光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
!4\`g? 3%{A"^S=} 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
Eo
5p- DygMavA. 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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(g 目录
s\y+ xa: 1. Introduction and Basic Principles
!`"@! 1.1 Historical Development
A:PQIcR;V 1.2 The Electron Mean Free Path
(7^5jo[D 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
Zz}Wg@&
1.4 Experimental Aspects
*@/1]W 1.5 Very High Resolution
^kJ(bBY 1.6 The Theory of Photoemission
AdB B#zd 1.6.1 Core-Level Photoemission
p vone,y2 1.6.2 Valence-State Photoemission
)d5Hv2/0 1.6.3 Three-Step and One-Step Considerations
"#1KO1@G 1.7 Deviations from the Simple Theory of Photoemission
6-#<*Pg References
lz=$Dz "#,]`ME; 2. Core Levels and Final States
>xrO W`p] 2.1 Core-Level Binding Energies in Atoms and Molecules
<%w)EQf4m 2.1.1 The Equivalent-Core Approximation
#tX\m; 2.1.2 Chemical Shifts
4UwXrEQp 2.2 Core-Level Binding Energies in Solids
Bh3N6j+$d 2.2.1 The Born-Haber Cycle in Insulators
WqQAt{W/< 2.2.2 Theory of Binding Energies
?pSb,kN}' 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
S}L$-7Ct 2.3 Core Polarization
vEQw`OC 2.4 Final-State Multiplets in Rare-Earth Valence Bands
'YQ^K`lV 2.5 Vibrational Side Bands
r\nKJdh;ka 2.6 Core Levels of Adsorbed Molecules
u\-WArntc 2.7 Quantitative Chemical Analysis from Core-Level Intensities
|,!]]YO.V References
qyi5j0)W t6-He~ 3. Charge-Excitation Final States: Satellites
]`@= ;w 3.1 Copper Dihalides; 3d Transition Metal Compounds
}U <T>0 3.1.1 Characterization of a Satellite
G bW1Lq&" 3.1.2 Analysis of Charge-Transfer Satellites
f3 _-{<FZ 3.1.3 Non-local Screening
g-G;8x'n 3.2 The 6-eV Satellite in Nickel
Y)~Y; ;/G 3.2.1 Resonance Photoemission
$ glt%a 3.2.2 Satellites in Other Metals
9Q\CJ9 3.3 The Gunnarsson-Sch6nhammer Theory
yC%zX}5 3.4 Photoemission Signals and Narrow Bands in Metals
OYnxEdo7 References
`Wc"Ix0 d_t> 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
R#"LP7\ 4.1 Theory
VTS7K2lBvX 4.1.1 General
7Iz%Jty 4.1.2 Core-Line Shape
U`)\|\NY 4.1.3 Intrinsic Plasmons
x}^:Bs+j 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
JAt$WW{ 4.1.5 The Total Photoelectron Spectrum
V_'!# 4.2 Experimental Results
]81t~t9LQ 4.2.1 The Core Line Without Plasmons
<@F.qMl 4.2.2 Core-Level Spectra Including Plasmoas
c<k=8P 4.2.3 Valence-Band Spectra of the Simple Metals
k4n4BL 4.2.4 Simple Metals: A General Comment
)GT*HJR(vc 4.3 The Background Correction
Fx@ovI- 5 References
_cRCG1CJ 7dm:L'0 5. Valence Orbitals in Simple Molecules and Insulating Solids
<w,NMu" 5.1 UPS Spectra of Monatomic Gases
Ym% $!# 5.2 Photoelectron Spectra of Diatomic Molecules
@PQ%
xcOC7 5.3 Binding Energy of the H2 Molecule
v[7iWBqJ 5.4 Hydrides Isoelectronic with Noble Gases
lRk) Neon (Ne)
Yg<L pjq5X Hydrogen Fluoride (HF)
B|f
=hlY Water (H2O)
dCb7sqJ% Ammonia (NH3)
qsT@aSIo9 Methane (CH4)
=~D QX\ 5.5 Spectra of the Alkali HMides
hR4\:s+[ 5.6 Transition Metal Dihalides
[
pe{,lp 5.7 Hydrocarbons
@%^JB 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
%#jW 5.7.2 Linear Polymers
B,5kG{2! 5.8 Insulating Solids with Valence d Electrons
w=QlQ\ 5.8.1 The NiO Problem
& FpoMW 5.8.2 Mort Insulation
L*8U.{NY 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
ez-jVi-Fi 5.8.4Band Structures of Transition Metal Compounds
L-9AJk>V 5.9 High—Temperature Superconductors
/ucS*m:<x 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
/'l"Us},^! 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
v[2N- 5.9.3 The Superconducting Gap
A"}Ib' 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
rj
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W%wc@.P 5.10 The Fermi Liquid and the Luttinger Liquid
B'v~0Kau 5.11 Adsorbed Molecules
5-RA<d# 5.11.1 Outline
]:r(U5 # 5.11.2 CO on Metal Surfaces
nZX`y
-AZ References
Djr/!j Pr_DMu 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
JKF/z@Vbe\ 6.1 Theory of Photoemission:A Summary of the Three-Step Model
[OYSNAs*y 6.2 Discussion of the Photocurrent
^4~?]5Y\ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
xdgbs-a) 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
%D49A-R 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
@x@wo9<Fc 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
m2\[L/W] 6.3.1 Band Structure Regime
"H\R*\-0 6.3.2 XPS Regime
EEP&Y? 6.3.3 Surface Emission
pHzl/b8 6.3.4 One-Step Calculations
r@c!M|m@ 6.4 Thermal Effects
9hei8L: 6.5 Dipole Selection Rules for Direct Optical Transitions
J6mUU3F9f References
"#8I &xZK gbu*6&j9 7.Band Structtire and Angular-Resolved Photoelectron Spectra
`4,]Mr1b 7.1 Free-Electron Final—State Model
ge ]Z5E(1 7.2 Methods Employing Calculated Band Structures
ZmvtUma 7.3 Methods for the Absolute Determination of the Crystal Momentum
TMD*-wYr 7.3.1 Triangulation or Energy Coincidence Method
(@NW2 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
K_fJ{Vc>O 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
w>4( hGO 7.3.4 The Surface Emission Method and Electron Damping
gNC'kCx0c 7.3.5 The Very-Low-Energy Electron Diffraction Method
]l}bk] 7.3.6 The Fermi Surface Method
|\RN%w7E8 7.3.7 Intensities and Their Use in Band-Structure Determinations
[W99}bi$ 7.3.8 Summary
Ckhwd 7.4 Experimental Band Structures
mr,GHx 7.4.1 One- and Two-Dimensional Systems
l-2lb&n 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
S`& yVzv 7..4.3UPS Band Structures and XPS Density of States
g&\;62lV% 7.5 A Comment
3}B-n!|* References
i "aQm hVdGxT]6 8.Surface States, Surface Effects
nv3TxG 8.1 Theoretical Considerations
GL^
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+&*>FeJY 8.3 Quantum-Well States
[OFT!=.y & 8.4 Surface Core-Level Shifts
&zPM#Q References
_I%mY!x\` 5a/3nsup5 9.Inverse Photoelectron Spectroscopy
!v*#E{r"g= 9.1 Surface States
Up>,~bs] 9.2 Bulk Band Structures
LNvkC4 9.3 Adsorbed Molecules
n&8N`!^o References
{X W>3 " zu1gP/ 10. Spin-Polarized Photoelectron Spectroscopy
YGi_7fTyc= 10.1 General Description
fVZ_*'v 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
UHDcheeRD 10.3 Magnetic Dichroism
(; Zl References
eoPoGC 'v@1_HHW\ 11. Photoelectron Diffraction
&jDRRT3 11.1 Examples
ND5E`Va5R 11.2 Substrate Photoelectron Diffraction
i{PX= 11.3 Adsorbate Photoelectron Diffraction
B^hK 11.4 Fermi Surface Scans
$P&27 References
cH7D@p} !v 3wl0 Appendix
a[gN+DX%L A.1 Table of Binding Energies
q{.~=~ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
y] ~X{v A.3 Compilation of Work Functions
L^nS%lm References
ix}*whW=U Index