光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
72@raA#y I{AteL 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
nk9Kq\2f: 1tU}}l 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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7$x~}*u q}*"0r 目录
Fy5xIRyI\F 1. Introduction and Basic Principles
(-DA% 1.1 Historical Development
t=J\zyX! 1.2 The Electron Mean Free Path
l;zp f|.Vc 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
'$*d:1 1.4 Experimental Aspects
/\*,|y\< 1.5 Very High Resolution
iX qB-4" 1.6 The Theory of Photoemission
J
Sz'oA5 1.6.1 Core-Level Photoemission
f~-81ctu 1.6.2 Valence-State Photoemission
tJo,^fdfv 1.6.3 Three-Step and One-Step Considerations
Rq~\Yf+Pm 1.7 Deviations from the Simple Theory of Photoemission
}C.M4{a\ References
w~@.& 2j8^Z 2. Core Levels and Final States
)nU%}Z 2.1 Core-Level Binding Energies in Atoms and Molecules
% Uybp 2.1.1 The Equivalent-Core Approximation
@gc lks/M 2.1.2 Chemical Shifts
_S5\5[^ 2.2 Core-Level Binding Energies in Solids
a(&!{Y1bt 2.2.1 The Born-Haber Cycle in Insulators
1$oVcDLl 2.2.2 Theory of Binding Energies
w-\U;&8 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
5f2ah4 g 2.3 Core Polarization
]C^D5(t/cd 2.4 Final-State Multiplets in Rare-Earth Valence Bands
[?VYxX@ 2.5 Vibrational Side Bands
'{WYho! 2.6 Core Levels of Adsorbed Molecules
Vc|r(lM 2.7 Quantitative Chemical Analysis from Core-Level Intensities
J;4x-R$W References
"|w..%Wc B8-v!4b0` 3. Charge-Excitation Final States: Satellites
zvB!= 3.1 Copper Dihalides; 3d Transition Metal Compounds
J8I_tF6 3.1.1 Characterization of a Satellite
zq-"jpZG 3.1.2 Analysis of Charge-Transfer Satellites
R[ p. )F7 3.1.3 Non-local Screening
0 ;kcSz 3.2 The 6-eV Satellite in Nickel
;mH1J'.(a 3.2.1 Resonance Photoemission
G4->7n N 3.2.2 Satellites in Other Metals
K}ACZT)Wp 3.3 The Gunnarsson-Sch6nhammer Theory
6T{Zee 3.4 Photoemission Signals and Narrow Bands in Metals
+N1oOcPC>C References
5\1Z"? g{wIdV 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
<r]7xsr 4.1 Theory
CL%?K<um 4.1.1 General
;K 38I} 4.1.2 Core-Line Shape
1><\3+8 4.1.3 Intrinsic Plasmons
*%_:[> 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
R<
@o]p 4.1.5 The Total Photoelectron Spectrum
(yQ]n91 Q, 4.2 Experimental Results
~8~B VwZ_ 4.2.1 The Core Line Without Plasmons
$~c?qU 4.2.2 Core-Level Spectra Including Plasmoas
:"? boA#L 4.2.3 Valence-Band Spectra of the Simple Metals
R)?b\VK2$ 4.2.4 Simple Metals: A General Comment
f2Frb
4.3 The Background Correction
INSI$tA~ References
<e"O`*ZJ V3baEy>=z 5. Valence Orbitals in Simple Molecules and Insulating Solids
CK[2duf^~ 5.1 UPS Spectra of Monatomic Gases
a*JM2^,HO 5.2 Photoelectron Spectra of Diatomic Molecules
9], ;i7c 5.3 Binding Energy of the H2 Molecule
FrD.{(/~ 5.4 Hydrides Isoelectronic with Noble Gases
X.<_TBos| Neon (Ne)
2f\;#- Hydrogen Fluoride (HF)
KpBh@S Water (H2O)
I$0JAy Ammonia (NH3)
?l#9ydi? Methane (CH4)
O-B~~$g 5.5 Spectra of the Alkali HMides
Jhu<^pjs 5.6 Transition Metal Dihalides
)}L*8 LV 5.7 Hydrocarbons
c 2j?<F1 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
)BNm~sP 5.7.2 Linear Polymers
aVvi_cau 5.8 Insulating Solids with Valence d Electrons
`84pql, 5.8.1 The NiO Problem
4S|! iOY 5.8.2 Mort Insulation
'JY*K:- 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
jQ.]m 5.8.4Band Structures of Transition Metal Compounds
G3&ES3L 5.9 High—Temperature Superconductors
j{N;2#.u 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
tVQfR*= 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
p3O%|)yV 5.9.3 The Superconducting Gap
}/BwFB+(/ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
s`Fv! 5.9.5 Core—Level Shifts
m! &bK5+* 5.10 The Fermi Liquid and the Luttinger Liquid
K6=-Zf 5.11 Adsorbed Molecules
R-]QU`c 5.11.1 Outline
vfzGRr 5.11.2 CO on Metal Surfaces
u.iFlU References
#EtS9D'd+ vFY/o,b \ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
j~c7nWfX 6.1 Theory of Photoemission:A Summary of the Three-Step Model
P$_Y:XI ! 6.2 Discussion of the Photocurrent
g(<02t!OT= 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
GyJp!
xFB 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
^T"9ZBkb 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
V[,/Hw~d% 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
T:x5 ,vpM 6.3.1 Band Structure Regime
%Bmi3
=Rr 6.3.2 XPS Regime
AC3K*)`E 6.3.3 Surface Emission
R[
S*ON 6.3.4 One-Step Calculations
_v4TyJ 6.4 Thermal Effects
A$ %5l 6.5 Dipole Selection Rules for Direct Optical Transitions
a*&P>Lwe7& References
XG<J'3 d+~c$(M) 7.Band Structtire and Angular-Resolved Photoelectron Spectra
udB:ys 7.1 Free-Electron Final—State Model
L5%~H?K( 7.2 Methods Employing Calculated Band Structures
Y{Kpopst 7.3 Methods for the Absolute Determination of the Crystal Momentum
jo=XxA 7.3.1 Triangulation or Energy Coincidence Method
eJ)Bs20Q 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
Vi`+2%4 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
94I8~Jj4 7.3.4 The Surface Emission Method and Electron Damping
>#dNXH]9 7.3.5 The Very-Low-Energy Electron Diffraction Method
H? N!F7s 7.3.6 The Fermi Surface Method
_6THyj$f 7.3.7 Intensities and Their Use in Band-Structure Determinations
* b>W 7.3.8 Summary
KL*ZPKG 7.4 Experimental Band Structures
{>OuxVl??k 7.4.1 One- and Two-Dimensional Systems
i\2MphS 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
CZE5RzG 7..4.3UPS Band Structures and XPS Density of States
/a17B 7.5 A Comment
NFY,$ References
s2g}IZfo yXY8 oE 8.Surface States, Surface Effects
NAV}q<@v 8.1 Theoretical Considerations
Z<En3^j` 8.2 Experimental Results on Surface States
2j-|.l c 8.3 Quantum-Well States
aGNt?)8WPZ 8.4 Surface Core-Level Shifts
h+zJ"\ References
bj(U?$ >!A&@1[M 9.Inverse Photoelectron Spectroscopy
Q`g0g)3w 9.1 Surface States
m\U@L+L 9.2 Bulk Band Structures
IvetQ+ 9.3 Adsorbed Molecules
&GwBxJ
References
2|tZ xlt- dGQxGt1 10. Spin-Polarized Photoelectron Spectroscopy
1W8[
RET 10.1 General Description
e+bpbyV_# 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
s!Y>\3rMW 10.3 Magnetic Dichroism
6VolTy@(x References
]jG%<j9A G9 z Q{E 11. Photoelectron Diffraction
M]jzbJ3Q 11.1 Examples
&of%;>$>M 11.2 Substrate Photoelectron Diffraction
1 dz&J\|E# 11.3 Adsorbate Photoelectron Diffraction
`>rdn*B 11.4 Fermi Surface Scans
u)&6;A4 References
$q
DH O-wR48Q Appendix
CY)Wuv ^ A.1 Table of Binding Energies
@`k!7?
Sq A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
f!P.=Qo[= A.3 Compilation of Work Functions
8l>/ZZ.NXi References
WXNJc Index