光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
MtE18m"z "mT95x\NA\ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
@ qFE6! fpMnA 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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>R|*FYam }mGOEG|F2 目录
/48W]a}JS 1. Introduction and Basic Principles
W40GW 1.1 Historical Development
7\ .Ax 1.2 The Electron Mean Free Path
D+$ k 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
agQ5%t# 1.4 Experimental Aspects
mX@Un9k 1.5 Very High Resolution
G` !ff 1.6 The Theory of Photoemission
Ub1?dk 1.6.1 Core-Level Photoemission
@\~qXz{6J 1.6.2 Valence-State Photoemission
NF?FEUoxz 1.6.3 Three-Step and One-Step Considerations
}h+_kRQ 1.7 Deviations from the Simple Theory of Photoemission
eFO+@
References
TF\<`}akX b0\'JZ 2. Core Levels and Final States
ONx|c'0g 2.1 Core-Level Binding Energies in Atoms and Molecules
ZqI.n4:9 2.1.1 The Equivalent-Core Approximation
D+ki2UVt& 2.1.2 Chemical Shifts
Y~RZf /` 2.2 Core-Level Binding Energies in Solids
c[=%v]j:u 2.2.1 The Born-Haber Cycle in Insulators
Bjg 21bw^ 2.2.2 Theory of Binding Energies
mtfyhFk 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
Sr7+DCr 2.3 Core Polarization
>.R6\>N% 2.4 Final-State Multiplets in Rare-Earth Valence Bands
xx}R6VKU. 2.5 Vibrational Side Bands
o?G^=0T 2.6 Core Levels of Adsorbed Molecules
)B d`N^k+ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
,v"/3Ff{, References
^V^In-[!y: WY@x2bBi 3. Charge-Excitation Final States: Satellites
vFfvvRda4x 3.1 Copper Dihalides; 3d Transition Metal Compounds
S}"?#=Q.%O 3.1.1 Characterization of a Satellite
DdI7%?hK 3.1.2 Analysis of Charge-Transfer Satellites
/)80@ 3.1.3 Non-local Screening
^q"wd?((h 3.2 The 6-eV Satellite in Nickel
Y^dVNC3vd 3.2.1 Resonance Photoemission
rT`D@
I 3.2.2 Satellites in Other Metals
y$)gj4k/D 3.3 The Gunnarsson-Sch6nhammer Theory
uo1G 3.4 Photoemission Signals and Narrow Bands in Metals
':,6s References
l<<G".? ?KxI|os 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
`R@24 ) 4.1 Theory
Ow\9vf6H 4.1.1 General
F"a^`E& 4.1.2 Core-Line Shape
0w >DU^+ 4.1.3 Intrinsic Plasmons
(l22p
4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
oeXNb4; 4 4.1.5 The Total Photoelectron Spectrum
&%pB; dk 4.2 Experimental Results
@S~'m; 4.2.1 The Core Line Without Plasmons
=J8)Z'Jr 4.2.2 Core-Level Spectra Including Plasmoas
A>L(#lz#ek 4.2.3 Valence-Band Spectra of the Simple Metals
Q6S[sTKR 4.2.4 Simple Metals: A General Comment
$"{V],:T
| 4.3 The Background Correction
IidZ-Il References
D} 0>x~ D<7S
P,D 5. Valence Orbitals in Simple Molecules and Insulating Solids
y? [*qnPj 5.1 UPS Spectra of Monatomic Gases
}\u~He% 5.2 Photoelectron Spectra of Diatomic Molecules
C!w@Naj 5.3 Binding Energy of the H2 Molecule
bcpH|}[F) 5.4 Hydrides Isoelectronic with Noble Gases
tYfhKJzGC Neon (Ne)
NrvS/cI!t Hydrogen Fluoride (HF)
*9^CgLF Water (H2O)
SX}GKu Ammonia (NH3)
"sFdrXJ Methane (CH4)
whNRUOK: 5.5 Spectra of the Alkali HMides
PqcuSb6 5.6 Transition Metal Dihalides
[[D}vL8d 5.7 Hydrocarbons
HZQ I | 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
#)R;6" 5.7.2 Linear Polymers
We#*.nr{3Z 5.8 Insulating Solids with Valence d Electrons
&3{:h 5.8.1 The NiO Problem
P7\(D` 5.8.2 Mort Insulation
KHr8\qLH 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
oW]&]*>J 5.8.4Band Structures of Transition Metal Compounds
jn\\,n"6 5.9 High—Temperature Superconductors
RA[` Cp" 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
LWbWj ^ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
~s^&*KaA 5.9.3 The Superconducting Gap
w& RpQcV 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
v )7d 5.9.5 Core—Level Shifts
`@.YyPxX\ 5.10 The Fermi Liquid and the Luttinger Liquid
`M>{43dj 5.11 Adsorbed Molecules
5, Yk5?l<' 5.11.1 Outline
U7crbj;c)d 5.11.2 CO on Metal Surfaces
%o4d43uZ References
6X|KKsPzX l^`!:BOtR 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
Q,\lS 6.1 Theory of Photoemission:A Summary of the Three-Step Model
>\DXA)nc 6.2 Discussion of the Photocurrent
|[34<tIN 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
j{_MDE7N 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
uy\YJ.WMQ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
n]Dq 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
(f#W:]o/ 6.3.1 Band Structure Regime
A#1y>k 6.3.2 XPS Regime
PLLlo~Bb 6.3.3 Surface Emission
/HzhgMV3 6.3.4 One-Step Calculations
YSrFHVq 6.4 Thermal Effects
l}Xmm^@) 6.5 Dipole Selection Rules for Direct Optical Transitions
`MTOe1 References
!y] Y'j 5 (H; x74 7.Band Structtire and Angular-Resolved Photoelectron Spectra
McsqMI6 7.1 Free-Electron Final—State Model
b!.# `. 7.2 Methods Employing Calculated Band Structures
/v!H{Zw=c 7.3 Methods for the Absolute Determination of the Crystal Momentum
;
wHuL\ 7.3.1 Triangulation or Energy Coincidence Method
V$v;lvt^Uq 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
!;\-V}V 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
=m/2)R{ 7.3.4 The Surface Emission Method and Electron Damping
W)4xO>ck*3 7.3.5 The Very-Low-Energy Electron Diffraction Method
LnJ7i"Q 7.3.6 The Fermi Surface Method
3F.O0Vz 7.3.7 Intensities and Their Use in Band-Structure Determinations
xBw"RCBz^ 7.3.8 Summary
+^69>L2V 7.4 Experimental Band Structures
9q8
rf\& 7.4.1 One- and Two-Dimensional Systems
V)(pe #P 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
JR<R8+@g_ 7..4.3UPS Band Structures and XPS Density of States
q6G([h7 7.5 A Comment
ONfJ"Rp3 References
Gc 8 e@,L~\ 8.Surface States, Surface Effects
#&8Opo( 8.1 Theoretical Considerations
WG}QLcP 8.2 Experimental Results on Surface States
2Q k\}KWs 8.3 Quantum-Well States
0~S<}N 8.4 Surface Core-Level Shifts
nVM`&azD References
gRqz8UI ?=4t~\g? 9.Inverse Photoelectron Spectroscopy
?,8b-U#A1 9.1 Surface States
x<3vA|o 9.2 Bulk Band Structures
l|up3A3) 9.3 Adsorbed Molecules
& {/u>, References
O0{v`|w9+ &GZR-/ 10. Spin-Polarized Photoelectron Spectroscopy
9E#(i P 10.1 General Description
QV 'y6m\ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
./g#< 10.3 Magnetic Dichroism
U92hv~\ References
6?iP z?5 .z4FuG,R 11. Photoelectron Diffraction
*oWzH_ 11.1 Examples
Ce)Wvuh 11.2 Substrate Photoelectron Diffraction
v}mmY>M% 11.3 Adsorbate Photoelectron Diffraction
Qv=Z 11.4 Fermi Surface Scans
vSL{WT]m References
a|53E<5X VsMN i#? Appendix
ZT8j9zs A.1 Table of Binding Energies
~VGK#'X: A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
t&uHn5 A.3 Compilation of Work Functions
1lQ10J References
a[!d)Y:zx Index