光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
|Ptv)D `V[{,!l;X 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
%2D9]L2Up vMV}M%~ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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nuip /G h?z 目录
Qs5^kddz= 1. Introduction and Basic Principles
B#T4m]E/ 1.1 Historical Development
G F-\WD 1.2 The Electron Mean Free Path
d}t7bgk'j 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
e$3{URg 1.4 Experimental Aspects
+bw>9VmG 1.5 Very High Resolution
Bqd'2HQd 1.6 The Theory of Photoemission
93*MY7j} 1.6.1 Core-Level Photoemission
j!:^+F/ 1.6.2 Valence-State Photoemission
x4C}AyR 1.6.3 Three-Step and One-Step Considerations
i/%+x-# 1.7 Deviations from the Simple Theory of Photoemission
`i,l)X] References
r{T}pc>^ /RzL,~] 2. Core Levels and Final States
[Cx'a7KWL 2.1 Core-Level Binding Energies in Atoms and Molecules
yIL6Sb 2.1.1 The Equivalent-Core Approximation
jLRh/pbz4 2.1.2 Chemical Shifts
fvDt_g9 oI 2.2 Core-Level Binding Energies in Solids
F5|6* K 2.2.1 The Born-Haber Cycle in Insulators
Gb\Nqx( 2.2.2 Theory of Binding Energies
uoM;p' 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
{T^"`%[ 2.3 Core Polarization
.W#-Cl&n8 2.4 Final-State Multiplets in Rare-Earth Valence Bands
Az}.Z'LJ 2.5 Vibrational Side Bands
'51 8S"T @ 2.6 Core Levels of Adsorbed Molecules
a$*)d($ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
q`l%NE References
8tR(i[L
1yS[; 3. Charge-Excitation Final States: Satellites
0#AS>K5 3.1 Copper Dihalides; 3d Transition Metal Compounds
:QGd/JX$n` 3.1.1 Characterization of a Satellite
t0 1@h_WS 3.1.2 Analysis of Charge-Transfer Satellites
NYoh6AR 3.1.3 Non-local Screening
\CP)$0j-&o 3.2 The 6-eV Satellite in Nickel
_qq> 43 3.2.1 Resonance Photoemission
kf8-#Q/B 3.2.2 Satellites in Other Metals
n\v;4ly^ 3.3 The Gunnarsson-Sch6nhammer Theory
ZPieL&uV` 3.4 Photoemission Signals and Narrow Bands in Metals
pu:Ie#xTDf References
D+Ke)-/ L|wD2iw 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
UbD1h_b 4.1 Theory
*ydkx\pT 4.1.1 General
=z5'A|Wa=, 4.1.2 Core-Line Shape
6V"| 4.1.3 Intrinsic Plasmons
]ZD W+< 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
LyaFWx 4.1.5 The Total Photoelectron Spectrum
:ub 4p4h* 4.2 Experimental Results
0UJ%tPS 4.2.1 The Core Line Without Plasmons
b?p <y` 4.2.2 Core-Level Spectra Including Plasmoas
.$r=:k_d 4.2.3 Valence-Band Spectra of the Simple Metals
N%hV +># Z 4.2.4 Simple Metals: A General Comment
xpJ6M<O{8 4.3 The Background Correction
yMU>vr References
9w^lRbn TN xl?5: 5. Valence Orbitals in Simple Molecules and Insulating Solids
;"}yVV/4 5.1 UPS Spectra of Monatomic Gases
\{Qd 5.2 Photoelectron Spectra of Diatomic Molecules
.^aakM 5.3 Binding Energy of the H2 Molecule
|Va*=@&6J 5.4 Hydrides Isoelectronic with Noble Gases
Vq'\`$_
Neon (Ne)
4GA9oLl Hydrogen Fluoride (HF)
3@qy}Nm Water (H2O)
0zQ^ 6@ Ammonia (NH3)
@H{QHi Methane (CH4)
O_zW/# 5.5 Spectra of the Alkali HMides
emhI1
*} 5.6 Transition Metal Dihalides
8T7ex(w 5.7 Hydrocarbons
64)Fz} 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
{XHAQ9' 5.7.2 Linear Polymers
S(B$[)( 5.8 Insulating Solids with Valence d Electrons
4pvT?s>68 5.8.1 The NiO Problem
C 2f=9n/ 5.8.2 Mort Insulation
PQl^jS 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
9O8na
'w 5.8.4Band Structures of Transition Metal Compounds
BHVC&F*> 5.9 High—Temperature Superconductors
Zj+S"`P 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
:y/1Jf'2f 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
|WiE`&?xP 5.9.3 The Superconducting Gap
DzfgPY_Py 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
pyvH [ 5.9.5 Core—Level Shifts
WH>= *\ 5.10 The Fermi Liquid and the Luttinger Liquid
BBV"nm_(/ 5.11 Adsorbed Molecules
;Y6XX_ 5.11.1 Outline
B]KR * 5.11.2 CO on Metal Surfaces
}Y}f73-| References
F@8G,$ @q98ac*{ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
B0h|Y.S8%1 6.1 Theory of Photoemission:A Summary of the Three-Step Model
'|I8byiK 6.2 Discussion of the Photocurrent
zBQV2.@ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
Y X`BX$ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
/ [s TN.MG 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
O$qxo
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`"(FWK=8)" 6.3.1 Band Structure Regime
Su]@~^w 6.3.2 XPS Regime
O'm5k l 6.3.3 Surface Emission
i/vo 6.3.4 One-Step Calculations
M_I.Y1| 6.4 Thermal Effects
yt'P,m 6.5 Dipole Selection Rules for Direct Optical Transitions
fY4I(~Q References
3X;k c> e(=() :4is 7.Band Structtire and Angular-Resolved Photoelectron Spectra
B\73Vf 7.1 Free-Electron Final—State Model
`rLcJcW 7.2 Methods Employing Calculated Band Structures
H[S}&l\D4 7.3 Methods for the Absolute Determination of the Crystal Momentum
R)@2={fd} 7.3.1 Triangulation or Energy Coincidence Method
':>u* 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
Silh[8 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
<2n5|.:> 7.3.4 The Surface Emission Method and Electron Damping
^xyU*A}D 7.3.5 The Very-Low-Energy Electron Diffraction Method
W\c1QY$E 7.3.6 The Fermi Surface Method
>1}@Q(n/}{ 7.3.7 Intensities and Their Use in Band-Structure Determinations
+]3kcm7B 7.3.8 Summary
V0l"tr@ 7.4 Experimental Band Structures
0.aIcc 7.4.1 One- and Two-Dimensional Systems
O"M2*qiH 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
5%_aN_1?ef 7..4.3UPS Band Structures and XPS Density of States
Y&XO:jB 7.5 A Comment
;p(I0X References
b8
^O"oDrp =*5< w 8.Surface States, Surface Effects
~n"?*I` 8.1 Theoretical Considerations
Ka_g3 8.2 Experimental Results on Surface States
|AQU\BUj 8.3 Quantum-Well States
,M.phRJ-` 8.4 Surface Core-Level Shifts
"5!T-Z+F References
VnYcqeCm DFXHD,o 9.Inverse Photoelectron Spectroscopy
3;O4o]` 9.1 Surface States
Q}: $F{ 9.2 Bulk Band Structures
h6Q~Di 9.3 Adsorbed Molecules
'8yC wk References
k-N}tk/5 q^DQ9B 10. Spin-Polarized Photoelectron Spectroscopy
&7XsyDo6 10.1 General Description
Vb8Qh601 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
uq2C|=M-x\ 10.3 Magnetic Dichroism
#z1/VZ References
;u-[%(00S Z[9t?ePL 11. Photoelectron Diffraction
[[#R ry 11.1 Examples
F%:74.]Y 11.2 Substrate Photoelectron Diffraction
I7#^'/ 11.3 Adsorbate Photoelectron Diffraction
`h'7X( 11.4 Fermi Surface Scans
AxfQ{>)0 References
>B<#,G GJ{XlH Appendix
`Frr?.3&- A.1 Table of Binding Energies
9SBTeJ$RZ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
Q!!u=}GYK A.3 Compilation of Work Functions
?Rk[P
cX< References
jL7r1pu5 Index