光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
dFS>uIT7X ah1d0eP 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
X|q&0W= k*(c8/<.d 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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"CLoM\M) OXe+=Lp< 目录
1uZ[Ewl] 1. Introduction and Basic Principles
?:vp3f# 1.1 Historical Development
K#rfQ0QK/! 1.2 The Electron Mean Free Path
dF:@BEo 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
{a\O7$A\F 1.4 Experimental Aspects
VR ^qwS/ 1.5 Very High Resolution
$,v
'> 1.6 The Theory of Photoemission
GR@!mf 1.6.1 Core-Level Photoemission
^hzlR[ 1.6.2 Valence-State Photoemission
FRd!UqMXY 1.6.3 Three-Step and One-Step Considerations
<`k\kZM 1.7 Deviations from the Simple Theory of Photoemission
'9c`[^ References
X1&Ug^ _*7h1[,{f 2. Core Levels and Final States
.<`i!Ls 2.1 Core-Level Binding Energies in Atoms and Molecules
3XF.$=@ 2.1.1 The Equivalent-Core Approximation
GmP)"@O](; 2.1.2 Chemical Shifts
JQ=i{ 9iJ 2.2 Core-Level Binding Energies in Solids
fOJ0#^Z 2.2.1 The Born-Haber Cycle in Insulators
6E/>]3~! 2.2.2 Theory of Binding Energies
d9>*a$x;/ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
o(w!x![" 2.3 Core Polarization
5LdVcXf 2.4 Final-State Multiplets in Rare-Earth Valence Bands
(|)`~z 2.5 Vibrational Side Bands
*GleeJWz 2.6 Core Levels of Adsorbed Molecules
w
F6ywr 2.7 Quantitative Chemical Analysis from Core-Level Intensities
;*1bTdB5a References
IROX]f}r ( JBfDz0P 3. Charge-Excitation Final States: Satellites
#N^TqOr 3.1 Copper Dihalides; 3d Transition Metal Compounds
F1) B-wW 3.1.1 Characterization of a Satellite
_;(`u!@/{ 3.1.2 Analysis of Charge-Transfer Satellites
g+/%r91hZ 3.1.3 Non-local Screening
3WyK!@{ 3.2 The 6-eV Satellite in Nickel
'|^LNAx 3.2.1 Resonance Photoemission
&_FNDJ>MCk 3.2.2 Satellites in Other Metals
bb;fV 3.3 The Gunnarsson-Sch6nhammer Theory
PJj{5,#@3 3.4 Photoemission Signals and Narrow Bands in Metals
8)/i\=N3; References
xVoWGz7 b~06-dk1 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
Sp)KtMV 4.1 Theory
1!/+~J[# 4.1.1 General
w?ssV 4.1.2 Core-Line Shape
aKs!*uo0H 4.1.3 Intrinsic Plasmons
hTI8hh 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
lEi,duS) 4.1.5 The Total Photoelectron Spectrum
TRz~rW
k 4.2 Experimental Results
tW5\Ktjno 4.2.1 The Core Line Without Plasmons
_dqjRhu 4.2.2 Core-Level Spectra Including Plasmoas
>`*iM 4.2.3 Valence-Band Spectra of the Simple Metals
TI}H(XL( 4.2.4 Simple Metals: A General Comment
Y0BvN`E 4.3 The Background Correction
lp[3z&u References
4,9AoK)yp n? "ti 5. Valence Orbitals in Simple Molecules and Insulating Solids
qGkrG38K 5.1 UPS Spectra of Monatomic Gases
(PGmA>BT 5.2 Photoelectron Spectra of Diatomic Molecules
W9 y8dw. 5.3 Binding Energy of the H2 Molecule
FcIH<_r 5.4 Hydrides Isoelectronic with Noble Gases
m6V1m0M Neon (Ne)
rP ;~<IxEr Hydrogen Fluoride (HF)
V2es.I Water (H2O)
80$P35Q" Ammonia (NH3)
1W~-C B> Methane (CH4)
+C;ZO6%w 5.5 Spectra of the Alkali HMides
Y=X"YH| 5.6 Transition Metal Dihalides
OdQ>h$ gZ 5.7 Hydrocarbons
<0P`ct0,i 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
,- ]2s_ 5.7.2 Linear Polymers
bI[!y#_z4 5.8 Insulating Solids with Valence d Electrons
!N$4.slr<p 5.8.1 The NiO Problem
xy mK| 5.8.2 Mort Insulation
<6/XE@" 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
w GZ(bKyO 5.8.4Band Structures of Transition Metal Compounds
{%D
"0* ^ 5.9 High—Temperature Superconductors
dQM# -t4* 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
4:r^6m%% 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
>|0yH9af 5.9.3 The Superconducting Gap
P},S[GaZ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
VK`_Qc#B 5.9.5 Core—Level Shifts
uW>AH@Pij 5.10 The Fermi Liquid and the Luttinger Liquid
-Kg@Sj/U}R 5.11 Adsorbed Molecules
yD1*^~ loJ 5.11.1 Outline
t)XV'J 5.11.2 CO on Metal Surfaces
L:Wy- Z References
i?=3RdP/R1 SJU93n"G/ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
{J})f>x<xM 6.1 Theory of Photoemission:A Summary of the Three-Step Model
O#O~A| 6.2 Discussion of the Photocurrent
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