光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
tq'hiS(b z~p!7q&g 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
m3P7*S5NJ7 M3]eqxLC 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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#sjGju"#_ b|kL*{; 目录
|G6'GTwZD 1. Introduction and Basic Principles
I D-I<Ev 1.1 Historical Development
xpuTh"ED 1.2 The Electron Mean Free Path
|+sAqx1IF 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
ls9Y? 1.4 Experimental Aspects
3jJV5J'" 1.5 Very High Resolution
p*YV*Arv 1.6 The Theory of Photoemission
b{-|q6 1.6.1 Core-Level Photoemission
'4~I%Z7L 1.6.2 Valence-State Photoemission
M($GZ~ b%A 1.6.3 Three-Step and One-Step Considerations
?g@X+!RB 1.7 Deviations from the Simple Theory of Photoemission
/.A"HGAk References
&%/T4$'+Y+ e F}KOOfC 2. Core Levels and Final States
DXO'MZon3 2.1 Core-Level Binding Energies in Atoms and Molecules
UEYJd&n0CB 2.1.1 The Equivalent-Core Approximation
z/QYy)_j 2.1.2 Chemical Shifts
0/7.RpX,. 2.2 Core-Level Binding Energies in Solids
/#eS3`48 2.2.1 The Born-Haber Cycle in Insulators
k_?OEkgUh 2.2.2 Theory of Binding Energies
e!w2_6?3 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
}>621L3 - 2.3 Core Polarization
En&gI`3n 2.4 Final-State Multiplets in Rare-Earth Valence Bands
7o!t/WEEq 2.5 Vibrational Side Bands
.s41Tc5u 2.6 Core Levels of Adsorbed Molecules
T4ugG?B* 2.7 Quantitative Chemical Analysis from Core-Level Intensities
>nvK{6xR: References
).e}.Z6[i` ^AOJ^@H^> 3. Charge-Excitation Final States: Satellites
4sH?85=j 3.1 Copper Dihalides; 3d Transition Metal Compounds
e8(Qx3T?b 3.1.1 Characterization of a Satellite
b~YIaD[Z 3.1.2 Analysis of Charge-Transfer Satellites
i=P}i8,^= 3.1.3 Non-local Screening
7z/O#Fbs 3.2 The 6-eV Satellite in Nickel
y
)<+?@sP 3.2.1 Resonance Photoemission
^x^(Rk}| 3.2.2 Satellites in Other Metals
_;S~nn 3.3 The Gunnarsson-Sch6nhammer Theory
fN<Y3^i" 3.4 Photoemission Signals and Narrow Bands in Metals
[4dX[ References
sP%b?6 P39oHW 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
JdWav!PYm 4.1 Theory
=kK%,Mr 4.1.1 General
.We{W{ 4.1.2 Core-Line Shape
]8Xip/uE 4.1.3 Intrinsic Plasmons
10m|? 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
>$r o\/ 4.1.5 The Total Photoelectron Spectrum
A
=&`TfXu 4.2 Experimental Results
wPcEvGBN= 4.2.1 The Core Line Without Plasmons
pY\=f0] 4.2.2 Core-Level Spectra Including Plasmoas
-2 8bJ, 4.2.3 Valence-Band Spectra of the Simple Metals
,\RR@~u' 4.2.4 Simple Metals: A General Comment
4HGS 4.3 The Background Correction
^7;s4q References
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;n}ECg # M!1W5# 5. Valence Orbitals in Simple Molecules and Insulating Solids
,]n~j-X 5.1 UPS Spectra of Monatomic Gases
pNmWBp|ER 5.2 Photoelectron Spectra of Diatomic Molecules
V 7ZGT
5.3 Binding Energy of the H2 Molecule
Y)(yw \&v 5.4 Hydrides Isoelectronic with Noble Gases
H ="I=} Neon (Ne)
I-Ut7W Hydrogen Fluoride (HF)
9 v8^uPA Water (H2O)
*uy<Om Ammonia (NH3)
PQh s^D Methane (CH4)
PqF&[M<) 5.5 Spectra of the Alkali HMides
jPZpJ: 5.6 Transition Metal Dihalides
kh#fUAt 5.7 Hydrocarbons
p:0X3?IG3 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
zf^|H%
~^ 5.7.2 Linear Polymers
fYh<S 5.8 Insulating Solids with Valence d Electrons
SN\c2^# 5.8.1 The NiO Problem
Q#K10*-O6 5.8.2 Mort Insulation
H?xYS|
n 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
2\T\p<_20 5.8.4Band Structures of Transition Metal Compounds
~$"2,& 5.9 High—Temperature Superconductors
"J+4 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
kl9~obX
1 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
]T2Nr[vu 5.9.3 The Superconducting Gap
r}D#(G$ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
6Q_A-X3hk 5.9.5 Core—Level Shifts
%&V%=-O_7 5.10 The Fermi Liquid and the Luttinger Liquid
j4]3}t0q 5.11 Adsorbed Molecules
Y#=MN~##t 5.11.1 Outline
-R\dg S3 5.11.2 CO on Metal Surfaces
5wl;fL~e References
B##X94aTT #V#!@@c;? 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
've[Mx 6.1 Theory of Photoemission:A Summary of the Three-Step Model
#reW)P> 6.2 Discussion of the Photocurrent
?N!kYTR%} 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
C4|OsC7J 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
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6.2.3 Angle-Integrated and Angle-Resolved Data Collection
~<_WYSzS 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
(hQi { 6.3.1 Band Structure Regime
4udj"-V 6.3.2 XPS Regime
rzLW@k 6.3.3 Surface Emission
j|!t3}(( 6.3.4 One-Step Calculations
kOq8zYU| 6.4 Thermal Effects
#Q*V9kvU/H 6.5 Dipole Selection Rules for Direct Optical Transitions
?A*!rW:l; References
3T4HX|rC 9
Qa_3+.B 7.Band Structtire and Angular-Resolved Photoelectron Spectra
hCd? Kti 7.1 Free-Electron Final—State Model
A=p'`]Yld 7.2 Methods Employing Calculated Band Structures
v_WQ<G? 7.3 Methods for the Absolute Determination of the Crystal Momentum
V{A`?Jl6{ 7.3.1 Triangulation or Energy Coincidence Method
SO[ u4b_"h 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
RgQs`aI 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
mdEl
CC0 7.3.4 The Surface Emission Method and Electron Damping
^w<aS
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:XG~AR/ 7.3.6 The Fermi Surface Method
R<{Vgy 7.3.7 Intensities and Their Use in Band-Structure Determinations
9|v%bO 7.3.8 Summary
uN>5Eh&=Pf 7.4 Experimental Band Structures
vZ.<OD4 7.4.1 One- and Two-Dimensional Systems
ACZK]~Y'N* 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
>!a- " 7..4.3UPS Band Structures and XPS Density of States
w-LENdw 7.5 A Comment
N@}h References
57gt"f Qx8(w"k* 8.Surface States, Surface Effects
dt+r P% 8.1 Theoretical Considerations
nb<o o:^ 8.2 Experimental Results on Surface States
;+6><O!G 8.3 Quantum-Well States
Z[ (d7 8.4 Surface Core-Level Shifts
eNVuw: Q+ References
!U1
vW}H pi/0~ke4" 9.Inverse Photoelectron Spectroscopy
G
:k'm^k 9.1 Surface States
1;V_E2?V 9.2 Bulk Band Structures
" r o'? 9.3 Adsorbed Molecules
A~<!@`NjB References
m_@XoS
yxI 0H_uxkB~ 10. Spin-Polarized Photoelectron Spectroscopy
>0<n%V#s:r 10.1 General Description
ov;^ev,( 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
Ef28 10.3 Magnetic Dichroism
g,]m8%GHE References
xdM'v{N#m #vga
qe9 11. Photoelectron Diffraction
)`R}@(r. 11.1 Examples
[3nWxFz$R 11.2 Substrate Photoelectron Diffraction
C c:<F_UI 11.3 Adsorbate Photoelectron Diffraction
dpylJ2 11.4 Fermi Surface Scans
vO~Tx References
z8JW iRn o.0tD Appendix
dM= &?g A.1 Table of Binding Energies
liH#=C8l*% A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
[xr^t1 A.3 Compilation of Work Functions
)E>yoUhN References
n-l_PhPQ` Index