光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
6LOnU~l, 09X01X[ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
B8nf,dj?X Ff$L| 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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j| v%)A t9,\Hdo 目录
nG,A@/N 1. Introduction and Basic Principles
wg7V-+@i 1.1 Historical Development
X>1,!I9 1.2 The Electron Mean Free Path
3)F|*F3R 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
KK1gNC4R 1.4 Experimental Aspects
q
0$,*[PH 1.5 Very High Resolution
G<At_YS 1.6 The Theory of Photoemission
T_i:}ul 1.6.1 Core-Level Photoemission
=[H;orMr 1.6.2 Valence-State Photoemission
-(~.6WnhS 1.6.3 Three-Step and One-Step Considerations
S/}2; \Xm 1.7 Deviations from the Simple Theory of Photoemission
FK:;e
lZ References
cGtO
+DE O-ew%@_ 2. Core Levels and Final States
))R5(R 2.1 Core-Level Binding Energies in Atoms and Molecules
%j:]^vqFA 2.1.1 The Equivalent-Core Approximation
J@^8ko 2.1.2 Chemical Shifts
f1`gdQ)H 2.2 Core-Level Binding Energies in Solids
P?8GV%0$ 2.2.1 The Born-Haber Cycle in Insulators
=@m &s^R 2.2.2 Theory of Binding Energies
MC?,UDNd% 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
oo,uO;0G 2.3 Core Polarization
pf%=h
| 2.4 Final-State Multiplets in Rare-Earth Valence Bands
O;z,qo X 2.5 Vibrational Side Bands
M=%l}FSTw( 2.6 Core Levels of Adsorbed Molecules
'[U8}z3 2.7 Quantitative Chemical Analysis from Core-Level Intensities
b1^vd@(lx References
VbJiZw(aR I, -hf=- 3. Charge-Excitation Final States: Satellites
||T2~Q*:y 3.1 Copper Dihalides; 3d Transition Metal Compounds
W0(_~ 3.1.1 Characterization of a Satellite
SHvq.lYJ 3.1.2 Analysis of Charge-Transfer Satellites
]=.\-K 3.1.3 Non-local Screening
)'Oh`$M 3.2 The 6-eV Satellite in Nickel
Gn\_+Pj$ 3.2.1 Resonance Photoemission
qd9c I& 3.2.2 Satellites in Other Metals
B\<Q ;RI2; 3.3 The Gunnarsson-Sch6nhammer Theory
+EFgE1w 3.4 Photoemission Signals and Narrow Bands in Metals
,LTH;<zB) References
IM:=@a{ *meZ8DV2DH 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
`k=bL"T>\ 4.1 Theory
K\>tA)IPSV 4.1.1 General
3Vsc 9B"w 4.1.2 Core-Line Shape
l\BVS) 4.1.3 Intrinsic Plasmons
G %N
$C 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
r>dwDBE 4.1.5 The Total Photoelectron Spectrum
&J55P]7w 4.2 Experimental Results
ZtV9&rd7 4.2.1 The Core Line Without Plasmons
M^MdRu 4.2.2 Core-Level Spectra Including Plasmoas
dI*pDDq# 4.2.3 Valence-Band Spectra of the Simple Metals
\[BK1JP 4.2.4 Simple Metals: A General Comment
4FEk5D 4.3 The Background Correction
IN4=YrM^ References
9!f/aI $i&e[O7T; 5. Valence Orbitals in Simple Molecules and Insulating Solids
$@sEn4h 5.1 UPS Spectra of Monatomic Gases
aY3^C q(r 5.2 Photoelectron Spectra of Diatomic Molecules
JCz@s~f\y 5.3 Binding Energy of the H2 Molecule
y]2qd35u_A 5.4 Hydrides Isoelectronic with Noble Gases
+)k b( Neon (Ne)
E>&n.% Hydrogen Fluoride (HF)
E_Im^a Water (H2O)
D Gr>
2 Ammonia (NH3)
4Yxo~ m( Methane (CH4)
wDcj,:h` 5.5 Spectra of the Alkali HMides
s<*XNNE7 5.6 Transition Metal Dihalides
/rg*p 5.7 Hydrocarbons
_Bj)r}~7# 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
SLO%7%>p 5.7.2 Linear Polymers
q:l>O5 5.8 Insulating Solids with Valence d Electrons
)_1zRT| 9 5.8.1 The NiO Problem
=6woWlf b 5.8.2 Mort Insulation
c#a@n 4 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
L~_9_9c 5.8.4Band Structures of Transition Metal Compounds
7Ok;Lt!x 5.9 High—Temperature Superconductors
g1XZ5P} f 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
q/4YS0CqE 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
"vXxv'0\f 5.9.3 The Superconducting Gap
8S>&WR%jH] 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
'I_Qb$ 5.9.5 Core—Level Shifts
I'PeN0T
f 5.10 The Fermi Liquid and the Luttinger Liquid
7+]=- 5.11 Adsorbed Molecules
/[O(ea$U 5.11.1 Outline
.^N/peUq 5.11.2 CO on Metal Surfaces
GMMp|WV| References
thV>j9' D<|qaHB= 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
}MRd@ 0-?! 6.1 Theory of Photoemission:A Summary of the Three-Step Model
#~SP)Ukp 6.2 Discussion of the Photocurrent
p+l !6 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
_Xn qb+ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
*4_jA]( 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
gfsI6/Y 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
t0z!DOODZP 6.3.1 Band Structure Regime
HU%o6c w 6.3.2 XPS Regime
k:JrHBKv\ 6.3.3 Surface Emission
A6GE,FhsG 6.3.4 One-Step Calculations
hZh9uI7. 6.4 Thermal Effects
mu?Eco`~ 6.5 Dipole Selection Rules for Direct Optical Transitions
fNb`X References
-`<kCW" 3BB%Z6F 7.Band Structtire and Angular-Resolved Photoelectron Spectra
{S,l_d+( 7.1 Free-Electron Final—State Model
(ohq0Y 7.2 Methods Employing Calculated Band Structures
Y3r%B9~ 7.3 Methods for the Absolute Determination of the Crystal Momentum
D_/^+H]1 7.3.1 Triangulation or Energy Coincidence Method
ObLly%|i 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
/3eKN 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
#k_HN}B 7.3.4 The Surface Emission Method and Electron Damping
!6s"]WvF 7.3.5 The Very-Low-Energy Electron Diffraction Method
mocI&=EF2X 7.3.6 The Fermi Surface Method
=0^Ruh 7.3.7 Intensities and Their Use in Band-Structure Determinations
_7IKzUn9g[ 7.3.8 Summary
j{Hao\F8 7.4 Experimental Band Structures
z74in8] 7.4.1 One- and Two-Dimensional Systems
0TN;86Mo 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
R&|mdY8 7..4.3UPS Band Structures and XPS Density of States
^&bRX4pYo 7.5 A Comment
=i_-F$pV References
a["2VY6Eq@ s:p[DEj- 8.Surface States, Surface Effects
SV:4GVf 8.1 Theoretical Considerations
r`AuvwHPs[ 8.2 Experimental Results on Surface States
q6_u@:3u 8.3 Quantum-Well States
'rMN=1:iu" 8.4 Surface Core-Level Shifts
/I)yU>o References
[F*.\ '|S%aMLZ) 9.Inverse Photoelectron Spectroscopy
pX&pLaF 9.1 Surface States
!PrwH; 9.2 Bulk Band Structures
o4*+T8[|5 9.3 Adsorbed Molecules
0G7K8`a References
:T]o) A-,up{g 10. Spin-Polarized Photoelectron Spectroscopy
dFH$l 10.1 General Description
9Xl`pEhC 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
%^I88,$&L 10.3 Magnetic Dichroism
JNkwEZhHyg References
[%9noB /%0<p,T 11. Photoelectron Diffraction
3dht!7/ 11.1 Examples
@;<ht c 11.2 Substrate Photoelectron Diffraction
ua5OGx 11.3 Adsorbate Photoelectron Diffraction
TUHi5K 11.4 Fermi Surface Scans
SVv;q?jZ References
Qtbbb3m; HPb]Zj Appendix
6U[4%( A.1 Table of Binding Energies
]%BWIqbr A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
/e]'u&a A.3 Compilation of Work Functions
?;vgUO References
?[)}l9 Index