光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
/sV?JV[t u{P~zyx 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
c"qPTjY 6J"(xT 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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o~k;D{Snr ;b| 目录
S?2YJl8B 1. Introduction and Basic Principles
p>&S7M/9 1.1 Historical Development
Tm\OYYyk 1.2 The Electron Mean Free Path
=R2l3-HA= 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
>+SZd7p 1.4 Experimental Aspects
NFV_+{X\ 1.5 Very High Resolution
%}ixgs7*c0 1.6 The Theory of Photoemission
Pr2;Kp 1.6.1 Core-Level Photoemission
?y46o2b*) 1.6.2 Valence-State Photoemission
WDvV
LU` 1.6.3 Three-Step and One-Step Considerations
!")WZq^` 1.7 Deviations from the Simple Theory of Photoemission
@C07k^j=U References
_6LH"o3 X+%u(>> 2. Core Levels and Final States
ivD^HhG 2.1 Core-Level Binding Energies in Atoms and Molecules
EzUPah 2.1.1 The Equivalent-Core Approximation
A-;^~I 2.1.2 Chemical Shifts
U&s(1~e\ 2.2 Core-Level Binding Energies in Solids
El+Ft.7 2.2.1 The Born-Haber Cycle in Insulators
P|8e%P 2.2.2 Theory of Binding Energies
FTbtAlqh< 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
0NrTJ R` 2.3 Core Polarization
fSr`>UpxC 2.4 Final-State Multiplets in Rare-Earth Valence Bands
xh`Du|jvm 2.5 Vibrational Side Bands
t%:G|n Sz 2.6 Core Levels of Adsorbed Molecules
-? Ejbko 2.7 Quantitative Chemical Analysis from Core-Level Intensities
5c)<'EP References
MorW\7-} "d2LyQy 3. Charge-Excitation Final States: Satellites
j37: 3.1 Copper Dihalides; 3d Transition Metal Compounds
"!^c 3.1.1 Characterization of a Satellite
^ISQ{M#_ 3.1.2 Analysis of Charge-Transfer Satellites
[{?;c+[ 3.1.3 Non-local Screening
j $KM9 3.2 The 6-eV Satellite in Nickel
$CM4&{B"i 3.2.1 Resonance Photoemission
D*qzNT@`LR 3.2.2 Satellites in Other Metals
K# /Ch5? 3.3 The Gunnarsson-Sch6nhammer Theory
$=lJG(2% 3.4 Photoemission Signals and Narrow Bands in Metals
FJW`$5? References
~%/'0}F 0T=jR{j!o 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
tgc@7 4.1 Theory
Iht@mE 4.1.1 General
]2P/G5C3tU 4.1.2 Core-Line Shape
Xa>}4j. 4.1.3 Intrinsic Plasmons
}0vtc[! 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
W;91H'`?H 4.1.5 The Total Photoelectron Spectrum
Bg5;Q) 4.2 Experimental Results
8dlInms 4.2.1 The Core Line Without Plasmons
z(#=tC| 4.2.2 Core-Level Spectra Including Plasmoas
??q!jm-m 4.2.3 Valence-Band Spectra of the Simple Metals
`9:v*KuM#R 4.2.4 Simple Metals: A General Comment
'H|;%J6d> 4.3 The Background Correction
EmF]W+!z% References
O.dux5lfBd p
FXd4* 5. Valence Orbitals in Simple Molecules and Insulating Solids
,b.kw}k 5.1 UPS Spectra of Monatomic Gases
eK\|SQb 5.2 Photoelectron Spectra of Diatomic Molecules
X
E!2Q7Q9 5.3 Binding Energy of the H2 Molecule
t;oT {Hge 5.4 Hydrides Isoelectronic with Noble Gases
on6<l Neon (Ne)
AUu5g Hydrogen Fluoride (HF)
Ja^7$WY Water (H2O)
'T6B_9GQ8 Ammonia (NH3)
IruyE(;HS Methane (CH4)
O\3r%=TF 5.5 Spectra of the Alkali HMides
-`,~9y;tx 5.6 Transition Metal Dihalides
r*c82}tc 5.7 Hydrocarbons
\YjB+[. 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
,>:XE@xcp 5.7.2 Linear Polymers
#/\pUK~km 5.8 Insulating Solids with Valence d Electrons
u=1B^V,6V 5.8.1 The NiO Problem
=%:JjgKc*t 5.8.2 Mort Insulation
$,p.=j;P 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
aB/{ %%o 5.8.4Band Structures of Transition Metal Compounds
$:xF)E 5.9 High—Temperature Superconductors
[]^PJ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
z<FV1niE 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
sj#{TTW 5.9.3 The Superconducting Gap
c1 gz#, 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
h4J{j h. 5.9.5 Core—Level Shifts
p)K9ZI 5.10 The Fermi Liquid and the Luttinger Liquid
{yGZc3e1j 5.11 Adsorbed Molecules
;bUJ+6f: 5.11.1 Outline
tn(f rccy 5.11.2 CO on Metal Surfaces
BDarJY References
?v0A/68s# wjN`EF5$}& 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
L#83f]vG 6.1 Theory of Photoemission:A Summary of the Three-Step Model
FSI]k: 6.2 Discussion of the Photocurrent
1\M"`L/ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
Vp5V
m 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
>OF:"_fh 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
& y#y>([~ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
Ah(\%35& 6.3.1 Band Structure Regime
%4QoF 6.3.2 XPS Regime
_|Y.!ZRYP 6.3.3 Surface Emission
MR^umLM88 6.3.4 One-Step Calculations
p,M3#^ q 6.4 Thermal Effects
&!H~bzg 6.5 Dipole Selection Rules for Direct Optical Transitions
>w%d'e$ References
D5o+0R ;m2"cL>{l 7.Band Structtire and Angular-Resolved Photoelectron Spectra
~(Ih~/5\^ 7.1 Free-Electron Final—State Model
8=ukS_?Vy 7.2 Methods Employing Calculated Band Structures
==PQ-Ia 7.3 Methods for the Absolute Determination of the Crystal Momentum
6qz!M 7.3.1 Triangulation or Energy Coincidence Method
?qq!%4mTB 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
jQH5$ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
X_^_r{ 7.3.4 The Surface Emission Method and Electron Damping
="'rH.n # 7.3.5 The Very-Low-Energy Electron Diffraction Method
eG[umv.9b 7.3.6 The Fermi Surface Method
~@)-qV^~ 7.3.7 Intensities and Their Use in Band-Structure Determinations
. }-@;:yh 7.3.8 Summary
f 4
Sw,A 7.4 Experimental Band Structures
es*_Oo1 7.4.1 One- and Two-Dimensional Systems
iXr`0V 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
1@1+4P0NF[ 7..4.3UPS Band Structures and XPS Density of States
^`hI00u( 7.5 A Comment
:N+K^gI) References
c_D,MW\IC cNuuzA 8.Surface States, Surface Effects
)cv0$ 8.1 Theoretical Considerations
: .FfE 8.2 Experimental Results on Surface States
'.}6]l 8.3 Quantum-Well States
Os]!B2j14 8.4 Surface Core-Level Shifts
eNlF2M References
IlC:dA D>"{H7mY 9.Inverse Photoelectron Spectroscopy
goBKr: &]w 9.1 Surface States
Nd]%ati? 9.2 Bulk Band Structures
3;-@<9 9.3 Adsorbed Molecules
qxecp2>U References
R~x;X3 D x>1y 10. Spin-Polarized Photoelectron Spectroscopy
*x#&[> 10.1 General Description
;/hH=IT 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
z9);e8ck 10.3 Magnetic Dichroism
H(DVVHx References
cfy/*| &EbD.>Ci 11. Photoelectron Diffraction
YWn6wzu%Vc 11.1 Examples
J _[e9 11.2 Substrate Photoelectron Diffraction
6\S$I5 11.3 Adsorbate Photoelectron Diffraction
R;Gl{ 11.4 Fermi Surface Scans
(x@i,Ba@ References
#%=vy\r Wj f>:\w Appendix
-Uhl9
= A.1 Table of Binding Energies
\3js} A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
tl,x@['p` A.3 Compilation of Work Functions
1>*UbV<R;u References
B3g82dm Index