光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
Q"Exmn3p T*S)U ; 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
bl^pMt1fv ,S
m?2< 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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zlB[Eg^X CKSs(-hkJ 目录
~[kI![ 1. Introduction and Basic Principles
Dw 5Ze 1.1 Historical Development
<WbO&;% 1.2 The Electron Mean Free Path
i-#D c(9 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
VZe'6?# 1.4 Experimental Aspects
%{UW!/ 1.5 Very High Resolution
]ncK M?'O 1.6 The Theory of Photoemission
~]Av$S 1.6.1 Core-Level Photoemission
/XA*:8~! 1.6.2 Valence-State Photoemission
Ic^
(6 1.6.3 Three-Step and One-Step Considerations
}A[5\V^D* 1.7 Deviations from the Simple Theory of Photoemission
R&:Qy7" References
P(o>UDy 0+)1KU)I 2. Core Levels and Final States
DjiI*HLNR 2.1 Core-Level Binding Energies in Atoms and Molecules
"uj@!SEs`? 2.1.1 The Equivalent-Core Approximation
aI|X~b 2.1.2 Chemical Shifts
Nx+5r p 2.2 Core-Level Binding Energies in Solids
i7rk%q 2.2.1 The Born-Haber Cycle in Insulators
eYn/F~5- 2.2.2 Theory of Binding Energies
>6W #v[ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
:c Er{U8 2.3 Core Polarization
}jP/XO1f 2.4 Final-State Multiplets in Rare-Earth Valence Bands
D(Q]ddUi' 2.5 Vibrational Side Bands
DGw*BN%` 2.6 Core Levels of Adsorbed Molecules
* bhb=~ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
(dy:d^ References
1. <g C G8MLg # 3. Charge-Excitation Final States: Satellites
7AqbfLO 3.1 Copper Dihalides; 3d Transition Metal Compounds
/n:Q>8^n'W 3.1.1 Characterization of a Satellite
g&Uu~;jq] 3.1.2 Analysis of Charge-Transfer Satellites
bA'N2~., 3.1.3 Non-local Screening
Q ~n%c7 3.2 The 6-eV Satellite in Nickel
*.VNyay 3.2.1 Resonance Photoemission
91nB?8ZE6, 3.2.2 Satellites in Other Metals
cXr_,>k 3.3 The Gunnarsson-Sch6nhammer Theory
dDAl n+ 3.4 Photoemission Signals and Narrow Bands in Metals
4Me3{!HJ z References
m( %PZ*s V&/Cb&~Uw 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
b.8T<@a 4.1 Theory
I47sq z7 4.1.1 General
|Ho}
D~ 4.1.2 Core-Line Shape
(yeWArQ 4.1.3 Intrinsic Plasmons
L)S
V?FBx 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
aWP9i& 4.1.5 The Total Photoelectron Spectrum
7{k?"NF 4.2 Experimental Results
OB^j
b8 4.2.1 The Core Line Without Plasmons
gNkBHwv 4.2.2 Core-Level Spectra Including Plasmoas
K$s{e0
79 4.2.3 Valence-Band Spectra of the Simple Metals
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|4O<@ 4.2.4 Simple Metals: A General Comment
Z^%HDB9^ 4.3 The Background Correction
TN08,:k References
"5Z5x%3I 4af^SZ)l 5. Valence Orbitals in Simple Molecules and Insulating Solids
v`Ja Bn 5.1 UPS Spectra of Monatomic Gases
_Kh8
<$h 5.2 Photoelectron Spectra of Diatomic Molecules
Cy)QS{YX 5.3 Binding Energy of the H2 Molecule
NSR][h_ 5.4 Hydrides Isoelectronic with Noble Gases
'z=d&K Neon (Ne)
.ezZ+@LI+# Hydrogen Fluoride (HF)
\J;]g\&I" Water (H2O)
m%.[|sZ3EM Ammonia (NH3)
d69dC*> Methane (CH4)
mgodvX 5.5 Spectra of the Alkali HMides
64<*\z_ 5.6 Transition Metal Dihalides
9T1-{s
R 5.7 Hydrocarbons
)wdd"*hv 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
=rkW325O 5.7.2 Linear Polymers
F[)tg#}@G 5.8 Insulating Solids with Valence d Electrons
T&:~= 5.8.1 The NiO Problem
rd=+[:7L 5.8.2 Mort Insulation
0xaK"\Q 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
PIoBK CJ 5.8.4Band Structures of Transition Metal Compounds
afu!.}4Ct 5.9 High—Temperature Superconductors
5aXE^.` 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
^7t1'A8e< 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
()n2 KT 5.9.3 The Superconducting Gap
MlW*Tugg 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
pTncx%!W5 5.9.5 Core—Level Shifts
"x0KiIoPk 5.10 The Fermi Liquid and the Luttinger Liquid
KYl!Iw67d 5.11 Adsorbed Molecules
~8-xj6^ 5.11.1 Outline
glBS|b$\: 5.11.2 CO on Metal Surfaces
|8)\8b|VuC References
h}DKFrHW;- hrXk 7}9 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
K `A8N 6.1 Theory of Photoemission:A Summary of the Three-Step Model
,e
GF~ 6.2 Discussion of the Photocurrent
@%fL*^yr;C 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
1?Tj 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
`lt[Q>Z 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
[| N73m,& 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
ft4hzmuzM 6.3.1 Band Structure Regime
[h8macx 6.3.2 XPS Regime
9kbczL^Y
6.3.3 Surface Emission
FchO
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%c8@ 6.4 Thermal Effects
8==_43 6.5 Dipole Selection Rules for Direct Optical Transitions
}_7 References
vkeZ!klYB k]2_vk^ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
Dz8aJ6g 7.1 Free-Electron Final—State Model
SDs#w 7.2 Methods Employing Calculated Band Structures
rD9:4W`^ 7.3 Methods for the Absolute Determination of the Crystal Momentum
,K|UUosS-# 7.3.1 Triangulation or Energy Coincidence Method
NYzBfL
x 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
D#^euNiWd 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
~mv5{C 7.3.4 The Surface Emission Method and Electron Damping
/Ba/gq0j 7.3.5 The Very-Low-Energy Electron Diffraction Method
I8YCXh 7.3.6 The Fermi Surface Method
}d5~w[ 7.3.7 Intensities and Their Use in Band-Structure Determinations
EG3u)}vI 7.3.8 Summary
uH[:R vC0 7.4 Experimental Band Structures
dQO5 7.4.1 One- and Two-Dimensional Systems
oa`7ClzD 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Gi*_ & 7..4.3UPS Band Structures and XPS Density of States
\p]B8hLW 7.5 A Comment
b #Llu$ References
JU)k+:\a nyBT4e 8.Surface States, Surface Effects
2^f7GP 8.1 Theoretical Considerations
=1<v1s|)q 8.2 Experimental Results on Surface States
D'BGoVP 8.3 Quantum-Well States
tk>J
mcTw 8.4 Surface Core-Level Shifts
wz BI<0]z References
)t CNp P4+PY 8 9.Inverse Photoelectron Spectroscopy
MIh\z7gW 9.1 Surface States
!/=.~B 9.2 Bulk Band Structures
3e1P!^'\ 9.3 Adsorbed Molecules
C;.,+(G References
aK
3'u Ch:EL-L 10. Spin-Polarized Photoelectron Spectroscopy
<d >!% 10.1 General Description
F07X9s44E 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
}]JHY P\ 10.3 Magnetic Dichroism
;WgUhA
;q References
~R50-O {<?8Y 11. Photoelectron Diffraction
wN :"(mQ 11.1 Examples
bR8`Y(=F9b 11.2 Substrate Photoelectron Diffraction
ExeZj8U 11.3 Adsorbate Photoelectron Diffraction
<Y$(
lszT 11.4 Fermi Surface Scans
R'" c References
7+qKA1t^ |"+Ufw^ Appendix
8IE^u<H(: A.1 Table of Binding Energies
@7KG0<]h A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
T''<y S A.3 Compilation of Work Functions
?nWzJ5w3 References
LWhPd\ Index