光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
@:CM<+ r3' DXP 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
&S+*1<|`K `qmwAT 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
*V:U\G RjviHd#DXn
{G vGV iT{4-j7|P4 市场价:¥88.00
V#$QKn`; 优惠价:¥78.60 为您节省:9.40元 (89折)
25`W"x_
.?3roQ ~),%w*L 目录
,_(=w.F
1. Introduction and Basic Principles
NvIg,@} 1.1 Historical Development
rG~W=!bj 1.2 The Electron Mean Free Path
nHbi{,3 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
wxK71OH 1.4 Experimental Aspects
[Uq`B&F: 1.5 Very High Resolution
%K3U`6kHcd 1.6 The Theory of Photoemission
4.,|vtp 1.6.1 Core-Level Photoemission
,{:qbt 1.6.2 Valence-State Photoemission
T7mT:z>: 1.6.3 Three-Step and One-Step Considerations
ZGH
7_K 1.7 Deviations from the Simple Theory of Photoemission
9A4n8,&sm References
SbX^DAlB1 rz|Sjtq 2. Core Levels and Final States
\6a' p
Q, 2.1 Core-Level Binding Energies in Atoms and Molecules
5s^vC2$) 2.1.1 The Equivalent-Core Approximation
t1iz5%`p} 2.1.2 Chemical Shifts
. mO8~Z 2.2 Core-Level Binding Energies in Solids
V+1c<LwT 2.2.1 The Born-Haber Cycle in Insulators
<?KgzIq2 2.2.2 Theory of Binding Energies
R?lTB3" 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
zFFYl7] 2.3 Core Polarization
UGM:'xa<T 2.4 Final-State Multiplets in Rare-Earth Valence Bands
MwQtf(_ 2.5 Vibrational Side Bands
&/^p:I 2.6 Core Levels of Adsorbed Molecules
kb~
s,@p 2.7 Quantitative Chemical Analysis from Core-Level Intensities
YY tVp_) References
bt1bTo EmUt/] 3. Charge-Excitation Final States: Satellites
E%E`\mFD 3.1 Copper Dihalides; 3d Transition Metal Compounds
#
{k$Fk 3.1.1 Characterization of a Satellite
7ZAxhFC 3.1.2 Analysis of Charge-Transfer Satellites
-6_<] 3.1.3 Non-local Screening
%jj-\Gz! 3.2 The 6-eV Satellite in Nickel
"dndhoMq 3.2.1 Resonance Photoemission
w_`;Mn%p 3.2.2 Satellites in Other Metals
r`FTiPD.C 3.3 The Gunnarsson-Sch6nhammer Theory
n3V$Xtxw 3.4 Photoemission Signals and Narrow Bands in Metals
9({ 9 r[U References
Vo{
~D:) ) xV>Va8) 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
$Nvox<d0 4.1 Theory
F3!6}u\F 4.1.1 General
|]q{qsy 4.1.2 Core-Line Shape
[W[awGf 4.1.3 Intrinsic Plasmons
*dB3Gu{
+ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
En-=z`j
G 4.1.5 The Total Photoelectron Spectrum
J
Z@sk2 4.2 Experimental Results
`3[W~Cq 4.2.1 The Core Line Without Plasmons
h-Ks:pcR 4.2.2 Core-Level Spectra Including Plasmoas
OBlQ 4.2.3 Valence-Band Spectra of the Simple Metals
gP8}d*W%b 4.2.4 Simple Metals: A General Comment
.u7grC C 4.3 The Background Correction
4>Ht_B<< References
Gl{2"!mt= >W/mRv& 5. Valence Orbitals in Simple Molecules and Insulating Solids
"\9beK:l 5.1 UPS Spectra of Monatomic Gases
9P
<1/W! 5.2 Photoelectron Spectra of Diatomic Molecules
'dQGb-<_< 5.3 Binding Energy of the H2 Molecule
H<^3H 5.4 Hydrides Isoelectronic with Noble Gases
UDkH'x$= Neon (Ne)
>PdrLwKS Hydrogen Fluoride (HF)
I`@>v%0 Water (H2O)
):=8w.yC Ammonia (NH3)
IwbV+mWQ Methane (CH4)
k?3mFWc 5.5 Spectra of the Alkali HMides
OL#i!ia. 5.6 Transition Metal Dihalides
6eB~S)Ko 5.7 Hydrocarbons
hQzT
=0 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
H,/=<Th;i 5.7.2 Linear Polymers
YyYp-0# 5.8 Insulating Solids with Valence d Electrons
;6]ag< Q 5.8.1 The NiO Problem
rf^IJY[ 5.8.2 Mort Insulation
[ryII hQ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Y>nQ< 5.8.4Band Structures of Transition Metal Compounds
]U4C2}u 5.9 High—Temperature Superconductors
DeN2P 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
ZLP0SCkuR 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
a(-t"OL\ 5.9.3 The Superconducting Gap
/^~)iTwH 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
)h(=X&(d 5.9.5 Core—Level Shifts
- sq=| 5.10 The Fermi Liquid and the Luttinger Liquid
,*L3 5.11 Adsorbed Molecules
tC+11M 5.11.1 Outline
{Aj=Rj@ 5.11.2 CO on Metal Surfaces
X"f] References
r5lPO*?Df nGJ+.z 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
|D;I>O^"R 6.1 Theory of Photoemission:A Summary of the Three-Step Model
FV OPC:}bj 6.2 Discussion of the Photocurrent
_lH:%E* 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
7/=r- 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
UY\E uA9 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
@9]TjZd 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
4Dd]:2|D 6.3.1 Band Structure Regime
}&l%>P 6.3.2 XPS Regime
/I`- 6.3.3 Surface Emission
>#;>6q9_ 6.3.4 One-Step Calculations
K9RRY,JB 6.4 Thermal Effects
7;#o?6!7 6.5 Dipole Selection Rules for Direct Optical Transitions
>\lBbqa#
References
'2p,0Bk9i IS{>(XT{ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
u3 4.
7.1 Free-Electron Final—State Model
6D4u?P, 7.2 Methods Employing Calculated Band Structures
Lp{uA4:=K 7.3 Methods for the Absolute Determination of the Crystal Momentum
1R.6Xer 7.3.1 Triangulation or Energy Coincidence Method
9PR?'X;4 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
)RT:u)N 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
~f8:sDJ 7.3.4 The Surface Emission Method and Electron Damping
DnB :~&Dw 7.3.5 The Very-Low-Energy Electron Diffraction Method
dP/1E6*m 7.3.6 The Fermi Surface Method
.T~Oc'wGo 7.3.7 Intensities and Their Use in Band-Structure Determinations
K>2 Bz&) 7.3.8 Summary
SQG9m2 7.4 Experimental Band Structures
U]E~7C 7.4.1 One- and Two-Dimensional Systems
^{O1+7d[. 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
?j8_j 7..4.3UPS Band Structures and XPS Density of States
s<LYSr d 7.5 A Comment
40;4= References
AHP;N6Y6 5q}7#{A 8.Surface States, Surface Effects
Ch&2{ng 8.1 Theoretical Considerations
$)jf 8.2 Experimental Results on Surface States
q+9c81b 8.3 Quantum-Well States
$r(9'm}W 8.4 Surface Core-Level Shifts
7}fT7tsN References
S1*xM u5P2* 9.Inverse Photoelectron Spectroscopy
K@!Gs'Op 9.1 Surface States
to] ~$~Q|> 9.2 Bulk Band Structures
\2 `|eo 9.3 Adsorbed Molecules
lM%3 ?~?Q& References
ekSSqj9"; JHsxaX;c 10. Spin-Polarized Photoelectron Spectroscopy
x?G"58 10.1 General Description
-h&KC{Xab 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
|)YN"nqg 10.3 Magnetic Dichroism
Zx%6pZ(. References
lMb&F[KJ7 Z2I2 [pA 11. Photoelectron Diffraction
,D{D
QJ(B 11.1 Examples
ggzcANCD< 11.2 Substrate Photoelectron Diffraction
4Mv] z^ 11.3 Adsorbate Photoelectron Diffraction
-pm%F8{T] 11.4 Fermi Surface Scans
<L<d_ References
J4m2|HK ;v%f + Appendix
{bO
O?pp A.1 Table of Binding Energies
GsNZr=;C A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
&^K,"a{ A.3 Compilation of Work Functions
<3[0A;W=1 References
c[4I> "w Index