光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
YnX6U1/^ EN~ha:9 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
_,E! < yA-UXKT 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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Tg#%5~IX =VDtZSa!$^ 目录
aZYs?b>Gm 1. Introduction and Basic Principles
l|~SVk| 1.1 Historical Development
|PW.CV0, 1.2 The Electron Mean Free Path
OwG:+T_ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
oA$]% 1.4 Experimental Aspects
o`ijdg!5qG 1.5 Very High Resolution
tU(vt0~b 1.6 The Theory of Photoemission
mi$*,fz 1.6.1 Core-Level Photoemission
Mj- B;r 1.6.2 Valence-State Photoemission
1M/_:UH` 1.6.3 Three-Step and One-Step Considerations
NW@guhK. 1.7 Deviations from the Simple Theory of Photoemission
@1G`d53N References
#
>L^W7^ BJ7m3[lz 2. Core Levels and Final States
FQ6{NMz,h 2.1 Core-Level Binding Energies in Atoms and Molecules
nV+]jQ~o 2.1.1 The Equivalent-Core Approximation
nXcOFU 2.1.2 Chemical Shifts
9x[|75}l 2.2 Core-Level Binding Energies in Solids
5nJmabw3 2.2.1 The Born-Haber Cycle in Insulators
\l9S5%L9 2.2.2 Theory of Binding Energies
!JVpR]lWS 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
lhhp6-r 2.3 Core Polarization
@mrGG F 2.4 Final-State Multiplets in Rare-Earth Valence Bands
'9#h^. 2.5 Vibrational Side Bands
z2.Z xL"* 2.6 Core Levels of Adsorbed Molecules
Zp*0%x!e 2.7 Quantitative Chemical Analysis from Core-Level Intensities
[}!obbM References
(3M7 RpsL@ q<*UeyE
S 3. Charge-Excitation Final States: Satellites
!aub@wH3 3.1 Copper Dihalides; 3d Transition Metal Compounds
^\zf8kPti 3.1.1 Characterization of a Satellite
4mJ[Wr\y 3.1.2 Analysis of Charge-Transfer Satellites
w0N8a% 3.1.3 Non-local Screening
SRf.8j 3.2 The 6-eV Satellite in Nickel
74q|FQ 3.2.1 Resonance Photoemission
J`x!c9 zg7 3.2.2 Satellites in Other Metals
3"J85V%h]n 3.3 The Gunnarsson-Sch6nhammer Theory
QnNddCiu= 3.4 Photoemission Signals and Narrow Bands in Metals
5(sWV:_2 References
iH""dtO dY%>C75O 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
2
.)`8|c9 4.1 Theory
#'jd.'> 4.1.1 General
-v7O*xm" 4.1.2 Core-Line Shape
}c~o3t(7`b 4.1.3 Intrinsic Plasmons
SvD^'(
x 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
-YHyJs-bU 4.1.5 The Total Photoelectron Spectrum
5Myp#!|x: 4.2 Experimental Results
juc;]CHt' 4.2.1 The Core Line Without Plasmons
*yxn*B_xZ 4.2.2 Core-Level Spectra Including Plasmoas
49m}~J=* 4.2.3 Valence-Band Spectra of the Simple Metals
e+=P)Zp/ 4.2.4 Simple Metals: A General Comment
SYsbe 5j 4.3 The Background Correction
G`"
9/FI7 References
;3H#8x- 79JU 5. Valence Orbitals in Simple Molecules and Insulating Solids
9!06R-h 5.1 UPS Spectra of Monatomic Gases
0ynvn9@t 5.2 Photoelectron Spectra of Diatomic Molecules
#fR~7K R 5.3 Binding Energy of the H2 Molecule
=`MU*Arcs[ 5.4 Hydrides Isoelectronic with Noble Gases
D-IXO@x Neon (Ne)
E)=X8y Hydrogen Fluoride (HF)
?pJUbZ#J Water (H2O)
&^4 E )F Ammonia (NH3)
3l8k O Methane (CH4)
>^fkHbgNQ 5.5 Spectra of the Alkali HMides
\h}a?T6 5.6 Transition Metal Dihalides
8QYM/yAM 5.7 Hydrocarbons
>X"V 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
xfyUT^ 5.7.2 Linear Polymers
*3>$f.QU 5.8 Insulating Solids with Valence d Electrons
K^'NG! 5.8.1 The NiO Problem
&:"[hU 5.8.2 Mort Insulation
O$Z<R:vVA 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
8={"j 5.8.4Band Structures of Transition Metal Compounds
CkJ\v%JAW 5.9 High—Temperature Superconductors
{tlt5p!4 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
C3p/|{TP
5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
yj48GQP] 5.9.3 The Superconducting Gap
i$ :\, 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
,`ZIW 5.9.5 Core—Level Shifts
a8Q=_4
l 5.10 The Fermi Liquid and the Luttinger Liquid
*&VqAc%qD 5.11 Adsorbed Molecules
UFoxv) 5.11.1 Outline
L,B#%t 5.11.2 CO on Metal Surfaces
v)a$;P% References
~J Xqyw} (K(6`~ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
j5yxdjx9 6.1 Theory of Photoemission:A Summary of the Three-Step Model
9.
7XRxR^ 6.2 Discussion of the Photocurrent
'kz[Gh*8 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
`T]1u4^E 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
0Q1sJDa. 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
8"\g?/ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
RI
q9wD}4( 6.3.1 Band Structure Regime
ZKv^q%92 6.3.2 XPS Regime
%;Dp~T`0 6.3.3 Surface Emission
BrQXSN$i 6.3.4 One-Step Calculations
P;#}@ /E 6.4 Thermal Effects
smM*HDK 6.5 Dipole Selection Rules for Direct Optical Transitions
;
iK9'u References
+Xg]@IS-eg f;k'dqlv 7.Band Structtire and Angular-Resolved Photoelectron Spectra
*0
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:$`"M#vMX 7.2 Methods Employing Calculated Band Structures
\v'\
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FD&"k=p+X 7.3.1 Triangulation or Energy Coincidence Method
HktvUJ(Ii 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
3',|HA /x 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
MU ;
L7^ 7.3.4 The Surface Emission Method and Electron Damping
) DzbJ} 7.3.5 The Very-Low-Energy Electron Diffraction Method
R0n#FL^E 7.3.6 The Fermi Surface Method
BihXYux* 7.3.7 Intensities and Their Use in Band-Structure Determinations
j(`L)/|O 7.3.8 Summary
@} 61D 7.4 Experimental Band Structures
y3 R+060\3 7.4.1 One- and Two-Dimensional Systems
F|3 =Cl 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
q5irKT*Hs 7..4.3UPS Band Structures and XPS Density of States
1HF=,K+ 7.5 A Comment
?~;8Y=O References
W+&w'~M =c-,uW11[ 8.Surface States, Surface Effects
Q)7iu 8.1 Theoretical Considerations
ng-g\&- 8.2 Experimental Results on Surface States
<4gT8kQ$x 8.3 Quantum-Well States
`@acQs;0 8.4 Surface Core-Level Shifts
F0O/SI(cA References
w+P?JR!)+ ?3Ytn+Py 9.Inverse Photoelectron Spectroscopy
ZE ())W" 9.1 Surface States
OIuEC7XM^C 9.2 Bulk Band Structures
p/4\O 9.3 Adsorbed Molecules
R).?lnS References
;$Eg4uX poqcoSL"} 10. Spin-Polarized Photoelectron Spectroscopy
a)+;<GZ~ 10.1 General Description
,Qgxf';+$ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
ltKUpRE\? 10.3 Magnetic Dichroism
X
8V^ References
q
F\a]e `g2DN#q[0 11. Photoelectron Diffraction
#PzRhanX 11.1 Examples
B cMgfa/ 11.2 Substrate Photoelectron Diffraction
uY,(3x 11.3 Adsorbate Photoelectron Diffraction
A8?uCkG 11.4 Fermi Surface Scans
y{.s
4NT References
q;dg,Om $"d< F3k Appendix
OC$Y8Ofr A.1 Table of Binding Energies
+mReWf:o A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
< sJ A.3 Compilation of Work Functions
0-ISOA& References
n+Ia@$|m Index