光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
e[5=?p@| J})#43P 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
u+
wKs` D)0pm?*5A 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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*^h$%<QI W.nQYH 目录
Z.!tp 1. Introduction and Basic Principles
%+>t @F,GM 1.1 Historical Development
6LVJ*sjSy 1.2 The Electron Mean Free Path
<OYy;s 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
g)o?nAr 1.4 Experimental Aspects
I\8f`l 1.5 Very High Resolution
49/j9#hr 1.6 The Theory of Photoemission
R9dC$Y]\M 1.6.1 Core-Level Photoemission
G{4~{{tI 1.6.2 Valence-State Photoemission
[1Os.G2 1.6.3 Three-Step and One-Step Considerations
Yh^~4S? 1.7 Deviations from the Simple Theory of Photoemission
6[iu CMOZ References
0u,OW ,[ogh 2. Core Levels and Final States
T*m;G( 2.1 Core-Level Binding Energies in Atoms and Molecules
@|7Ma/8v 2.1.1 The Equivalent-Core Approximation
gy%/zbZx 2.1.2 Chemical Shifts
PA=.)8 2.2 Core-Level Binding Energies in Solids
WKHEU)'! 2.2.1 The Born-Haber Cycle in Insulators
xt{f+c@P 2.2.2 Theory of Binding Energies
d{~5tv- H 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
$
N7J:Q 2.3 Core Polarization
h[Hn*g 2.4 Final-State Multiplets in Rare-Earth Valence Bands
AdCi*="m 2.5 Vibrational Side Bands
%cPz>PTW@ 2.6 Core Levels of Adsorbed Molecules
OJ2O?Te8 2.7 Quantitative Chemical Analysis from Core-Level Intensities
Glt%%TJb References
KINKq`Sx vZ<@m2 3. Charge-Excitation Final States: Satellites
."8bW^: 3.1 Copper Dihalides; 3d Transition Metal Compounds
6f$h1$$)^ 3.1.1 Characterization of a Satellite
n$z}DE5 # 3.1.2 Analysis of Charge-Transfer Satellites
h3 Bs 3.1.3 Non-local Screening
=f4v: j}'| 3.2 The 6-eV Satellite in Nickel
2f;fdzjk8K 3.2.1 Resonance Photoemission
9PpPAF 3.2.2 Satellites in Other Metals
$U{\T4 3.3 The Gunnarsson-Sch6nhammer Theory
,g2oqq ? 3.4 Photoemission Signals and Narrow Bands in Metals
vCPiT2G References
]w)*8
w.) Q@7-UIV|q 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
`2 vv8cg^ 4.1 Theory
t1y
hU"(J 4.1.1 General
/1h
0l; 4.1.2 Core-Line Shape
0Q2P"1>KT/ 4.1.3 Intrinsic Plasmons
R0 g- 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
"F,d}3} 4.1.5 The Total Photoelectron Spectrum
d"7l<y5 4.2 Experimental Results
ujo3"j[b 4.2.1 The Core Line Without Plasmons
;M<jQntqS{ 4.2.2 Core-Level Spectra Including Plasmoas
f1Ak0s,zrc 4.2.3 Valence-Band Spectra of the Simple Metals
o0f{ePZ= 4.2.4 Simple Metals: A General Comment
O{sb{kk 4.3 The Background Correction
GMY"*J<E References
8T}Ycm5} L_3undy, 5. Valence Orbitals in Simple Molecules and Insulating Solids
{5ujKQOcR 5.1 UPS Spectra of Monatomic Gases
r306`)kX 5.2 Photoelectron Spectra of Diatomic Molecules
>
xc7Hr~ 5.3 Binding Energy of the H2 Molecule
G=[=[o\ 5.4 Hydrides Isoelectronic with Noble Gases
"R"7'sJMI Neon (Ne)
q#8$@*I Hydrogen Fluoride (HF)
!,f#oCL Water (H2O)
Rf&~7h'+ Ammonia (NH3)
#$<7 Methane (CH4)
r9x.c7=O 5.5 Spectra of the Alkali HMides
:HDl-8]Lw 5.6 Transition Metal Dihalides
`M
"O # 5.7 Hydrocarbons
LI>tN R~ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
o6 FSSKM 5.7.2 Linear Polymers
SiD [54OM 5.8 Insulating Solids with Valence d Electrons
U%swqle4 5.8.1 The NiO Problem
CB<i 5.8.2 Mort Insulation
CC(At.dd 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
|@}Yady@C 5.8.4Band Structures of Transition Metal Compounds
zi^T?<t 5.9 High—Temperature Superconductors
6[-N}) 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
H#/}FoBiS 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
Z3ucJH/)V 5.9.3 The Superconducting Gap
DI P( 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
XJ3 5Z+M 5.9.5 Core—Level Shifts
rtl|zCst 5.10 The Fermi Liquid and the Luttinger Liquid
YS}uJ&WoF 5.11 Adsorbed Molecules
4t(V)1+ 5.11.1 Outline
l s(lL\ 5.11.2 CO on Metal Surfaces
NH?q/4=I0W References
DP rFB y cU,]^/0Y 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
3NEbCILF 6.1 Theory of Photoemission:A Summary of the Three-Step Model
vgfLI}|5 6.2 Discussion of the Photocurrent
tgu}^TfKkg 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
6cCC+*V{ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
qOyg&]7 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
{x3"/sF 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
DE GEr- 6.3.1 Band Structure Regime
67Z.aaXD1 6.3.2 XPS Regime
QLq^[>n 6.3.3 Surface Emission
&cty&(2p 6.3.4 One-Step Calculations
F_m[EB 6.4 Thermal Effects
82w='~y 6.5 Dipole Selection Rules for Direct Optical Transitions
VEolyPcsg& References
hpftVEB N# Ru`; 7.Band Structtire and Angular-Resolved Photoelectron Spectra
/65ddt 7.1 Free-Electron Final—State Model
(T1)7%Xs 7.2 Methods Employing Calculated Band Structures
b%w?YR 7.3 Methods for the Absolute Determination of the Crystal Momentum
[m>kOv6>^ 7.3.1 Triangulation or Energy Coincidence Method
_Y7uM6HL\ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
l{:7*U{d 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
3JB?G>\! 7.3.4 The Surface Emission Method and Electron Damping
[25[c><:w" 7.3.5 The Very-Low-Energy Electron Diffraction Method
Mlr\#BO"9 7.3.6 The Fermi Surface Method
] m$;ra] 7.3.7 Intensities and Their Use in Band-Structure Determinations
(#Vkk]-p 7.3.8 Summary
x|#R$^4CY 7.4 Experimental Band Structures
3`ov?T(H 7.4.1 One- and Two-Dimensional Systems
%P!6cyQS 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
58x=CN\QU 7..4.3UPS Band Structures and XPS Density of States
k"*A@ 7.5 A Comment
J2X;=X5 References
[:cy.K!Uo% ]>E)0<t 8.Surface States, Surface Effects
5PY,}1` 8.1 Theoretical Considerations
w8!S;~xKI 8.2 Experimental Results on Surface States
M2UF3xD 8.3 Quantum-Well States
+RXKI{0Km 8.4 Surface Core-Level Shifts
![=C`O6K References
hn: RAw/Q$I 9.Inverse Photoelectron Spectroscopy
xgw[)!g^\ 9.1 Surface States
sEpY&6* 9.2 Bulk Band Structures
ZWZRG-:&H 9.3 Adsorbed Molecules
inO)Y]|f References
UY@^KT] 7 &y'\ 10. Spin-Polarized Photoelectron Spectroscopy
ao2NwH## 10.1 General Description
clE_a? 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
#bxU I{*J 10.3 Magnetic Dichroism
Wn61;kV_) References
T%GdvtmS> (9!$p|d* 11. Photoelectron Diffraction
X?m"86L 11.1 Examples
_J'V5]=4 11.2 Substrate Photoelectron Diffraction
84xA/BR W 11.3 Adsorbate Photoelectron Diffraction
}m!L2iK4qk 11.4 Fermi Surface Scans
H/qv%!/o References
U ?vG?{A ZE+VLV v Appendix
HYd&.*41rE A.1 Table of Binding Energies
;?-A4!V, A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
ZCdlTdY A.3 Compilation of Work Functions
F:p'%#3rU/ References
0L3v[%_j" Index