光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
a,GOS:?O5 o1m+4.- 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
m+t<<5I[- J-6l<%962% 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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,Iv<Hg 目录
m#\I&(l+ 1. Introduction and Basic Principles
9vQI
~rz? 1.1 Historical Development
ZU=omRh5
1.2 The Electron Mean Free Path
4jOq.j 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
X=8CZq4 1.4 Experimental Aspects
(R.l{(A 1.5 Very High Resolution
hu]l{TXi 1.6 The Theory of Photoemission
*{t]fds 1.6.1 Core-Level Photoemission
lUL6L4m 1.6.2 Valence-State Photoemission
WE-cq1) 1.6.3 Three-Step and One-Step Considerations
N(6Q`zs 1.7 Deviations from the Simple Theory of Photoemission
t",=]k References
~rUcko8 |ODi[~y 2. Core Levels and Final States
/IO<TF(X 2.1 Core-Level Binding Energies in Atoms and Molecules
I@$cw3 2.1.1 The Equivalent-Core Approximation
b"DV8fdX 2.1.2 Chemical Shifts
{Wi)/B} 2.2 Core-Level Binding Energies in Solids
$s2Y,0>I6 2.2.1 The Born-Haber Cycle in Insulators
I"=a:q 2.2.2 Theory of Binding Energies
XF6ed 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
wM-I*<L> 2.3 Core Polarization
?M}W;Z 2.4 Final-State Multiplets in Rare-Earth Valence Bands
'`)r<lYN, 2.5 Vibrational Side Bands
qZV.~F+
2.6 Core Levels of Adsorbed Molecules
q =\3jd
2.7 Quantitative Chemical Analysis from Core-Level Intensities
'%W`:K' References
d)R7#HLZ7 e5}KzFZmZ 3. Charge-Excitation Final States: Satellites
!kTI@103Wd 3.1 Copper Dihalides; 3d Transition Metal Compounds
R_vF$X'O w 3.1.1 Characterization of a Satellite
j>}<FW-N 3.1.2 Analysis of Charge-Transfer Satellites
e5s=@-[ 3.1.3 Non-local Screening
m,Fug1+N 3.2 The 6-eV Satellite in Nickel
<>Nq]WqA 3.2.1 Resonance Photoemission
7;8#iS/ 3.2.2 Satellites in Other Metals
9'My/A0 3.3 The Gunnarsson-Sch6nhammer Theory
<Z>p1S 3.4 Photoemission Signals and Narrow Bands in Metals
;VS\'#{e References
z#( `H6n: JZUf-0q 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
_Nx#)(x 4.1 Theory
?V{APM$x 4.1.1 General
f4[Bj{F 4.1.2 Core-Line Shape
J"$Y`; 4.1.3 Intrinsic Plasmons
6^+T_{gl 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
,ix> e 4.1.5 The Total Photoelectron Spectrum
3d>3f3D8; 4.2 Experimental Results
]\.3<^ 4.2.1 The Core Line Without Plasmons
Ih;I&D+e; 4.2.2 Core-Level Spectra Including Plasmoas
)HL[_WfY 4.2.3 Valence-Band Spectra of the Simple Metals
eyIbjgpV 4.2.4 Simple Metals: A General Comment
YQ`m;< 4.3 The Background Correction
UNC%<= References
sN8)p%'Lg ssx#\ 5. Valence Orbitals in Simple Molecules and Insulating Solids
uto
E}U7] 5.1 UPS Spectra of Monatomic Gases
ImG7E
w 5.2 Photoelectron Spectra of Diatomic Molecules
*}Cm/li/w 5.3 Binding Energy of the H2 Molecule
w vQ.9 5.4 Hydrides Isoelectronic with Noble Gases
gz~)v\5D/ Neon (Ne)
,K-?M5(n9 Hydrogen Fluoride (HF)
1UwpLd Water (H2O)
iiWm>yy Ammonia (NH3)
}u
`~lw(Z Methane (CH4)
{Rv0@)P$ 5.5 Spectra of the Alkali HMides
A4mnm6Tf 5.6 Transition Metal Dihalides
]iHSUP 5.7 Hydrocarbons
5/f"dX 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
+*')0I 5.7.2 Linear Polymers
LPRvzlY= 5.8 Insulating Solids with Valence d Electrons
q(nPI 5.8.1 The NiO Problem
sq;nUA= 5.8.2 Mort Insulation
@krh <T6| 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
_KSlIgQ
}0 5.8.4Band Structures of Transition Metal Compounds
{*NM~yQ 5.9 High—Temperature Superconductors
z"PU`v 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
"P9SW?', 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
9N*!C{VW 5.9.3 The Superconducting Gap
j
+u3VP 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
ySP%i6!au 5.9.5 Core—Level Shifts
#sJL"GB 5.10 The Fermi Liquid and the Luttinger Liquid
_]"uq/UWp 5.11 Adsorbed Molecules
c_Fz?R+f?K 5.11.1 Outline
*vS)aRK 5.11.2 CO on Metal Surfaces
j3$\+<m] References
!gX(Vh*k QZ?%xN(4 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
loByT
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^ 6.1 Theory of Photoemission:A Summary of the Three-Step Model
` &{ 6.2 Discussion of the Photocurrent
|-zefzD| 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
yq]/r=e!k 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
L8.u7(-# 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
U+7!Vpq 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
F*{1, gb 6.3.1 Band Structure Regime
[qHtN. 6.3.2 XPS Regime
e00s*LdC 6.3.3 Surface Emission
u[b0MNE~ 6.3.4 One-Step Calculations
Q?WgGE4> 6.4 Thermal Effects
+T*]!9%<`: 6.5 Dipole Selection Rules for Direct Optical Transitions
- D^.I References
UkzLUok]U %}ASll0uq 7.Band Structtire and Angular-Resolved Photoelectron Spectra
*If]f0?% 7.1 Free-Electron Final—State Model
3Jj 3!aDB 7.2 Methods Employing Calculated Band Structures
J,,+JoD 7.3 Methods for the Absolute Determination of the Crystal Momentum
w7"&\8a 7.3.1 Triangulation or Energy Coincidence Method
VcpN
PU6 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
%5-
7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
_]q%H ve 7.3.4 The Surface Emission Method and Electron Damping
F0 ^kUyF| 7.3.5 The Very-Low-Energy Electron Diffraction Method
v#E RXIrf 7.3.6 The Fermi Surface Method
c3X8Wi7m 7.3.7 Intensities and Their Use in Band-Structure Determinations
E*]%@6tH 7.3.8 Summary
FtmI\, 7.4 Experimental Band Structures
=qy{8MsjA 7.4.1 One- and Two-Dimensional Systems
-h1FrDBt 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Ua\<oD79] 7..4.3UPS Band Structures and XPS Density of States
c,FhI~>R 7.5 A Comment
vI1UFD
D References
l~j{i/> ;{S7bH'6m 8.Surface States, Surface Effects
z3|)WS^ 8.1 Theoretical Considerations
3lo.YLP^ 8.2 Experimental Results on Surface States
Zrm!,qs 8.3 Quantum-Well States
!dZpV~g0 8.4 Surface Core-Level Shifts
M F_VMAq References
vm4q1!!( Y&y5^nG 9.Inverse Photoelectron Spectroscopy
vgbk
{ 9.1 Surface States
UukHz}(E 9.2 Bulk Band Structures
\r^*4P,, 9.3 Adsorbed Molecules
6S6E
1~ References
t}A n: DY' 1#$; 10. Spin-Polarized Photoelectron Spectroscopy
zbyJ5~ 10.1 General Description
Yt#e[CYnu 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
y+K21(z. 10.3 Magnetic Dichroism
/Q*cyLv References
wML5T+ ^ Z~'>J 11. Photoelectron Diffraction
T*ir Ce 11.1 Examples
{H$m1=S 11.2 Substrate Photoelectron Diffraction
9G)q U 11.3 Adsorbate Photoelectron Diffraction
hY^-kdQ>M 11.4 Fermi Surface Scans
Ey* *j References
Ii4lwZnz dt=5 Pnf[y Appendix
Q?"-[6[v A.1 Table of Binding Energies
5p5S_%R$e A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
pGh A A.3 Compilation of Work Functions
Bp:i[9w References
n]]!:jFC Index