光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
~+<xFi `xX4!^0Hm 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
r'd:SaU+ Vo9>o@FlLM 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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(g\ B 9LSxB 目录
mX@j 1. Introduction and Basic Principles
3V/_I<y 1.1 Historical Development
nOoKGT 1.2 The Electron Mean Free Path
}$|%/Y 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
..jq[(;N 1.4 Experimental Aspects
#u8*CA9 1.5 Very High Resolution
,Um 5S6 Z 1.6 The Theory of Photoemission
>HcYVp~G 1.6.1 Core-Level Photoemission
8>Du 1.6.2 Valence-State Photoemission
Bw3F7W~l 1.6.3 Three-Step and One-Step Considerations
NWJcFj_ 1.7 Deviations from the Simple Theory of Photoemission
JlC<MQ? References
'!wPnYT@D %Lp2jyv. 2. Core Levels and Final States
DYo<5^0 2.1 Core-Level Binding Energies in Atoms and Molecules
PyC;f8n'(
2.1.1 The Equivalent-Core Approximation
W>Mse[6`c 2.1.2 Chemical Shifts
wTTTrk 2.2 Core-Level Binding Energies in Solids
F2bm+0vOJ 2.2.1 The Born-Haber Cycle in Insulators
+R
"AA_A? 2.2.2 Theory of Binding Energies
r7Nu>[r5 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
"JzfL(yt 2.3 Core Polarization
7szls71/= 2.4 Final-State Multiplets in Rare-Earth Valence Bands
>oft :7p 2.5 Vibrational Side Bands
[as-3&5S 2.6 Core Levels of Adsorbed Molecules
d[Rb:Yw 2.7 Quantitative Chemical Analysis from Core-Level Intensities
20rN,@2< References
<G\
<QV8W +"YTCzv;t 3. Charge-Excitation Final States: Satellites
fDU+3b 3.1 Copper Dihalides; 3d Transition Metal Compounds
hz<|W5 3.1.1 Characterization of a Satellite
*nYB o\@g 3.1.2 Analysis of Charge-Transfer Satellites
<ZigCo w 3.1.3 Non-local Screening
AA))KBXq 3.2 The 6-eV Satellite in Nickel
kF+ZW%6N 3.2.1 Resonance Photoemission
2;~KL-h0TK 3.2.2 Satellites in Other Metals
$Q8P@L)[ 3.3 The Gunnarsson-Sch6nhammer Theory
'"`
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i^je.,Bi References
[urH a #mgA/q?A 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
;c>>$lr 4.1 Theory
>65
TkAp 4.1.1 General
Sdgb#?MR| 4.1.2 Core-Line Shape
HG3.~ 6X 4.1.3 Intrinsic Plasmons
3%XG@OgP 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
UG6M9 4.1.5 The Total Photoelectron Spectrum
TT|-aS0l(u 4.2 Experimental Results
w`M]0'zls 4.2.1 The Core Line Without Plasmons
>W8bWQ^fK 4.2.2 Core-Level Spectra Including Plasmoas
)*!1bgXQ 4.2.3 Valence-Band Spectra of the Simple Metals
*I=_*LoG2 4.2.4 Simple Metals: A General Comment
4$%`Qh>yA 4.3 The Background Correction
ewo*7j4* References
"YuZ fL`bb De;, =BSp 5. Valence Orbitals in Simple Molecules and Insulating Solids
"\`>2 5.1 UPS Spectra of Monatomic Gases
LL{t5(- _ 5.2 Photoelectron Spectra of Diatomic Molecules
w3<Z?lj: 5.3 Binding Energy of the H2 Molecule
h=hoV5d@ 5.4 Hydrides Isoelectronic with Noble Gases
6yN"
l
Q7 Neon (Ne)
-<O JqB Hydrogen Fluoride (HF)
'yE*|Sx
Water (H2O)
/M 0 p_4 Ammonia (NH3)
F
b1EMVu Methane (CH4)
,MRvuw0P 5.5 Spectra of the Alkali HMides
@|^jq 5.6 Transition Metal Dihalides
]yo_wGiwY 5.7 Hydrocarbons
(%i!%{!] 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
B9wp*:. 5.7.2 Linear Polymers
fzl=d_ 5.8 Insulating Solids with Valence d Electrons
K~USK?Q% 5.8.1 The NiO Problem
_=uviMuE 5.8.2 Mort Insulation
Y]~IY?I 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
%Hh3u$Y, 5.8.4Band Structures of Transition Metal Compounds
6mwvI4) 5.9 High—Temperature Superconductors
L5/mO6;k 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
BjYOfu'~z 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
\kxh#{$z? 5.9.3 The Superconducting Gap
"rVU4F) 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
fc3 Fi'^ 5.9.5 Core—Level Shifts
{h,_"g\V 5.10 The Fermi Liquid and the Luttinger Liquid
gTnS[ 5.11 Adsorbed Molecules
Im6U_JsNZh 5.11.1 Outline
GN0duV 5.11.2 CO on Metal Surfaces
FK6K6wU52m References
sqT^t! ?<E0zM+ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
1f<RyAE?5 6.1 Theory of Photoemission:A Summary of the Three-Step Model
A&NqQ
V, 6.2 Discussion of the Photocurrent
'v\j.j/i 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
L/)B}8m\ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
;:U<ce= 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
"tKNlHBu' 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
{b2 aL7 6.3.1 Band Structure Regime
/0
_zXQyV 6.3.2 XPS Regime
o,J^ e_ 6.3.3 Surface Emission
yu=piP 6.3.4 One-Step Calculations
q4)Ey 6.4 Thermal Effects
G,B?&gFX 6.5 Dipole Selection Rules for Direct Optical Transitions
|f<9miNu References
<z',]hy b )Tl* 7.Band Structtire and Angular-Resolved Photoelectron Spectra
kAeNQRjR 7.1 Free-Electron Final—State Model
"(<%Ua 7.2 Methods Employing Calculated Band Structures
a/b92*&k 7.3 Methods for the Absolute Determination of the Crystal Momentum
]9s\_A9 7.3.1 Triangulation or Energy Coincidence Method
u7[pLtOwN 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
IYLZ
+> 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
}Fm\+JOS
7.3.4 The Surface Emission Method and Electron Damping
zXjwnep 7.3.5 The Very-Low-Energy Electron Diffraction Method
7u|%^Ao6 7.3.6 The Fermi Surface Method
"ct58Y@ 7.3.7 Intensities and Their Use in Band-Structure Determinations
-n-Z/5~ X 7.3.8 Summary
?T
<rt 7.4 Experimental Band Structures
hox< vr4 7.4.1 One- and Two-Dimensional Systems
1 )'Iu`k/ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
l77'Lne 7..4.3UPS Band Structures and XPS Density of States
IhfZLE., 7.5 A Comment
fQO
""qh References
]hL:33 .+HcA x{/2 8.Surface States, Surface Effects
**n y! 8.1 Theoretical Considerations
1U'ZVJ5bpK 8.2 Experimental Results on Surface States
UG # X/%p 8.3 Quantum-Well States
j$mz3Yk 8.4 Surface Core-Level Shifts
<n\i>A3`,S References
m d_g}N(C >O3IfS(l 9.Inverse Photoelectron Spectroscopy
+X[8wUm|^ 9.1 Surface States
WI{ ;#A 9.2 Bulk Band Structures
Ok,HD7 9.3 Adsorbed Molecules
s*.3ZS5 References
I3PQdAs~&h 9>;} /*:H 10. Spin-Polarized Photoelectron Spectroscopy
9*DEv0}a^ 10.1 General Description
G1/Gq.< 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
,WGc7NN` 10.3 Magnetic Dichroism
[83>T , References
f7
wmw2 9$wAm89 11. Photoelectron Diffraction
%i595Ij-] 11.1 Examples
?9Ma^C;} 11.2 Substrate Photoelectron Diffraction
)'t&q/Wn 11.3 Adsorbate Photoelectron Diffraction
},s_nJR:8 11.4 Fermi Surface Scans
8O9Gs References
=W<[Fe3 <%&_#<C) Appendix
) $J7sa A.1 Table of Binding Energies
8jNOEM(0Y+ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
]VDn'@uM A.3 Compilation of Work Functions
C/)`<b( References
x9D/s`! Index