光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
"Jt.lL ]5 {)
Q@c)' 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
TYJ:! 3E>frR\!I 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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m9" n4a|: j:E<p_T 目录
QAvir%Y9Q 1. Introduction and Basic Principles
VJdIHsI 1.1 Historical Development
A-4h 1.2 The Electron Mean Free Path
bzX\IrJpOZ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
t?9v^vFR 1.4 Experimental Aspects
"\}@gV#r$A 1.5 Very High Resolution
Md0sK 1.6 The Theory of Photoemission
7VMvF/ap]u 1.6.1 Core-Level Photoemission
G8r``{C! 1.6.2 Valence-State Photoemission
5m9*85Ib 1.6.3 Three-Step and One-Step Considerations
4?-.ZUT-1 1.7 Deviations from the Simple Theory of Photoemission
xZ4~Oo@@_' References
&_"]5/"( "FTfk 2. Core Levels and Final States
P@,nA41,j 2.1 Core-Level Binding Energies in Atoms and Molecules
>2,Gy-&"0 2.1.1 The Equivalent-Core Approximation
'bo~%WA]n 2.1.2 Chemical Shifts
T}"6wywM 2.2 Core-Level Binding Energies in Solids
^}:# 2.2.1 The Born-Haber Cycle in Insulators
+"8,Mh 2.2.2 Theory of Binding Energies
'g$(QvGF9 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
czm&~n6$ 2.3 Core Polarization
q-c=nkN3 2.4 Final-State Multiplets in Rare-Earth Valence Bands
~-PjW#J% 2.5 Vibrational Side Bands
\'9PZ6q{ 2.6 Core Levels of Adsorbed Molecules
gFHTG 2.7 Quantitative Chemical Analysis from Core-Level Intensities
0#ClWynjRO References
yQ^($#Yk e46/{4F, 3. Charge-Excitation Final States: Satellites
6IWxPt~ 3.1 Copper Dihalides; 3d Transition Metal Compounds
OtGb<v<_H 3.1.1 Characterization of a Satellite
'JNElXqrv 3.1.2 Analysis of Charge-Transfer Satellites
>2]JXLq 3.1.3 Non-local Screening
VY)9|JJCO 3.2 The 6-eV Satellite in Nickel
cZT({uYGL 3.2.1 Resonance Photoemission
zOGU8Wg 3.2.2 Satellites in Other Metals
RLSc+kDH_ 3.3 The Gunnarsson-Sch6nhammer Theory
#/I[Jqf 3.4 Photoemission Signals and Narrow Bands in Metals
<<i3r|} References
}S3qBQTYL ]ut5S>," 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
+reor@h 4.1 Theory
TpHfS]W-P 4.1.1 General
8HR mQ 4.1.2 Core-Line Shape
"R3d+p 4.1.3 Intrinsic Plasmons
CE"JS-S? 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
(4\d]*u5-c 4.1.5 The Total Photoelectron Spectrum
A?`jnRo=\ 4.2 Experimental Results
_L@2_#h! 4.2.1 The Core Line Without Plasmons
1}tbH[ 4.2.2 Core-Level Spectra Including Plasmoas
G 2mX; 4.2.3 Valence-Band Spectra of the Simple Metals
!}4MN:r 4.2.4 Simple Metals: A General Comment
({NAMc* 4.3 The Background Correction
04*6(L)h* References
#(1j#\ 6<$Odd 5. Valence Orbitals in Simple Molecules and Insulating Solids
Vo7dAHHL 5.1 UPS Spectra of Monatomic Gases
vmLxkjUm# 5.2 Photoelectron Spectra of Diatomic Molecules
C#H:-Q& 5.3 Binding Energy of the H2 Molecule
8,atX+tc 5.4 Hydrides Isoelectronic with Noble Gases
<}sq?Sfq! Neon (Ne)
<D::9c j Hydrogen Fluoride (HF)
E=cwq" Water (H2O)
.58qL-iC Ammonia (NH3)
I8QjKI ( Methane (CH4)
M4d47<'*~ 5.5 Spectra of the Alkali HMides
fPrLM' 5.6 Transition Metal Dihalides
r YF #^ 5.7 Hydrocarbons
j~FD{%4N 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
tOOchu?= 5.7.2 Linear Polymers
aDehqP6vf 5.8 Insulating Solids with Valence d Electrons
yB3; 5.8.1 The NiO Problem
NHl|x4Zpw 5.8.2 Mort Insulation
A.D{.a 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
2CzaL,je[ 5.8.4Band Structures of Transition Metal Compounds
TuW/N
L| 5.9 High—Temperature Superconductors
Y2O"]phi@ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
P<Zh XN' 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
Fh*j#*oe 5.9.3 The Superconducting Gap
[|lB5gi4t! 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
JICawj:I 5.9.5 Core—Level Shifts
~`D|IWMDq 5.10 The Fermi Liquid and the Luttinger Liquid
+z9gbcx 5.11 Adsorbed Molecules
vBsP+K 5.11.1 Outline
%J8|zKT5t 5.11.2 CO on Metal Surfaces
<&!v1yR References
p2N:;lXM r)T:7zy 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
<HRBMSR+ 6.1 Theory of Photoemission:A Summary of the Three-Step Model
<BW[1h1k5_ 6.2 Discussion of the Photocurrent
[j"9rO" + 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
T2D<UhP 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
9<vWcq*4 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
TI !a )X 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
*-12VIG'H 6.3.1 Band Structure Regime
fl;s9:< 6.3.2 XPS Regime
.7
asW( 6.3.3 Surface Emission
5'Q|EIL 6.3.4 One-Step Calculations
)~V4+*< 6.4 Thermal Effects
!I\!;b 6.5 Dipole Selection Rules for Direct Optical Transitions
Nk[2nyeO> References
\@>b;4Fb+N o0ZM[0@j 7.Band Structtire and Angular-Resolved Photoelectron Spectra
k/03ZxC- 7.1 Free-Electron Final—State Model
tV9LD>3 7.2 Methods Employing Calculated Band Structures
[|~2X> 7.3 Methods for the Absolute Determination of the Crystal Momentum
@
a4/ELx 7.3.1 Triangulation or Energy Coincidence Method
QaGlR`Y 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
CdUAy|!`R 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
x'zBK0i 7.3.4 The Surface Emission Method and Electron Damping
BI:k#jO! 7.3.5 The Very-Low-Energy Electron Diffraction Method
"/]| Hhc{ 7.3.6 The Fermi Surface Method
ms_ VM>l 7.3.7 Intensities and Their Use in Band-Structure Determinations
5`]UE7gT 7.3.8 Summary
dtPoo\@ 7.4 Experimental Band Structures
O,<IGO 7.4.1 One- and Two-Dimensional Systems
ZvGgmLN 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
cV-1?h63 7..4.3UPS Band Structures and XPS Density of States
hfcIvs/! 7.5 A Comment
-AYA~O(& References
cE iu)2*e E`j-6: 8.Surface States, Surface Effects
F/1#l@qN 8.1 Theoretical Considerations
Ke-)vPc 8.2 Experimental Results on Surface States
`mH %!{P 8.3 Quantum-Well States
L'i-fM[# 8.4 Surface Core-Level Shifts
[~\PQYm' References
m uW!xY B$ KwkhMe 9.Inverse Photoelectron Spectroscopy
$hR)i 9.1 Surface States
93IFcmO.H@ 9.2 Bulk Band Structures
PS
S?|Vk 9.3 Adsorbed Molecules
*[eL~oN.c References
J!ntXF 0)m8)!gj 10. Spin-Polarized Photoelectron Spectroscopy
{ m8+Wju} 10.1 General Description
<As9>5|% 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
YHV-|UNF 10.3 Magnetic Dichroism
Q/I)V2a1i References
QFPfIb/ QMo}W{D 11. Photoelectron Diffraction
qP!P
+'B 11.1 Examples
%b?$@H-Re 11.2 Substrate Photoelectron Diffraction
% p?brc 11.3 Adsorbate Photoelectron Diffraction
!}M, 11.4 Fermi Surface Scans
mgZf3?,) References
"tS'b+SJ-S /cFzotr"9 Appendix
Oq(VvS/ A.1 Table of Binding Energies
M!M!Ni A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
?RFg$Z'^ A.3 Compilation of Work Functions
vQ@2FZzu> References
<uP^-bv;( Index