV~nf 3. Charge-Excitation Final States: Satellites
g:U ul4 3.1 Copper Dihalides; 3d Transition Metal Compounds
nKdLhCN'= 3.1.1 Characterization of a Satellite
7_,gAE:kG 3.1.2 Analysis of Charge-Transfer Satellites
b3+PC$z2h 3.1.3 Non-local Screening
/eQn$ZRP, 3.2 The 6-eV Satellite in Nickel
jxvVp*-=<j 3.2.1 Resonance Photoemission
+Sfv.6~v 3.2.2 Satellites in Other Metals
'Nh^SbD+_| 3.3 The Gunnarsson-Sch6nhammer Theory
32yNEP{ 3.4 Photoemission Signals and Narrow Bands in Metals
"|if<hx+ References
KXJHb{? XJ;/kR 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
N2>JG]G 4.1 Theory
i weP3u## 4.1.1 General
0*)79Sz 4.1.2 Core-Line Shape
fvDwg 4.1.3 Intrinsic Plasmons
D6w0Y:A{. 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
`;;!>rm 4.1.5 The Total Photoelectron Spectrum
9=|5-?^ 4.2 Experimental Results
0NxaQ`\ 4.2.1 The Core Line Without Plasmons
cu-WY8n 4.2.2 Core-Level Spectra Including Plasmoas
`f'P 4.2.3 Valence-Band Spectra of the Simple Metals
K_i2%t3 4.2.4 Simple Metals: A General Comment
5S1m&s5k 4.3 The Background Correction
t(Uoi~#[ References
qb Q> z+c 'g#GUSXfj 5. Valence Orbitals in Simple Molecules and Insulating Solids
e\<I:7%Rg 5.1 UPS Spectra of Monatomic Gases
=u(fP" |{ 5.2 Photoelectron Spectra of Diatomic Molecules
_bX)fnUu 5.3 Binding Energy of the H2 Molecule
Q*I/mUP&f 5.4 Hydrides Isoelectronic with Noble Gases
xk/(|f{L Neon (Ne)
h>wU';5#f Hydrogen Fluoride (HF)
$IHa]9 { Water (H2O)
[#:k3aFz Ammonia (NH3)
?U |lZ~o Methane (CH4)
_PIk,!< 5.5 Spectra of the Alkali HMides
F}X_I 5.6 Transition Metal Dihalides
J?&9ofj& 5.7 Hydrocarbons
4:.M*Dz 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
wQ5__"D 5.7.2 Linear Polymers
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RY~;i 5.8 Insulating Solids with Valence d Electrons
5GKz@as8 5.8.1 The NiO Problem
|s:!LU&OL\ 5.8.2 Mort Insulation
"P6MLf1 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
_#+i;$cO-X 5.8.4Band Structures of Transition Metal Compounds
sdb#K?l 5.9 High—Temperature Superconductors
p s2C8;zT 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
n3(HA 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
2h=RNU| 5.9.3 The Superconducting Gap
L,i-T:Z~= 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
0^+W"O 5.9.5 Core—Level Shifts
:z[SI{Y 5.10 The Fermi Liquid and the Luttinger Liquid
99`xY$ 5.11 Adsorbed Molecules
t?\osPL 5.11.1 Outline
@c.pOX[]m, 5.11.2 CO on Metal Surfaces
MStaP;| References
C<3An_Dy m`/OO;/; 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
BEw(SQH 6.1 Theory of Photoemission:A Summary of the Three-Step Model
'G&w[8mqY 6.2 Discussion of the Photocurrent
d$!ibL#o 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
YJ6Xq||_ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
Cd4G&(= 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
(j(6%U 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
[Mx+t3M 6.3.1 Band Structure Regime
7j^,4; 6.3.2 XPS Regime
^Kn}{m/3Y 6.3.3 Surface Emission
o.,hCg)X 6.3.4 One-Step Calculations
JH 8^ZP:d' 6.4 Thermal Effects
},l3N K 6.5 Dipole Selection Rules for Direct Optical Transitions
BwR)--75 References
oZQu&O' Lr`yl$6 7.Band Structtire and Angular-Resolved Photoelectron Spectra
\n}cx~j 7.1 Free-Electron Final—State Model
Qk((H~I} 7.2 Methods Employing Calculated Band Structures
1c]GS&(RP 7.3 Methods for the Absolute Determination of the Crystal Momentum
Ra/S46$ 7.3.1 Triangulation or Energy Coincidence Method
;e+ErN`a.~ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
lyP<&<Y5 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
HM`;%0T0( 7.3.4 The Surface Emission Method and Electron Damping
[l0>pHl@ 7.3.5 The Very-Low-Energy Electron Diffraction Method
`U(FdT 7.3.6 The Fermi Surface Method
7v{Dwg 7.3.7 Intensities and Their Use in Band-Structure Determinations
qTG/7tn
" 7.3.8 Summary
LVX.s tN#p 7.4 Experimental Band Structures
=m UtBD.; 7.4.1 One- and Two-Dimensional Systems
z&w@67
>j 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
{<V{0
s% 7..4.3UPS Band Structures and XPS Density of States
Z\n
nVM= 7.5 A Comment
06ZyR@.@v References
tks1*I$S< `rvS(p[s 8.Surface States, Surface Effects
d-X<+&VZ 8.1 Theoretical Considerations
wtK+\Qnb 8.2 Experimental Results on Surface States
?e0ljx; 8.3 Quantum-Well States
n* uT 8.4 Surface Core-Level Shifts
#}o*1 References
G#UO>i0jy s_/CJ6s 9.Inverse Photoelectron Spectroscopy
q>t#5Z81 9.1 Surface States
m)V%l0 9.2 Bulk Band Structures
t~3!| @3i 9.3 Adsorbed Molecules
P9BShC5 References
5LR
k)@t l4RZ!K*X_" 10. Spin-Polarized Photoelectron Spectroscopy
O|d"0P 10.1 General Description
W2'u]1bs 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
m;'ebkq 10.3 Magnetic Dichroism
?|kwYA$4o References
J.$N<. vkp_v1F%+ 11. Photoelectron Diffraction
",Mr+;;:[ 11.1 Examples
;O+=
6>W 11.2 Substrate Photoelectron Diffraction
N:_.z~>% 11.3 Adsorbate Photoelectron Diffraction
uWkW T.>$ 11.4 Fermi Surface Scans
7*.nd References
,?S1e# 3VaL%+T$, Appendix
]V^ >aUlj A.1 Table of Binding Energies
UyENzK<%u A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
Zcjh A.3 Compilation of Work Functions
s+DOr$\ References
e w?4; Index