光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
Gu0 ,)jy\ 3251Vq % 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
0#p/A^\#7M V|D]M{O 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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'fd1Pj9~$ ts~{w;c 目录
F\JUx L@8 1. Introduction and Basic Principles
oMH.u^b]fT 1.1 Historical Development
SI:ifR&T 1.2 The Electron Mean Free Path
|UnUG 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
Q4]4@96Aj 1.4 Experimental Aspects
u'~;Y.@i' 1.5 Very High Resolution
2\D8.nQr 1.6 The Theory of Photoemission
W&Y"K)` 1.6.1 Core-Level Photoemission
{tP%epQ 1.6.2 Valence-State Photoemission
_"a=8a06G 1.6.3 Three-Step and One-Step Considerations
)u:Q)
%$t 1.7 Deviations from the Simple Theory of Photoemission
'-$XX%TOAc References
7;:#;YSha +a@GHx4- 2. Core Levels and Final States
lEjwgk { 2.1 Core-Level Binding Energies in Atoms and Molecules
?X$,fQ#F| 2.1.1 The Equivalent-Core Approximation
~`MS~,, 2.1.2 Chemical Shifts
>p\e0n 2.2 Core-Level Binding Energies in Solids
iI1n2>V3y 2.2.1 The Born-Haber Cycle in Insulators
v-j3bB 2.2.2 Theory of Binding Energies
~#K@ADYr 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
/7c~nBU 2.3 Core Polarization
}GwVKAjP 2.4 Final-State Multiplets in Rare-Earth Valence Bands
V<Z'(UI 2.5 Vibrational Side Bands
tl yJmdl 2.6 Core Levels of Adsorbed Molecules
5N$E()m$ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
1%[_`J;>Z References
IIFMYl gF j V3)2C} 3. Charge-Excitation Final States: Satellites
-Yi,_#3{ 3.1 Copper Dihalides; 3d Transition Metal Compounds
zt24qTKL 3.1.1 Characterization of a Satellite
#Il_J\# 3.1.2 Analysis of Charge-Transfer Satellites
$RX'(/ 3.1.3 Non-local Screening
Z3KO90O!8 3.2 The 6-eV Satellite in Nickel
+FG$x/\*0 3.2.1 Resonance Photoemission
:fcM:w& 3.2.2 Satellites in Other Metals
.1 )RW5|c 3.3 The Gunnarsson-Sch6nhammer Theory
Rg&-0b 3.4 Photoemission Signals and Narrow Bands in Metals
LwqC~N References
xg`h40c eP1nUy=T 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
F?+3%>/A@ 4.1 Theory
sfT+i;p 4.1.1 General
7u.|XmUz 4.1.2 Core-Line Shape
!\ND( 4.1.3 Intrinsic Plasmons
<Q< AwP 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
IV16d 4.1.5 The Total Photoelectron Spectrum
)P&9A)8 4.2 Experimental Results
nv0@xnbz 4.2.1 The Core Line Without Plasmons
.\Fss(Zn 4.2.2 Core-Level Spectra Including Plasmoas
9 ;t]Hp_+K 4.2.3 Valence-Band Spectra of the Simple Metals
Nt`b;X& 4.2.4 Simple Metals: A General Comment
\p&~,% 4.3 The Background Correction
+Lm4kA+aE5 References
"bQ[CD klOp ^w 5. Valence Orbitals in Simple Molecules and Insulating Solids
0X|_^"! 5.1 UPS Spectra of Monatomic Gases
le)DgIT>= 5.2 Photoelectron Spectra of Diatomic Molecules
b8KsR=]4I 5.3 Binding Energy of the H2 Molecule
&-l8n^ 5.4 Hydrides Isoelectronic with Noble Gases
NUJ~YWO; Neon (Ne)
hn)a@ Hydrogen Fluoride (HF)
NW9n Water (H2O)
2C^B_FUg|] Ammonia (NH3)
sd re#@n} Methane (CH4)
'XOX@UH d 5.5 Spectra of the Alkali HMides
M(q'%XL^ 5.6 Transition Metal Dihalides
^n.WZUk 5.7 Hydrocarbons
\uOdALZ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
Tpp & 5.7.2 Linear Polymers
G* b2,9&F 5.8 Insulating Solids with Valence d Electrons
A~(l{g 5.8.1 The NiO Problem
u`:hMFTID 5.8.2 Mort Insulation
=1;= 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
9%)=`W 5.8.4Band Structures of Transition Metal Compounds
"VxWj}+] 5.9 High—Temperature Superconductors
^nK7i[yF.k 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
:6kj EI 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
4\5uY 5.9.3 The Superconducting Gap
eLD?jTi' 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
.ae O}^ 5.9.5 Core—Level Shifts
(n{wg(R 5.10 The Fermi Liquid and the Luttinger Liquid
*!e(A ]& 5.11 Adsorbed Molecules
q~K(]Ya/ 5.11.1 Outline
`D5HC 5.11.2 CO on Metal Surfaces
i7[uLdQ References
]<uQ.~ AN:@fZ 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
)QiQn=Ce 6.1 Theory of Photoemission:A Summary of the Three-Step Model
K!AAGj` 6.2 Discussion of the Photocurrent
JOnyrks 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
rEZ8eeB[3 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
>XW*T5aUA 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
ra ' 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
AF,BwLN 6.3.1 Band Structure Regime
n";02?@F 6.3.2 XPS Regime
;(6g\'m 6.3.3 Surface Emission
{Z;t ^:s# 6.3.4 One-Step Calculations
#1-xw~_ 6.4 Thermal Effects
5x2Ay=s 6.5 Dipole Selection Rules for Direct Optical Transitions
[|`U6
8}u References
&:*q_$]Oz 3 *S{;p 7.Band Structtire and Angular-Resolved Photoelectron Spectra
_1Z=q.sC 7.1 Free-Electron Final—State Model
]LPQYL 7.2 Methods Employing Calculated Band Structures
v0*N)eqDGd 7.3 Methods for the Absolute Determination of the Crystal Momentum
O!1TthI 7.3.1 Triangulation or Energy Coincidence Method
(LAXM
x 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
bBxw#_3A?E 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
a)-FGP^ 7.3.4 The Surface Emission Method and Electron Damping
2Nc>6 7.3.5 The Very-Low-Energy Electron Diffraction Method
hmbj*8 7.3.6 The Fermi Surface Method
\6|/RFT 7.3.7 Intensities and Their Use in Band-Structure Determinations
^
?hA@{T/1 7.3.8 Summary
CENVp"C/` 7.4 Experimental Band Structures
JMBK{J K> 7.4.1 One- and Two-Dimensional Systems
BG2)v.CU 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
=wu*D5 7..4.3UPS Band Structures and XPS Density of States
}]P4-KqI 7.5 A Comment
]Z<_ "F References
a5'#j35 q]&.#&h 8.Surface States, Surface Effects
Wa/g`} 8.1 Theoretical Considerations
Ft{[ae?4 8.2 Experimental Results on Surface States
T".]m7! 8.3 Quantum-Well States
TTNkr` 8.4 Surface Core-Level Shifts
&(rWw Oo6 References
Nf,Z;5e i?;r7> 9.Inverse Photoelectron Spectroscopy
n_K~vD 9.1 Surface States
{-zMHVw=} 9.2 Bulk Band Structures
y k161\ 9.3 Adsorbed Molecules
FeJr\|FT References
[^H"FA[ F-Z%6O,2 10. Spin-Polarized Photoelectron Spectroscopy
JYqSL)Ta*t 10.1 General Description
}WFf''Z- 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
sE(HZR1 10.3 Magnetic Dichroism
d=.2@Ry References
i hL/n "GT4s?6O 11. Photoelectron Diffraction
9e!NOl\_;. 11.1 Examples
<T?oKOD ] 11.2 Substrate Photoelectron Diffraction
|BMV.Zi 11.3 Adsorbate Photoelectron Diffraction
pz^<\ 11.4 Fermi Surface Scans
{xcZ*m!B References
VUU]Pu &
pI`?(5iK6| Appendix
fCAiLkT,C[ A.1 Table of Binding Energies
eZhPu'id\s A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
D?jk$^p~m# A.3 Compilation of Work Functions
1a0kfM$ References
AtS;IRN@ Index