光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
1p%75VW m0(]%Kdw 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
&|8R4l C| 6_#:LFke 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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K:3u/C` K>a+-QWK3 目录
1[&V6=n 1. Introduction and Basic Principles
]g0h7q)79 1.1 Historical Development
<hA1[S} 1.2 The Electron Mean Free Path
{0t-Q k 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
w$2Z7S 1.4 Experimental Aspects
[G=+f6 a 1.5 Very High Resolution
;
wpX 1.6 The Theory of Photoemission
Q Jnji 1.6.1 Core-Level Photoemission
f'>270pH 1.6.2 Valence-State Photoemission
Pgp`g.$< 1.6.3 Three-Step and One-Step Considerations
*sPG,6> 1.7 Deviations from the Simple Theory of Photoemission
\W',g[Y: References
#F~^m 0:SR29(p1 2. Core Levels and Final States
i4XE26B;e 2.1 Core-Level Binding Energies in Atoms and Molecules
\j$q';9p 2.1.1 The Equivalent-Core Approximation
mTsl"A> 2.1.2 Chemical Shifts
VYj*LiR 2.2 Core-Level Binding Energies in Solids
`BA,_N|6 2.2.1 The Born-Haber Cycle in Insulators
Q-qM"8I 2.2.2 Theory of Binding Energies
n=+K$ R 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
k ='c*`IE 2.3 Core Polarization
6S2u%-] 2.4 Final-State Multiplets in Rare-Earth Valence Bands
l^$8;$Rq
2.5 Vibrational Side Bands
\~O}V~wE 2.6 Core Levels of Adsorbed Molecules
S=R}# 2.7 Quantitative Chemical Analysis from Core-Level Intensities
ox2?d<dC6 References
=%\y E0# >>nt3q 3. Charge-Excitation Final States: Satellites
sr*3uI-)L 3.1 Copper Dihalides; 3d Transition Metal Compounds
'0juZ~>} 3.1.1 Characterization of a Satellite
4 )U,A~! 3.1.2 Analysis of Charge-Transfer Satellites
1$]hyC/f 3.1.3 Non-local Screening
g3`:d)| 3.2 The 6-eV Satellite in Nickel
@o g&l; 3.2.1 Resonance Photoemission
A{3?G-]* 3.2.2 Satellites in Other Metals
fF"\$Ny 3.3 The Gunnarsson-Sch6nhammer Theory
+frkC| . 3.4 Photoemission Signals and Narrow Bands in Metals
f.~-31 References
?<l,a!V'6 %e71BZo~^s 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
Ca?:x tt 4.1 Theory
^Iz(V2 4.1.1 General
Eed5sm$H 4.1.2 Core-Line Shape
6]/LrM, 23 4.1.3 Intrinsic Plasmons
9AxeA2/X 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
/;[Zw8K7 4.1.5 The Total Photoelectron Spectrum
te 0a6 4.2 Experimental Results
^zv,VD 4.2.1 The Core Line Without Plasmons
OjUZ-_J 4.2.2 Core-Level Spectra Including Plasmoas
n&`=.[+A 4.2.3 Valence-Band Spectra of the Simple Metals
S"/M+m+ ] 4.2.4 Simple Metals: A General Comment
SS/9fT"[ 4.3 The Background Correction
ZE!dg^-L References
:+G1=TuXw~ :ziV3jRM 5. Valence Orbitals in Simple Molecules and Insulating Solids
$Eo)i 5.1 UPS Spectra of Monatomic Gases
7LQLeQvB 5.2 Photoelectron Spectra of Diatomic Molecules
?/SI A9VK 5.3 Binding Energy of the H2 Molecule
|BO!q9633V 5.4 Hydrides Isoelectronic with Noble Gases
f*{~N!g Neon (Ne)
YCWt%a*I' Hydrogen Fluoride (HF)
NJVAvq2E. Water (H2O)
SXA`o<Ma Ammonia (NH3)
Td7=La0
Methane (CH4)
}=+J&cR 5.5 Spectra of the Alkali HMides
} ! jk 5.6 Transition Metal Dihalides
>A+0"5+_p 5.7 Hydrocarbons
^Ia:e
?)W 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
c']3N 5.7.2 Linear Polymers
W[dK{?RB 5.8 Insulating Solids with Valence d Electrons
TT'sO[N[ 5.8.1 The NiO Problem
+E{'A7im8= 5.8.2 Mort Insulation
)_|;h2I 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
O e-FI+7 5.8.4Band Structures of Transition Metal Compounds
&Ow[ 5.9 High—Temperature Superconductors
u; c)Tt 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
E&}@P0^ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
#LGAvFA*_F 5.9.3 The Superconducting Gap
e~NEyS~3 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
O,&nCxB] 5.9.5 Core—Level Shifts
|Sne\N>% 5.10 The Fermi Liquid and the Luttinger Liquid
wNHvYulI 5.11 Adsorbed Molecules
:U,n[.$5' 5.11.1 Outline
aCq ) hR 5.11.2 CO on Metal Surfaces
wRa$b References
pCE,l'Xa ) r8yt} 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
*gq~~(jH 6.1 Theory of Photoemission:A Summary of the Three-Step Model
WSt&?+Y 6.2 Discussion of the Photocurrent
V<ZohB?y 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
tSP)'N< 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
Qh4<HQ<9 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
<"93 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
f.Uvf^T}2 6.3.1 Band Structure Regime
r+4<Lon~ 6.3.2 XPS Regime
$P9'"a)Lm 6.3.3 Surface Emission
8"f Z>XQ 6.3.4 One-Step Calculations
QoGvjf3z 6.4 Thermal Effects
s/;iZiWK 6.5 Dipole Selection Rules for Direct Optical Transitions
1ZUmMa1( References
#- l1(m 7S
+YQ$_ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
w^_[(9
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1Qc>A8SU 7.2 Methods Employing Calculated Band Structures
5uVSbo. 7.3 Methods for the Absolute Determination of the Crystal Momentum
%Sgdhgk1 7.3.1 Triangulation or Energy Coincidence Method
Kx-s95t 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
i]>)'i 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
TVk C pO,H 7.3.4 The Surface Emission Method and Electron Damping
z A ~aiX 7.3.5 The Very-Low-Energy Electron Diffraction Method
H pZD^h?L 7.3.6 The Fermi Surface Method
SuO@LroxTB 7.3.7 Intensities and Their Use in Band-Structure Determinations
3gUGfedi 7.3.8 Summary
9S.J%*F7 7.4 Experimental Band Structures
8?YWE62 7.4.1 One- and Two-Dimensional Systems
a2'si}'3 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
*!~jHy8F 7..4.3UPS Band Structures and XPS Density of States
~ AU!Gm. 7.5 A Comment
6N6}3J5 References
7U@;X~c &Z.zem?n 8.Surface States, Surface Effects
#@i1jZ 8.1 Theoretical Considerations
3M?vK(zG>P 8.2 Experimental Results on Surface States
zqDG#}3f^ 8.3 Quantum-Well States
5._=m"Pl 8.4 Surface Core-Level Shifts
da'7*
&/ References
x#-+// ZwC\n(_y 9.Inverse Photoelectron Spectroscopy
1 2Lc$\3P 9.1 Surface States
SR+<v=i 9.2 Bulk Band Structures
ls^|j%$J 9.3 Adsorbed Molecules
82EH'C References
H{XD>q. lZt{L0 10. Spin-Polarized Photoelectron Spectroscopy
`egyk)"aM 10.1 General Description
~h:/9q 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
B{In
"R8 10.3 Magnetic Dichroism
q h+c}"4m References
PB
W.nm lT<4c5% 11. Photoelectron Diffraction
^GyGh{@,f 11.1 Examples
Ykt{]# 11.2 Substrate Photoelectron Diffraction
Fz3QSr7FU 11.3 Adsorbate Photoelectron Diffraction
YgeU>I|v 11.4 Fermi Surface Scans
l'K3)yQEJ References
zUe)f~4 OYj4G?c Appendix
VSxls A.1 Table of Binding Energies
2I!L+j_ A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
Tej&1'G A.3 Compilation of Work Functions
!%1=|PX_ References
Q9[$8 Index