光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
?a/n<V ' [6(Iwz? 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
PI5j"u UO k5+]SG`]] 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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& 7QH^ k3@HI| 目录
0o&}mKe 1. Introduction and Basic Principles
#-u [$TA 1.1 Historical Development
UCqs}U8 1.2 The Electron Mean Free Path
<R1X\s. 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
Y9}8M27vQG 1.4 Experimental Aspects
L~FTr 1.5 Very High Resolution
n+2J Dq|?p 1.6 The Theory of Photoemission
|Svk^m q 1.6.1 Core-Level Photoemission
w! q& 1.6.2 Valence-State Photoemission
heD,&OX 1.6.3 Three-Step and One-Step Considerations
0|)19LR 1.7 Deviations from the Simple Theory of Photoemission
DOm-)zl{|x References
r!/0 j) iH)Nk^ 2. Core Levels and Final States
7$b?m6fmK 2.1 Core-Level Binding Energies in Atoms and Molecules
W$\X ~Q'0 2.1.1 The Equivalent-Core Approximation
K^i"9D)A 2.1.2 Chemical Shifts
M$CVQ>op: 2.2 Core-Level Binding Energies in Solids
}_4 6y*o8 2.2.1 The Born-Haber Cycle in Insulators
vrrt @y 2.2.2 Theory of Binding Energies
]O!s'lC 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
dhR(_ 2.3 Core Polarization
f?0s &Xo 2.4 Final-State Multiplets in Rare-Earth Valence Bands
j.c8}r& 2.5 Vibrational Side Bands
C%H9[%k 2.6 Core Levels of Adsorbed Molecules
c"Y!$'|Q 2.7 Quantitative Chemical Analysis from Core-Level Intensities
_dmL}t- References
Sr
y,@p) >,g5Hkmqr 3. Charge-Excitation Final States: Satellites
A_r<QYq0| 3.1 Copper Dihalides; 3d Transition Metal Compounds
-ID!pT vW 3.1.1 Characterization of a Satellite
F ! )-|n} 3.1.2 Analysis of Charge-Transfer Satellites
P%GkcV 3.1.3 Non-local Screening
_p4}<pG 3.2 The 6-eV Satellite in Nickel
zv%J=N$G 3.2.1 Resonance Photoemission
?f2G?Y 3.2.2 Satellites in Other Metals
cgNt_8qC 3.3 The Gunnarsson-Sch6nhammer Theory
X!0kK8v 3.4 Photoemission Signals and Narrow Bands in Metals
R#6H'TVE References
_.f@Y`4d 41;)-(1 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
|[w^eg 4.1 Theory
0^\/ERK 4.1.1 General
*h,3}\ 4.1.2 Core-Line Shape
#Go(tS~o 4.1.3 Intrinsic Plasmons
B82,.? 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
vo b$iS`>= 4.1.5 The Total Photoelectron Spectrum
7s]Wq6 4.2 Experimental Results
R@ QQNYU.D 4.2.1 The Core Line Without Plasmons
a@SUi~+3 4.2.2 Core-Level Spectra Including Plasmoas
(@?eLJlT 4.2.3 Valence-Band Spectra of the Simple Metals
6:RMU 4.2.4 Simple Metals: A General Comment
z_(eQP]) 4.3 The Background Correction
9A*rE.B+W References
Dm4B "8t\MKt( 5. Valence Orbitals in Simple Molecules and Insulating Solids
o4'v> b 5.1 UPS Spectra of Monatomic Gases
%AgA -pBp 5.2 Photoelectron Spectra of Diatomic Molecules
8m7eaZ 5.3 Binding Energy of the H2 Molecule
;vUxO<cKFq 5.4 Hydrides Isoelectronic with Noble Gases
0 0,9azs Neon (Ne)
D%
@KRcp^b Hydrogen Fluoride (HF)
#O6
EP#B Water (H2O)
pU DO7Q] Ammonia (NH3)
z.59]\;U> Methane (CH4)
fv5C!> t 5.5 Spectra of the Alkali HMides
,9UCb$mh 5.6 Transition Metal Dihalides
qhwoV4@f 5.7 Hydrocarbons
qp1\I$Y 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
>e_%M50 5.7.2 Linear Polymers
0:PSt_33F 5.8 Insulating Solids with Valence d Electrons
SauHFl8? 5.8.1 The NiO Problem
9mm2V ps; 5.8.2 Mort Insulation
^hysC c 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
Ge~,[If+ 5.8.4Band Structures of Transition Metal Compounds
/b+;:
z 5.9 High—Temperature Superconductors
NY 4C@@" 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
Dpj-{q7C 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
y*(_\\ 5.9.3 The Superconducting Gap
wzxdVn
'S 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
?+Hp?i$1 5.9.5 Core—Level Shifts
@4@PuWI0- 5.10 The Fermi Liquid and the Luttinger Liquid
To^#
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Y'&8L'2Z[ 5.11.1 Outline
`;}H% 5.11.2 CO on Metal Surfaces
6mAB(X^+ References
a G@nErdW !(yT7#?hP 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
i9y3PP) 6.1 Theory of Photoemission:A Summary of the Three-Step Model
86#-q7aX 6.2 Discussion of the Photocurrent
tU(y~)] 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
y,^";7U 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
])S$x{.g 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
G#'Q~N 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
+>u>`| 6.3.1 Band Structure Regime
?'Oj=k"c7 6.3.2 XPS Regime
g?gqkoI 6.3.3 Surface Emission
,FY-d$3) 6.3.4 One-Step Calculations
yz8-&4YRNd 6.4 Thermal Effects
quY " 6.5 Dipole Selection Rules for Direct Optical Transitions
^pN 5NwC5 References
k=ts&9\ }E,jR=@ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
=hPG_4# 7.1 Free-Electron Final—State Model
/Ht/F)&P 7.2 Methods Employing Calculated Band Structures
@+$cZ3, 7.3 Methods for the Absolute Determination of the Crystal Momentum
B%2L1T= 7.3.1 Triangulation or Energy Coincidence Method
D {Oq\* 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
RrKfTiK H 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
TbMdQbj} 7.3.4 The Surface Emission Method and Electron Damping
.<HC[ls 7.3.5 The Very-Low-Energy Electron Diffraction Method
f.J9) lfb 7.3.6 The Fermi Surface Method
E*OG-r 7.3.7 Intensities and Their Use in Band-Structure Determinations
})KJ60B 7.3.8 Summary
M5F(<,n; 7.4 Experimental Band Structures
|7]?>- 7.4.1 One- and Two-Dimensional Systems
hEWx. 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
wZ$tJQO 7..4.3UPS Band Structures and XPS Density of States
abL/Y23
" 7.5 A Comment
RZW$!tyI= References
amMjuyW C1KfXC*|L 8.Surface States, Surface Effects
F OeVRq:# 8.1 Theoretical Considerations
sr;:Dvx~ 8.2 Experimental Results on Surface States
;*W=c 8.3 Quantum-Well States
I88Zrhw 8.4 Surface Core-Level Shifts
m"<4\;GK References
8^8>qSD1 tCX9:2c 9.Inverse Photoelectron Spectroscopy
w2 /* `YO 9.1 Surface States
kJI3`gS+ 9.2 Bulk Band Structures
MF&3e#mdB 9.3 Adsorbed Molecules
*wViH References
zIP[R):3&U Cy<T Vk8 10. Spin-Polarized Photoelectron Spectroscopy
TH<fbd 10.1 General Description
`b#/[3 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
.F4oo = 10.3 Magnetic Dichroism
z<n"{% References
u\M4`p!g= 3\7'm] 11. Photoelectron Diffraction
yQ8M >H#J 11.1 Examples
"EN98^
Sl 11.2 Substrate Photoelectron Diffraction
3b+7^0frY# 11.3 Adsorbate Photoelectron Diffraction
ri#,ec|J 11.4 Fermi Surface Scans
e)*mC oR References
GXarUj s ZEL/Ndk Appendix
?E%U|(S)=L A.1 Table of Binding Energies
*C5:#A0 A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
{-o7w0d_ A.3 Compilation of Work Functions
y>@v>S References
+Y^-e.UO Index