光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
*jps}uk< M8
E8r
作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
szY=N7\S* $~|#Rz%v 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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p=Nord 38wt=0br 目录
h]rF2 B 1. Introduction and Basic Principles
)19As8rL/o 1.1 Historical Development
cC.=,n 1.2 The Electron Mean Free Path
mr+J# 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
rRN7HL+b 1.4 Experimental Aspects
K; 7o+Xr 1.5 Very High Resolution
Mt@P}4 1.6 The Theory of Photoemission
u;xl} 1.6.1 Core-Level Photoemission
Kp+Lk 1.6.2 Valence-State Photoemission
m]yt6b4 1.6.3 Three-Step and One-Step Considerations
JCu3,O!q 1.7 Deviations from the Simple Theory of Photoemission
I<q=lK References
x<'(b7{U0 *TpzX
y 2. Core Levels and Final States
R6ynL([xh 2.1 Core-Level Binding Energies in Atoms and Molecules
V[R33NYG 2.1.1 The Equivalent-Core Approximation
N`tBDl"ld 2.1.2 Chemical Shifts
F)we^'X 2.2 Core-Level Binding Energies in Solids
6B)3SC 2.2.1 The Born-Haber Cycle in Insulators
cSYW)c|t 2.2.2 Theory of Binding Energies
,"PKGd]^ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
(~~*PT- 2.3 Core Polarization
=_%i5]89P 2.4 Final-State Multiplets in Rare-Earth Valence Bands
"p43# 2.5 Vibrational Side Bands
K|-?1)Um 2.6 Core Levels of Adsorbed Molecules
9]AiaV9 2.7 Quantitative Chemical Analysis from Core-Level Intensities
a1;P2ikuK References
?=:wIMV
>^#OtFHuT) 3. Charge-Excitation Final States: Satellites
ceakTAB[ 3.1 Copper Dihalides; 3d Transition Metal Compounds
-9XB.)\# 3.1.1 Characterization of a Satellite
CKShz]1 3.1.2 Analysis of Charge-Transfer Satellites
as1ZLfN. 3.1.3 Non-local Screening
z
z@;UbD" 3.2 The 6-eV Satellite in Nickel
C3n_'O 3.2.1 Resonance Photoemission
$2uZdl8Rvj 3.2.2 Satellites in Other Metals
}QszOi\fV1 3.3 The Gunnarsson-Sch6nhammer Theory
K-&&%Id6R 3.4 Photoemission Signals and Narrow Bands in Metals
HH>"J/;c, References
~Qzb<^9] ;2||g8' 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
,EyZ2`| 4.1 Theory
HS{a^c% 4.1.1 General
bkQEfx. 4.1.2 Core-Line Shape
b[Z5:[@\# 4.1.3 Intrinsic Plasmons
=H T:p:S 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
D-8NDa(` 4.1.5 The Total Photoelectron Spectrum
C9-IJj
4.2 Experimental Results
E5d?toZ,8" 4.2.1 The Core Line Without Plasmons
G.2ij%Zz 4.2.2 Core-Level Spectra Including Plasmoas
W+3ZuAP\n 4.2.3 Valence-Band Spectra of the Simple Metals
9Foo8e 4.2.4 Simple Metals: A General Comment
G3{t{XkV 4.3 The Background Correction
SST1vzm! References
T:ye2yg W=v4dy]B 5. Valence Orbitals in Simple Molecules and Insulating Solids
8+no>%L 5.1 UPS Spectra of Monatomic Gases
<szD"p|K 5.2 Photoelectron Spectra of Diatomic Molecules
V`OeJVe 5.3 Binding Energy of the H2 Molecule
P q\m8iS,w 5.4 Hydrides Isoelectronic with Noble Gases
c[:OK9TH Neon (Ne)
(?SK< 4! Hydrogen Fluoride (HF)
x0^O?UR Water (H2O)
h+e Oe} Ammonia (NH3)
gxEa?QH Methane (CH4)
tGGv 2TCEy 5.5 Spectra of the Alkali HMides
aRBTuLa)fo 5.6 Transition Metal Dihalides
2|vArRKt 5.7 Hydrocarbons
[h
"*>J{ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
ViV"+b#gu 5.7.2 Linear Polymers
PI>PEge!& 5.8 Insulating Solids with Valence d Electrons
Ue:'55 5.8.1 The NiO Problem
+NGjDa 5.8.2 Mort Insulation
Nz`4q%+ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
d,}fp) 5.8.4Band Structures of Transition Metal Compounds
Z%3] 5.9 High—Temperature Superconductors
Sa!r ,l 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
^,L vQW4 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
csg:#-gE 5.9.3 The Superconducting Gap
G}aw{Vbg_ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
*vn^
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LG6VeYe|\X 5.10 The Fermi Liquid and the Luttinger Liquid
NET?Ep 5.11 Adsorbed Molecules
~b+TkPU 5.11.1 Outline
8X=cGYC# 5.11.2 CO on Metal Surfaces
,}15Cse References
5'f4=J$Z)
laX(?{_ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
;D^%)v/i 6.1 Theory of Photoemission:A Summary of the Three-Step Model
V eO$n*O 6.2 Discussion of the Photocurrent
]M
AB 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
_@CY_`a 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
Fy|tKMhnc 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
\|2 0E51B[ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
SVsLu2tVY 6.3.1 Band Structure Regime
Fj\}&H*+ 6.3.2 XPS Regime
Ju3-ZFUS4 6.3.3 Surface Emission
7.fpGzUM 6.3.4 One-Step Calculations
74YMFI 6.4 Thermal Effects
1{N73]-M: 6.5 Dipole Selection Rules for Direct Optical Transitions
h&eu}aF References
Bw-<xwD \F]X!#&+ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
pKDP1S#< 7.1 Free-Electron Final—State Model
_E eH 7.2 Methods Employing Calculated Band Structures
'>[l1<d!G 7.3 Methods for the Absolute Determination of the Crystal Momentum
[:gPp)f, 7.3.1 Triangulation or Energy Coincidence Method
2XhtK 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
yidUtSv=, 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
:5!>h8p; 7.3.4 The Surface Emission Method and Electron Damping
J2cqnwUV 7.3.5 The Very-Low-Energy Electron Diffraction Method
K*;e>{p 7.3.6 The Fermi Surface Method
)i8Hdtn 7.3.7 Intensities and Their Use in Band-Structure Determinations
;xFx%^M}br 7.3.8 Summary
IXb]\ ) 7.4 Experimental Band Structures
TWF6YAQm 7.4.1 One- and Two-Dimensional Systems
QC7Ceeh]4 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
R;,&s!\< 7..4.3UPS Band Structures and XPS Density of States
juQ&v>9W) 7.5 A Comment
( ONn{12Q References
.`Ey'T_ Oo'IeXQ9( 8.Surface States, Surface Effects
UhuEE 8.1 Theoretical Considerations
YXE?b@W" 8.2 Experimental Results on Surface States
j^ L"l;m 8.3 Quantum-Well States
#m_3ls}W$ 8.4 Surface Core-Level Shifts
_@I8B References
>ZMB}pt` +`pS 7d 9.Inverse Photoelectron Spectroscopy
WP)r5;Hv` 9.1 Surface States
5W/!o&x~7 9.2 Bulk Band Structures
noY~fq/U 9.3 Adsorbed Molecules
Pw`26mB References
ZH8O%>! e?W-vi% 10. Spin-Polarized Photoelectron Spectroscopy
+a$'<GvP 10.1 General Description
5\RTy}w3x 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
$hexJzX 10.3 Magnetic Dichroism
kO:|?}Koc References
mQ 1) d5 r*#ApM"L 11. Photoelectron Diffraction
(XtN3FTY 11.1 Examples
-2NXQ+m ; 11.2 Substrate Photoelectron Diffraction
SMHQo/c r 11.3 Adsorbate Photoelectron Diffraction
e~#;ux 11.4 Fermi Surface Scans
\)Sa!XLfT References
6&8 ([J l ;"v&? Appendix
[?rK9I& A.1 Table of Binding Energies
ML6Y_|6
| A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
kTQ.7mo/\' A.3 Compilation of Work Functions
}Ruj h4* References
j`JY3RDD Index