光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
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作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
0#eb] c jS[=Zx` 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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hk:>*B} gDLS)4^w 目录
^@RvCJ+ 1. Introduction and Basic Principles
U'(zKqC 1.1 Historical Development
%sOY:>
1.2 The Electron Mean Free Path
,3T"fT-( 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
hx9t{Zi 1.4 Experimental Aspects
j,^&U|! 1.5 Very High Resolution
mHW%:a\L 1.6 The Theory of Photoemission
pgh(~[ 1.6.1 Core-Level Photoemission
l~o!(rpX 1.6.2 Valence-State Photoemission
gggD "alDx 1.6.3 Three-Step and One-Step Considerations
.x,y[/[[) 1.7 Deviations from the Simple Theory of Photoemission
IAwS39B References
ud5}jyJ CZu=/8? 2. Core Levels and Final States
6A]I" E]5 2.1 Core-Level Binding Energies in Atoms and Molecules
[O&}Qk 2.1.1 The Equivalent-Core Approximation
Bt}90# 2.1.2 Chemical Shifts
XK3O,XM 2.2 Core-Level Binding Energies in Solids
&T0]tzk*, 2.2.1 The Born-Haber Cycle in Insulators
N WF h<
2.2.2 Theory of Binding Energies
v9Ii8{ca| 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
C 4C/ 2.3 Core Polarization
\L~^c1s3r 2.4 Final-State Multiplets in Rare-Earth Valence Bands
6_QAE6A 2.5 Vibrational Side Bands
ph6'(, 2.6 Core Levels of Adsorbed Molecules
s)]T"87H'_ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
Os$E,4,py References
OHBCanZZ, HYGd
:SeH 3. Charge-Excitation Final States: Satellites
lCp6UkE 3.1 Copper Dihalides; 3d Transition Metal Compounds
qKd ="PR} 3.1.1 Characterization of a Satellite
t :YZua 3.1.2 Analysis of Charge-Transfer Satellites
K=0xR*ll5 3.1.3 Non-local Screening
/KOI%x 3.2 The 6-eV Satellite in Nickel
P}5bSQ( a3 3.2.1 Resonance Photoemission
b<~8\\& 3.2.2 Satellites in Other Metals
):>?N`{V 3.3 The Gunnarsson-Sch6nhammer Theory
c:0n/DC 3.4 Photoemission Signals and Narrow Bands in Metals
:23S%B~X References
EniV-Uj\D Lr:n 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
grgs r_)[ 4.1 Theory
r/AOgS 4.1.1 General
3 5.&!4} 4.1.2 Core-Line Shape
mwLf)xt0' 4.1.3 Intrinsic Plasmons
uGC5XX^ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
)GVTa4}p 4.1.5 The Total Photoelectron Spectrum
(BP p2^ 4.2 Experimental Results
WJONk_WAc 4.2.1 The Core Line Without Plasmons
l3 F$5n 4.2.2 Core-Level Spectra Including Plasmoas
P7=`P 4.2.3 Valence-Band Spectra of the Simple Metals
o"BED!/ 4.2.4 Simple Metals: A General Comment
/mz.HCs 4.3 The Background Correction
ANBuX6q References
)u{]rb[ W[Q<# Ju 5. Valence Orbitals in Simple Molecules and Insulating Solids
;-~E!_$ 5.1 UPS Spectra of Monatomic Gases
PVlCj 5.2 Photoelectron Spectra of Diatomic Molecules
oX:&;KA 5.3 Binding Energy of the H2 Molecule
V{oFig 6 5.4 Hydrides Isoelectronic with Noble Gases
e16H@ Neon (Ne)
"Tser*i ) Hydrogen Fluoride (HF)
/+%aSPQ Water (H2O)
tkk8b6%h?p Ammonia (NH3)
Yl&[_
l Methane (CH4)
w%qnH e9 5.5 Spectra of the Alkali HMides
>qNpY(Ql 5.6 Transition Metal Dihalides
lmHQ"z 3G 5.7 Hydrocarbons
~HGSA( 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
hzM;{g>t 5.7.2 Linear Polymers
?sdSi-- 5.8 Insulating Solids with Valence d Electrons
C=o-3w
5.8.1 The NiO Problem
:tO4LEb 5.8.2 Mort Insulation
)-[$m% 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
.qohHJ& 5.8.4Band Structures of Transition Metal Compounds
QObVJg,GD 5.9 High—Temperature Superconductors
[Lje?M* r 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
QAxy?m,' 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
{0F/6GwUC 5.9.3 The Superconducting Gap
wg)Bx#>\L: 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
BZ.l[LMp 5.9.5 Core—Level Shifts
{~O4*2zg;K 5.10 The Fermi Liquid and the Luttinger Liquid
%$zak@3%' 5.11 Adsorbed Molecules
[6RODp3') 5.11.1 Outline
!c)F; 5.11.2 CO on Metal Surfaces
)tJaw#Mih References
C)i8XX Tf5m
YCk 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
uVD^X* 6.1 Theory of Photoemission:A Summary of the Three-Step Model
bi}aVtG~z 6.2 Discussion of the Photocurrent
/
S' + 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
Sw E7U~ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
,^e2ma|z 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
W"@'}y 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
h@O\j&# 6.3.1 Band Structure Regime
?m~1b_@A{ 6.3.2 XPS Regime
^wZx=kas 6.3.3 Surface Emission
R[\1Kk(Zo 6.3.4 One-Step Calculations
Ng;?hT w 6.4 Thermal Effects
jG&HPVr 6.5 Dipole Selection Rules for Direct Optical Transitions
[!;sp~ References
fWA#n +|g*<0T5< 7.Band Structtire and Angular-Resolved Photoelectron Spectra
,rN$ah$CL 7.1 Free-Electron Final—State Model
iNkN'(" 7.2 Methods Employing Calculated Band Structures
>CrrxiG 7.3 Methods for the Absolute Determination of the Crystal Momentum
:I&y@@UG 7.3.1 Triangulation or Energy Coincidence Method
G|nBja8vm 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
BhAT@% 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
(|AZO! 7.3.4 The Surface Emission Method and Electron Damping
1qAE)8ie 7.3.5 The Very-Low-Energy Electron Diffraction Method
IfB .2e` 7.3.6 The Fermi Surface Method
%pxJ2 7Q 7.3.7 Intensities and Their Use in Band-Structure Determinations
^C~_}/cZ 7.3.8 Summary
F;`c0ja] 7.4 Experimental Band Structures
mgH~GKf^ 7.4.1 One- and Two-Dimensional Systems
V0A> + 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
b7^q(}qE 7..4.3UPS Band Structures and XPS Density of States
fCNQUK{Gs5 7.5 A Comment
UZFs]z!,k References
e^@ZN9qQ
"[]oWPOj 8.Surface States, Surface Effects
]Zh$9YK 8.1 Theoretical Considerations
aO}hE2] 8.2 Experimental Results on Surface States
'")'h 8.3 Quantum-Well States
`'iO+/;GY 8.4 Surface Core-Level Shifts
J?#vL\8 References
I__b$ 0OG
3#pE 9.Inverse Photoelectron Spectroscopy
j|[$P4w}U 9.1 Surface States
R73@!5N% 9.2 Bulk Band Structures
-a|b.p 9.3 Adsorbed Molecules
F(/<ADx References
<tZtt9j_ I&i6-xp 10. Spin-Polarized Photoelectron Spectroscopy
$FT6c@&y 10.1 General Description
Jo[&y, 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
R*cef 10.3 Magnetic Dichroism
Or$"f3gq References
rkWy3X{%2< p3-~cr.LD 11. Photoelectron Diffraction
W!" $g 11.1 Examples
~~&Bp_9QXN 11.2 Substrate Photoelectron Diffraction
D0bpD 11.3 Adsorbate Photoelectron Diffraction
rIB./, 11.4 Fermi Surface Scans
jdVj
FCl^# References
E[ -yfP~[ n4{?Odrf Appendix
r@i)Sluf A.1 Table of Binding Energies
jT0iJ?d,! A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
\rh+\9( A.3 Compilation of Work Functions
}+`,AC`RM References
;m|N9' Index