光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
SwSBQq%h]M D}\%
Q # 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
<5C3c&sds 9O@eJ$ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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8LR_K]\ 7c+TS-- 目录
#XC\=pZX 1. Introduction and Basic Principles
~p8-#A)X,) 1.1 Historical Development
/p X\)wi 1.2 The Electron Mean Free Path
Z$HYXm 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
7CM<"pV 1.4 Experimental Aspects
Bv!j.$0d{ 1.5 Very High Resolution
(B,CL222x 1.6 The Theory of Photoemission
":eHR}Hzx 1.6.1 Core-Level Photoemission
R:i7Rb2C 1.6.2 Valence-State Photoemission
JsVW:8QO~ 1.6.3 Three-Step and One-Step Considerations
`C] t2^ 1.7 Deviations from the Simple Theory of Photoemission
oh#6>| References
t[iE > !:rQ@PSy9 2. Core Levels and Final States
3Yg/-=U( 2.1 Core-Level Binding Energies in Atoms and Molecules
I&R4.;LW 2.1.1 The Equivalent-Core Approximation
yy/wSk 2.1.2 Chemical Shifts
Tfs7SC8ta 2.2 Core-Level Binding Energies in Solids
SaQ_%-p 2.2.1 The Born-Haber Cycle in Insulators
-br/ 2.2.2 Theory of Binding Energies
[T~O%ly7x& 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
)Hl;9 2.3 Core Polarization
,Iwri\ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
Wx;9N 2.5 Vibrational Side Bands
x:@Ht TX 2.6 Core Levels of Adsorbed Molecules
g3Kc? wTC 2.7 Quantitative Chemical Analysis from Core-Level Intensities
/g@.1z1w References
R}>Gk K^s!0[6 3. Charge-Excitation Final States: Satellites
@ZD1HA,h" 3.1 Copper Dihalides; 3d Transition Metal Compounds
h_x"/z& 3.1.1 Characterization of a Satellite
^Zydy 3.1.2 Analysis of Charge-Transfer Satellites
TQ>kmHWf/ 3.1.3 Non-local Screening
}UQBaqDH 3.2 The 6-eV Satellite in Nickel
:m^eNS6: 3.2.1 Resonance Photoemission
QfT&y & 3.2.2 Satellites in Other Metals
T4o}5sq}S 3.3 The Gunnarsson-Sch6nhammer Theory
I)Lg=n$ 3.4 Photoemission Signals and Narrow Bands in Metals
}T4"#'` References
$>8+t>| j4+hWalm 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
WR gAc% 4.1 Theory
!u>29VN 4.1.1 General
p24sWDf 4.1.2 Core-Line Shape
5NBc8h7 V 4.1.3 Intrinsic Plasmons
l|U=(aA]h 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
URX>(Y}g9^ 4.1.5 The Total Photoelectron Spectrum
!-LPFy> 4.2 Experimental Results
q
( H^H 4.2.1 The Core Line Without Plasmons
IkL|bV3E0 4.2.2 Core-Level Spectra Including Plasmoas
Hc5@gN 4.2.3 Valence-Band Spectra of the Simple Metals
&tHT6,Xv( 4.2.4 Simple Metals: A General Comment
tlI3jrgw 4.3 The Background Correction
$PHKI B( References
76mQ$ze 8O("o7~" 5. Valence Orbitals in Simple Molecules and Insulating Solids
L?4c8!Q 5.1 UPS Spectra of Monatomic Gases
`3/,- 5.2 Photoelectron Spectra of Diatomic Molecules
H_vOZ0 5.3 Binding Energy of the H2 Molecule
@H1pPr 5.4 Hydrides Isoelectronic with Noble Gases
0[);v/@Ho Neon (Ne)
}g5h"N\$o Hydrogen Fluoride (HF)
)Xl/|YD Water (H2O)
DJ[U^dWRn Ammonia (NH3)
.oN<c]iqE Methane (CH4)
IAhyGD{b 5.5 Spectra of the Alkali HMides
\SA5@.W 5.6 Transition Metal Dihalides
kIP~XV~ 5.7 Hydrocarbons
=pN?h<dc 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
T"dX)~E; 5.7.2 Linear Polymers
*N[.']#n 5.8 Insulating Solids with Valence d Electrons
fPZBm&`C 5.8.1 The NiO Problem
J$j&j` 5.8.2 Mort Insulation
ShF
][v1L 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
3yZtyXRPn 5.8.4Band Structures of Transition Metal Compounds
Xe:B* 5.9 High—Temperature Superconductors
~EpMO]I 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
\*v}IO>2}) 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
k2,n:7 5.9.3 The Superconducting Gap
#Z98D9Pv`o 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
J0C<Qb[ 5.9.5 Core—Level Shifts
U$ _?T-x 5.10 The Fermi Liquid and the Luttinger Liquid
H.v`JNs( 5.11 Adsorbed Molecules
IP-CN 5.11.1 Outline
-r/# 20Y 5.11.2 CO on Metal Surfaces
Bwn9ZYu#r References
2RT9Q!BX{ yQM7QLbTk 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
uy~5!i& 6.1 Theory of Photoemission:A Summary of the Three-Step Model
&5O 6.2 Discussion of the Photocurrent
LV4x9?& 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
Q^b_+M 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
k_-=:(Z 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
f/eT4y 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
/^P^K 6.3.1 Band Structure Regime
S%kE<M? 6.3.2 XPS Regime
05=O5<l
6.3.3 Surface Emission
F,%qG, 6.3.4 One-Step Calculations
]J~37 35] 6.4 Thermal Effects
;7K5Bo 6.5 Dipole Selection Rules for Direct Optical Transitions
bxqXFy/I References
j<R,}nmD3\ {!o-y= 7.Band Structtire and Angular-Resolved Photoelectron Spectra
h"
P4 7.1 Free-Electron Final—State Model
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