光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
,^2>k3= -4
SY=NC_ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
[k/@E+; S[J}UpV 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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C$XU%5qi sM `DL 目录
;EP:o%r 1. Introduction and Basic Principles
9-fLz?J 1.1 Historical Development
'Wmx)0) 1.2 The Electron Mean Free Path
HK2[]G 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
v@
lM3_rbO 1.4 Experimental Aspects
1=d6NX)B 1.5 Very High Resolution
+l<5#pazx 1.6 The Theory of Photoemission
H _zo1AW 1.6.1 Core-Level Photoemission
-C(crn 1.6.2 Valence-State Photoemission
?fi,ifp*|l 1.6.3 Three-Step and One-Step Considerations
#ML%ij 1 1.7 Deviations from the Simple Theory of Photoemission
woGAf)vV# References
@~"h62=]
- ).`1+b 2. Core Levels and Final States
%[ Z \S0C 2.1 Core-Level Binding Energies in Atoms and Molecules
~d|A!S` 2.1.1 The Equivalent-Core Approximation
Nh_Mz;ITuu 2.1.2 Chemical Shifts
"hH.#5j 2.2 Core-Level Binding Energies in Solids
/rnu<Q#iH 2.2.1 The Born-Haber Cycle in Insulators
j i7[nY 2.2.2 Theory of Binding Energies
V{/?FO?E 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
8c9*\S 2.3 Core Polarization
4NheWM6 2.4 Final-State Multiplets in Rare-Earth Valence Bands
2fnkw/ 2.5 Vibrational Side Bands
)<h*eS{ 2.6 Core Levels of Adsorbed Molecules
3KlbP 2.7 Quantitative Chemical Analysis from Core-Level Intensities
"Q@ronP(~ References
P-y jN iJ1"at 3. Charge-Excitation Final States: Satellites
FQ<Ju. 3.1 Copper Dihalides; 3d Transition Metal Compounds
4;yKOQD| 3.1.1 Characterization of a Satellite
!Prg_6
` 3.1.2 Analysis of Charge-Transfer Satellites
4%>$-($ 3.1.3 Non-local Screening
jCOIuw 3.2 The 6-eV Satellite in Nickel
FKDk +ojw 3.2.1 Resonance Photoemission
^
*k?pJ5 3.2.2 Satellites in Other Metals
6xTuNE1 3.3 The Gunnarsson-Sch6nhammer Theory
<Tzrj1"Q3 3.4 Photoemission Signals and Narrow Bands in Metals
N8F~8lTi References
1ySk;;3 Vc&!OE 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
3no%E03p 4.1 Theory
V5V
bJBpf 4.1.1 General
S9]'?| 4.1.2 Core-Line Shape
cQCSe,$ W 4.1.3 Intrinsic Plasmons
4i)1'{e 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
/R]U}o^/(% 4.1.5 The Total Photoelectron Spectrum
Z'`<5A%; 4.2 Experimental Results
n8~N$tDU 4.2.1 The Core Line Without Plasmons
snE8 K}4 4.2.2 Core-Level Spectra Including Plasmoas
.sha& 4.2.3 Valence-Band Spectra of the Simple Metals
KX ,S 4.2.4 Simple Metals: A General Comment
f-vCm 5f 4.3 The Background Correction
PUT=C1,OFR References
}~e8e \A 2r] 5. Valence Orbitals in Simple Molecules and Insulating Solids
4gI/!,J(b 5.1 UPS Spectra of Monatomic Gases
z+0I#kM"1 5.2 Photoelectron Spectra of Diatomic Molecules
Y,<{vLEC 5.3 Binding Energy of the H2 Molecule
;DqWh0 5.4 Hydrides Isoelectronic with Noble Gases
k]F[>26k Neon (Ne)
AVlhNIr Hydrogen Fluoride (HF)
BO~0ON0 Water (H2O)
Gw/Pk4R Ammonia (NH3)
sBj(Qd Methane (CH4)
k:t]s_`< 5.5 Spectra of the Alkali HMides
6tgt>\y 5.6 Transition Metal Dihalides
[kVS
O 5.7 Hydrocarbons
PxWT1 ! 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
GZN ^k+w 5.7.2 Linear Polymers
9UdM`v)( 5.8 Insulating Solids with Valence d Electrons
%
L$bf# 5.8.1 The NiO Problem
,>bh$| 5.8.2 Mort Insulation
}eCw6 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
%KCyb 5.8.4Band Structures of Transition Metal Compounds
T"{>t 5.9 High—Temperature Superconductors
!#], hok8X 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
eBZXI)pPh 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
R1adWBD> 5.9.3 The Superconducting Gap
Q|S.R1L^ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
B3pCy~*5 5.9.5 Core—Level Shifts
"h{q#~s 5.10 The Fermi Liquid and the Luttinger Liquid
! E<[JM 5.11 Adsorbed Molecules
q<xCb%#Jl 5.11.1 Outline
cM(:xv 5.11.2 CO on Metal Surfaces
\(?rQg@U References
x|/|jzJSX x[FJgI'r 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
fx41,0;gZq 6.1 Theory of Photoemission:A Summary of the Three-Step Model
%P;lv*v. 6.2 Discussion of the Photocurrent
:KQ~Cb 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
Q3kdlxXR 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
yZ0-wI 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
w$3,A$8 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
~8'sBT 6.3.1 Band Structure Regime
ePOG}k($/% 6.3.2 XPS Regime
$t$ShT) 6.3.3 Surface Emission
($q-_m 6.3.4 One-Step Calculations
epA:v|S 6.4 Thermal Effects
so,t 6.5 Dipole Selection Rules for Direct Optical Transitions
F&!6jv References
~8q)^vm>f? %0S3V[4I 7.Band Structtire and Angular-Resolved Photoelectron Spectra
&jS>UsGh 7.1 Free-Electron Final—State Model
m ifxiV 7.2 Methods Employing Calculated Band Structures
8zZvht* 7.3 Methods for the Absolute Determination of the Crystal Momentum
~Otq %MQ 7.3.1 Triangulation or Energy Coincidence Method
R5N%e%[ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
+F R0(T 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
&|s0P 7.3.4 The Surface Emission Method and Electron Damping
x>**;#7) 7.3.5 The Very-Low-Energy Electron Diffraction Method
|U:k,YH 7.3.6 The Fermi Surface Method
E-T)*`e 7.3.7 Intensities and Their Use in Band-Structure Determinations
C8J[Up 7.3.8 Summary
rMdt:` 7.4 Experimental Band Structures
9g9HlB&Ze 7.4.1 One- and Two-Dimensional Systems
!y\'EW3|G 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
UFXaEl}R 7..4.3UPS Band Structures and XPS Density of States
,82S=N5V! 7.5 A Comment
^=GC3%
J References
/Wi[OT14 E(*0jAvO[z 8.Surface States, Surface Effects
}5ret 8.1 Theoretical Considerations
Gw}%{=D9 8.2 Experimental Results on Surface States
G!Op~p@Jm 8.3 Quantum-Well States
.M qP_Z', 8.4 Surface Core-Level Shifts
GSoX<*i References
!O\82d1P %"q9:{m 9.Inverse Photoelectron Spectroscopy
VpE*(i$ 9.1 Surface States
JgxtlYjl 9.2 Bulk Band Structures
MUaq7B_> 9.3 Adsorbed Molecules
[]\+k31D References
W =D4r TJ2=m9Z 10. Spin-Polarized Photoelectron Spectroscopy
P@,XEQRd` 10.1 General Description
0CZ:Bo[3 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
'F/~o1\. 10.3 Magnetic Dichroism
_'#n6^Us< References
_('=b/ T.])diuvj- 11. Photoelectron Diffraction
T(#J_Y 11.1 Examples
PIJr{6B/PA 11.2 Substrate Photoelectron Diffraction
%41m~Wh2 11.3 Adsorbate Photoelectron Diffraction
zG }@0 11.4 Fermi Surface Scans
e6`Jbu+J<f References
=J18eH!] E@z<:pG{ Appendix
`XJG(Oas\ A.1 Table of Binding Energies
Q$a{\*[:+ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
;!>rnxB?4 A.3 Compilation of Work Functions
ny]?I References
evya7^,F Index