光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
"QS(4yw?jg GHLnwym 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
]e5aHpgR= .Jg<H %%f 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
4IB`7QJq `|"o\Bg<
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5>CeFy RT'5i$q[ 目录
v,N!cp1 1. Introduction and Basic Principles
kO^ 1.1 Historical Development
i@WO>+iB 1.2 The Electron Mean Free Path
!@Vj&>mH$ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
ak3WER|f# 1.4 Experimental Aspects
knHrMD; 1.5 Very High Resolution
cdH`#X 1.6 The Theory of Photoemission
^mI`P}5Y 1.6.1 Core-Level Photoemission
@q]!C5
1.6.2 Valence-State Photoemission
uQW[2f 1.6.3 Three-Step and One-Step Considerations
#=Xa(<t 1.7 Deviations from the Simple Theory of Photoemission
iH]0
YT.E References
}V.fY3J- 1y U!rEH 2. Core Levels and Final States
54TWFDmGi 2.1 Core-Level Binding Energies in Atoms and Molecules
hZUS#75M5 2.1.1 The Equivalent-Core Approximation
TQ/# 2.1.2 Chemical Shifts
X,o ]tgg= 2.2 Core-Level Binding Energies in Solids
GO][`zZJ] 2.2.1 The Born-Haber Cycle in Insulators
jamai8 2.2.2 Theory of Binding Energies
Ly, ]; 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
n
Zx^ej\ 2.3 Core Polarization
C5Fq%y{$. 2.4 Final-State Multiplets in Rare-Earth Valence Bands
6~s{HI! 2.5 Vibrational Side Bands
>B;S;_5=
2.6 Core Levels of Adsorbed Molecules
\B/( H)Cd* 2.7 Quantitative Chemical Analysis from Core-Level Intensities
EOqV5$+ References
_Bn8i( D,-L!P 3. Charge-Excitation Final States: Satellites
*x2u 3.1 Copper Dihalides; 3d Transition Metal Compounds
\4 t;{_ 3.1.1 Characterization of a Satellite
>i61+uzEd+ 3.1.2 Analysis of Charge-Transfer Satellites
FEa%wS{ 3.1.3 Non-local Screening
lu1T+@t 3.2 The 6-eV Satellite in Nickel
Ja\B%f 3.2.1 Resonance Photoemission
ND 8;1+3 3.2.2 Satellites in Other Metals
GBd
mT-7 3.3 The Gunnarsson-Sch6nhammer Theory
=PLy^% 3.4 Photoemission Signals and Narrow Bands in Metals
\4*i;a.kU References
*;t_VlaZ !a5e{QG0 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
#]} G{
P 4.1 Theory
n=!5ha%#N 4.1.1 General
W"xRf0\V 4.1.2 Core-Line Shape
ROfke.N\' 4.1.3 Intrinsic Plasmons
?0s&Kz4B 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
yAel4b/} 4.1.5 The Total Photoelectron Spectrum
XT==N-5, 4.2 Experimental Results
tjm@+xs 4.2.1 The Core Line Without Plasmons
1tpt433 4.2.2 Core-Level Spectra Including Plasmoas
aMJ9U)wnK 4.2.3 Valence-Band Spectra of the Simple Metals
5M3)7 4.2.4 Simple Metals: A General Comment
<@@@Pl!~ 4.3 The Background Correction
D%'rq References
$:D hK h&{>4{ 5. Valence Orbitals in Simple Molecules and Insulating Solids
qRZLv7X*j 5.1 UPS Spectra of Monatomic Gases
cC,gd\}M 5.2 Photoelectron Spectra of Diatomic Molecules
MP 8s} 5.3 Binding Energy of the H2 Molecule
D2#.qoP # 5.4 Hydrides Isoelectronic with Noble Gases
)jRaQ~Sm Neon (Ne)
_Q\u-VN*hv Hydrogen Fluoride (HF)
n ZS*"O#L Water (H2O)
pQ+4++7ID Ammonia (NH3)
YwB\kN Methane (CH4)
2 BwpxV8 5.5 Spectra of the Alkali HMides
@L^30>?l 5.6 Transition Metal Dihalides
Zxv{qbF 5.7 Hydrocarbons
/lvH p
5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
;\+A6(GX{ 5.7.2 Linear Polymers
ga91#NWgK 5.8 Insulating Solids with Valence d Electrons
X_I.f6v{ 5.8.1 The NiO Problem
zB{be_Tw 5.8.2 Mort Insulation
{D&:^f 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
4\8k~# 5.8.4Band Structures of Transition Metal Compounds
=CO#Q$ 5.9 High—Temperature Superconductors
y
`w5u.' 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
qZP>h4 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
>E(IkpZ 5.9.3 The Superconducting Gap
)'?@raB! 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
rw dj 5.9.5 Core—Level Shifts
hLLg 5.10 The Fermi Liquid and the Luttinger Liquid
YPav5<{a 5.11 Adsorbed Molecules
We#O'm 5.11.1 Outline
b*qC 5.11.2 CO on Metal Surfaces
})r[qsv References
~ +z'pK~c ldm=uW 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
"7a;Apq* 6.1 Theory of Photoemission:A Summary of the Three-Step Model
*YY:JLe 6.2 Discussion of the Photocurrent
[mk!]r 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
}vdhk0 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
;-65~i0Iu 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
%S4pkFR 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
%7rWebd- 6.3.1 Band Structure Regime
b$ )XS 6.3.2 XPS Regime
^?tF'l` 6.3.3 Surface Emission
kQm\;[R 6.3.4 One-Step Calculations
pfvNVu 6.4 Thermal Effects
^Q4m1?
40 6.5 Dipole Selection Rules for Direct Optical Transitions
@7';bfsix References
QFf lx Y1vSwS%{T 7.Band Structtire and Angular-Resolved Photoelectron Spectra
*tT}y(M 7.1 Free-Electron Final—State Model
F/w!4,'<?5 7.2 Methods Employing Calculated Band Structures
G%K<YyAP 7.3 Methods for the Absolute Determination of the Crystal Momentum
v
~%6!Tr 7.3.1 Triangulation or Energy Coincidence Method
"V cG3. 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
l2!4}zI2 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
"I]% aK0 7.3.4 The Surface Emission Method and Electron Damping
}3!.e 7.3.5 The Very-Low-Energy Electron Diffraction Method
b9([)8 7.3.6 The Fermi Surface Method
4o2C=?@( 7.3.7 Intensities and Their Use in Band-Structure Determinations
?<slB>8 7.3.8 Summary
rm4j8~Ef 7.4 Experimental Band Structures
A`Bg"k:D 7.4.1 One- and Two-Dimensional Systems
G}\E{VvWh 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
g=:C/>g 7..4.3UPS Band Structures and XPS Density of States
D|n`9yv a 7.5 A Comment
w_I}FPT<(: References
T{j&w% (z iffRGnN^e 8.Surface States, Surface Effects
|L7
`7!Z 8.1 Theoretical Considerations
i5*sG^<$H 8.2 Experimental Results on Surface States
\^3\_T&6 8.3 Quantum-Well States
9oY%v7 8.4 Surface Core-Level Shifts
|S:St HZm References
,.fGZ4 gKS0!U 9.Inverse Photoelectron Spectroscopy
M(S:&GOU 9.1 Surface States
mi3 yiR 9.2 Bulk Band Structures
nK6{_Y> 9.3 Adsorbed Molecules
j4Cad References
|k+Y >I& y)!K@ 10. Spin-Polarized Photoelectron Spectroscopy
K$\]\qG6 10.1 General Description
4>>d
"<}C 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
SVaC)O( 10.3 Magnetic Dichroism
8fJ- XFK$: References
=8fp4#]7 (Y!@,rKd 11. Photoelectron Diffraction
#G^?4Za 11.1 Examples
'LR5s[$j 11.2 Substrate Photoelectron Diffraction
vh+IhGi 11.3 Adsorbate Photoelectron Diffraction
}}l04kN_ 11.4 Fermi Surface Scans
?
S>"yAoe References
t8 #&bUX #IyxH$ Appendix
rRL:]%POT A.1 Table of Binding Energies
&B7X LO[ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
pVPCxP A.3 Compilation of Work Functions
!5Kv9P79 References
Fmk,
"qs Index