光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
l kW5<s_ 8osP$"/o 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
[nf5< ]Q#k"Je 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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c8Nl$|B Vqr]Ui 目录
(>uA(#Z 1. Introduction and Basic Principles
=fJ /6 1.1 Historical Development
LIll@2[ 1.2 The Electron Mean Free Path
nrR2U` 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
.hJcK/m 1.4 Experimental Aspects
Sx1|Oq] 1.5 Very High Resolution
vX_;Y#uD 1.6 The Theory of Photoemission
)J?8"+_Y 1.6.1 Core-Level Photoemission
b&6lu4D 1.6.2 Valence-State Photoemission
\,#;gS" 1.6.3 Three-Step and One-Step Considerations
5Z:T9F4 1.7 Deviations from the Simple Theory of Photoemission
{Wndp% References
h.wffk, 4dy!2KZN 2. Core Levels and Final States
}0sLeGJ! 2.1 Core-Level Binding Energies in Atoms and Molecules
%rV|{@J ` 2.1.1 The Equivalent-Core Approximation
jX0^1d@ 2.1.2 Chemical Shifts
{<1uV']x 2.2 Core-Level Binding Energies in Solids
kgI8PybY 2.2.1 The Born-Haber Cycle in Insulators
ilyF1=bp 2.2.2 Theory of Binding Energies
"gFw:t"VV 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
H^dw=kS 2.3 Core Polarization
"MK2QIo 2.4 Final-State Multiplets in Rare-Earth Valence Bands
0+&K; 2.5 Vibrational Side Bands
hAsReZ? 2.6 Core Levels of Adsorbed Molecules
6&QOC9JW+7 2.7 Quantitative Chemical Analysis from Core-Level Intensities
oF a,IA References
$@l=FV_; * U}-Y* 3. Charge-Excitation Final States: Satellites
+d?|R5{3 3.1 Copper Dihalides; 3d Transition Metal Compounds
i6$HwRZm# 3.1.1 Characterization of a Satellite
R"l6|9tmP 3.1.2 Analysis of Charge-Transfer Satellites
ysPm4am$ 3.1.3 Non-local Screening
:iGK9I 3.2 The 6-eV Satellite in Nickel
JLz32 %-M 3.2.1 Resonance Photoemission
`,]_r4~ ~ 3.2.2 Satellites in Other Metals
$:# :"
3.3 The Gunnarsson-Sch6nhammer Theory
o5sw]R5 3.4 Photoemission Signals and Narrow Bands in Metals
F'F6 &a+ References
X&h?1lMJ / IuA4eDr^Y% 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
c`&g.s@N\ 4.1 Theory
oRJ!TAbD 4.1.1 General
8B]\;m 4.1.2 Core-Line Shape
cK2;)&U7 4.1.3 Intrinsic Plasmons
MppT"t 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
9HPmJ`b 4.1.5 The Total Photoelectron Spectrum
U&{w:P 4.2 Experimental Results
V#|/\-@ 4.2.1 The Core Line Without Plasmons
KeB??1S 4.2.2 Core-Level Spectra Including Plasmoas
US=K}B=g 4.2.3 Valence-Band Spectra of the Simple Metals
~kj96w4eAR 4.2.4 Simple Metals: A General Comment
zb4{nzX= 4.3 The Background Correction
Qa\,)<'D: References
b|@zjh;]A7 J#FHR/zV 5. Valence Orbitals in Simple Molecules and Insulating Solids
^TjC 5.1 UPS Spectra of Monatomic Gases
<RpTk*Yo^= 5.2 Photoelectron Spectra of Diatomic Molecules
U$y wO4. 5.3 Binding Energy of the H2 Molecule
xf8[&? 5.4 Hydrides Isoelectronic with Noble Gases
n~BQq-1 Neon (Ne)
\jV2":[%c Hydrogen Fluoride (HF)
Q[aF"5h% Water (H2O)
0I :5}$+J? Ammonia (NH3)
LFqY2,#i Methane (CH4)
vM]5IHqeE 5.5 Spectra of the Alkali HMides
V6_5v+n 5.6 Transition Metal Dihalides
#H<}xC2 5.7 Hydrocarbons
:8`$BbV 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
+'iqGg- 5.7.2 Linear Polymers
6d6Dk>(V 5.8 Insulating Solids with Valence d Electrons
%Tu(>vnuj 5.8.1 The NiO Problem
[u=yl0f 5.8.2 Mort Insulation
r..f$FF)\ 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
bA2[=6 5.8.4Band Structures of Transition Metal Compounds
S.`hl/ 5.9 High—Temperature Superconductors
S 1^t;{" 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
0_-o]BY 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
)F\kGe 5.9.3 The Superconducting Gap
,UC|[-J 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
,quUGS 5.9.5 Core—Level Shifts
nT2b"wkTT 5.10 The Fermi Liquid and the Luttinger Liquid
a5O$he 5.11 Adsorbed Molecules
AZ^>osr 5.11.1 Outline
trjeGSt& 5.11.2 CO on Metal Surfaces
ahZ@4v References
T][c^K* 4 #KC\C 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
WBJn1 6.1 Theory of Photoemission:A Summary of the Three-Step Model
xluAjOQ6 6.2 Discussion of the Photocurrent
Wd(|w8J{a 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
$!!y v'K 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
1:M'|uc 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
g`C"t3~%S 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
zVe,HKF/ 6.3.1 Band Structure Regime
{M=B5- 6.3.2 XPS Regime
7@y}J5, 6.3.3 Surface Emission
F3$8l[O_ 6.3.4 One-Step Calculations
6Fk[wH7 6.4 Thermal Effects
Au/'|%2#( 6.5 Dipole Selection Rules for Direct Optical Transitions
S;iD~> KP References
TV_a(#S /:BC<]s 7.Band Structtire and Angular-Resolved Photoelectron Spectra
-Gl!W`$I` 7.1 Free-Electron Final—State Model
;Z;` BGZJ 7.2 Methods Employing Calculated Band Structures
4\ )WMP 7.3 Methods for the Absolute Determination of the Crystal Momentum
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