光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
/R)wM#& K@D\5s|1| 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
$<}c[Nm {Mx(|)WkL 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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NxT"A)u )9QtnM 目录
Rj8%% G-pt 1. Introduction and Basic Principles
JfY*#({y 1.1 Historical Development
1yy?1&88S 1.2 The Electron Mean Free Path
v9*m0|T0M 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
xO~ElzGm 1.4 Experimental Aspects
0#q=-M/?` 1.5 Very High Resolution
ZL MH~cc 1.6 The Theory of Photoemission
Ui{%q@ 1.6.1 Core-Level Photoemission
Vz{+3vfra6 1.6.2 Valence-State Photoemission
6cQgp]% 1.6.3 Three-Step and One-Step Considerations
KyvZ?R 1.7 Deviations from the Simple Theory of Photoemission
?$ r`T]>`2 References
d0cL9&~qW NFK`, 2. Core Levels and Final States
$6hPTc<C 2.1 Core-Level Binding Energies in Atoms and Molecules
@ZKf3,J0 2.1.1 The Equivalent-Core Approximation
I.2J-pu} 2.1.2 Chemical Shifts
x&}]8S) 2.2 Core-Level Binding Energies in Solids
jG5HW*>k0 2.2.1 The Born-Haber Cycle in Insulators
LF<&gC 2.2.2 Theory of Binding Energies
gEA SYIQ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
]I*c:(qwu 2.3 Core Polarization
!3v&+Jrf6 2.4 Final-State Multiplets in Rare-Earth Valence Bands
FMfpjuHk 2.5 Vibrational Side Bands
gL; Kie6Z 2.6 Core Levels of Adsorbed Molecules
ZzT=m*tQ& 2.7 Quantitative Chemical Analysis from Core-Level Intensities
0c_xPBbB+ References
:|7#D,2 5=dL` 3. Charge-Excitation Final States: Satellites
@[$_cGR7 3.1 Copper Dihalides; 3d Transition Metal Compounds
[,%=\%5 3.1.1 Characterization of a Satellite
4ls:BO;k] 3.1.2 Analysis of Charge-Transfer Satellites
OMGggg 3.1.3 Non-local Screening
i;[y!U 3.2 The 6-eV Satellite in Nickel
0}{xH 3.2.1 Resonance Photoemission
<N<Q9}`V 3.2.2 Satellites in Other Metals
,S)r%[ru^ 3.3 The Gunnarsson-Sch6nhammer Theory
O 4 !$ 3.4 Photoemission Signals and Narrow Bands in Metals
%|Ps|iV References
IG-\&
5xY{Q 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
95DEuReKi 4.1 Theory
Rx%S<i;9 4.1.1 General
<v"o+ 4.1.2 Core-Line Shape
! -gU~0 4.1.3 Intrinsic Plasmons
n,la<N] 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
w =^.ICyb@ 4.1.5 The Total Photoelectron Spectrum
0lw>mxN 4.2 Experimental Results
y(A' *G9 4.2.1 The Core Line Without Plasmons
J~YT~D2L 4.2.2 Core-Level Spectra Including Plasmoas
GK?ual1 4.2.3 Valence-Band Spectra of the Simple Metals
'U@o!\=a 4.2.4 Simple Metals: A General Comment
|WS)KR ! 4.3 The Background Correction
Cs $5Of( References
QYJ
EUC@ '\Xkvi 5. Valence Orbitals in Simple Molecules and Insulating Solids
1Pf(.&/9_ 5.1 UPS Spectra of Monatomic Gases
BD g]M/{ 5.2 Photoelectron Spectra of Diatomic Molecules
7#8Gn=g 5.3 Binding Energy of the H2 Molecule
*kr/,_K 5.4 Hydrides Isoelectronic with Noble Gases
V\~. Neon (Ne)
I[Ra0Q>([k Hydrogen Fluoride (HF)
5&Oc`5QD Water (H2O)
+A9~h/"kt Ammonia (NH3)
AerU`^ Methane (CH4)
DM.lQ0xk 5.5 Spectra of the Alkali HMides
jX53 owZ 5.6 Transition Metal Dihalides
3"fDFR 5.7 Hydrocarbons
$JE,u'JQ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
-(VJ,)8t2 5.7.2 Linear Polymers
.Po"qoGy 5.8 Insulating Solids with Valence d Electrons
0^;2 5.8.1 The NiO Problem
:=QX ^* 5.8.2 Mort Insulation
L"_XWno 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
=KRM`_QShg 5.8.4Band Structures of Transition Metal Compounds
7 WJ\nK 5.9 High—Temperature Superconductors
bMH~vR 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
ZsGvv]P 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
@SQsEq+A?\ 5.9.3 The Superconducting Gap
gLiJ&H 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
Dc9uq5l 5.9.5 Core—Level Shifts
\0$+*ejz 5.10 The Fermi Liquid and the Luttinger Liquid
'H1~Zhv 5.11 Adsorbed Molecules
Daf|.5>(@ 5.11.1 Outline
MJn-] E 5.11.2 CO on Metal Surfaces
tm1= References
r924!zdbR =C\Tl-$\f 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
F^ q{[Z 6.1 Theory of Photoemission:A Summary of the Three-Step Model
HB07 n4 | 6.2 Discussion of the Photocurrent
'g v0;L 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
*dBy<dIy 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
sqkWQ`Ur 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
FaHOutP 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
(f/(q-7VWt 6.3.1 Band Structure Regime
'u,|*o 6.3.2 XPS Regime
rxCzPF 6.3.3 Surface Emission
)>a~ %~: 6.3.4 One-Step Calculations
xATx2*@X2 6.4 Thermal Effects
E0HqXd? 6.5 Dipole Selection Rules for Direct Optical Transitions
["Zvwes#7 References
FW]tDGJOw /A_:`MAZ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
R >x d*A 7.1 Free-Electron Final—State Model
)e(<YST 7.2 Methods Employing Calculated Band Structures
\C~X_/sg 7.3 Methods for the Absolute Determination of the Crystal Momentum
\"P{8<h.3 7.3.1 Triangulation or Energy Coincidence Method
U-|]A\`)I 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
~Xi@#s~ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
D(b01EQ;d 7.3.4 The Surface Emission Method and Electron Damping
:e<jD_.X 7.3.5 The Very-Low-Energy Electron Diffraction Method
NAYLlW}A 7.3.6 The Fermi Surface Method
3(YvqPp& 7.3.7 Intensities and Their Use in Band-Structure Determinations
hBgE%#`s 7.3.8 Summary
}YwaN'3p! 7.4 Experimental Band Structures
i_qY=*a?y 7.4.1 One- and Two-Dimensional Systems
*WE8J#]d 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
CmEqo;Is 7..4.3UPS Band Structures and XPS Density of States
J[/WBVFDf 7.5 A Comment
xAmtm" References
8SRR)O[)} 41
F;X{Br 8.Surface States, Surface Effects
{C |R@S 8.1 Theoretical Considerations
Nt>^2Mv
8.2 Experimental Results on Surface States
}#z1>y!# 8.3 Quantum-Well States
dsTX?E<R 8.4 Surface Core-Level Shifts
m8n) sw,, References
Gp%po@A&
cILS 9.Inverse Photoelectron Spectroscopy
JCWTB`EB> 9.1 Surface States
7q0_lEh 9.2 Bulk Band Structures
m*^)# 9.3 Adsorbed Molecules
<kB:`&X<\ References
vQWmHv\P ]545:)Q1 10. Spin-Polarized Photoelectron Spectroscopy
0X)vr~` 10.1 General Description
PV68d; $:8 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
5c- P lm% 10.3 Magnetic Dichroism
s5~k]"{j References
v9(5HY !73y(Y%TE 11. Photoelectron Diffraction
tYA@J[" ^ 11.1 Examples
"i&)+dr- 11.2 Substrate Photoelectron Diffraction
Q2
q~m8( 11.3 Adsorbate Photoelectron Diffraction
la[pA 11.4 Fermi Surface Scans
G,C`+1$* References
?(ORk|)kU zx@!8Z Appendix
<83Ky;ry A.1 Table of Binding Energies
@*%3+9`yq A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
s|C[{n<_ A.3 Compilation of Work Functions
Hf4_zd References
n;Bb/Z!~ Index