光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
x3JX}yCX *Q@%<R 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
:i4>&4j f;k'dqlv 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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cG"+n@\ V*m@Rs!)2 目录
nzdJ*C 1. Introduction and Basic Principles
?y\gjC6CNG 1.1 Historical Development
j(`L)/|O 1.2 The Electron Mean Free Path
KKz{a{ePY% 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
.5',w"R 1.4 Experimental Aspects
EMDsi2 1.5 Very High Resolution
ctv =8SFv( 1.6 The Theory of Photoemission
i U^tv_1 1.6.1 Core-Level Photoemission
b`@aiXN)+ 1.6.2 Valence-State Photoemission
Q.q'pJ- 1.6.3 Three-Step and One-Step Considerations
Hq{i-z+ 1.7 Deviations from the Simple Theory of Photoemission
?(&)p~o References
}4!R2c ,<[Q/:}[ 2. Core Levels and Final States
~v2E<S3 2.1 Core-Level Binding Energies in Atoms and Molecules
vpoeK'bi, 2.1.1 The Equivalent-Core Approximation
|z!Y,zaX 2.1.2 Chemical Shifts
!);kjXQS? 2.2 Core-Level Binding Energies in Solids
0i[,`>-Av 2.2.1 The Born-Haber Cycle in Insulators
'nOc_b0 2.2.2 Theory of Binding Energies
C0xjM0 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
Q1fJ`A= 2.3 Core Polarization
*Txt`z[| 2.4 Final-State Multiplets in Rare-Earth Valence Bands
!+;'kI2 2.5 Vibrational Side Bands
~>af"< 2.6 Core Levels of Adsorbed Molecules
Jon<?DQj
2.7 Quantitative Chemical Analysis from Core-Level Intensities
Hoaf3
`n References
TwlrncK* HQ8oOn 3. Charge-Excitation Final States: Satellites
(RP"VEVR 3.1 Copper Dihalides; 3d Transition Metal Compounds
q;dg,Om 3.1.1 Characterization of a Satellite
c:SA#. 3.1.2 Analysis of Charge-Transfer Satellites
;+%(@C51GE 3.1.3 Non-local Screening
JmJ8s hq 3.2 The 6-eV Satellite in Nickel
2qY`*Y.2 3.2.1 Resonance Photoemission
zj ;'0Zu 3.2.2 Satellites in Other Metals
xwZcO 3.3 The Gunnarsson-Sch6nhammer Theory
|U*wMYC 3.4 Photoemission Signals and Narrow Bands in Metals
: Gp,d*M References
r sf +dC Iv6(Z>pAB 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
'!)|;qe 4.1 Theory
Voi`OCut 4.1.1 General
RR u1/nam 4.1.2 Core-Line Shape
5]/i[T_ 4.1.3 Intrinsic Plasmons
VP|ga}( 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
T}ZUw;}BL 4.1.5 The Total Photoelectron Spectrum
lg)jc3 4.2 Experimental Results
>4gGb) 4.2.1 The Core Line Without Plasmons
TA=VfA B 4.2.2 Core-Level Spectra Including Plasmoas
_5F8F4QY` 4.2.3 Valence-Band Spectra of the Simple Metals
uyt]\zVT 4.2.4 Simple Metals: A General Comment
xef@-%mcoy 4.3 The Background Correction
O7p>"Bh References
uqaP\ |K(j}^1k 5. Valence Orbitals in Simple Molecules and Insulating Solids
xFU*,Y 5.1 UPS Spectra of Monatomic Gases
VCzmTnD 5.2 Photoelectron Spectra of Diatomic Molecules
_ lrCf 5.3 Binding Energy of the H2 Molecule
1l$c*STK 5.4 Hydrides Isoelectronic with Noble Gases
s2-`}LL Neon (Ne)
[whX),3> Hydrogen Fluoride (HF)
(^fiw%# Water (H2O)
Byx8`Cx1 Ammonia (NH3)
KTV~g@Jf Methane (CH4)
%F'*0< 5.5 Spectra of the Alkali HMides
iElE-g@Ws 5.6 Transition Metal Dihalides
;A~efC^< 5.7 Hydrocarbons
M_wqb'= 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
(1`z16 5.7.2 Linear Polymers
"PM!03rb 5.8 Insulating Solids with Valence d Electrons
|D `r o 5.8.1 The NiO Problem
AV"fOK;#A 5.8.2 Mort Insulation
Xr54/.{&@ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
DYS|"tSk 5.8.4Band Structures of Transition Metal Compounds
Bvke@|]kW 5.9 High—Temperature Superconductors
yi7m!+D3 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
%E\&9, 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
2&st/y(hs 5.9.3 The Superconducting Gap
bo]xah|."j 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
OF^:_%c/ 5.9.5 Core—Level Shifts
8cq H0{ 5.10 The Fermi Liquid and the Luttinger Liquid
}cov"o 5.11 Adsorbed Molecules
iGG; 5.11.1 Outline
cVHv>nd# 5.11.2 CO on Metal Surfaces
YzTmXwuA5 References
GfEg][f MO7:ZYq 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
g. V6:>, 6.1 Theory of Photoemission:A Summary of the Three-Step Model
%1E:rw@ 6.2 Discussion of the Photocurrent
fmuAX w> 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
Ku6bY| 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
oLJP@J 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
i
#5rk(^t 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
<I}O_:% 6.3.1 Band Structure Regime
.8[Db1W 6.3.2 XPS Regime
Y9h~ hD 6.3.3 Surface Emission
NXQdy g, 6.3.4 One-Step Calculations
qT(
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{-28% 6.5 Dipole Selection Rules for Direct Optical Transitions
%G~f> References
qla$}dnvc d|UK=B^x 7.Band Structtire and Angular-Resolved Photoelectron Spectra
D8u_Z<6IjI 7.1 Free-Electron Final—State Model
F<'@T,LVc 7.2 Methods Employing Calculated Band Structures
[I*BEJ;W' 7.3 Methods for the Absolute Determination of the Crystal Momentum
Vz$X0C=W;H 7.3.1 Triangulation or Energy Coincidence Method
Hu"?wZj 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
-]1F]d 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
?eUhHKS5 7.3.4 The Surface Emission Method and Electron Damping
~(2G7x)
7.3.5 The Very-Low-Energy Electron Diffraction Method
2jQ|4$9j 7.3.6 The Fermi Surface Method
_e/>CiN/ 7.3.7 Intensities and Their Use in Band-Structure Determinations
Mz}yf5{f 7.3.8 Summary
l1X&Nw1W 7.4 Experimental Band Structures
Etk`>,]Y>y 7.4.1 One- and Two-Dimensional Systems
#q`-"2"| 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
lNtZd?=> 7..4.3UPS Band Structures and XPS Density of States
&5fM8Opkd 7.5 A Comment
<a@'Pcsk References
L_Q1:nL-0 Z!Y ^iN 8.Surface States, Surface Effects
_KSYt32N 8.1 Theoretical Considerations
jPG&Ypm1 8.2 Experimental Results on Surface States
0)}bJ,5/ 8.3 Quantum-Well States
Ip}(!D| 8.4 Surface Core-Level Shifts
C^]y
iR-U References
`&2AN%Xz /6_>d$ 9.Inverse Photoelectron Spectroscopy
^:Vwblv( 9.1 Surface States
ve.rpF\ 9.2 Bulk Band Structures
2+pLDIIT 9.3 Adsorbed Molecules
;IX3w:Aw References
+R}(t{b# >mzK96 10. Spin-Polarized Photoelectron Spectroscopy
o
g.LD7&/ 10.1 General Description
3cK`RM ` 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
[([?+Ouy 10.3 Magnetic Dichroism
Pyc/6~? References
'+tU8 Pb uVJ;1H! 11. Photoelectron Diffraction
g`)2I+L7 11.1 Examples
q=8I0E&q 11.2 Substrate Photoelectron Diffraction
j'lfH6_')e 11.3 Adsorbate Photoelectron Diffraction
!2oe;q2X[G 11.4 Fermi Surface Scans
"T4Z#t References
&f1dCL%z7 @C40H/dE Appendix
a@_.uD A.1 Table of Binding Energies
&E.ckWf A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
Cg NfqT0 A.3 Compilation of Work Functions
S[!-M\b References
6AgevyVG Index