光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
vWzm@ ZxGJzakB5$ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
C~,a!qY 5F)C jQ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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<J<{l ]!?;@$wx 目录
kCWV r 1. Introduction and Basic Principles
+%yfcyZ. 1.1 Historical Development
%?0:vn 1.2 The Electron Mean Free Path
:~&~y-14 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
_{I3i:f9X8 1.4 Experimental Aspects
3%#3iZ=_ 1.5 Very High Resolution
D=j-!{zB 1.6 The Theory of Photoemission
ry`Ho8N 1.6.1 Core-Level Photoemission
sBj(Qd 1.6.2 Valence-State Photoemission
k:t]s_`< 1.6.3 Three-Step and One-Step Considerations
6tgt>\y 1.7 Deviations from the Simple Theory of Photoemission
[kVS
O References
hZ?Rof 6iVxc|Ia 2. Core Levels and Final States
SoW9p^HJ 2.1 Core-Level Binding Energies in Atoms and Molecules
V\ZG d+? 2.1.1 The Equivalent-Core Approximation
?PuBa`zDE 2.1.2 Chemical Shifts
ZCMw3]* 2.2 Core-Level Binding Energies in Solids
h5*JkRm 2.2.1 The Born-Haber Cycle in Insulators
!"?#6-,Xn 2.2.2 Theory of Binding Energies
q6McG HT 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
`uv2H$ 2.3 Core Polarization
b[r8e 2.4 Final-State Multiplets in Rare-Earth Valence Bands
+nrbShV 2.5 Vibrational Side Bands
uw>Ba %5 2.6 Core Levels of Adsorbed Molecules
SE@LYeC}dE 2.7 Quantitative Chemical Analysis from Core-Level Intensities
%aG5F}S2~ References
k^3>Y%^1 *'Sd/%8{ 3. Charge-Excitation Final States: Satellites
OcR$zlgs[v 3.1 Copper Dihalides; 3d Transition Metal Compounds
CM/H9Kz. 3.1.1 Characterization of a Satellite
>N^Jj:~l 3.1.2 Analysis of Charge-Transfer Satellites
yr)G]K[/ 3.1.3 Non-local Screening
u@Ih GME 3.2 The 6-eV Satellite in Nickel
dP9qSwTa 3.2.1 Resonance Photoemission
L*Tj^q!t+ 3.2.2 Satellites in Other Metals
6KXtcXQ 3.3 The Gunnarsson-Sch6nhammer Theory
5kc/Y/4o 3.4 Photoemission Signals and Narrow Bands in Metals
"@e3EX7h References
Sj%u)#Ub 'F+C4QAq 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
x,=&JtKVc 4.1 Theory
>!eAM ) 4.1.1 General
;km`P|<U 4.1.2 Core-Line Shape
~8q)^vm>f? 4.1.3 Intrinsic Plasmons
%0S3V[4I 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
&jS>UsGh 4.1.5 The Total Photoelectron Spectrum
m ifxiV 4.2 Experimental Results
8zZvht* 4.2.1 The Core Line Without Plasmons
LdYB7T,
4.2.2 Core-Level Spectra Including Plasmoas
(ZS}G8 4.2.3 Valence-Band Spectra of the Simple Metals
&|s0P 4.2.4 Simple Metals: A General Comment
`l\7+0W 4.3 The Background Correction
Y+kfBvxyf References
qmkAg }2 [`ebM,W 5. Valence Orbitals in Simple Molecules and Insulating Solids
Z+*9#!?J 5.1 UPS Spectra of Monatomic Gases
!EvAB+`jLI 5.2 Photoelectron Spectra of Diatomic Molecules
zIqU,n|]s 5.3 Binding Energy of the H2 Molecule
]0Y4U7W 5.4 Hydrides Isoelectronic with Noble Gases
ax"+0L{ Neon (Ne)
iFd+2S% Hydrogen Fluoride (HF)
/K+r?
]kf Water (H2O)
sQYkQ81 Ammonia (NH3)
M1k{t%M+S Methane (CH4)
Tr_w]' 5.5 Spectra of the Alkali HMides
Zd3S:),& 5.6 Transition Metal Dihalides
7o7)0l9! 5.7 Hydrocarbons
p2hB8zL 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
z 9vInf@M 5.7.2 Linear Polymers
fe\mL mK9 5.8 Insulating Solids with Valence d Electrons
QVv#fy1"6 5.8.1 The NiO Problem
hCi 60%g/n 5.8.2 Mort Insulation
dH;8mb|#' 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Ow+GS{-q 5.8.4Band Structures of Transition Metal Compounds
"Bh}}!13 5.9 High—Temperature Superconductors
Yk'XGr) 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
n4O]8C'lW9 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
,kyJAju> 5.9.3 The Superconducting Gap
t;|@o\ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
5VfyU8)7X 5.9.5 Core—Level Shifts
ayn) 5q/z 5.10 The Fermi Liquid and the Luttinger Liquid
qEyyT[: 5.11 Adsorbed Molecules
6Pz4\uE= 5.11.1 Outline
R}-(cc%5 5.11.2 CO on Metal Surfaces
K%,2=. References
Me r/G2#& ?qmRbDI 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
jte.Xy~g 6.1 Theory of Photoemission:A Summary of the Three-Step Model
{JO^tI 6.2 Discussion of the Photocurrent
&yct!YOB2 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
R 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
+! ]zA4x 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
oK9( /v 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
:,3C 0T3r 6.3.1 Band Structure Regime
3$jT*OyG# 6.3.2 XPS Regime
Q0)#8Rcm 6.3.3 Surface Emission
~IY% 6.3.4 One-Step Calculations
G'nmllB`] 6.4 Thermal Effects
[meO[otb 6.5 Dipole Selection Rules for Direct Optical Transitions
l#g\X'bK References
R8Wr^s>' U#0Q) 7.Band Structtire and Angular-Resolved Photoelectron Spectra
lXx=But 7.1 Free-Electron Final—State Model
h8x MI 7.2 Methods Employing Calculated Band Structures
l?E{YQq] 7.3 Methods for the Absolute Determination of the Crystal Momentum
WEw6He; 7.3.1 Triangulation or Energy Coincidence Method
^+*N%yr 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
$|zX| 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
jrCfWa}z 7.3.4 The Surface Emission Method and Electron Damping
jSJqE_ 1 7.3.5 The Very-Low-Energy Electron Diffraction Method
^\hG"5# 7.3.6 The Fermi Surface Method
5^}\4.eXo 7.3.7 Intensities and Their Use in Band-Structure Determinations
I
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E`kG-Q5Dw 7.4 Experimental Band Structures
|-b#9JQ[A 7.4.1 One- and Two-Dimensional Systems
I:E`PZ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
B*eC3ok3z 7..4.3UPS Band Structures and XPS Density of States
0XOp3 7.5 A Comment
C0sX gM References
jkQ*D(;p u^^vB\"^ 8.Surface States, Surface Effects
k
9_`(nx 8.1 Theoretical Considerations
$6#CqWhI 8.2 Experimental Results on Surface States
aacpM[{f 8.3 Quantum-Well States
V"[g.%%Y 8.4 Surface Core-Level Shifts
bc7/V#W References
<h!_>:2L _Ym]Mj' ln 9.Inverse Photoelectron Spectroscopy
R
&nPj~ 9.1 Surface States
L s
G\OG 9.2 Bulk Band Structures
SDC4L <! 9.3 Adsorbed Molecules
}cM}Oavh References
2ElJbN# \9.bt:k@OT 10. Spin-Polarized Photoelectron Spectroscopy
|+{)_? 10.1 General Description
FW;m\vu 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
R$EW4]j 10.3 Magnetic Dichroism
/~DI 6g References
Qu"8(Jk/ q'+)t7! 11. Photoelectron Diffraction
#9=Vg 11.1 Examples
pXtl
6K% 11.2 Substrate Photoelectron Diffraction
#./fY;:cj 11.3 Adsorbate Photoelectron Diffraction
CYt?,qk-r 11.4 Fermi Surface Scans
>R|/M`<ph References
J;S
(>c Z3%}ajPu[ Appendix
l(yZO$ A.1 Table of Binding Energies
J.3u^~zy A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
_PPy44r2 A.3 Compilation of Work Functions
[RS|gem` References
B[qzUD*P_n Index