光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
4Gs#_|! j78WPG 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
lo*OmAF !E!i`yF 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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Fb=(FQ2Y? stuj,8 目录
koOkm:(, 1. Introduction and Basic Principles
OE' ?3S 1.1 Historical Development
jGpSECs 1.2 The Electron Mean Free Path
c} )U:?6 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
hw! l{yv 1.4 Experimental Aspects
-F=?M+9[ 1.5 Very High Resolution
2Ya)I k{ 1.6 The Theory of Photoemission
O O?e8OU 1.6.1 Core-Level Photoemission
|/<,71Ae 1.6.2 Valence-State Photoemission
0/K?'&$yvb 1.6.3 Three-Step and One-Step Considerations
Z`x|\jI 1.7 Deviations from the Simple Theory of Photoemission
j8n_:;i* References
0WT]fY?IS j6v|D>I 2. Core Levels and Final States
8*7t1$ 2.1 Core-Level Binding Energies in Atoms and Molecules
R<.<wQ4I 2.1.1 The Equivalent-Core Approximation
J1OZG6|e 2.1.2 Chemical Shifts
m,}0p 2.2 Core-Level Binding Energies in Solids
]v^/c~"${ 2.2.1 The Born-Haber Cycle in Insulators
9A_{*E(wd 2.2.2 Theory of Binding Energies
ro|mWP0 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
Uytq,3Gj6 2.3 Core Polarization
_M'WTe 2.4 Final-State Multiplets in Rare-Earth Valence Bands
kQ~2mU 2.5 Vibrational Side Bands
?;84 M@ 2.6 Core Levels of Adsorbed Molecules
1o"/5T:S[ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
ql"&E{u? References
Zoe>Ow8mE` iV9wqUkMv 3. Charge-Excitation Final States: Satellites
H$'|hUwds% 3.1 Copper Dihalides; 3d Transition Metal Compounds
N(i%Oxp1 3.1.1 Characterization of a Satellite
p3tu_If 3.1.2 Analysis of Charge-Transfer Satellites
sF9{(Us 3.1.3 Non-local Screening
hojP3 [ 3.2 The 6-eV Satellite in Nickel
od~^''/b 3.2.1 Resonance Photoemission
ycYT1Sg8 3.2.2 Satellites in Other Metals
s18o,Zs' 3.3 The Gunnarsson-Sch6nhammer Theory
,n\"zYf]^ 3.4 Photoemission Signals and Narrow Bands in Metals
Q{%2Npvq References
)Z6bMAb0'N AI
KLJvte 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
}/tT=G]91 4.1 Theory
o95)-Wb 4.1.1 General
d4ANh+}X"_ 4.1.2 Core-Line Shape
B
~u9"SR. 4.1.3 Intrinsic Plasmons
x_za
R}WI 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
3OnIAk3 4.1.5 The Total Photoelectron Spectrum
G!]%xFwYa 4.2 Experimental Results
x)evjX=q 4.2.1 The Core Line Without Plasmons
'{]1!yMh 4.2.2 Core-Level Spectra Including Plasmoas
n(X {|? 4.2.3 Valence-Band Spectra of the Simple Metals
/V'^$enK!} 4.2.4 Simple Metals: A General Comment
J%VcvBaJm 4.3 The Background Correction
a=ye!CN^ References
-64@}Ts*? 'ec G:B`S 5. Valence Orbitals in Simple Molecules and Insulating Solids
nc<wDE6 5.1 UPS Spectra of Monatomic Gases
feJzX*u 5.2 Photoelectron Spectra of Diatomic Molecules
Skb,cKU 5.3 Binding Energy of the H2 Molecule
gut[q 5.4 Hydrides Isoelectronic with Noble Gases
mCM7FFl I Neon (Ne)
lT.Q)( Hydrogen Fluoride (HF)
;8F|Q<`pV Water (H2O)
v[$-)vs*ag Ammonia (NH3)
m7<HK,d Methane (CH4)
*"cK_MH/o 5.5 Spectra of the Alkali HMides
So?.V4aD_ 5.6 Transition Metal Dihalides
(pBPf 5.7 Hydrocarbons
@8keLrp 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
[tN^)c`s/ 5.7.2 Linear Polymers
2Y~UeJ_\Lq 5.8 Insulating Solids with Valence d Electrons
!Cqm=q{K 5.8.1 The NiO Problem
S8=Am7D]1 5.8.2 Mort Insulation
\VY!= 9EV 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
$H0diwl9R 5.8.4Band Structures of Transition Metal Compounds
7JC^+rk 5.9 High—Temperature Superconductors
2bJqZ,@ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
K)-Gv|*t 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
MHF31/g\ 5.9.3 The Superconducting Gap
T >pz/7gb 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
l'yX_`*Iq 5.9.5 Core—Level Shifts
O$dcy! 5.10 The Fermi Liquid and the Luttinger Liquid
v %?y5w 5.11 Adsorbed Molecules
CMQlxX? 5.11.1 Outline
tKr.{#) 5.11.2 CO on Metal Surfaces
A%Ov.~&\G References
}Iyr u3M][ t1LIZ5JY 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
3o).8b_3g 6.1 Theory of Photoemission:A Summary of the Three-Step Model
Z>897> 6.2 Discussion of the Photocurrent
=D&xw2 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
xg:r5Z/|) 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
$5(_U 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
24Y8n 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
*HT)Au"5 6.3.1 Band Structure Regime
#=}dv8 6.3.2 XPS Regime
d3nx"=Cy0I 6.3.3 Surface Emission
tQ:g#EqL9B 6.3.4 One-Step Calculations
{z^6V\O5 6.4 Thermal Effects
h;q=<[h\ 6.5 Dipole Selection Rules for Direct Optical Transitions
96NZrT References
trl:\m s=[Tm}[ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
fPW|)e" 7.1 Free-Electron Final—State Model
Y 6NoNc]h 7.2 Methods Employing Calculated Band Structures
+2DzX/3 7.3 Methods for the Absolute Determination of the Crystal Momentum
,H_b@$]n8 7.3.1 Triangulation or Energy Coincidence Method
xgdS]Sz 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
%NyV2W=~X 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
knX*fp 7.3.4 The Surface Emission Method and Electron Damping
)+Nm@+B 7.3.5 The Very-Low-Energy Electron Diffraction Method
v jTs[eq> 7.3.6 The Fermi Surface Method
/0S2Omh 7.3.7 Intensities and Their Use in Band-Structure Determinations
TT85G 7.3.8 Summary
p"xti+2, 7.4 Experimental Band Structures
`.MY"g9 7.4.1 One- and Two-Dimensional Systems
jY~W* 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
+*I'!)T^B 7..4.3UPS Band Structures and XPS Density of States
S.: m$s 7.5 A Comment
miWPLnw=L References
<yoCW?# ;)6LX- 8.Surface States, Surface Effects
]+U:8* 8.1 Theoretical Considerations
\d"uR@$3mG 8.2 Experimental Results on Surface States
F!>92H~3G 8.3 Quantum-Well States
g6s&nH`Z2 8.4 Surface Core-Level Shifts
!=)R+g6b References
wgN)*dpuI A`5/u"]*D 9.Inverse Photoelectron Spectroscopy
{6y@;Fd 9.1 Surface States
ZqDanDM 9.2 Bulk Band Structures
"M-zBBY ] 9.3 Adsorbed Molecules
zeC@!,lH References
+vDEDOS1 46yq F 10. Spin-Polarized Photoelectron Spectroscopy
0h3-;% 10.1 General Description
cC4 2b2+
10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
>}uDQwX8 10.3 Magnetic Dichroism
hJ)\Vo References
6\+ZTw #mK/xbW 11. Photoelectron Diffraction
A`#/:O4|f 11.1 Examples
;Dw6pmZ 11.2 Substrate Photoelectron Diffraction
(O[:-Aqm 11.3 Adsorbate Photoelectron Diffraction
ms(Z1ix^ 11.4 Fermi Surface Scans
M0B6v}^H References
Gz_[|,i !1X^lFf;~ Appendix
4lb(qKea A.1 Table of Binding Energies
#NvL@bH A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
i"B q*b@ A.3 Compilation of Work Functions
1#Ls4+]5 References
J{69iQ Index