光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
3@n>*7/E zKFp5H1!%+ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
9e U[*S jEz+1Nl) 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
m uW!xY @FN*TJ
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O9(r{Vu7u as+GbstN 目录
mfny4R1_ 1. Introduction and Basic Principles
?8,%LIQ? 1.1 Historical Development
\uG`|Dn 1.2 The Electron Mean Free Path
l$*=<tV 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
pbHsR^ 1.4 Experimental Aspects
xw<OLWW 1.5 Very High Resolution
}%TSGC4{ 1.6 The Theory of Photoemission
fWGOP~0 1.6.1 Core-Level Photoemission
S>q>K"j^! 1.6.2 Valence-State Photoemission
c~<1': 1.6.3 Three-Step and One-Step Considerations
nsb4S{ 1.7 Deviations from the Simple Theory of Photoemission
*FR$vLGn References
MYe
HS jy2IZ o 2. Core Levels and Final States
":Edu,6O 2.1 Core-Level Binding Energies in Atoms and Molecules
'rb'7=z5 2.1.1 The Equivalent-Core Approximation
O)R(==P26P 2.1.2 Chemical Shifts
wyxGe<1 2.2 Core-Level Binding Energies in Solids
;oH,~|K 2.2.1 The Born-Haber Cycle in Insulators
iO1nwl !# 2.2.2 Theory of Binding Energies
i;PL\Er:tX 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
4y}"Hy 2.3 Core Polarization
MVCl.o 2.4 Final-State Multiplets in Rare-Earth Valence Bands
$mA5@O~C5\ 2.5 Vibrational Side Bands
VyG4(Xva 2.6 Core Levels of Adsorbed Molecules
^4v*W;Q 2.7 Quantitative Chemical Analysis from Core-Level Intensities
{}>n{_ References
aaWJ*
>rJ mV9A{h 3. Charge-Excitation Final States: Satellites
ps:f=6m2 3.1 Copper Dihalides; 3d Transition Metal Compounds
]r]k-GZ$ 3.1.1 Characterization of a Satellite
Lp:6 ; 3.1.2 Analysis of Charge-Transfer Satellites
M] V.!z9B 3.1.3 Non-local Screening
Bz2'=~J 3.2 The 6-eV Satellite in Nickel
;/AG@$) 3.2.1 Resonance Photoemission
>
^[z3T 3.2.2 Satellites in Other Metals
BRG|Asg( 3.3 The Gunnarsson-Sch6nhammer Theory
@nV5.r0W}B 3.4 Photoemission Signals and Narrow Bands in Metals
`BZ&~vJ_ References
0>6DSQq~t( 6er(% 4! 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
MN;/*t 4.1 Theory
}ZZ5].-a<D 4.1.1 General
^DAa%u 4.1.2 Core-Line Shape
eo#^L} 4.1.3 Intrinsic Plasmons
@fn6<3 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
zz$q5[n 4.1.5 The Total Photoelectron Spectrum
\X}8q 4.2 Experimental Results
Ln#a<Rx.E7 4.2.1 The Core Line Without Plasmons
GSVdb/+ 4.2.2 Core-Level Spectra Including Plasmoas
rE!1wc>L 4.2.3 Valence-Band Spectra of the Simple Metals
msTB'0 4.2.4 Simple Metals: A General Comment
9 |:^k. 4.3 The Background Correction
[!*xO?yCJ References
M7y|EB)) {0jIY 5. Valence Orbitals in Simple Molecules and Insulating Solids
!DjT<dxf 5.1 UPS Spectra of Monatomic Gases
cHvF* A 5.2 Photoelectron Spectra of Diatomic Molecules
CSn<]%GL 5.3 Binding Energy of the H2 Molecule
j=sBq.S 5.4 Hydrides Isoelectronic with Noble Gases
CUmH,`hu Neon (Ne)
&&RA4 Hydrogen Fluoride (HF)
KHj6Tg;) Water (H2O)
~\_T5/I% Ammonia (NH3)
U1m\\<, Methane (CH4)
^o<[.
) 5.5 Spectra of the Alkali HMides
$@[)nvV\ 5.6 Transition Metal Dihalides
r:l96^xs 5.7 Hydrocarbons
pz}mF D&[ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
,a(O`##Bn 5.7.2 Linear Polymers
?g}kb 5.8 Insulating Solids with Valence d Electrons
nX
x=1*X 5.8.1 The NiO Problem
;lfWuU%R 5.8.2 Mort Insulation
!ng\`
|8? 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
J 3?Dj 5.8.4Band Structures of Transition Metal Compounds
#Q6w+" 5.9 High—Temperature Superconductors
L~0&
Q 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
:k"rhI 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
[ #]jC[ 5.9.3 The Superconducting Gap
%O) Z 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
_-a|VTM 5.9.5 Core—Level Shifts
Yw"P)Zp 5.10 The Fermi Liquid and the Luttinger Liquid
ckwF|:e7* 5.11 Adsorbed Molecules
?n*fy 5.11.1 Outline
hLA;Bl 5.11.2 CO on Metal Surfaces
!UNNjBBP7 References
Wvr+y!F d(l|hmj4j9 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
zO2{.4 6.1 Theory of Photoemission:A Summary of the Three-Step Model
x0x $ 9 6.2 Discussion of the Photocurrent
0$Ff#8 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
K\sbt7~ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
u6_jnZGB 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
%Dyh:h 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
lP0k: 6.3.1 Band Structure Regime
r{ "uv=,` 6.3.2 XPS Regime
UH40~LxIma 6.3.3 Surface Emission
*)%dXVf 6.3.4 One-Step Calculations
ONWO`XD 6.4 Thermal Effects
y&rY0bm 6.5 Dipole Selection Rules for Direct Optical Transitions
M.k|bh8 References
6lU|mJ`M a!u3HS-i 7.Band Structtire and Angular-Resolved Photoelectron Spectra
A+2oh3 7.1 Free-Electron Final—State Model
)k%M.{&bji 7.2 Methods Employing Calculated Band Structures
n0FYfqH 7.3 Methods for the Absolute Determination of the Crystal Momentum
B! `\L! 7.3.1 Triangulation or Energy Coincidence Method
<JH9StGGc? 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
`@\^m_!} 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
8nu> gA 7.3.4 The Surface Emission Method and Electron Damping
%MNk4UsV 7.3.5 The Very-Low-Energy Electron Diffraction Method
RUc \u93n 7.3.6 The Fermi Surface Method
TolrEcI 7.3.7 Intensities and Their Use in Band-Structure Determinations
<UK5eVQn 7.3.8 Summary
V85.DK! 7.4 Experimental Band Structures
Y UZKle 7.4.1 One- and Two-Dimensional Systems
\*9Ua/H 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
&<{}8/x8( 7..4.3UPS Band Structures and XPS Density of States
=+(Q.LmhC 7.5 A Comment
65"uD7; References
&?}1AQAYg nk>8SW^ 8.Surface States, Surface Effects
=BW9/fG 8.1 Theoretical Considerations
7<4xtK`+b 8.2 Experimental Results on Surface States
M\jB)@) 8.3 Quantum-Well States
$P_x v 8.4 Surface Core-Level Shifts
LO}z)j~W References
1w) fu r$?Vx_f`Q 9.Inverse Photoelectron Spectroscopy
p.aE 9.1 Surface States
M%;"c?g 9.2 Bulk Band Structures
,#Ln/; 9.3 Adsorbed Molecules
|P~q/Wff References
Av[Ud
*~ UC;=) 10. Spin-Polarized Photoelectron Spectroscopy
L,%Z9 10.1 General Description
2moIgJ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
$%;jk 10.3 Magnetic Dichroism
ytob/tc References
W%H]Uyt 1::LN(`< 11. Photoelectron Diffraction
VB's 11.1 Examples
:OX$LCi 11.2 Substrate Photoelectron Diffraction
GM77Z.Y 11.3 Adsorbate Photoelectron Diffraction
.CvFE~
11.4 Fermi Surface Scans
+qZc}
7rJF References
PgTDjEo n8Q*
_?Z/ Appendix
m/KjJ"s, A.1 Table of Binding Energies
_Z0\`kba+ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
'me:Zd A.3 Compilation of Work Functions
{[N?+ZJD*L References
|thad!? Index