光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
h@D!/PS '/<f'R^ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
I?Q[ZH:M 4inMd![ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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.=/TT|eMS Ab:+AC5{ 目录
&u9@FFBT8 1. Introduction and Basic Principles
Bx ru7E" 1.1 Historical Development
sf'+; 1.2 The Electron Mean Free Path
JnXVI!+JDL 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
&K-0ld(; 1.4 Experimental Aspects
t@3y9U$ 1.5 Very High Resolution
>
ZKHjw 1.6 The Theory of Photoemission
}\hz@G< 1.6.1 Core-Level Photoemission
u=PYm+q{ 1.6.2 Valence-State Photoemission
A%%Vyz 1.6.3 Three-Step and One-Step Considerations
&Q[|FO;[ 1.7 Deviations from the Simple Theory of Photoemission
a>BPK"K2 References
*dX
7 G
q2@37U 2. Core Levels and Final States
7uxUqM 2.1 Core-Level Binding Energies in Atoms and Molecules
\CZD.2p#& 2.1.1 The Equivalent-Core Approximation
50NLguE 2.1.2 Chemical Shifts
d\j[O9W> 2.2 Core-Level Binding Energies in Solids
1'BC
R 2.2.1 The Born-Haber Cycle in Insulators
)LjW=;(b 2.2.2 Theory of Binding Energies
mD go@f 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
:a'[4w 2.3 Core Polarization
%%hG],w 2.4 Final-State Multiplets in Rare-Earth Valence Bands
a0
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i6$q1* 2.6 Core Levels of Adsorbed Molecules
W&;,7T8@ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
G^qt@,n$; References
Ql{:H5 rtZEK:.# 3. Charge-Excitation Final States: Satellites
t-VU&.Y 3.1 Copper Dihalides; 3d Transition Metal Compounds
xw~3x*{ 3.1.1 Characterization of a Satellite
L_Lhmtm}m 3.1.2 Analysis of Charge-Transfer Satellites
I9O%/^5^[w 3.1.3 Non-local Screening
-~WDv[[ 3.2 The 6-eV Satellite in Nickel
(Kb_/ 3.2.1 Resonance Photoemission
p{oc}dWin 3.2.2 Satellites in Other Metals
wlw`%z-B2 3.3 The Gunnarsson-Sch6nhammer Theory
b+e9Pi*\ 3.4 Photoemission Signals and Narrow Bands in Metals
i{4J$KT References
t lpTq\; ?[c{pb,| 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
,<!v!~Iy 4.1 Theory
`xF^9;5mi 4.1.1 General
*`~]XM@H 4.1.2 Core-Line Shape
eizni\ 4.1.3 Intrinsic Plasmons
s|9[=JMG 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
NM0s*s42 4.1.5 The Total Photoelectron Spectrum
ANq3r( 4.2 Experimental Results
IT:8k5(L5j 4.2.1 The Core Line Without Plasmons
kKz>]t"A 4.2.2 Core-Level Spectra Including Plasmoas
r74'
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*dPG[ } 4.2.4 Simple Metals: A General Comment
o3(:R0 4.3 The Background Correction
OI^sd_gkZ References
qw6i|JM% x|GkXD3 5. Valence Orbitals in Simple Molecules and Insulating Solids
>Q[3t79^ 5.1 UPS Spectra of Monatomic Gases
.njk^,N 5.2 Photoelectron Spectra of Diatomic Molecules
YWF Hv@ 5.3 Binding Energy of the H2 Molecule
\t?rHB3" 5.4 Hydrides Isoelectronic with Noble Gases
v?(z4oOD/> Neon (Ne)
yz^4TqJ Hydrogen Fluoride (HF)
tx ,q=.( Water (H2O)
XWag+K Ammonia (NH3)
V2>+s
y Methane (CH4)
%Z+FX,AK 5.5 Spectra of the Alkali HMides
DLD 5> 5.6 Transition Metal Dihalides
N<^)tR8+ 5.7 Hydrocarbons
&.[I}KH|B 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
=2e{T J/ 5.7.2 Linear Polymers
<ZjT4>< 5.8 Insulating Solids with Valence d Electrons
vE&K!k` 5.8.1 The NiO Problem
@Io@1[k j 5.8.2 Mort Insulation
+,T z +! 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
N^f_hL|:9 5.8.4Band Structures of Transition Metal Compounds
S9%ZeM+ 5.9 High—Temperature Superconductors
P71] Z 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
W:JR\KKU 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
lx:.9> 5.9.3 The Superconducting Gap
_0"s6D$ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
sQBKzvFO3 5.9.5 Core—Level Shifts
/p$+oA+ 5.10 The Fermi Liquid and the Luttinger Liquid
@K\hgaQ 5.11 Adsorbed Molecules
"P
yG;N!W 5.11.1 Outline
G.]'pn 5.11.2 CO on Metal Surfaces
C2H2*" References
jbWgL$ ~-
eB 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
>f70-D28 6.1 Theory of Photoemission:A Summary of the Three-Step Model
5QP`2I_n 6.2 Discussion of the Photocurrent
mwO9`AU; 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
pU1miA ' 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
{$Z
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27 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
/Xl(>^|& 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
u4h.\ul8% 6.3.1 Band Structure Regime
Jk;dtLL}4 6.3.2 XPS Regime
W/<Lp+p 6.3.3 Surface Emission
{LBL8sG 6.3.4 One-Step Calculations
g[N3jt@ 6.4 Thermal Effects
uc aa;zj 6.5 Dipole Selection Rules for Direct Optical Transitions
$bl<mG%#9 References
E8L\3V4 {9vMc 7.Band Structtire and Angular-Resolved Photoelectron Spectra
OmlM9cXm^4 7.1 Free-Electron Final—State Model
s*R UYx 7.2 Methods Employing Calculated Band Structures
VUC_|=?dL 7.3 Methods for the Absolute Determination of the Crystal Momentum
QL:Qzr[ 7.3.1 Triangulation or Energy Coincidence Method
Ffig0K+` 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
ndu$N$7+ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
|k#EYf#Y 7.3.4 The Surface Emission Method and Electron Damping
B]I*ymc# 7.3.5 The Very-Low-Energy Electron Diffraction Method
SB,#y>Zv? 7.3.6 The Fermi Surface Method
M[P1hFuna 7.3.7 Intensities and Their Use in Band-Structure Determinations
2=,d.1E3d 7.3.8 Summary
|E&|6h1 7.4 Experimental Band Structures
a fLE9 7.4.1 One- and Two-Dimensional Systems
L@.Trso 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
baGV]=j 7..4.3UPS Band Structures and XPS Density of States
a]!u
go} 7.5 A Comment
iUq_vQ@}} References
=R*IOJ wb ^>/ 8.Surface States, Surface Effects
ZEs^b 8.1 Theoretical Considerations
+mN8uU~(kx 8.2 Experimental Results on Surface States
9<.8mW^68 8.3 Quantum-Well States
~( :$c3\ 8.4 Surface Core-Level Shifts
b^A7R{G7 References
n.Y45(@E <?%49 9.Inverse Photoelectron Spectroscopy
~:*V'/2k
9.1 Surface States
OZ/"W)
9.2 Bulk Band Structures
'p)DJUwt 9.3 Adsorbed Molecules
{LT2^gy= References
2 ,krVb?< XB a^
A 10. Spin-Polarized Photoelectron Spectroscopy
}\1V%c 10.1 General Description
nfh<3v|kvR 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
\d3 ~kq3 10.3 Magnetic Dichroism
qB+OxyT& References
"n{JH9sA: ~MP/[,j` 11. Photoelectron Diffraction
W6):IW(E 11.1 Examples
89t"2|9 u 11.2 Substrate Photoelectron Diffraction
&~'i,v|E 11.3 Adsorbate Photoelectron Diffraction
b>]UNf"- 11.4 Fermi Surface Scans
u Yc}eMb References
ZCA= n &{q< Appendix
EyHL& A.1 Table of Binding Energies
*+(eH#_2/ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
qDgy7kkQ A.3 Compilation of Work Functions
qcge#S> References
^S 45!mSb Index