光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
O]!DNN e%>E| 9*u 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
`<Nc
Y* #Og_q$})f 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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<#`L&w. QKQy)g 目录
0CYI,V 1. Introduction and Basic Principles
vM8]fSc 1.1 Historical Development
%hQ`b$07t 1.2 The Electron Mean Free Path
t|_g O!w8 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
!4fL|0 1.4 Experimental Aspects
b,`N;* 1.5 Very High Resolution
2US8<sq+ 1.6 The Theory of Photoemission
*i90[3l 1.6.1 Core-Level Photoemission
?~8V;Qn 1.6.2 Valence-State Photoemission
W;W\L? r 1.6.3 Three-Step and One-Step Considerations
=!aV?kNS8 1.7 Deviations from the Simple Theory of Photoemission
GM~jR-FZ References
Pr'py KDk^)zv%! 2. Core Levels and Final States
wDzS<mm 2.1 Core-Level Binding Energies in Atoms and Molecules
@ZZ Lh= 2.1.1 The Equivalent-Core Approximation
KxI(#}5o& 2.1.2 Chemical Shifts
K;O\Pd 2.2 Core-Level Binding Energies in Solids
l-rI|0D# 2.2.1 The Born-Haber Cycle in Insulators
g}7%3D 2.2.2 Theory of Binding Energies
aqgSr| 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
.v'8G)6g 2.3 Core Polarization
MI 3_<[ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
Ns{4BM6j 2.5 Vibrational Side Bands
Rlu;l 2.6 Core Levels of Adsorbed Molecules
u)ItML 2.7 Quantitative Chemical Analysis from Core-Level Intensities
6|x<)Gc References
0jq#,p=l; ektFk"W3A\ 3. Charge-Excitation Final States: Satellites
f}A^rWO 3.1 Copper Dihalides; 3d Transition Metal Compounds
8[V!e[ 3.1.1 Characterization of a Satellite
nLQJ~(" 3.1.2 Analysis of Charge-Transfer Satellites
w@R-@
G 3.1.3 Non-local Screening
L[efiiLh$ 3.2 The 6-eV Satellite in Nickel
[aW#7 3.2.1 Resonance Photoemission
z
Ey&%Ok 3.2.2 Satellites in Other Metals
Z]dc%> 3.3 The Gunnarsson-Sch6nhammer Theory
6AY%onY 3.4 Photoemission Signals and Narrow Bands in Metals
?*HlAVDcFT References
TM9>r :j' ?Z"}RMM)8 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
Q{l;8MCL 4.1 Theory
6Z 7$ZQ~ 4.1.1 General
dpS 4.1.2 Core-Line Shape
OpfFF;"A' 4.1.3 Intrinsic Plasmons
#i?TCO 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
v%r! }s 4.1.5 The Total Photoelectron Spectrum
m`|+_{4[n 4.2 Experimental Results
/TdTo@ 4.2.1 The Core Line Without Plasmons
WO^h\#^n 4.2.2 Core-Level Spectra Including Plasmoas
6+>rf{5P7 4.2.3 Valence-Band Spectra of the Simple Metals
f>o@Y]/l 4.2.4 Simple Metals: A General Comment
FM5$83Q 4.3 The Background Correction
Sq,x@ References
$%<gp@Gz x:(e:I8x( 5. Valence Orbitals in Simple Molecules and Insulating Solids
l[gL(p"W 5.1 UPS Spectra of Monatomic Gases
9%8T09I! 5.2 Photoelectron Spectra of Diatomic Molecules
F+X3CB,f 5.3 Binding Energy of the H2 Molecule
Mg].# 5.4 Hydrides Isoelectronic with Noble Gases
B{Rig5Sc Neon (Ne)
QP'*
)gjO7 Hydrogen Fluoride (HF)
W'[!4RQL Water (H2O)
/*[a>B4-q Ammonia (NH3)
NEvt71k Methane (CH4)
*i|hcDk 5.5 Spectra of the Alkali HMides
jU=)4nx 5.6 Transition Metal Dihalides
XHV+Y+VG 5.7 Hydrocarbons
,v/C-b)I 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
_=rXaTp 5.7.2 Linear Polymers
ZyTah\yPM 5.8 Insulating Solids with Valence d Electrons
CZ@M~Si_ 5.8.1 The NiO Problem
{\k9%2V*+ 5.8.2 Mort Insulation
IBR;q[Dj} 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
/H)l\m
+ 5.8.4Band Structures of Transition Metal Compounds
TYp{nWwi 5.9 High—Temperature Superconductors
]uP{Sj 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
McfSB(59 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
U+W8)7bc 5.9.3 The Superconducting Gap
#ws6z`mt 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
.UJk0%1 5.9.5 Core—Level Shifts
r J&1[=s 5.10 The Fermi Liquid and the Luttinger Liquid
Wd[XQZ< 5.11 Adsorbed Molecules
>k:)'* 5.11.1 Outline
q,2
@X~T
5.11.2 CO on Metal Surfaces
Cnc77EUD References
z*FlZLHY Bk8U\Ut 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
?p`}6s Q} 6.1 Theory of Photoemission:A Summary of the Three-Step Model
?Hy++ 6.2 Discussion of the Photocurrent
d(k`Yk8 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
yfV{2[8ux 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
3p7*UVR" 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
3#dUQ1qo6 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
:yv!
x 6.3.1 Band Structure Regime
\4V'NTjB 6.3.2 XPS Regime
G G7N!eZ 6.3.3 Surface Emission
m0:8thZN 6.3.4 One-Step Calculations
lp4sO#>` 6.4 Thermal Effects
)p&xpB( 6.5 Dipole Selection Rules for Direct Optical Transitions
D0uf=BbS References
&98qAO]Z ]SK (cfA` 7.Band Structtire and Angular-Resolved Photoelectron Spectra
l*h6JgU 7.1 Free-Electron Final—State Model
qoOHWh& 7.2 Methods Employing Calculated Band Structures
IUzRE?Kzf 7.3 Methods for the Absolute Determination of the Crystal Momentum
Y~Zg^x2 7.3.1 Triangulation or Energy Coincidence Method
2t_E\W7w+ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
')_jK',1 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
\2W( >_z 7.3.4 The Surface Emission Method and Electron Damping
2-2'c?% 7.3.5 The Very-Low-Energy Electron Diffraction Method
CvlAn7r,@ 7.3.6 The Fermi Surface Method
)U8F6GIC&} 7.3.7 Intensities and Their Use in Band-Structure Determinations
i3YAK$w;& 7.3.8 Summary
Rd 2* 7.4 Experimental Band Structures
m"u 9AOH k 7.4.1 One- and Two-Dimensional Systems
h4sEH 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
\@5W&Be^ 7..4.3UPS Band Structures and XPS Density of States
|
YvO$4=s 7.5 A Comment
GJ!usv u References
H.'_NCF&;L DT_012z 8.Surface States, Surface Effects
W&GDE 8.1 Theoretical Considerations
I_v]^>Xw 8.2 Experimental Results on Surface States
=_=jXWOQv 8.3 Quantum-Well States
; <3w ,r 8.4 Surface Core-Level Shifts
KPKby?qQ^ References
x%LWcT/ p_tMl%K 9.Inverse Photoelectron Spectroscopy
`lr\V;o! 9.1 Surface States
}**^g: 9.2 Bulk Band Structures
nLYyS# 9.3 Adsorbed Molecules
B,}%1+* References
'v4AM@%u {d=y9Jb^ 10. Spin-Polarized Photoelectron Spectroscopy
vw3%u+Z& 10.1 General Description
uI.4zbgl[ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
tBdvk>d 10.3 Magnetic Dichroism
IiSO{ References
g`\Vy4w
RtK/bUa 11. Photoelectron Diffraction
N\mV+f3A@, 11.1 Examples
SrU,-mA W 11.2 Substrate Photoelectron Diffraction
?DM-C5$ 11.3 Adsorbate Photoelectron Diffraction
:Ruj;j 11.4 Fermi Surface Scans
&:w{[H$- References
(,HAOs
_k
_F Appendix
9v0f4Pbxm A.1 Table of Binding Energies
H~&9xtuHN A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
F^KoEWj[H A.3 Compilation of Work Functions
5Gg`+o References
fH}` Index