光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
FcM)v"bF&] eXKEx4rU 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
9
3)fC @Pcgm"H< 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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EY"of[p
WOj}+?/3 R CsZm8oL$ 目录
&V*MNi,4Z 1. Introduction and Basic Principles
GwF8ze+cH 1.1 Historical Development
)dfhy 1.2 The Electron Mean Free Path
Kuh3.1#o 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
ZX&e,X~V 1.4 Experimental Aspects
f@;pN=PS 1.5 Very High Resolution
A<|9</9z 1.6 The Theory of Photoemission
_<f%==
I' 1.6.1 Core-Level Photoemission
Ph
P)|P 1.6.2 Valence-State Photoemission
:N<Qk 1.6.3 Three-Step and One-Step Considerations
1"CWEL`i 1.7 Deviations from the Simple Theory of Photoemission
w98M#GqV References
6V$ )ym*F nmiJ2edx 2. Core Levels and Final States
.pPuBJL]< 2.1 Core-Level Binding Energies in Atoms and Molecules
3?j:M]fR 2.1.1 The Equivalent-Core Approximation
p7> 9
m 2.1.2 Chemical Shifts
@}6<,;|DQ 2.2 Core-Level Binding Energies in Solids
s~Ivq+ipr; 2.2.1 The Born-Haber Cycle in Insulators
Kkq-x'gt^ 2.2.2 Theory of Binding Energies
424iFc[ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
ng+sK 2.3 Core Polarization
R5e[cC8o. 2.4 Final-State Multiplets in Rare-Earth Valence Bands
mQ1 2.5 Vibrational Side Bands
;!f~ 2.6 Core Levels of Adsorbed Molecules
\h'7[vkr 2.7 Quantitative Chemical Analysis from Core-Level Intensities
hkl0N%[ References
J=Kv-@I>E .t[u_tBL 3. Charge-Excitation Final States: Satellites
=LLpJ+ 3.1 Copper Dihalides; 3d Transition Metal Compounds
fLs>|Rh 3.1.1 Characterization of a Satellite
Vq0X:<9 3.1.2 Analysis of Charge-Transfer Satellites
ZhCd** 3.1.3 Non-local Screening
pmBN?< 3.2 The 6-eV Satellite in Nickel
HYO/]\al 3.2.1 Resonance Photoemission
I*%3E.Z@g 3.2.2 Satellites in Other Metals
OP+*%$wR 3.3 The Gunnarsson-Sch6nhammer Theory
axmq/8X 3.4 Photoemission Signals and Narrow Bands in Metals
Z{vc6oj References
Q^va+O j.6!T'$| 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
HgW!Q(* 4.1 Theory
9j^rFG!n 4.1.1 General
%|+aI? 4.1.2 Core-Line Shape
^|oI^"IQ= 4.1.3 Intrinsic Plasmons
@nwVl8 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
'2Zs15)V 4.1.5 The Total Photoelectron Spectrum
.B xQF 4.2 Experimental Results
~6t<`&f 4.2.1 The Core Line Without Plasmons
>|RoLV 4.2.2 Core-Level Spectra Including Plasmoas
Da)p%E>Q 4.2.3 Valence-Band Spectra of the Simple Metals
0.+Eo.AX4M 4.2.4 Simple Metals: A General Comment
&;?+ ^L> 4.3 The Background Correction
:4[>]&:u3 References
"uuM#@h qPz_PRje 5. Valence Orbitals in Simple Molecules and Insulating Solids
x(sKkm`Q 5.1 UPS Spectra of Monatomic Gases
G)YmaHeI;[ 5.2 Photoelectron Spectra of Diatomic Molecules
ncadVheKt 5.3 Binding Energy of the H2 Molecule
;\}dQsX 5.4 Hydrides Isoelectronic with Noble Gases
E8PwA. Neon (Ne)
i{N?Y0YQs0 Hydrogen Fluoride (HF)
;yqHt!N Water (H2O)
]6^S:K_" Ammonia (NH3)
2?LPr Methane (CH4)
E3p$^['vx 5.5 Spectra of the Alkali HMides
1O,5bi>t7 5.6 Transition Metal Dihalides
bHm/Z Zx 5.7 Hydrocarbons
l#C<bDw 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
0?t;3z$n 5.7.2 Linear Polymers
>q?{'#i
/ 5.8 Insulating Solids with Valence d Electrons
h3E}Sa(MQ: 5.8.1 The NiO Problem
;~r- P$kCY 5.8.2 Mort Insulation
AW\uE[kg 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
SN")u 5.8.4Band Structures of Transition Metal Compounds
|1H9,:*% 5.9 High—Temperature Superconductors
8(-
29 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
\H>Psv{ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
QsPg4y3?D 5.9.3 The Superconducting Gap
416}# Mk 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
s+_8U}R 5.9.5 Core—Level Shifts
8[,R4@ 5.10 The Fermi Liquid and the Luttinger Liquid
6qmV/DL 5.11 Adsorbed Molecules
XySkm2y 5.11.1 Outline
(bsywM 5.11.2 CO on Metal Surfaces
GMZ6 dK References
1Hhr6T^) )(.g~Q: 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
+8"8s 6.1 Theory of Photoemission:A Summary of the Three-Step Model
Iw?f1] 6.2 Discussion of the Photocurrent
T1RY1hb|g> 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
BE&8E\w 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
^^
SMr l 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
1NZpd'$c 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
EJz!#f~ 6.3.1 Band Structure Regime
T
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qmPu D/c 6.3.3 Surface Emission
^h=gaNL 6.3.4 One-Step Calculations
r91i : 6.4 Thermal Effects
3NZK$d=4 6.5 Dipole Selection Rules for Direct Optical Transitions
Zw4%L? References
#D(=[F '-~J.8-</ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
m@I}$ 7.1 Free-Electron Final—State Model
XmwR^ 7.2 Methods Employing Calculated Band Structures
OU/3U(%n]e 7.3 Methods for the Absolute Determination of the Crystal Momentum
+3AX1o%p,# 7.3.1 Triangulation or Energy Coincidence Method
Jb9@U/<\ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
k[ pk R{e 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
P!j*4t 7.3.4 The Surface Emission Method and Electron Damping
]fh(b)8_, 7.3.5 The Very-Low-Energy Electron Diffraction Method
bM_fuy55Op 7.3.6 The Fermi Surface Method
5i{J0/'Xu) 7.3.7 Intensities and Their Use in Band-Structure Determinations
N|"q6M!ZL 7.3.8 Summary
vd^Z^cpip 7.4 Experimental Band Structures
"5$p=| 7.4.1 One- and Two-Dimensional Systems
2|1CGHj\ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
45Zh8 k 7..4.3UPS Band Structures and XPS Density of States
F 3q<j$y 7.5 A Comment
.*595SuF References
MVQ6I/EA4 {@x-T 8.Surface States, Surface Effects
i*4v!(E 8.1 Theoretical Considerations
XmVst*2= 8.2 Experimental Results on Surface States
Y>E` 7n 8.3 Quantum-Well States
6v}q @z 8.4 Surface Core-Level Shifts
DBu8}2R References
*GhV1# < &F;bg 9.Inverse Photoelectron Spectroscopy
Hi\z-P- 9.1 Surface States
Wy1.nn[ 9.2 Bulk Band Structures
@kT@IQkri 9.3 Adsorbed Molecules
Xa"I References
8{icY|:MTN 0[uOKFgE 10. Spin-Polarized Photoelectron Spectroscopy
6&LmR75C 10.1 General Description
7FaF]G 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
/{[tU-}qJ 10.3 Magnetic Dichroism
F$|d#ny References
)"tM[~e` 3T 0'zJ2f 11. Photoelectron Diffraction
wLfH/J 11.1 Examples
V!@6Nv 11.2 Substrate Photoelectron Diffraction
0Nk!.gY 11.3 Adsorbate Photoelectron Diffraction
!iX/Ni: 11.4 Fermi Surface Scans
g38MF References
UpQda`rb 3:sx%Ci/2 Appendix
5YI6$ZdQ A.1 Table of Binding Energies
7''iT{-[p A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
;3Z?MQe"NQ A.3 Compilation of Work Functions
|hDN$By References
YiL^KK Index