光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
g\,HiKBXd LZ~$=< 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
W;wu2 ' ((_v>{ 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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<0)@Ikhx 1hgmlY` 目录
5fa_L'L# 1. Introduction and Basic Principles
V0
OT _F 1.1 Historical Development
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pQ_ 1.2 The Electron Mean Free Path
eTa[~esu. 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
NvlG@^&S 1.4 Experimental Aspects
kv3jbSKCT 1.5 Very High Resolution
v~>4c<eG
1.6 The Theory of Photoemission
8/E?3a_g- 1.6.1 Core-Level Photoemission
"Mmvf'N 1.6.2 Valence-State Photoemission
rru `%~'O 1.6.3 Three-Step and One-Step Considerations
!~k-Sexh 1.7 Deviations from the Simple Theory of Photoemission
CpICb9w References
;H8A"$%n~ MA:8gD 2. Core Levels and Final States
Lv
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<)(STo 2.1.1 The Equivalent-Core Approximation
)zVD!eG_9 2.1.2 Chemical Shifts
R|AGN*. 2.2 Core-Level Binding Energies in Solids
e[8p /hId 2.2.1 The Born-Haber Cycle in Insulators
6*2z^P9FRj 2.2.2 Theory of Binding Energies
ve /Q6j{ 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
'rdg 2.3 Core Polarization
`ja**re 2.4 Final-State Multiplets in Rare-Earth Valence Bands
kST 2.5 Vibrational Side Bands
GVp2|\-L 2.6 Core Levels of Adsorbed Molecules
dKyX70Zy9 2.7 Quantitative Chemical Analysis from Core-Level Intensities
5ff66CRw References
;dYpdy 2}Q)&;u 3. Charge-Excitation Final States: Satellites
=jmn 3.1 Copper Dihalides; 3d Transition Metal Compounds
`+QrgtcEy4 3.1.1 Characterization of a Satellite
8f | 3.1.2 Analysis of Charge-Transfer Satellites
x_\e&"x 3.1.3 Non-local Screening
R('44v5JQp 3.2 The 6-eV Satellite in Nickel
A{hWFSv 3.2.1 Resonance Photoemission
_dq.hW7 3.2.2 Satellites in Other Metals
!W8'apG&[ 3.3 The Gunnarsson-Sch6nhammer Theory
2,<!l(X 3.4 Photoemission Signals and Narrow Bands in Metals
HtIM8z#/ References
A:ef}OCL p]#%e0 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
@&2bLJJ+ 4.1 Theory
z6R<*$4 4.1.1 General
R
'/Ilz` 4.1.2 Core-Line Shape
Bf F$ 4.1.3 Intrinsic Plasmons
}o?@ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
sEL[d2oO 4.1.5 The Total Photoelectron Spectrum
e p;_' 4.2 Experimental Results
:nw4K(:f 4.2.1 The Core Line Without Plasmons
?!-2G 4.2.2 Core-Level Spectra Including Plasmoas
[N925?--S 4.2.3 Valence-Band Spectra of the Simple Metals
-q\1Tlc]3 4.2.4 Simple Metals: A General Comment
VHB5 4.3 The Background Correction
>kK References
z&d&Ky 0*8[m+j1 5. Valence Orbitals in Simple Molecules and Insulating Solids
dM 7-,9Vc 5.1 UPS Spectra of Monatomic Gases
a3037~X 5.2 Photoelectron Spectra of Diatomic Molecules
r/fLm8+ 5.3 Binding Energy of the H2 Molecule
6546"sU 5.4 Hydrides Isoelectronic with Noble Gases
T.aY{Y Neon (Ne)
-pc*$oe Hydrogen Fluoride (HF)
%Sfew/"R0 Water (H2O)
X'WbS Ammonia (NH3)
K9gfS V>] Methane (CH4)
qI"@ PI!s 5.5 Spectra of the Alkali HMides
uQ{ &x6.1 5.6 Transition Metal Dihalides
Qg9 N?e{z 5.7 Hydrocarbons
s&!g ) 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
m
Fwx},dl 5.7.2 Linear Polymers
b4s.`%U 5.8 Insulating Solids with Valence d Electrons
V\WqA8 5.8.1 The NiO Problem
W[:
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`(EY/EsY 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
=x9zy] 5.8.4Band Structures of Transition Metal Compounds
<`b)56v:+ 5.9 High—Temperature Superconductors
SV}I+O_w 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
sUcx;<|BC 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
c:4M|t= 5.9.3 The Superconducting Gap
c63DuHA*C 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
zVYX#- nv 5.9.5 Core—Level Shifts
)avli@W-3j 5.10 The Fermi Liquid and the Luttinger Liquid
DnP>ed"M! 5.11 Adsorbed Molecules
J O`S 5.11.1 Outline
z'JtH^^Z 5.11.2 CO on Metal Surfaces
<MI>>$seiJ References
kc\^xq~ ]4yWcnf 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
m49GCo k+ 6.1 Theory of Photoemission:A Summary of the Three-Step Model
6+e@)[l.zc 6.2 Discussion of the Photocurrent
$3|++? 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
1p<m>s=D=e 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
I8)x0)Lx 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
(qnzz!s 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
3@*J=LGhKc 6.3.1 Band Structure Regime
lphQZ{8 6.3.2 XPS Regime
r:2G 11[ 6.3.3 Surface Emission
+HQX]t:Y
6.3.4 One-Step Calculations
(2Z-NVU# 6.4 Thermal Effects
9H$#c_zrq 6.5 Dipole Selection Rules for Direct Optical Transitions
ds,NNN<HW References
(\>3FwFHW| +;tXk
7.Band Structtire and Angular-Resolved Photoelectron Spectra
hMh8)S 7.1 Free-Electron Final—State Model
iF?4G^ 7.2 Methods Employing Calculated Band Structures
%Iw6oG 7.3 Methods for the Absolute Determination of the Crystal Momentum
_$ ]3&P 7.3.1 Triangulation or Energy Coincidence Method
;tP-#Xf 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
anjU3j 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
V<Q''%k 7.3.4 The Surface Emission Method and Electron Damping
+1~Y2 7.3.5 The Very-Low-Energy Electron Diffraction Method
0qqk:h 7.3.6 The Fermi Surface Method
k*d0ws#<l 7.3.7 Intensities and Their Use in Band-Structure Determinations
Q\z6/1:9Z 7.3.8 Summary
/qa{*"2Qo 7.4 Experimental Band Structures
Tz[ck'k 7.4.1 One- and Two-Dimensional Systems
/-)\$T1d 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
HKbyi~8N= 7..4.3UPS Band Structures and XPS Density of States
A}v!vVg 7.5 A Comment
z'Atw"kA References
U}<5%"!; 9AO`Zk{/Ez 8.Surface States, Surface Effects
zgXg-cr 8.1 Theoretical Considerations
DJvmwFx 8.2 Experimental Results on Surface States
^pruQp1X 8.3 Quantum-Well States
N"1o>
! 8.4 Surface Core-Level Shifts
S=B?bD_,c References
$(/=Wn UKV0xl
9.Inverse Photoelectron Spectroscopy
(3~h)vaJ 9.1 Surface States
}W^%5o87{ 9.2 Bulk Band Structures
],#Xa.r 9.3 Adsorbed Molecules
\9j +ejGf References
q#B=PZ'NA viB'ul7o 10. Spin-Polarized Photoelectron Spectroscopy
=jXBF. 10.1 General Description
4zyN>f| 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
$p:RnH\H1 10.3 Magnetic Dichroism
BdBwfH%: References
|LhVANz V>D8l @ 11. Photoelectron Diffraction
ybNo`:8A; 11.1 Examples
g27 iE 11.2 Substrate Photoelectron Diffraction
~(i#A> 11.3 Adsorbate Photoelectron Diffraction
}7?_> 11.4 Fermi Surface Scans
tQ =3Oa[u References
*\Z9=8yK $eHYy,, Appendix
2%4u/ A.1 Table of Binding Energies
Nz/PAs7g6 A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
w5fVug/;P A.3 Compilation of Work Functions
?='2@@8; References
!r\u,l^ Index