光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
VI/77 RX \%R 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
OjFB_
N H+6+I53 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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目录
k>SPtiAs 1. Introduction and Basic Principles
t}w<xe 1.1 Historical Development
Qv~lH&jG 1.2 The Electron Mean Free Path
;2*hN( 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
g:8k,1y5 1.4 Experimental Aspects
%=e^MN1 1.5 Very High Resolution
rK(TekU 1.6 The Theory of Photoemission
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1.6.1 Core-Level Photoemission
L.X"wIs^ 1.6.2 Valence-State Photoemission
LYhjI 1.6.3 Three-Step and One-Step Considerations
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[T{{ 1.7 Deviations from the Simple Theory of Photoemission
[&eG>zF" References
Z}$wvd kT^|%bB[i 2. Core Levels and Final States
QN)EPS:y 2.1 Core-Level Binding Energies in Atoms and Molecules
/3#) 2.1.1 The Equivalent-Core Approximation
+7E&IK 2.1.2 Chemical Shifts
fkk&pu 2.2 Core-Level Binding Energies in Solids
\3q Z0 2.2.1 The Born-Haber Cycle in Insulators
= Zi'L48 2.2.2 Theory of Binding Energies
VYG o; 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
rJtpTV@. 2.3 Core Polarization
1{15#W 2.4 Final-State Multiplets in Rare-Earth Valence Bands
l_$le 2.5 Vibrational Side Bands
0Sx$6:-~ 2.6 Core Levels of Adsorbed Molecules
7fE U5@ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
_O#R,Y2# References
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f2} *{<460`!q 3. Charge-Excitation Final States: Satellites
b@X+vW{S 3.1 Copper Dihalides; 3d Transition Metal Compounds
FIu|eW+<l 3.1.1 Characterization of a Satellite
^J~5k,7jX 3.1.2 Analysis of Charge-Transfer Satellites
5LaF'>1yY 3.1.3 Non-local Screening
}o[NB 3.2 The 6-eV Satellite in Nickel
'u}OeS"f 3.2.1 Resonance Photoemission
C:r3z50 3.2.2 Satellites in Other Metals
03Uj0.Z|7 3.3 The Gunnarsson-Sch6nhammer Theory
<]Btx;} 3.4 Photoemission Signals and Narrow Bands in Metals
T0|hp7WM References
dC>[[_ /`s{!t#Y 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
=[do([A 4.1 Theory
bt'lT 4.1.1 General
U2G[uDa; 4.1.2 Core-Line Shape
9s4>hw@u 4.1.3 Intrinsic Plasmons
,8@q2a/ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
=C#22xqQ. 4.1.5 The Total Photoelectron Spectrum
3;?DKRIcX 4.2 Experimental Results
weH;,e*r 4.2.1 The Core Line Without Plasmons
k5g vo 4.2.2 Core-Level Spectra Including Plasmoas
UX24*0`\~ 4.2.3 Valence-Band Spectra of the Simple Metals
4OOI$J$Jh 4.2.4 Simple Metals: A General Comment
zD@RW<M 4.3 The Background Correction
y?'Z' References
0d/
f4 AGhr(\j 5. Valence Orbitals in Simple Molecules and Insulating Solids
JuDadIrd{ 5.1 UPS Spectra of Monatomic Gases
eNDc220b 5.2 Photoelectron Spectra of Diatomic Molecules
VXPsYR& 5.3 Binding Energy of the H2 Molecule
O^Y@&S RrQ 5.4 Hydrides Isoelectronic with Noble Gases
R+# g_"1@p Neon (Ne)
]u|5ZCv0 Hydrogen Fluoride (HF)
* `3+x Water (H2O)
e'X"uH Xt. Ammonia (NH3)
NqC}}N\, Methane (CH4)
@rE+H
5 5.5 Spectra of the Alkali HMides
O:j=L{,d^ 5.6 Transition Metal Dihalides
$Zn>W@\ 5.7 Hydrocarbons
oM!zeJNA 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
Pd+Wb3 5.7.2 Linear Polymers
7V%b!R} 5.8 Insulating Solids with Valence d Electrons
?$@E}t8g\ 5.8.1 The NiO Problem
8;i'dF:) 5.8.2 Mort Insulation
af_bG; 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
"lA8CA 5.8.4Band Structures of Transition Metal Compounds
Iuve~ugO 5.9 High—Temperature Superconductors
i4<n#]1!t 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
TBmmC}PEd 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
b"(bT6XO! 5.9.3 The Superconducting Gap
({<qs}H" 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
PTpGZ2FZ 5.9.5 Core—Level Shifts
GLA4O) 5.10 The Fermi Liquid and the Luttinger Liquid
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5.11 Adsorbed Molecules
r!c7{6N 5.11.1 Outline
EouI S2e;a 5.11.2 CO on Metal Surfaces
ow9Vj$m References
b\vL^\bX8 4oPr|OKj{* 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
>mMmc!u>G 6.1 Theory of Photoemission:A Summary of the Three-Step Model
:0% $u>;O: 6.2 Discussion of the Photocurrent
uA%cie 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
<3 I0$?xL 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
i9^m;Y)^I 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
Zr|\T7w 3 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
es1'z.U J 6.3.1 Band Structure Regime
\tfhF#' 6.3.2 XPS Regime
ub-vtRpm 6.3.3 Surface Emission
/t04}+,e^ 6.3.4 One-Step Calculations
,-)ww: 6.4 Thermal Effects
Ym
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SJO^.[ References
4Y{&y6 a;v;% rs 7.Band Structtire and Angular-Resolved Photoelectron Spectra
i%otvDn1 7.1 Free-Electron Final—State Model
jN%+)Kj0C) 7.2 Methods Employing Calculated Band Structures
l j %k/u 7.3 Methods for the Absolute Determination of the Crystal Momentum
4EFP*7X 7.3.1 Triangulation or Energy Coincidence Method
i&Me7=~ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
XBos^Q 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
oN[#C>#( 7.3.4 The Surface Emission Method and Electron Damping
~2}^
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&Ui&2EW 7.3.6 The Fermi Surface Method
\l?.VE D 7.3.7 Intensities and Their Use in Band-Structure Determinations
S%7%@Qs"% 7.3.8 Summary
IWnyqt(k 7.4 Experimental Band Structures
JT*Pm"} 7.4.1 One- and Two-Dimensional Systems
W4S]2P>T 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
s/OXZ<C| 7..4.3UPS Band Structures and XPS Density of States
wi S8S{K5 7.5 A Comment
F
<.} q|b References
A5YS
"i oT^r 8.Surface States, Surface Effects
KDYyLkI dr 8.1 Theoretical Considerations
6'JP%~QlS 8.2 Experimental Results on Surface States
2"B3Q:0he| 8.3 Quantum-Well States
(Ek=0;Cr 8.4 Surface Core-Level Shifts
6EkD(w References
Op
;){JT \\,z[C 9.Inverse Photoelectron Spectroscopy
YL@d+
-\ 9.1 Surface States
#*;Nb 9.2 Bulk Band Structures
.iH#8Z
9.3 Adsorbed Molecules
-0:B2B References
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jXN82 AK5$>Pkvk 10. Spin-Polarized Photoelectron Spectroscopy
Wg5i#6y8w 10.1 General Description
{#%;Hq P 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
p&(~c/0 10.3 Magnetic Dichroism
ot.R Gpg% References
b6gD*w< eE[/#5tK 11. Photoelectron Diffraction
!d=Q@oy5 11.1 Examples
K7$Vl"l 11.2 Substrate Photoelectron Diffraction
me/ae{ 11.3 Adsorbate Photoelectron Diffraction
7x:j4 11.4 Fermi Surface Scans
.X(ocs$} References
0Z>oiBr4 0 ;ov^] Appendix
m#(ve1E A.1 Table of Binding Energies
N>_d {=P A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
^Sz?c_<2P A.3 Compilation of Work Functions
_\2^s&iJh References
*oz=k Index