光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
B!0[LlF+ QB3AL;7 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
dhbJ1/z^ y5I7pbe 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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tH(Z9\L 7
U,N4+F}FR (,>`\\ 目录
`S|gfJ 1. Introduction and Basic Principles
f
36rU 1.1 Historical Development
P+xZaf
H 1.2 The Electron Mean Free Path
TocqoYX{{ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
Vufw:}i+^ 1.4 Experimental Aspects
!?96P|G 1.5 Very High Resolution
8eNGPuoL) 1.6 The Theory of Photoemission
Kmtr.]Nj 1.6.1 Core-Level Photoemission
ETtR*5Y 5 1.6.2 Valence-State Photoemission
XB?!V|bno 1.6.3 Three-Step and One-Step Considerations
o?>)CAo 1.7 Deviations from the Simple Theory of Photoemission
Y+E@afsKs References
*T3"U|0_ y lWR 2. Core Levels and Final States
;8!D8o(+ 2.1 Core-Level Binding Energies in Atoms and Molecules
< mxUgU 2.1.1 The Equivalent-Core Approximation
_Uq'eZol 2.1.2 Chemical Shifts
=~)n,5 2.2 Core-Level Binding Energies in Solids
_+U`afV 2.2.1 The Born-Haber Cycle in Insulators
-M4#dHR_! 2.2.2 Theory of Binding Energies
${?Px
c{- 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
xucV$[f 2.3 Core Polarization
uQDu<@5^[ 2.4 Final-State Multiplets in Rare-Earth Valence Bands
aPbHrk*/ 2.5 Vibrational Side Bands
C9fJLCufC 2.6 Core Levels of Adsorbed Molecules
x?k6ek 2.7 Quantitative Chemical Analysis from Core-Level Intensities
)S]c'}^ References
uzS57 O% 9wYbY* j 3. Charge-Excitation Final States: Satellites
>[#4Pb7_Y 3.1 Copper Dihalides; 3d Transition Metal Compounds
Q{%ow:;s* 3.1.1 Characterization of a Satellite
t6tqv 3.1.2 Analysis of Charge-Transfer Satellites
]2<g"zo0 3.1.3 Non-local Screening
,{%[/#~6 3.2 The 6-eV Satellite in Nickel
?lTQjw{ 3.2.1 Resonance Photoemission
hX^XtIC= 3.2.2 Satellites in Other Metals
Ruf*aF( 3.3 The Gunnarsson-Sch6nhammer Theory
EV}%D9: 3.4 Photoemission Signals and Narrow Bands in Metals
{uw]s<
6 References
)TLDNpH?J ALG + 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
V/03m3!q 4.1 Theory
dCinbAQ 4.1.1 General
_|F h^hq 4.1.2 Core-Line Shape
=Vi+wH{xM 4.1.3 Intrinsic Plasmons
4)`{ L$ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
Q5Wb) 4.1.5 The Total Photoelectron Spectrum
hfY2pG9N 4.2 Experimental Results
;;2s{{(R 4.2.1 The Core Line Without Plasmons
AojX)_"z 4.2.2 Core-Level Spectra Including Plasmoas
p4/D%*G^` 4.2.3 Valence-Band Spectra of the Simple Metals
/rquI y^ 4.2.4 Simple Metals: A General Comment
J[^-k!9M 4.3 The Background Correction
CkOd>Kn References
\X(.%5xC m$U2|5un& 5. Valence Orbitals in Simple Molecules and Insulating Solids
p}h)WjC 5.1 UPS Spectra of Monatomic Gases
RSp=If+4 5.2 Photoelectron Spectra of Diatomic Molecules
GhX>YzD7 5.3 Binding Energy of the H2 Molecule
*@D.=i> 5.4 Hydrides Isoelectronic with Noble Gases
5-MI7I@l Neon (Ne)
G-Y8<mEh Hydrogen Fluoride (HF)
FvRog<3X Water (H2O)
1vX97n<} Ammonia (NH3)
lK{h%2A\b Methane (CH4)
NL1Ajms` 5.5 Spectra of the Alkali HMides
d!>PqPo 5.6 Transition Metal Dihalides
1>n@`M8} 5.7 Hydrocarbons
7r:!HmRl 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
w'}b 8m(L 5.7.2 Linear Polymers
`CRW2^g 5.8 Insulating Solids with Valence d Electrons
SlmgFk!r! 5.8.1 The NiO Problem
1;>J9 5.8.2 Mort Insulation
i7iL[+f]Q 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
O
Qd,.m 5.8.4Band Structures of Transition Metal Compounds
Z/O5Dear/h 5.9 High—Temperature Superconductors
Z[ys>\_To 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
X'O3)Yg 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
Lb(=:Z!{ 5.9.3 The Superconducting Gap
@<h@d_8^k 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
,XR1N$LN8_ 5.9.5 Core—Level Shifts
wPyfne?~, 5.10 The Fermi Liquid and the Luttinger Liquid
c!b4Y4eJ 5.11 Adsorbed Molecules
iOw'NxmY 5.11.1 Outline
:Oxrw5`= 5.11.2 CO on Metal Surfaces
4v Ug:'DM References
?8pR RzV$ J#MUtpPdQ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
y%f'7YZ4 6.1 Theory of Photoemission:A Summary of the Three-Step Model
u`g|u:(r 6.2 Discussion of the Photocurrent
(r.[b 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
2Lm.;l4YO 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
Y'0H2B8 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
Ju#
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T-0fVTeN 6.3.1 Band Structure Regime
%qNT<>c 6.3.2 XPS Regime
z]K:Amp;Z 6.3.3 Surface Emission
'V/+v#V+> 6.3.4 One-Step Calculations
)ui]vS:> 6.4 Thermal Effects
`-IX"rf 6.5 Dipole Selection Rules for Direct Optical Transitions
(*F/^4p!$ References
mSr(PIH{\ l%L..WCT] 7.Band Structtire and Angular-Resolved Photoelectron Spectra
}Dp/K4 7.1 Free-Electron Final—State Model
CKCot 7.2 Methods Employing Calculated Band Structures
yCpU173V 7.3 Methods for the Absolute Determination of the Crystal Momentum
s9X?tWuL 7.3.1 Triangulation or Energy Coincidence Method
3,t3\`= 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
0F/o 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
O!#r2Y"?K1 7.3.4 The Surface Emission Method and Electron Damping
C8ek{o)%W 7.3.5 The Very-Low-Energy Electron Diffraction Method
JYc;6p$<i 7.3.6 The Fermi Surface Method
m5`<XwD9 7.3.7 Intensities and Their Use in Band-Structure Determinations
]2Zl\}GwY 7.3.8 Summary
?NWc3 . 7.4 Experimental Band Structures
Jpm=V*P 7.4.1 One- and Two-Dimensional Systems
NSI$uS6 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
l$
^LY)i 7..4.3UPS Band Structures and XPS Density of States
>cJf D9-<h 7.5 A Comment
6fY-DqF! References
0o7*5| T4 c&X2k\ 8.Surface States, Surface Effects
ozB2L\D7 8.1 Theoretical Considerations
8#L
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Lh\ 1L 8.3 Quantum-Well States
lub_2Cb|j 8.4 Surface Core-Level Shifts
m) QV2n References
KDxqz$14- %W`
} 9.Inverse Photoelectron Spectroscopy
n`
M!K:Pq 9.1 Surface States
$raq,SP 9.2 Bulk Band Structures
~xCv_u^= 9.3 Adsorbed Molecules
<x-7MU& References
4 ))Z Bq? eI%9.Cx#I 10. Spin-Polarized Photoelectron Spectroscopy
?sD4S 10.1 General Description
2fN2!OT 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
#|8Ia:=s 10.3 Magnetic Dichroism
LT[g
+zGB References
l]R=I2t [] cF*en 11. Photoelectron Diffraction
Nux 11.1 Examples
wAD%1; 11.2 Substrate Photoelectron Diffraction
6pP:Q_U$ 11.3 Adsorbate Photoelectron Diffraction
q]Vxf!0*> 11.4 Fermi Surface Scans
#;D@`.#\ References
18nT
Iz_ /:B2-4>Q! Appendix
R`KlG/Tk A.1 Table of Binding Energies
N1iP!m9Q A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
cY]BtJ# A.3 Compilation of Work Functions
D,\hRQ References
WF] |-)vw Index