光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
Sy7^;/(ZZ ~$&r(9P 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
g&(~MD2{ gJcL{] 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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.&!{8jBX |4*2xDcl 目录
jc.Uh9Kc 1. Introduction and Basic Principles
1+ARV&bc 1.1 Historical Development
)C0X]? 1.2 The Electron Mean Free Path
p:n^c5 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
xI),0db 1.4 Experimental Aspects
1OwkLy,P 1.5 Very High Resolution
z:,!yU c 1.6 The Theory of Photoemission
`-`iS? 1.6.1 Core-Level Photoemission
@Sd:]h:f- 1.6.2 Valence-State Photoemission
. T>}O0L" 1.6.3 Three-Step and One-Step Considerations
D`ge3f8Wi 1.7 Deviations from the Simple Theory of Photoemission
C3h!?5 References
j`pR;XL1[ Nm.>C4 2. Core Levels and Final States
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Uk;xV 2.1 Core-Level Binding Energies in Atoms and Molecules
="eum7 2.1.1 The Equivalent-Core Approximation
Xr;noV-X 2.1.2 Chemical Shifts
bo/!u
s# 2.2 Core-Level Binding Energies in Solids
PP`n>v=n 2.2.1 The Born-Haber Cycle in Insulators
UR=s{nFd 2.2.2 Theory of Binding Energies
Qz$Dv@*y\ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
S.4YC>E 2.3 Core Polarization
*F&&rsb 2.4 Final-State Multiplets in Rare-Earth Valence Bands
a<36`#N 2.5 Vibrational Side Bands
i^KYZ4/% 2.6 Core Levels of Adsorbed Molecules
p&M'DMj+ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
6-YR'ikU References
*<j @+Ch JNl+UH:. 3. Charge-Excitation Final States: Satellites
/ kGX 6hh 3.1 Copper Dihalides; 3d Transition Metal Compounds
X'4
Yofs 3.1.1 Characterization of a Satellite
dz9-+C{m 3.1.2 Analysis of Charge-Transfer Satellites
LK5H~FK 3.1.3 Non-local Screening
J>PV{N 3.2 The 6-eV Satellite in Nickel
,99G2Ev4c 3.2.1 Resonance Photoemission
/RmCMT 3.2.2 Satellites in Other Metals
B+sqEj- 3.3 The Gunnarsson-Sch6nhammer Theory
?d)|vX3Uf 3.4 Photoemission Signals and Narrow Bands in Metals
9Q1GV>j>B References
`roSOX1f /Q_\h+` 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
kl9z;(6p 4.1 Theory
3dphS ^X 4.1.1 General
$O-, :<HY 4.1.2 Core-Line Shape
K),wAZI!7j 4.1.3 Intrinsic Plasmons
rT) R*3 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
]~ M
-KT 4.1.5 The Total Photoelectron Spectrum
.).<L`q 4.2 Experimental Results
0E[Se|! 4.2.1 The Core Line Without Plasmons
A UV$ S2 4.2.2 Core-Level Spectra Including Plasmoas
~.PYS!" + 4.2.3 Valence-Band Spectra of the Simple Metals
0/]vmDr 4.2.4 Simple Metals: A General Comment
Q.AM 4.3 The Background Correction
t}gqk' References
U:e9Vq'N m &O)mPnx` 5. Valence Orbitals in Simple Molecules and Insulating Solids
.D`#a 5.1 UPS Spectra of Monatomic Gases
0^z$COCv 5.2 Photoelectron Spectra of Diatomic Molecules
6iWuBsal 5.3 Binding Energy of the H2 Molecule
w (-n1oSo 5.4 Hydrides Isoelectronic with Noble Gases
#
GGmA. Neon (Ne)
I SmnZ@ Hydrogen Fluoride (HF)
|L&V-f&K Water (H2O)
[_-K Ammonia (NH3)
Hyg?as>}u Methane (CH4)
]0le=Ee^% 5.5 Spectra of the Alkali HMides
!Ua#smZ 5.6 Transition Metal Dihalides
F o6U" 5.7 Hydrocarbons
IWgC6)n@n 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
@~ L.m}GF 5.7.2 Linear Polymers
H !u:P?j@\ 5.8 Insulating Solids with Valence d Electrons
oJ+$&P( 5.8.1 The NiO Problem
)^+$5OR\c 5.8.2 Mort Insulation
Fu/CX4R_| 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
<-pbLL 9 5.8.4Band Structures of Transition Metal Compounds
ffVYlNQ7L 5.9 High—Temperature Superconductors
Dn?L 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
5P!17.W'u
5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
:u0433z: 5.9.3 The Superconducting Gap
6dUP's_ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
='j 5.9.5 Core—Level Shifts
;}qCIyuO] 5.10 The Fermi Liquid and the Luttinger Liquid
&Te:l-x 5.11 Adsorbed Molecules
L8J/GVmj 5.11.1 Outline
M{QNpoM 5.11.2 CO on Metal Surfaces
<k!G%R<9 References
10&A3C(E Zn//u<D 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
<]nI)W( 6.1 Theory of Photoemission:A Summary of the Three-Step Model
hl+Yr)0\ 6.2 Discussion of the Photocurrent
);[`rXH_ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
=`U[{3A_ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
W8^gPW*c5 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
eC-TZH@ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
"e"`Or 6.3.1 Band Structure Regime
?H`LrL/k 6.3.2 XPS Regime
hbK+\X 6.3.3 Surface Emission
mx yT==E 6.3.4 One-Step Calculations
2,\uY}4 6.4 Thermal Effects
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I?(ruL' 6.5 Dipole Selection Rules for Direct Optical Transitions
iR-O6*PTC References
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