光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
'Grii, 0c`nk\vUy 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
h`dQOH# BxjSo^n 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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{59>U~ \Ta5c31S+ 目录
Z,e|L4& 1. Introduction and Basic Principles
v/9ZTd 1.1 Historical Development
KFwuz()7 1.2 The Electron Mean Free Path
T3@2e0u ) 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
@#OL{yMy 1.4 Experimental Aspects
eZqEFMBTm 1.5 Very High Resolution
vt2.
i$u 1.6 The Theory of Photoemission
}DS%?6}Sy 1.6.1 Core-Level Photoemission
GDSXBa*7 1.6.2 Valence-State Photoemission
cWZITT{A 1.6.3 Three-Step and One-Step Considerations
|oLG c!i 1.7 Deviations from the Simple Theory of Photoemission
4
ZnQpKg References
GdI,&|/ *X/Vt$P 2. Core Levels and Final States
sTl^j gV7j 2.1 Core-Level Binding Energies in Atoms and Molecules
-^2p@^ 2.1.1 The Equivalent-Core Approximation
vj%"x/TP 2.1.2 Chemical Shifts
wbAwmOiZ 2.2 Core-Level Binding Energies in Solids
~`FRU/@r 2.2.1 The Born-Haber Cycle in Insulators
@Kz,TP!%A 2.2.2 Theory of Binding Energies
eyJWFJh 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
KR?aL:RYb 2.3 Core Polarization
''@Tke3IG6 2.4 Final-State Multiplets in Rare-Earth Valence Bands
w01[oU$x= 2.5 Vibrational Side Bands
I3Z?xsa@Z 2.6 Core Levels of Adsorbed Molecules
Qe>_\-f
2.7 Quantitative Chemical Analysis from Core-Level Intensities
2A;i References
S',h*e U&1O 3. Charge-Excitation Final States: Satellites
Y3DqsZ@ 3.1 Copper Dihalides; 3d Transition Metal Compounds
cM'MgX9 3.1.1 Characterization of a Satellite
XYuX+&XW/ 3.1.2 Analysis of Charge-Transfer Satellites
JX&]>#6|E 3.1.3 Non-local Screening
P"^Yx8 L# 3.2 The 6-eV Satellite in Nickel
Gg9s.]W 3.2.1 Resonance Photoemission
4 H0rS'5d 3.2.2 Satellites in Other Metals
~deS* 3.3 The Gunnarsson-Sch6nhammer Theory
zPp22 3.4 Photoemission Signals and Narrow Bands in Metals
s_/@`kd{ References
=o~+R\1ux+ ^3$U[u%q/{ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
7FcZxu\ 4.1 Theory
,$:u^;V( 4.1.1 General
eLPtdP5k 4.1.2 Core-Line Shape
ygnZ9ikh<- 4.1.3 Intrinsic Plasmons
ejZ-A?f-K 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
dY&v(~&;] 4.1.5 The Total Photoelectron Spectrum
,.p
36ZLP 4.2 Experimental Results
5X)QW5A 4.2.1 The Core Line Without Plasmons
l+F29_o# 4.2.2 Core-Level Spectra Including Plasmoas
-%MXt 4.2.3 Valence-Band Spectra of the Simple Metals
!9PAfi? 4.2.4 Simple Metals: A General Comment
%C,zR&]F 4.3 The Background Correction
"[~yu*
S References
k1xx>=md|C H"? 5]!p 5. Valence Orbitals in Simple Molecules and Insulating Solids
a5/, O4Q 5.1 UPS Spectra of Monatomic Gases
#Mn?Nn 5.2 Photoelectron Spectra of Diatomic Molecules
'yX\y
6I 5.3 Binding Energy of the H2 Molecule
DCiU?u~ 5.4 Hydrides Isoelectronic with Noble Gases
,Ohhl`q( Neon (Ne)
]rj~3du\ Hydrogen Fluoride (HF)
0vfMJzk Water (H2O)
vc|tp_M67 Ammonia (NH3)
Q2ne]MI Methane (CH4)
}EwE#sZ# 5.5 Spectra of the Alkali HMides
1q!k#Cliu 5.6 Transition Metal Dihalides
*
cW%Q@lit 5.7 Hydrocarbons
'+/mt_re= 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
YU-wE';H6 5.7.2 Linear Polymers
z_xy*Iif 5.8 Insulating Solids with Valence d Electrons
iu=Mq|t0 5.8.1 The NiO Problem
J&~I4ko] 5.8.2 Mort Insulation
ASoBa&vX 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
faRQj:R8 5.8.4Band Structures of Transition Metal Compounds
G`%rnu 5.9 High—Temperature Superconductors
<}~
/. Cx 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
_VdJFjY?zc 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
;W5.g8 5.9.3 The Superconducting Gap
+
>dC 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
vzI>:Bf 5.9.5 Core—Level Shifts
(Ud"+a 5.10 The Fermi Liquid and the Luttinger Liquid
c{1)-&W 5.11 Adsorbed Molecules
h\@X!Z, 5.11.1 Outline
v1yB 5.11.2 CO on Metal Surfaces
>x6\A7 References
A2\hmp@A@7 Xk%eU>d 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
GOdWc9Ta! 6.1 Theory of Photoemission:A Summary of the Three-Step Model
-FZNk} 6.2 Discussion of the Photocurrent
/'DAB** 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
h='&^1 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
=3'B$PY 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
;U?=YSHk7 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
wS|k3^OV% 6.3.1 Band Structure Regime
K{I "2c 6.3.2 XPS Regime
sYXLVJ>b 6.3.3 Surface Emission
7CR#\&h` 6.3.4 One-Step Calculations
?H_@/? 6.4 Thermal Effects
b)Nd}6}<? 6.5 Dipole Selection Rules for Direct Optical Transitions
'>|Kd{J0 References
C~>0K,C0^ e/g9r 7.Band Structtire and Angular-Resolved Photoelectron Spectra
]lGkZyUhI 7.1 Free-Electron Final—State Model
Dj=$Q44 7.2 Methods Employing Calculated Band Structures
r\fkx> 7.3 Methods for the Absolute Determination of the Crystal Momentum
`dX0F=Ag? 7.3.1 Triangulation or Energy Coincidence Method
zp9l u B 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
5#f_1
V 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
Ew.6y=Ba 7.3.4 The Surface Emission Method and Electron Damping
Fg
p|gw4 7.3.5 The Very-Low-Energy Electron Diffraction Method
ImB5F'HI$ 7.3.6 The Fermi Surface Method
MX#LtCG#V 7.3.7 Intensities and Their Use in Band-Structure Determinations
VgbT/v 7.3.8 Summary
wGs'qL"z 7.4 Experimental Band Structures
PyI"B96gz 7.4.1 One- and Two-Dimensional Systems
5.\|*+E~ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
)xU+M{p-os 7..4.3UPS Band Structures and XPS Density of States
(g[WZB3x 7.5 A Comment
<6.`(isph References
wU'+4N". u"7!EhX& 8.Surface States, Surface Effects
6:QlHuy0nH 8.1 Theoretical Considerations
//r)dN^ 8.2 Experimental Results on Surface States
\ 6taC 8.3 Quantum-Well States
(0y!{ (a 8.4 Surface Core-Level Shifts
6j1C=O@S References
er
BerbEEH t&JOASYC 9.Inverse Photoelectron Spectroscopy
j7I?K
:op= 9.1 Surface States
j)ln"u0R^B 9.2 Bulk Band Structures
(8ct'Q ; 9.3 Adsorbed Molecules
k&[6Ld0~56 References
0RSzDgX ]T5\LNyN 10. Spin-Polarized Photoelectron Spectroscopy
?)<zzL", 10.1 General Description
v`Y{.>[H[ 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
:>ca).cjac 10.3 Magnetic Dichroism
A[fTpS ~~% References
FD%OG6db]; 4;32f` 11. Photoelectron Diffraction
WCqa[=v)t 11.1 Examples
7;.Iat9gMf 11.2 Substrate Photoelectron Diffraction
:!$+dr(d 11.3 Adsorbate Photoelectron Diffraction
^g2Vz4u 11.4 Fermi Surface Scans
X<W${L$G References
Z"Q9^;0% XCxxm3t Appendix
eq"Xwq* A.1 Table of Binding Energies
1n6%EC|X A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
=%I;Y& K A.3 Compilation of Work Functions
T#Bj5H References
)3|a_
Index