光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
@fML.AT 'W>Zr}: 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
p`
'8M u\,("2ZW9+ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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0!^vQ
+/L "A qg(rG5kD@ 目录
svBT~P0x 1. Introduction and Basic Principles
D8b~-# 1.1 Historical Development
JDIQpO"Qji 1.2 The Electron Mean Free Path
}E}b/ulg1 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
]nEZQ+F 1.4 Experimental Aspects
~BSE8M+r 1.5 Very High Resolution
o,#[Se*n 1.6 The Theory of Photoemission
RH+'"f 1.6.1 Core-Level Photoemission
h kh b8zS 1.6.2 Valence-State Photoemission
BgzER[g|q{ 1.6.3 Three-Step and One-Step Considerations
iyRB}[y 1.7 Deviations from the Simple Theory of Photoemission
8\85Wk{b References
&?-LL{W{ D~< 3 2. Core Levels and Final States
2I2#o9(Ar 2.1 Core-Level Binding Energies in Atoms and Molecules
FzDZ<dJ 2.1.1 The Equivalent-Core Approximation
]Gm$0uS 2.1.2 Chemical Shifts
Mk*&CNo3 2.2 Core-Level Binding Energies in Solids
Q|^TR__ 2.2.1 The Born-Haber Cycle in Insulators
T2nbU6H 2.2.2 Theory of Binding Energies
e2SU)Tr%b 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
5K~kzRL$r 2.3 Core Polarization
b`4R`mo 2.4 Final-State Multiplets in Rare-Earth Valence Bands
Or0eY#c 2.5 Vibrational Side Bands
}P5zf$ 2.6 Core Levels of Adsorbed Molecules
| Q
Y_ci 2.7 Quantitative Chemical Analysis from Core-Level Intensities
V
ifQ@ References
l>Nz]Ul%{ #b~wIOR)Z 3. Charge-Excitation Final States: Satellites
ed,w-;(n~ 3.1 Copper Dihalides; 3d Transition Metal Compounds
S<hj6A 3.1.1 Characterization of a Satellite
]aqHk 3.1.2 Analysis of Charge-Transfer Satellites
<By6%<JTn 3.1.3 Non-local Screening
09f:%!^u 3.2 The 6-eV Satellite in Nickel
&IQp& 3.2.1 Resonance Photoemission
MZ(TST" 3.2.2 Satellites in Other Metals
H?dmNwkPY 3.3 The Gunnarsson-Sch6nhammer Theory
JY\8^}'9 3.4 Photoemission Signals and Narrow Bands in Metals
a:PS}_. References
VtR?/+8X n\nC.|_G@ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
> n~l\
fC 4.1 Theory
CvCk#:@HM 4.1.1 General
Q]';1#J\ 4.1.2 Core-Line Shape
*cdr,AD?lH 4.1.3 Intrinsic Plasmons
6,"fH{Bd
4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
Ek [V A\G 4.1.5 The Total Photoelectron Spectrum
kAbkhZ1^ 4.2 Experimental Results
TK )Kq 4.2.1 The Core Line Without Plasmons
t|gEMDGa3 4.2.2 Core-Level Spectra Including Plasmoas
x*H4o{o0 4.2.3 Valence-Band Spectra of the Simple Metals
%!r>]M < 4.2.4 Simple Metals: A General Comment
vrtK~5K 4.3 The Background Correction
;;zKHS References
BReNhk)S 05(lh<C 5. Valence Orbitals in Simple Molecules and Insulating Solids
}lzyl*. 5.1 UPS Spectra of Monatomic Gases
Y",Fs( 5.2 Photoelectron Spectra of Diatomic Molecules
uzO%+B! 5.3 Binding Energy of the H2 Molecule
U _~lpu 5.4 Hydrides Isoelectronic with Noble Gases
+$MNG Neon (Ne)
ZQT14. $L Hydrogen Fluoride (HF)
xw*T?!r=V Water (H2O)
g)*[W>M Ammonia (NH3)
pV#~$e Methane (CH4)
+Y!9)~f}7X 5.5 Spectra of the Alkali HMides
\*}JdEHB 5.6 Transition Metal Dihalides
v;S7i>\ 5.7 Hydrocarbons
kL.JrbM" 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
SRl:+!@. 5.7.2 Linear Polymers
i|X ;n 5.8 Insulating Solids with Valence d Electrons
oYNP,8r^ 5.8.1 The NiO Problem
0`=#1u8
5.8.2 Mort Insulation
N[%^0T$ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
fF208A7U
I 5.8.4Band Structures of Transition Metal Compounds
NymS8hxR 5.9 High—Temperature Superconductors
[>P@3t(/ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
`A@{})+ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
nXDU8|" 5.9.3 The Superconducting Gap
FbB>
Md; 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
4@PH5z 5.9.5 Core—Level Shifts
p=U*4[9k 5.10 The Fermi Liquid and the Luttinger Liquid
od{b]HvgS 5.11 Adsorbed Molecules
xrX^";}j 5.11.1 Outline
\ajy%$;$} 5.11.2 CO on Metal Surfaces
+tL]qOBP References
|3f?1:"Z ?Kw~O"L8 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
etdI:N*x 6.1 Theory of Photoemission:A Summary of the Three-Step Model
YEoQIR 6.2 Discussion of the Photocurrent
0c4H2RW 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
sQrP,:=r# 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
fYF\5/_ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
`;-K/)/x 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
jnvi_Rodm 6.3.1 Band Structure Regime
=Mb!&qq 6.3.2 XPS Regime
nwh7DUi 6.3.3 Surface Emission
^PIUA' 6.3.4 One-Step Calculations
ahNpHTPa 6.4 Thermal Effects
`_C4L=q" 6.5 Dipole Selection Rules for Direct Optical Transitions
dEU+\NY References
4y&%YLMpl Qvh: hkR 7.Band Structtire and Angular-Resolved Photoelectron Spectra
l5ww-#6Z 7.1 Free-Electron Final—State Model
w-l:* EV8 7.2 Methods Employing Calculated Band Structures
7A|n*'[T> 7.3 Methods for the Absolute Determination of the Crystal Momentum
K'.aQ&2 7.3.1 Triangulation or Energy Coincidence Method
$pK2H0c 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
lz.ta!6 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
p\66`\\l 7.3.4 The Surface Emission Method and Electron Damping
GGcNaW' 7.3.5 The Very-Low-Energy Electron Diffraction Method
5LU8QHj3 7.3.6 The Fermi Surface Method
F@Qzh 7.3.7 Intensities and Their Use in Band-Structure Determinations
L.XGD|m 7.3.8 Summary
)IQa]A 7.4 Experimental Band Structures
~G.'pyW 7.4.1 One- and Two-Dimensional Systems
5y;texsj[ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
K^j7T[pR 7..4.3UPS Band Structures and XPS Density of States
].=&^0cg 7.5 A Comment
aMQfg51W: References
?4Z`^uy ?zW4|0 8.Surface States, Surface Effects
6qQdTp{i 8.1 Theoretical Considerations
!, Y1FC 8.2 Experimental Results on Surface States
iIFM 5CT 8.3 Quantum-Well States
?|LR@M!S7 8.4 Surface Core-Level Shifts
3B#qQ# References
c8!q_H~ ;5qZQ8`4 9.Inverse Photoelectron Spectroscopy
2mj?&p? 9.1 Surface States
{2Jo|z 9.2 Bulk Band Structures
rM/Ona2x 9.3 Adsorbed Molecules
$'#hCs References
Nv!If$d 9<BC6M_/ 10. Spin-Polarized Photoelectron Spectroscopy
CN4Q++{ 10.1 General Description
H&`0I$8m 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
qyzmjV6J2 10.3 Magnetic Dichroism
g{wOq{7V References
yO\.dp ayR=GqZ1 11. Photoelectron Diffraction
Q!7il<S 11.1 Examples
M4[(.8iE 11.2 Substrate Photoelectron Diffraction
C;]}Ht:~I 11.3 Adsorbate Photoelectron Diffraction
#[$^M:X. 11.4 Fermi Surface Scans
~JhH ,E References
\
vf&Ldk ?:DeOBAb Appendix
Aw#@}TGT A.1 Table of Binding Energies
@I_!q* A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
6
axe A.3 Compilation of Work Functions
Zi'}qs$v References
XdS&s}J[I Index