光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
EOu[X'gLr r'{N_|:vv 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
/A,w{09G /g+-{+sx 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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W/BPf{U &^#iS<s1 目录
M;y*`<x 1. Introduction and Basic Principles
=9ff983 1.1 Historical Development
a r8iuwfZ 1.2 The Electron Mean Free Path
H5Eso*v@ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
xAd@.^ 1.4 Experimental Aspects
?lD)J?j 1.5 Very High Resolution
.o`Io[io 1.6 The Theory of Photoemission
#'1dCh
vZ 1.6.1 Core-Level Photoemission
;:
_K,FU 1.6.2 Valence-State Photoemission
TSewq4`K 1.6.3 Three-Step and One-Step Considerations
xkRMg2X.>9 1.7 Deviations from the Simple Theory of Photoemission
3,q?WH%_ References
\7b, Mz! \:{K",2 2. Core Levels and Final States
wO%lM 2.1 Core-Level Binding Energies in Atoms and Molecules
.kU^)H"l 2.1.1 The Equivalent-Core Approximation
~)_Nh 2.1.2 Chemical Shifts
K0(
S%v|,} 2.2 Core-Level Binding Energies in Solids
oB5\^V$ 2.2.1 The Born-Haber Cycle in Insulators
B;N<{Gb 2.2.2 Theory of Binding Energies
CBf[$[e 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
_N|%i J5 2.3 Core Polarization
ZS=H1 2.4 Final-State Multiplets in Rare-Earth Valence Bands
b]z_2h~` 2.5 Vibrational Side Bands
Z qn$ >mG- 2.6 Core Levels of Adsorbed Molecules
kE<CuO 2.7 Quantitative Chemical Analysis from Core-Level Intensities
50Gr\ References
Qb?a[[3 JS ^Cc 3. Charge-Excitation Final States: Satellites
+^(_S9CO 3.1 Copper Dihalides; 3d Transition Metal Compounds
Ll; v[Y 3.1.1 Characterization of a Satellite
FCNYfjB% 3.1.2 Analysis of Charge-Transfer Satellites
})^eaLBR4 3.1.3 Non-local Screening
N2s"$Ttq 3.2 The 6-eV Satellite in Nickel
7d>w]R,Z 3.2.1 Resonance Photoemission
_1E c54D 3.2.2 Satellites in Other Metals
{Ia1H 3.3 The Gunnarsson-Sch6nhammer Theory
E<+ G5j 3.4 Photoemission Signals and Narrow Bands in Metals
8%B_nVc References
)-!)D dlfjx 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
B,%6sa~I 4.1 Theory
p*lP9[7 4.1.1 General
8a8a:d 4.1.2 Core-Line Shape
$,by!w'e:l 4.1.3 Intrinsic Plasmons
id9QfJ9t 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
z9IW&f~~P 4.1.5 The Total Photoelectron Spectrum
2o<*rH 4.2 Experimental Results
trrNu 4.2.1 The Core Line Without Plasmons
cJ$jU{} 4.2.2 Core-Level Spectra Including Plasmoas
HI|egf@ 4.2.3 Valence-Band Spectra of the Simple Metals
Cydo~/ 4.2.4 Simple Metals: A General Comment
]dGH
i \ 4.3 The Background Correction
*Lrrl References
|MGT8C&^! ]2f-oz*hU 5. Valence Orbitals in Simple Molecules and Insulating Solids
]pe7I
P 5.1 UPS Spectra of Monatomic Gases
z8a{M$-Q 5.2 Photoelectron Spectra of Diatomic Molecules
3_
J'+ 5.3 Binding Energy of the H2 Molecule
Vc9Bg2f5 5.4 Hydrides Isoelectronic with Noble Gases
qc,E azmU Neon (Ne)
]'xci"qV` Hydrogen Fluoride (HF)
v[uVAbfQ Water (H2O)
H.l0kBeG Ammonia (NH3)
BN]o!Y Methane (CH4)
ZVH 9je 5.5 Spectra of the Alkali HMides
yT OZa-
5.6 Transition Metal Dihalides
,YM=?No 5.7 Hydrocarbons
gWU#NRRc 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
p]S'pzh 5.7.2 Linear Polymers
F>{bVPh
VA 5.8 Insulating Solids with Valence d Electrons
Qc*p+N+$ 5.8.1 The NiO Problem
Te}gmt+#% 5.8.2 Mort Insulation
UNb7WN 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
d4IQ;u 5.8.4Band Structures of Transition Metal Compounds
0O'M^[=d.8 5.9 High—Temperature Superconductors
-x6_HibbD 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
QmSj6pB> 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
;q-c[TZC 5.9.3 The Superconducting Gap
sT1OAK\^ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
4qDO(YWf 5.9.5 Core—Level Shifts
46T(1_Xt~ 5.10 The Fermi Liquid and the Luttinger Liquid
E!}'cxb^ 5.11 Adsorbed Molecules
?&:N|cltD 5.11.1 Outline
^n~Kr1}nj 5.11.2 CO on Metal Surfaces
U>!TM##1QD References
]~
N. qmpT G:+ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
R-pON4D"* 6.1 Theory of Photoemission:A Summary of the Three-Step Model
yj_/:eX 6.2 Discussion of the Photocurrent
]vcT2lr] 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
4Wz1O$* 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
)( 3)^/Xz 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
D#'CRJh;7 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
m
%+'St|qr 6.3.1 Band Structure Regime
Oi|cTZ@A- 6.3.2 XPS Regime
O2 Y|<m 6.3.3 Surface Emission
@dK_w'W 6.3.4 One-Step Calculations
nWCJY:q;5 6.4 Thermal Effects
rV"3oM]Lo 6.5 Dipole Selection Rules for Direct Optical Transitions
0aR.ct% References
.sit5BX kPy7e~ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
,DHH5sDCn 7.1 Free-Electron Final—State Model
?@x$ h 7.2 Methods Employing Calculated Band Structures
[YlRz 7.3 Methods for the Absolute Determination of the Crystal Momentum
a++gwl 7.3.1 Triangulation or Energy Coincidence Method
n>JJ Xw,, 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
%Jl6e}! 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
4Kj8i 7.3.4 The Surface Emission Method and Electron Damping
B7C<;`5TiD 7.3.5 The Very-Low-Energy Electron Diffraction Method
Se[=$W 7.3.6 The Fermi Surface Method
H{E(=S 7.3.7 Intensities and Their Use in Band-Structure Determinations
^0_ > 7.3.8 Summary
*cFGDQ!
7.4 Experimental Band Structures
fMf; 7.4.1 One- and Two-Dimensional Systems
&/' O?HWl 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
^`xS|Sq1D 7..4.3UPS Band Structures and XPS Density of States
x^[0UA]S9 7.5 A Comment
zuMz6#aCC8 References
5![ ILa_ ]c_lNHssmq 8.Surface States, Surface Effects
ec^{ez@` 8.1 Theoretical Considerations
z4J\BB 8.2 Experimental Results on Surface States
'9vsv\A& 8.3 Quantum-Well States
c9uu4%KG6< 8.4 Surface Core-Level Shifts
1l}Am>} References
'Eia=@ ffB<qf)?G 9.Inverse Photoelectron Spectroscopy
r.LO j6c 9.1 Surface States
b[&ri:AC 9.2 Bulk Band Structures
-
]We|{ 9.3 Adsorbed Molecules
?gU-a References
:O,,fJ<x.O #WDpiV7B 10. Spin-Polarized Photoelectron Spectroscopy
-=:tlH
n 10.1 General Description
K vPLA{ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
Ia9!ucN7DA 10.3 Magnetic Dichroism
_{LmJ?! References
B2BG*xa &2y9J2aA 11. Photoelectron Diffraction
'Q7t5v@FF 11.1 Examples
WzdlrkD 11.2 Substrate Photoelectron Diffraction
):+^893) 11.3 Adsorbate Photoelectron Diffraction
/HqD4GDoug 11.4 Fermi Surface Scans
FbdC3G|oA References
8j]QnH0& 01aw+o Appendix
ZS3T1
<z A.1 Table of Binding Energies
ept:<!4 A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
S._h->5f A.3 Compilation of Work Functions
%0815
5M References
\Ym$to Index