光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
7#N
?{3i '+GY6Ecg 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
t0za%q!fK< 1r5Z$3t\ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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i>C%[dk9 We*uZ?+ 目录
[q/eRIS_ 1. Introduction and Basic Principles
s){VU2.ra 1.1 Historical Development
MwL!2r 1.2 The Electron Mean Free Path
m8eoD{ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
l\!`ZhM, 1.4 Experimental Aspects
] VEc9? 1.5 Very High Resolution
Zqv 1.6 The Theory of Photoemission
xgtx5tg 1.6.1 Core-Level Photoemission
sn
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HdTB[( 1.6.3 Three-Step and One-Step Considerations
7UqDPEXU]` 1.7 Deviations from the Simple Theory of Photoemission
uc\G)BN References
A<(Fn_&W sQ&<cBs2 2. Core Levels and Final States
y 5?kv-"c 2.1 Core-Level Binding Energies in Atoms and Molecules
fo<nk|i 2.1.1 The Equivalent-Core Approximation
|oQhtk8. 2.1.2 Chemical Shifts
uz:r'+v 2.2 Core-Level Binding Energies in Solids
=>&~p\Aw 2.2.1 The Born-Haber Cycle in Insulators
KM[&WT 2.2.2 Theory of Binding Energies
32pPeYxB!- 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
%|ioNXMu 2.3 Core Polarization
PG@C5Rnu 2.4 Final-State Multiplets in Rare-Earth Valence Bands
2Ky|+s[`[ 2.5 Vibrational Side Bands
vg1E@rH|} 2.6 Core Levels of Adsorbed Molecules
&'/bnN +R 2.7 Quantitative Chemical Analysis from Core-Level Intensities
]vw%J ^7:a References
<-gGm=R_ $ LG{50sP` 3. Charge-Excitation Final States: Satellites
{IF$\{Al 3.1 Copper Dihalides; 3d Transition Metal Compounds
5 o[E8c8 3.1.1 Characterization of a Satellite
+(`.pa z@ 3.1.2 Analysis of Charge-Transfer Satellites
AbQnx%$u 3.1.3 Non-local Screening
1suP7o A; 3.2 The 6-eV Satellite in Nickel
.3wx}!:*| 3.2.1 Resonance Photoemission
|Qpd<L 3.2.2 Satellites in Other Metals
\K lY8\c[ 3.3 The Gunnarsson-Sch6nhammer Theory
:c(I-xif 3.4 Photoemission Signals and Narrow Bands in Metals
LaL{
^wP References
=tX"aCW~ QVmJ_WT 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
CUft 4.1 Theory
@Hr1.f 4.1.1 General
m!(dk] 4.1.2 Core-Line Shape
31F^ 38 4.1.3 Intrinsic Plasmons
61sEeM 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
_^$F^}{& 4.1.5 The Total Photoelectron Spectrum
p77=~s 4.2 Experimental Results
`'9t^6mk 4.2.1 The Core Line Without Plasmons
Y~I0\8s- 4.2.2 Core-Level Spectra Including Plasmoas
j#l1KO^y 4.2.3 Valence-Band Spectra of the Simple Metals
l=a<=i 4.2.4 Simple Metals: A General Comment
{+gK\Nz 4.3 The Background Correction
RF~c/en References
0&3zBL%Bo %+(fdk-k+ 5. Valence Orbitals in Simple Molecules and Insulating Solids
+JB*1dz>8 5.1 UPS Spectra of Monatomic Gases
I]Z"?T 5.2 Photoelectron Spectra of Diatomic Molecules
oJc7az 5.3 Binding Energy of the H2 Molecule
aCyn9Y$= 5.4 Hydrides Isoelectronic with Noble Gases
{>Qs+] Neon (Ne)
fJ%A_N} Hydrogen Fluoride (HF)
Qe]& Water (H2O)
\=(U tro Ammonia (NH3)
xo(>nFjo Methane (CH4)
\}gITc).j 5.5 Spectra of the Alkali HMides
VT;cz6"6b4 5.6 Transition Metal Dihalides
\Awqr:A& 5.7 Hydrocarbons
u~Y+YzCxV 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
bV*q~@xh 5.7.2 Linear Polymers
mE9ytFH\k 5.8 Insulating Solids with Valence d Electrons
5X^`qUSv 5.8.1 The NiO Problem
C2L=i3R 5.8.2 Mort Insulation
8vj]S5 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
g{hbq[>X] 5.8.4Band Structures of Transition Metal Compounds
Q.fD3g 5.9 High—Temperature Superconductors
HzZX=c 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
jtwe9 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
NRs%q}lX 5.9.3 The Superconducting Gap
JNI&]3[C>? 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
kvt^s0T8Q 5.9.5 Core—Level Shifts
vtq47i 5.10 The Fermi Liquid and the Luttinger Liquid
Mu_'C$zA 5.11 Adsorbed Molecules
1Nz#,IdQ 5.11.1 Outline
kP&Ekjt@ 5.11.2 CO on Metal Surfaces
3\|PwA9fN8 References
rWp+kV[Ec> pQ`S%]k.< 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
zKf0 :X 6.1 Theory of Photoemission:A Summary of the Three-Step Model
ZRUI';5x 6.2 Discussion of the Photocurrent
Eq5X/Hx 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
)!sjXiC!h 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
~tB9kLFG 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
NDG?Xs [2 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
(>-(~7PR 6.3.1 Band Structure Regime
nwJc%0 6.3.2 XPS Regime
UFj/Y; 6.3.3 Surface Emission
Rts}y:44 6.3.4 One-Step Calculations
|(5|6r3 6.4 Thermal Effects
VWMr\]g 6.5 Dipole Selection Rules for Direct Optical Transitions
Fz]!2rt References
zzX9Q: }vW3<|z 7.Band Structtire and Angular-Resolved Photoelectron Spectra
c`#4}$ 7.1 Free-Electron Final—State Model
E{'\(6z_ 7.2 Methods Employing Calculated Band Structures
lH>6;sE 7.3 Methods for the Absolute Determination of the Crystal Momentum
9}11>X 7.3.1 Triangulation or Energy Coincidence Method
^>h2.AJ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
n:JG+1I 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
r6e!";w:U 7.3.4 The Surface Emission Method and Electron Damping
!6*4^$i#o 7.3.5 The Very-Low-Energy Electron Diffraction Method
DE$T1pFV 7.3.6 The Fermi Surface Method
3\5I4#S 7.3.7 Intensities and Their Use in Band-Structure Determinations
"IoY$!Hk 7.3.8 Summary
a&gf0g;@I 7.4 Experimental Band Structures
n:%A4* 7.4.1 One- and Two-Dimensional Systems
qjIcRue'" 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
?$4CgN- 7..4.3UPS Band Structures and XPS Density of States
wM#q [m; 7.5 A Comment
^I!gteU; References
fXAD~7T*s *G,r:Bnb 8.Surface States, Surface Effects
!)uXCg9U 8.1 Theoretical Considerations
Y=
^o {C6 8.2 Experimental Results on Surface States
bpfSe 8.3 Quantum-Well States
`,6^eLU 8.4 Surface Core-Level Shifts
\LDcIK= References
_B\X&!G. #EO],!JM 9.Inverse Photoelectron Spectroscopy
15!b]': 9.1 Surface States
4\2~wSr 9.2 Bulk Band Structures
2Zw]Uu`sb 9.3 Adsorbed Molecules
~;nW+S$o
References
GoG_4:^#h +Z%8X!Q 10. Spin-Polarized Photoelectron Spectroscopy
S3YAc4 10.1 General Description
W7
9.,# 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
GI#TMFz3 10.3 Magnetic Dichroism
Q37zBC0 References
uszMzO~ %gXNWxv 11. Photoelectron Diffraction
bqUQadDB 11.1 Examples
F2["Ak NM 11.2 Substrate Photoelectron Diffraction
axd9b, 11.3 Adsorbate Photoelectron Diffraction
K.\- 11.4 Fermi Surface Scans
&/lmg!6 References
p2o66t O}"fhMk Appendix
vX}mwK8
A.1 Table of Binding Energies
p:8]jD@}% A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
|c!lZo/ A.3 Compilation of Work Functions
&bS!>_9 References
$a+)v#?, Index