光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
f& \Bs8la C@[U:\ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
+S+=lu _ R# .H&# 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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?=^\kXc[ VXlAK( 目录
GKOl{och 1. Introduction and Basic Principles
BX6kn/i
1.1 Historical Development
qJf\,7mi 1.2 The Electron Mean Free Path
Vp0_R9oQ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
%3|/t-US 1.4 Experimental Aspects
~)`\j 1.5 Very High Resolution
|W$|og'wC 1.6 The Theory of Photoemission
n)Cr<^j 1.6.1 Core-Level Photoemission
M#-E 1.6.2 Valence-State Photoemission
WRA L/ 1.6.3 Three-Step and One-Step Considerations
1X`,7B@pz 1.7 Deviations from the Simple Theory of Photoemission
z]C=nXbk References
6w(r}yO] Ziub%C[oV 2. Core Levels and Final States
zUNUH^Il 2.1 Core-Level Binding Energies in Atoms and Molecules
#B6f{D[pI 2.1.1 The Equivalent-Core Approximation
UBj&T^j 2.1.2 Chemical Shifts
1|!)*!hu 2.2 Core-Level Binding Energies in Solids
H~mp*S 2.2.1 The Born-Haber Cycle in Insulators
rlawH}1b 2.2.2 Theory of Binding Energies
lKQevoy' 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
XJKns 2.3 Core Polarization
WHOX<YJs 2.4 Final-State Multiplets in Rare-Earth Valence Bands
md?
cvGDE 2.5 Vibrational Side Bands
sWMln:= 2.6 Core Levels of Adsorbed Molecules
'1xhP}'3) 2.7 Quantitative Chemical Analysis from Core-Level Intensities
?G!~& References
C2\WvE%! ,6pGKCUU:y 3. Charge-Excitation Final States: Satellites
X9SOcg3a 3.1 Copper Dihalides; 3d Transition Metal Compounds
Q-F$Ryj^ 3.1.1 Characterization of a Satellite
`4X.UPJ 3.1.2 Analysis of Charge-Transfer Satellites
-*~
@? 3.1.3 Non-local Screening
:ir3u 3.2 The 6-eV Satellite in Nickel
:g'
'GqGZ 3.2.1 Resonance Photoemission
Y'bz>@1( 3.2.2 Satellites in Other Metals
K/*"U*9Kv 3.3 The Gunnarsson-Sch6nhammer Theory
nCp_RJu 3.4 Photoemission Signals and Narrow Bands in Metals
/V`SJ" References
N{&Lo}6F /':64#' 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
($/l_F 4.1 Theory
S
w%6- 4.1.1 General
NWPT89@ l 4.1.2 Core-Line Shape
aPK:k$. 4.1.3 Intrinsic Plasmons
>;Vfs{Z(q 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
Fj2z$ 4.1.5 The Total Photoelectron Spectrum
~m,~; 4.2 Experimental Results
s3y GL 4.2.1 The Core Line Without Plasmons
L-S5@;" 4.2.2 Core-Level Spectra Including Plasmoas
m&DI2he 4.2.3 Valence-Band Spectra of the Simple Metals
CDXN%~0h 4.2.4 Simple Metals: A General Comment
XksI .]tfj 4.3 The Background Correction
jF
j'6LT9/ References
DO~[VK%| @ <2y+_e 5. Valence Orbitals in Simple Molecules and Insulating Solids
p8@8b " 5.1 UPS Spectra of Monatomic Gases
WLwi 5.2 Photoelectron Spectra of Diatomic Molecules
2p#d 5.3 Binding Energy of the H2 Molecule
"aI)LlyCY 5.4 Hydrides Isoelectronic with Noble Gases
m ie~.
" Neon (Ne)
m[Ihte-> Hydrogen Fluoride (HF)
+!px+*)bW Water (H2O)
TOKt{`2} Ammonia (NH3)
U<=d@knH Methane (CH4)
sJ^Ff 5.5 Spectra of the Alkali HMides
(|o@ 5.6 Transition Metal Dihalides
5mpql[v3P 5.7 Hydrocarbons
j6~`C
?( 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
4F0w+wJD 5.7.2 Linear Polymers
(Cq 38~mR 5.8 Insulating Solids with Valence d Electrons
Vn:v{-i 5.8.1 The NiO Problem
:p@jslD 5.8.2 Mort Insulation
bp}97ZQ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
);iJ9+ V} 5.8.4Band Structures of Transition Metal Compounds
#3LZX! 5.9 High—Temperature Superconductors
P]y{3y:XxM 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
&08dW9H 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
ZsXw]Wa 5.9.3 The Superconducting Gap
QRKP;aYt 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
n7~4*B 5.9.5 Core—Level Shifts
{ pQJ.QI 5.10 The Fermi Liquid and the Luttinger Liquid
&{glwVKV 5.11 Adsorbed Molecules
R@NFpiw 5.11.1 Outline
NS`hXf 5.11.2 CO on Metal Surfaces
Qjnh;uBO References
NF4(+E9g cZF|oZ6< 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
_Li.}g@Bd 6.1 Theory of Photoemission:A Summary of the Three-Step Model
f{O-\ 6.2 Discussion of the Photocurrent
yHC[8l8% 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
7t#Q8u? 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
(G} }h 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
T+EwC)Ll 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
X(Mpg[,N" 6.3.1 Band Structure Regime
tWzB Qx 6.3.2 XPS Regime
Vj1V;dHv 6.3.3 Surface Emission
\),f?f-m 6.3.4 One-Step Calculations
dMsS OP0E 6.4 Thermal Effects
iHc(e(CB< 6.5 Dipole Selection Rules for Direct Optical Transitions
}:{ @nP References
>@cBDS<6R bc~WJ+ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
$|&<cenMT 7.1 Free-Electron Final—State Model
CMbID1M3 7.2 Methods Employing Calculated Band Structures
st)v'ce, 7.3 Methods for the Absolute Determination of the Crystal Momentum
OgQ8yKfDB 7.3.1 Triangulation or Energy Coincidence Method
6'e^np 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
WjR2:kT 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
*,:2O&P 7.3.4 The Surface Emission Method and Electron Damping
<8?
F\x@ 7.3.5 The Very-Low-Energy Electron Diffraction Method
jVOq/o 7.3.6 The Fermi Surface Method
)p;t
'*] 7.3.7 Intensities and Their Use in Band-Structure Determinations
Whp`\E<< 7.3.8 Summary
J1cz
D |( 7.4 Experimental Band Structures
FW;}S9u3 7.4.1 One- and Two-Dimensional Systems
#6YpV) 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
_w%:PnO 7..4.3UPS Band Structures and XPS Density of States
3dbaCusT$ 7.5 A Comment
<*^|Aj|# References
us1$ W-|CK&1 8.Surface States, Surface Effects
LD
NdHG6 8.1 Theoretical Considerations
g{sp<w0 8.2 Experimental Results on Surface States
[:(O`# 8.3 Quantum-Well States
sUmpf 4/ 8.4 Surface Core-Level Shifts
`W_&^>yl References
[Y.JC'F# U=j`RQ 9, 9.Inverse Photoelectron Spectroscopy
n{~&^Nby*I 9.1 Surface States
|&-*&)iD|w 9.2 Bulk Band Structures
Kf(Px%G6K 9.3 Adsorbed Molecules
rwW"B References
)G, S7A }1V+8'D 10. Spin-Polarized Photoelectron Spectroscopy
sGNHA(; 10.1 General Description
CKe72OC 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
<Z_\2
YWA 10.3 Magnetic Dichroism
VSCKWYy References
|x&4vHXR0 e&8Meiv+d 11. Photoelectron Diffraction
Xg1TX_3Ml 11.1 Examples
Ez-AQ' 11.2 Substrate Photoelectron Diffraction
HA}q.L]# 11.3 Adsorbate Photoelectron Diffraction
IDqUiN 11.4 Fermi Surface Scans
^qBm%R( References
|?^N@ hSAI G Appendix
Z[Iej:o5 A.1 Table of Binding Energies
-"2 t^Q A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
FqnD"]A A.3 Compilation of Work Functions
b5jD /X4 References
`}uM91; Index