光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
7mtg
NfmHa 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
~]'yUd1gSZ gyT0h?xDt 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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LyL(~Jc| Q5sJ|]Bc 目录
y'non0P. 1. Introduction and Basic Principles
D.ySnYzh 1.1 Historical Development
>&^jKfY 1.2 The Electron Mean Free Path
zw iS%-F 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
&)_
z! 1.4 Experimental Aspects
Q^* 33 1.5 Very High Resolution
1jaK N* 1.6 The Theory of Photoemission
[X>f;;h 1.6.1 Core-Level Photoemission
H?V
b 1.6.2 Valence-State Photoemission
o%0To{MAF- 1.6.3 Three-Step and One-Step Considerations
$\M];S=CY 1.7 Deviations from the Simple Theory of Photoemission
aP"!}* References
Wv~&Qh} 8NTE`l=>/ 2. Core Levels and Final States
_>8Q{N\-
{ 2.1 Core-Level Binding Energies in Atoms and Molecules
o8NRu7@? 2.1.1 The Equivalent-Core Approximation
u1\r:q 2.1.2 Chemical Shifts
T8yMaC 2.2 Core-Level Binding Energies in Solids
!fjB oK+ 2.2.1 The Born-Haber Cycle in Insulators
4=N(@mS 2.2.2 Theory of Binding Energies
yM,Y8^ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
jdx T662q 2.3 Core Polarization
62K#rRS 2.4 Final-State Multiplets in Rare-Earth Valence Bands
oArJ%Y> 2.5 Vibrational Side Bands
x0) WrDb 2.6 Core Levels of Adsorbed Molecules
Y%>u.HzL 2.7 Quantitative Chemical Analysis from Core-Level Intensities
: LT'#Q8 References
9}H]4"f7 BO%'/2eV 3. Charge-Excitation Final States: Satellites
*dPbV.HCl 3.1 Copper Dihalides; 3d Transition Metal Compounds
{faIyKtW 3.1.1 Characterization of a Satellite
Fh|{ib 3.1.2 Analysis of Charge-Transfer Satellites
Mz\l
C)\B 3.1.3 Non-local Screening
>`0mn|+ 3.2 The 6-eV Satellite in Nickel
$dA]GWW5A 3.2.1 Resonance Photoemission
*kEzGgTzoS 3.2.2 Satellites in Other Metals
*%E\mu,,c 3.3 The Gunnarsson-Sch6nhammer Theory
<Y$(
lszT 3.4 Photoemission Signals and Narrow Bands in Metals
syI|gANT/r References
N,3iSH=cN[ [+!&iN 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
+[_3h9BK 4.1 Theory
dP`B9>r 4.1.1 General
yrd1J$ 4.1.2 Core-Line Shape
0?dr( 4.1.3 Intrinsic Plasmons
[AA}P/iW 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
d`~~Ww1 4.1.5 The Total Photoelectron Spectrum
2U(qyC 4.2 Experimental Results
o$rF-? 4.2.1 The Core Line Without Plasmons
h_SkX@"/- 4.2.2 Core-Level Spectra Including Plasmoas
? Dn} 4.2.3 Valence-Band Spectra of the Simple Metals
3rjKwh7 4.2.4 Simple Metals: A General Comment
D3%2O`9 4.3 The Background Correction
g4952u References
V Ew| N) r4<aEj;l 5. Valence Orbitals in Simple Molecules and Insulating Solids
e[0"x.gu 5.1 UPS Spectra of Monatomic Gases
QHc([%oV 5.2 Photoelectron Spectra of Diatomic Molecules
{^1'' 5.3 Binding Energy of the H2 Molecule
yc`*zLWh 5.4 Hydrides Isoelectronic with Noble Gases
#<EYO Neon (Ne)
%l6E0[ Hydrogen Fluoride (HF)
JbQY{z! Water (H2O)
{8oGWQgrj Ammonia (NH3)
HrfS^B Methane (CH4)
E+#<WK- 5.5 Spectra of the Alkali HMides
$2RSYI`py 5.6 Transition Metal Dihalides
_x|.\j 5.7 Hydrocarbons
9y<h.T 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
JodD6;P 5.7.2 Linear Polymers
xu%eg] 5.8 Insulating Solids with Valence d Electrons
~_c1h@ 5.8.1 The NiO Problem
r a>2< 5.8.2 Mort Insulation
xV
2C4K 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
QWEE%}\3} 5.8.4Band Structures of Transition Metal Compounds
=0 !j"z= 5.9 High—Temperature Superconductors
egURRC! 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
c?u*,d) G 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
X6 N&:< 5.9.3 The Superconducting Gap
>]~|Nf/i 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
^$sqU 5.9.5 Core—Level Shifts
'tvuw\hhL 5.10 The Fermi Liquid and the Luttinger Liquid
%OHZOs 5.11 Adsorbed Molecules
C4P<GtR9 5.11.1 Outline
??U/Qi180 5.11.2 CO on Metal Surfaces
ai-rF^ehC References
p:z~>ca ] _5b
6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
@un+y9m[C 6.1 Theory of Photoemission:A Summary of the Three-Step Model
Qh(X7B 6.2 Discussion of the Photocurrent
\C h01LR" 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
f'H|K+bO 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
WmN(
( 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
2J8:_Ql3I 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
^|]Dg &N. 6.3.1 Band Structure Regime
?s3S$Ih 6.3.2 XPS Regime
W)/^*,
Q7 6.3.3 Surface Emission
tiHR&v 6.3.4 One-Step Calculations
c38XM]Jeq 6.4 Thermal Effects
*8/Xh)B; 6.5 Dipole Selection Rules for Direct Optical Transitions
Z0m`%(MJa References
=I)43ahd . R/y`:1:W 7.Band Structtire and Angular-Resolved Photoelectron Spectra
Xq&BL,lS 7.1 Free-Electron Final—State Model
0FgF, 7.2 Methods Employing Calculated Band Structures
s&(; 7.3 Methods for the Absolute Determination of the Crystal Momentum
kuV7nsXiQ 7.3.1 Triangulation or Energy Coincidence Method
7-!n- 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
_Uq' N0U 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
}Mt1C~{( 7.3.4 The Surface Emission Method and Electron Damping
NX.xEW@ 7.3.5 The Very-Low-Energy Electron Diffraction Method
>[,eK= 7.3.6 The Fermi Surface Method
bAGKi. 7.3.7 Intensities and Their Use in Band-Structure Determinations
uMS+,dXy 7.3.8 Summary
h0@a"DqK 7.4 Experimental Band Structures
!NkCki"W 7.4.1 One- and Two-Dimensional Systems
gtZmBe= 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
4n@lrcq( 7..4.3UPS Band Structures and XPS Density of States
,7]hjf_h 7.5 A Comment
xI{4<m/0N References
.t5.(0Xk[A EN2SI+ 8.Surface States, Surface Effects
N+rU|iMa. 8.1 Theoretical Considerations
<\u3p3"[4 8.2 Experimental Results on Surface States
U`mX
f#D 8.3 Quantum-Well States
"+-
'o+ 8.4 Surface Core-Level Shifts
DylO;+ References
2 HEU D3X4@sM 9.Inverse Photoelectron Spectroscopy
h<`aL;.g 9.1 Surface States
`KFEzv 9.2 Bulk Band Structures
4JAz{aw'b 9.3 Adsorbed Molecules
7GYf#} N References
2Jd(@DcJ2C !i^"3!.l,] 10. Spin-Polarized Photoelectron Spectroscopy
*;Mi/^pzK 10.1 General Description
=GPXuo 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
Og/aTR<;= 10.3 Magnetic Dichroism
f\]?, References
qTr P@F4`g d-D,Gx]>$ 11. Photoelectron Diffraction
&>,;ye>A 11.1 Examples
8(L$a1#5W 11.2 Substrate Photoelectron Diffraction
d+D~NA[M 11.3 Adsorbate Photoelectron Diffraction
3ic /xy;} 11.4 Fermi Surface Scans
%o0b~R References
w={q@.
g% I)Xf4FS@ Appendix
(Xh<F A.1 Table of Binding Energies
J rx^ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
tQ|c.`)W A.3 Compilation of Work Functions
F@i>l{C References
&q-&%~E@ Index