光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
4/{pz$ c]1AM)xo 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
dY.X/f -wH0g^Ed 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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O0r vr$. ,Gbc4x 目录
#]^C(qmb: 1. Introduction and Basic Principles
s+_8U}R 1.1 Historical Development
8[,R4@ 1.2 The Electron Mean Free Path
6qmV/DL 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
XySkm2y 1.4 Experimental Aspects
(bsywM 1.5 Very High Resolution
GMZ6 dK 1.6 The Theory of Photoemission
1Hhr6T^) 1.6.1 Core-Level Photoemission
)(.g~Q: 1.6.2 Valence-State Photoemission
+8"8s 1.6.3 Three-Step and One-Step Considerations
4gEw}WiP 1.7 Deviations from the Simple Theory of Photoemission
*!%n`BR ' References
.PT7 ?Qd`Vlp7 2. Core Levels and Final States
9
4bDJy1 2.1 Core-Level Binding Energies in Atoms and Molecules
3&E@#I^], 2.1.1 The Equivalent-Core Approximation
hN0h'JJ[7 2.1.2 Chemical Shifts
0n4( Rj|}2 2.2 Core-Level Binding Energies in Solids
R$IsP,Uw 2.2.1 The Born-Haber Cycle in Insulators
O5:U2o- 2.2.2 Theory of Binding Energies
SJc*Rl> 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
!"/"Mqs3$ 2.3 Core Polarization
/W
f.Gt9[ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
RWu<
dY#ym 2.5 Vibrational Side Bands
{C?$osrr 2.6 Core Levels of Adsorbed Molecules
t:oq't 2.7 Quantitative Chemical Analysis from Core-Level Intensities
w(S&X"~ References
uk WL3 uF3{FYM{I 3. Charge-Excitation Final States: Satellites
B
k\KG 3.1 Copper Dihalides; 3d Transition Metal Compounds
GHLFn~z@XJ 3.1.1 Characterization of a Satellite
v`'Iew } 3.1.2 Analysis of Charge-Transfer Satellites
QCDica `+* 3.1.3 Non-local Screening
Je"XIhBr 3.2 The 6-eV Satellite in Nickel
&\5bo=5V 3.2.1 Resonance Photoemission
FncP,F$8
3.2.2 Satellites in Other Metals
E.N>,N 3.3 The Gunnarsson-Sch6nhammer Theory
{Z!t:'x8 3.4 Photoemission Signals and Narrow Bands in Metals
#/9Y}2G|] References
<jFov`^ *yZta:(w-W 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
dpge:Qhr 4.1 Theory
1W0[|Hf2v* 4.1.1 General
qKeR}&b 4.1.2 Core-Line Shape
sGiK
S,.K 4.1.3 Intrinsic Plasmons
8eh3K8tL# 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
N5#j}tT 4.1.5 The Total Photoelectron Spectrum
^I6Vz?0Jl 4.2 Experimental Results
o9Mr7 4.2.1 The Core Line Without Plasmons
-y_q 4.2.2 Core-Level Spectra Including Plasmoas
wr:-n 4.2.3 Valence-Band Spectra of the Simple Metals
jC>mDnX 4.2.4 Simple Metals: A General Comment
#U3q
+d+^ 4.3 The Background Correction
m,6u+Z, References
ox.kL _~>WAm< 5. Valence Orbitals in Simple Molecules and Insulating Solids
&01KHJY)/G 5.1 UPS Spectra of Monatomic Gases
8WQc8 5.2 Photoelectron Spectra of Diatomic Molecules
+g1+,?cU 5.3 Binding Energy of the H2 Molecule
C!v%6[ 5.4 Hydrides Isoelectronic with Noble Gases
m>w{vqPwJ Neon (Ne)
l]R7A_| Hydrogen Fluoride (HF)
n#?y;Y\ Water (H2O)
>*^SQ{9 Ammonia (NH3)
nemC-4} Methane (CH4)
SuV3$-);z 5.5 Spectra of the Alkali HMides
J5f}-W@ 5.6 Transition Metal Dihalides
?%Q=l;W. 5.7 Hydrocarbons
QR-pji
y 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
sQrM"i0Y> 5.7.2 Linear Polymers
?c_:S]^ 5.8 Insulating Solids with Valence d Electrons
?<
Ma4yl</ 5.8.1 The NiO Problem
Gp?pSI,b.t 5.8.2 Mort Insulation
h y\iot 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
M3d%$q)<rW 5.8.4Band Structures of Transition Metal Compounds
)*.rl 5.9 High—Temperature Superconductors
WkpHe 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
r M}o) 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
I~ mu'T 5.9.3 The Superconducting Gap
VS~+W=5} 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
LH@Kn?R6 5.9.5 Core—Level Shifts
}KftVnD? 5.10 The Fermi Liquid and the Luttinger Liquid
BoARM{m 5.11 Adsorbed Molecules
m("KLp8 5.11.1 Outline
<
jX5}@`z 5.11.2 CO on Metal Surfaces
O
~[[JAi[ References
`oO*ORq& }-Nc}%5 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
qsQTJlq) 6.1 Theory of Photoemission:A Summary of the Three-Step Model
AOqL&z 6.2 Discussion of the Photocurrent
FId,/la 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
(II#9n) 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
PyQ\O* 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
^`$-c9M?' 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
']^]z".H 6.3.1 Band Structure Regime
v(uNqX.BC 6.3.2 XPS Regime
;<F^&/a|yQ 6.3.3 Surface Emission
bXM&VW?OP 6.3.4 One-Step Calculations
urL@SeV+$ 6.4 Thermal Effects
G8Ow;:Ro
6.5 Dipole Selection Rules for Direct Optical Transitions
M,r8 No References
g\49[U}[~F +t]Ge
>S 7.Band Structtire and Angular-Resolved Photoelectron Spectra
cwHbm% 7.1 Free-Electron Final—State Model
x97L>>| 7.2 Methods Employing Calculated Band Structures
'OU3-K 7.3 Methods for the Absolute Determination of the Crystal Momentum
zCS }i_ p 7.3.1 Triangulation or Energy Coincidence Method
! bX 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
#,"[sag 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
3n_t^= 7.3.4 The Surface Emission Method and Electron Damping
w H`GzB" 7.3.5 The Very-Low-Energy Electron Diffraction Method
?|Wxqo 7.3.6 The Fermi Surface Method
6jov8GIAt 7.3.7 Intensities and Their Use in Band-Structure Determinations
ZxCXru1 7.3.8 Summary
oy=ej+: 7.4 Experimental Band Structures
7PO]\X^(zE 7.4.1 One- and Two-Dimensional Systems
W=n
Hi\jLV 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
?. L]QU 7..4.3UPS Band Structures and XPS Density of States
W:8{}Iu< 7.5 A Comment
M pz9}[`3g References
b>}
)G7b} NR^3
1&}It 8.Surface States, Surface Effects
')WS :\J 8.1 Theoretical Considerations
\5HVX/ 8.2 Experimental Results on Surface States
=,s5>2 8.3 Quantum-Well States
PFbkkQKsT 8.4 Surface Core-Level Shifts
{Q^ -
References
t<^7s9r;I +\.0Pr 9.Inverse Photoelectron Spectroscopy
qE6D"+1y7 9.1 Surface States
/1+jQS 9.2 Bulk Band Structures
Iqj?wI1) 9.3 Adsorbed Molecules
IY@N References
[| C &5%~Qw.. 10. Spin-Polarized Photoelectron Spectroscopy
P (fWJVF7 10.1 General Description
>5t]Zlb` 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
5E${ 10.3 Magnetic Dichroism
a{.-qp References
~KxK+6[ : L*{E-m/ 11. Photoelectron Diffraction
:?)q"hE 11.1 Examples
HoZsDs.XZ 11.2 Substrate Photoelectron Diffraction
0.U-
tg0 11.3 Adsorbate Photoelectron Diffraction
:vE\r#hJ" 11.4 Fermi Surface Scans
:4Y5 References
Saks~m7, @|d`n\%x Appendix
kr44@!s+' A.1 Table of Binding Energies
]];LA!n A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
}e>OmfxDBt A.3 Compilation of Work Functions
*M6j)jqV References
U6YQ*%mZ_ Index