光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
DM7}&~ vW.%[] 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
eVnbRT2y& o0;7b>Tv 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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*d*oS7 2o{@nN8% 目录
. A<sr 1. Introduction and Basic Principles
e&J3N 1.1 Historical Development
4e%8D`/=M 1.2 The Electron Mean Free Path
6zYaA 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
i^%-aBZ 1.4 Experimental Aspects
X7cWgo66T 1.5 Very High Resolution
%<U{K; 1.6 The Theory of Photoemission
QJ<[Zx 1.6.1 Core-Level Photoemission
4UCwT1 1.6.2 Valence-State Photoemission
>_Uj?F: 1.6.3 Three-Step and One-Step Considerations
ko[TDh$T5 1.7 Deviations from the Simple Theory of Photoemission
PKtU:Eg References
{vfq QP\yaPE 2. Core Levels and Final States
^tE_LL+ji| 2.1 Core-Level Binding Energies in Atoms and Molecules
Qyj(L[K J 2.1.1 The Equivalent-Core Approximation
.)ST[G]WK 2.1.2 Chemical Shifts
iPU% /_> 2.2 Core-Level Binding Energies in Solids
^@_).:oX7 2.2.1 The Born-Haber Cycle in Insulators
[,7-w 2.2.2 Theory of Binding Energies
:GL7J6 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
x}"Q8kD 2.3 Core Polarization
#\b ;2> 2.4 Final-State Multiplets in Rare-Earth Valence Bands
]bfqcmh< 2.5 Vibrational Side Bands
w`#fH 2.6 Core Levels of Adsorbed Molecules
E/"SU*Co 2.7 Quantitative Chemical Analysis from Core-Level Intensities
rA#s References
94z8B;+H] wW()Zy0) 3. Charge-Excitation Final States: Satellites
=h\E<dw 3.1 Copper Dihalides; 3d Transition Metal Compounds
A70(W{6a9@ 3.1.1 Characterization of a Satellite
1l]C5P}E 3.1.2 Analysis of Charge-Transfer Satellites
>ITEd 3.1.3 Non-local Screening
.YiaXP 3.2 The 6-eV Satellite in Nickel
F!R2_89iy 3.2.1 Resonance Photoemission
9r8D*PvS 3.2.2 Satellites in Other Metals
V Cf|`V~ G 3.3 The Gunnarsson-Sch6nhammer Theory
*:#Z+7x
] 3.4 Photoemission Signals and Narrow Bands in Metals
n!?r } n8 References
Qtnv#9%Vi "UpOY 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
6h@+?{F. 4.1 Theory
$NCm;0\B| 4.1.1 General
QT_^M1% 4.1.2 Core-Line Shape
S>EDL 4.1.3 Intrinsic Plasmons
8bbVbP 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
^N{X " 4.1.5 The Total Photoelectron Spectrum
"3ug}k 4.2 Experimental Results
YE_6OLW 4.2.1 The Core Line Without Plasmons
\4@a 4.2.2 Core-Level Spectra Including Plasmoas
EP0a1.C 4.2.3 Valence-Band Spectra of the Simple Metals
[)iN)$Mv 4.2.4 Simple Metals: A General Comment
+U=KXv 4.3 The Background Correction
Fva]*5 References
HqRCjD D8 wG!X 5. Valence Orbitals in Simple Molecules and Insulating Solids
GDmv0V$6 5.1 UPS Spectra of Monatomic Gases
+Z$a1Y@ 5.2 Photoelectron Spectra of Diatomic Molecules
h{H]xe[Q 5.3 Binding Energy of the H2 Molecule
i]@c.QiFN 5.4 Hydrides Isoelectronic with Noble Gases
bQpoXs0w; Neon (Ne)
4%>+Wh[ Hydrogen Fluoride (HF)
P|v ? Water (H2O)
gQ,4xTX Ammonia (NH3)
@aUZ#,(< Methane (CH4)
DzE E:&*= 5.5 Spectra of the Alkali HMides
;Lqm#]C 5.6 Transition Metal Dihalides
y0y+%H- 5.7 Hydrocarbons
_[0I^o 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
CL )%p"[x 5.7.2 Linear Polymers
$WJy?_c 5.8 Insulating Solids with Valence d Electrons
W7T"d4 5.8.1 The NiO Problem
6<+8}`@B>G 5.8.2 Mort Insulation
?qIGQ/af& 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
',%5mF3j 5.8.4Band Structures of Transition Metal Compounds
lkyJ;}_** 5.9 High—Temperature Superconductors
%27G 2^1 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
<@%ma2 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
.;j"+Ef 5.9.3 The Superconducting Gap
zM)M_L 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
W >Kp\tD 5.9.5 Core—Level Shifts
L% zuI& q 5.10 The Fermi Liquid and the Luttinger Liquid
eNivlJ,K|@ 5.11 Adsorbed Molecules
l2r>|CGQ[ 5.11.1 Outline
iAg}pwU 5.11.2 CO on Metal Surfaces
sbpu
qOL References
U<|B7t4M br10ptEx 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
hN!.@L 6.1 Theory of Photoemission:A Summary of the Three-Step Model
lej^gxj/2 6.2 Discussion of the Photocurrent
`c> A>c| 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
DU(X,hDBF 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
9.jG\i 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
[CsM<:C 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
aTi0bQW{ 6.3.1 Band Structure Regime
mJ/^BT] 6.3.2 XPS Regime
\?[O,A 6.3.3 Surface Emission
%OTQRe: 6.3.4 One-Step Calculations
))$ CEh"X 6.4 Thermal Effects
$.=5e3 6.5 Dipole Selection Rules for Direct Optical Transitions
D_zcOq9 References
OrzM
hQaf EwC5[bRjUp 7.Band Structtire and Angular-Resolved Photoelectron Spectra
D~XU`;~u 7.1 Free-Electron Final—State Model
m<~>&mWr 7.2 Methods Employing Calculated Band Structures
n&3iz05} 7.3 Methods for the Absolute Determination of the Crystal Momentum
pFG]IM7o/u 7.3.1 Triangulation or Energy Coincidence Method
6Uch0xha! 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
T %$2k> 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
F%9e@{ 7.3.4 The Surface Emission Method and Electron Damping
l A 0-?k 7.3.5 The Very-Low-Energy Electron Diffraction Method
<d3PDO@w/ 7.3.6 The Fermi Surface Method
Q=dw 6 7.3.7 Intensities and Their Use in Band-Structure Determinations
/YS@[\j4 7.3.8 Summary
-Cg`x=G;z 7.4 Experimental Band Structures
LNWqgIq 7.4.1 One- and Two-Dimensional Systems
&9S8al
8" 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
xq8}6Q 7..4.3UPS Band Structures and XPS Density of States
p|xs|O6{ 7.5 A Comment
pW`ntE#L References
cu)@P 0I f6@^Mg 8.Surface States, Surface Effects
IY-(-
a8 8.1 Theoretical Considerations
qQwJJjf 8.2 Experimental Results on Surface States
mrw]yu;2<n 8.3 Quantum-Well States
|k/`WC6As. 8.4 Surface Core-Level Shifts
oSpi{ $x References
B4PW4>GF
uZo]8mV 9.Inverse Photoelectron Spectroscopy
#p']-No 9.1 Surface States
@&/s~3 9.2 Bulk Band Structures
<>ZBW9 9.3 Adsorbed Molecules
DKe6?PG References
6:e}v'q{ *##QXyyg 10. Spin-Polarized Photoelectron Spectroscopy
yBUZVqqDa 10.1 General Description
ahK?]:&QO 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
#RCZA4> 10.3 Magnetic Dichroism
~xsb5M5 References
tg4LE?nv g6x/f<2x 11. Photoelectron Diffraction
m^W*[^p 11.1 Examples
R !:eYoQ 11.2 Substrate Photoelectron Diffraction
Vu_7uSp,) 11.3 Adsorbate Photoelectron Diffraction
\<0G
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bW,BhUb,| References
LZ=wz.'u jV(xYA3 Appendix
xg*\j)_} A.1 Table of Binding Energies
7UeE(=Hr5 A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
'Qp&,xK A.3 Compilation of Work Functions
9b"}CEw References
ej)BR'* Index