光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
~-yq,x ! v%%_sRV 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
(w<llb`] ~WmA55 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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oBPm^ob4 0w2<2grQ 目录
]>+ teG:4 1. Introduction and Basic Principles
p{0rHu[ 1.1 Historical Development
JAmpU^(C 1.2 The Electron Mean Free Path
){tTB 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
-OgC. 6 1.4 Experimental Aspects
\gir 1.5 Very High Resolution
*2m{i:3 1.6 The Theory of Photoemission
{I$zmVG 1.6.1 Core-Level Photoemission
,F|49i.K 1.6.2 Valence-State Photoemission
Fe 78YDx? 1.6.3 Three-Step and One-Step Considerations
Qyj:!-o 1.7 Deviations from the Simple Theory of Photoemission
Z7MGBwP( References
`4|:8@,3{ :{#w-oC>6P 2. Core Levels and Final States
3qp\jh=FE 2.1 Core-Level Binding Energies in Atoms and Molecules
UtB~joaR 2.1.1 The Equivalent-Core Approximation
CY@#_z 2.1.2 Chemical Shifts
Is (
Ji 2.2 Core-Level Binding Energies in Solids
R36A_ 2.2.1 The Born-Haber Cycle in Insulators
.Ax]SNZ+:A 2.2.2 Theory of Binding Energies
VF:<q 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
5W_Rg:J{P 2.3 Core Polarization
[:{HX U7y 2.4 Final-State Multiplets in Rare-Earth Valence Bands
eyByAT~W, 2.5 Vibrational Side Bands
H$3:Ra+ S 2.6 Core Levels of Adsorbed Molecules
F^wm&:%{` 2.7 Quantitative Chemical Analysis from Core-Level Intensities
a7fn{VU8 References
$viZ[Lu!m Yc>.P 3. Charge-Excitation Final States: Satellites
*b(nX,e 3.1 Copper Dihalides; 3d Transition Metal Compounds
t "[2^2G 3.1.1 Characterization of a Satellite
#<R6!"TNoz 3.1.2 Analysis of Charge-Transfer Satellites
@_"Z]Y ,D0 3.1.3 Non-local Screening
D;oX*` 3.2 The 6-eV Satellite in Nickel
vSJ#
}& 3.2.1 Resonance Photoemission
+78cQqDY! 3.2.2 Satellites in Other Metals
CDG,l7 3.3 The Gunnarsson-Sch6nhammer Theory
gp]T.ol 3.4 Photoemission Signals and Narrow Bands in Metals
%Wg8dy| References
6L&_(/{Uw 5oY^;)\/ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
Wtj*Z.=: 4.1 Theory
\hqjk:o 4.1.1 General
eh6=- 4.1.2 Core-Line Shape
Ob
h@d| 4.1.3 Intrinsic Plasmons
>+ku:<Hw%. 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
5wm(gF_t 4.1.5 The Total Photoelectron Spectrum
X:OUu; 4.2 Experimental Results
n4Q ^ 4.2.1 The Core Line Without Plasmons
#J*hZ(Pq 4.2.2 Core-Level Spectra Including Plasmoas
KyRcZ" 4.2.3 Valence-Band Spectra of the Simple Metals
_h P7hhR 4.2.4 Simple Metals: A General Comment
d01]5'f?o 4.3 The Background Correction
=a_ >") References
LVBE+{P\5? P^m&oH5]EG 5. Valence Orbitals in Simple Molecules and Insulating Solids
}Gh95HwE 5.1 UPS Spectra of Monatomic Gases
d`J~w/]
`\ 5.2 Photoelectron Spectra of Diatomic Molecules
sk~inIj- 5.3 Binding Energy of the H2 Molecule
ee
.,D 5.4 Hydrides Isoelectronic with Noble Gases
\) g?mj^ Neon (Ne)
yo!Y%9 Hydrogen Fluoride (HF)
/n8\^4{fP{ Water (H2O)
(Ujry =f Ammonia (NH3)
AP/#?
Methane (CH4)
V*F |Yo: 5.5 Spectra of the Alkali HMides
t'e5!Ma 5.6 Transition Metal Dihalides
eDS,}Z' 5.7 Hydrocarbons
(cm8x 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
h~u|v[@{J 5.7.2 Linear Polymers
$VUX?ii$7= 5.8 Insulating Solids with Valence d Electrons
!4(QeV-= 5.8.1 The NiO Problem
ix_&<?8 5.8.2 Mort Insulation
_'Hw`0}s 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Q?{^8?7 5.8.4Band Structures of Transition Metal Compounds
YaAOP'p 5.9 High—Temperature Superconductors
^_G@a, 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
=nE^zY2m% 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
e#z#bz2< 5.9.3 The Superconducting Gap
RZqou|ki 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
b_a6| 5.9.5 Core—Level Shifts
4*V[^mht 5.10 The Fermi Liquid and the Luttinger Liquid
JO&L1<B{v 5.11 Adsorbed Molecules
?dAy_|
zD 5.11.1 Outline
9}aEV 0 V| 5.11.2 CO on Metal Surfaces
O{ |Ug~ References
Oc%W_Gb7 oR'u&\mB 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
#,Cz+k*4 6.1 Theory of Photoemission:A Summary of the Three-Step Model
/J[s5{ 6.2 Discussion of the Photocurrent
sff4N>XAl< 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
dnCurWjdk 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
?OVje9 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
Pd;G c@'~ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
K aNO&%qX 6.3.1 Band Structure Regime
aBWA hn 6.3.2 XPS Regime
tYCVVs`? 6.3.3 Surface Emission
KLgg([ 6.3.4 One-Step Calculations
[Lq9lw&
6.4 Thermal Effects
eR:C?v 6.5 Dipole Selection Rules for Direct Optical Transitions
lYhC2f
m_ References
uFn?U) ##a.=gl 7.Band Structtire and Angular-Resolved Photoelectron Spectra
|X;|=. 7.1 Free-Electron Final—State Model
nt$q< 57 7.2 Methods Employing Calculated Band Structures
t"jiLOQ[6 7.3 Methods for the Absolute Determination of the Crystal Momentum
qpV"ii 7.3.1 Triangulation or Energy Coincidence Method
=TJ9Gr/R&: 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
@z>DJ>htN 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
1\-r5e; BE 7.3.4 The Surface Emission Method and Electron Damping
eD!mR3Ai@D 7.3.5 The Very-Low-Energy Electron Diffraction Method
d8K|uEHVz 7.3.6 The Fermi Surface Method
QM@zy 7.3.7 Intensities and Their Use in Band-Structure Determinations
|G/WS0 7.3.8 Summary
1h?QEZ,6a 7.4 Experimental Band Structures
}mpFo2 7.4.1 One- and Two-Dimensional Systems
I %|;M%B 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
(h'Bz6K 7..4.3UPS Band Structures and XPS Density of States
pKaU
[1x?% 7.5 A Comment
'PWA References
H:cAORLB ~]SCf@pRk 8.Surface States, Surface Effects
@W-0ybv 8.1 Theoretical Considerations
CZog?O}< 8.2 Experimental Results on Surface States
`N8t2yF 8.3 Quantum-Well States
;
*\xdg{d 8.4 Surface Core-Level Shifts
0[E\h References
Q hdG(`PY~ &z@}9U*6b 9.Inverse Photoelectron Spectroscopy
RoNE7|gF: 9.1 Surface States
DMlr%)@{ 9.2 Bulk Band Structures
oSIP{lfp2Q 9.3 Adsorbed Molecules
Yz#E0aTTA References
d'iSvd. k~)@D| ? 10. Spin-Polarized Photoelectron Spectroscopy
nf1O8FwRb 10.1 General Description
Wg,7k9I 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
2S-f5&o 10.3 Magnetic Dichroism
[:+f Y[4== References
a(X V~o & H8 % 11. Photoelectron Diffraction
Xyjd7" 11.1 Examples
5+yy:#J] 11.2 Substrate Photoelectron Diffraction
A?ho<@^ 11.3 Adsorbate Photoelectron Diffraction
NS-0-o|4# 11.4 Fermi Surface Scans
S0M i References
~RLWr.pK #x`K4f) Appendix
~F%sO'4! A.1 Table of Binding Energies
>>|47ps3 A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
#}l$<7ZU A.3 Compilation of Work Functions
W8F@nY References
f3S 8~! Index