光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
[!#L6&:a8 U$ElV]N 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
N
+_t-5 h2]P]@nW;W 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
'XjZ_ng ~Otoqu|
@9RM9zK.q hRCJv#]HC 市场价:¥88.00
`0gyr(fES 优惠价:¥78.60 为您节省:9.40元 (89折)
04P}-L,
,m|h<faZL F/kWHVHU[ 目录
8^1 Te m 1. Introduction and Basic Principles
YZ8>OwQz2 1.1 Historical Development
oY3;.;'bk 1.2 The Electron Mean Free Path
zL0pw'4 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
LCKV>3+_# 1.4 Experimental Aspects
L^?qOylu 1.5 Very High Resolution
%pL''R9VF 1.6 The Theory of Photoemission
Q\7h`d%) 1.6.1 Core-Level Photoemission
#r\4sVg 1.6.2 Valence-State Photoemission
0pd'93C 1.6.3 Three-Step and One-Step Considerations
"JV_ 2K_i 1.7 Deviations from the Simple Theory of Photoemission
j>" @,B g* References
*P=VFP '-XXo=>0MV 2. Core Levels and Final States
SZ'R59Ee< 2.1 Core-Level Binding Energies in Atoms and Molecules
;'@9[N9 2.1.1 The Equivalent-Core Approximation
8wFJ4v3 2.1.2 Chemical Shifts
2uW;
xfeY 2.2 Core-Level Binding Energies in Solids
#h
]g?*}OJ 2.2.1 The Born-Haber Cycle in Insulators
SO'vpz{ 2.2.2 Theory of Binding Energies
Om2d.7S 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
S|N_ o 2.3 Core Polarization
X5$ Iyis 2.4 Final-State Multiplets in Rare-Earth Valence Bands
;dgp+ 2.5 Vibrational Side Bands
7[XRd9a5( 2.6 Core Levels of Adsorbed Molecules
>}i E( 2.7 Quantitative Chemical Analysis from Core-Level Intensities
C33J5'(CA References
9qzHS~l y_-0tI\J 3. Charge-Excitation Final States: Satellites
OA;XiR$xP 3.1 Copper Dihalides; 3d Transition Metal Compounds
i<Zc"v; 3.1.1 Characterization of a Satellite
'7@zGk##( 3.1.2 Analysis of Charge-Transfer Satellites
"@0]G<H
3.1.3 Non-local Screening
7;wd(8 3.2 The 6-eV Satellite in Nickel
2pa5U;u:+ 3.2.1 Resonance Photoemission
Lk}J8 V^2 3.2.2 Satellites in Other Metals
Pu$Tk| 3.3 The Gunnarsson-Sch6nhammer Theory
=GMkR+<) 3.4 Photoemission Signals and Narrow Bands in Metals
v`Oc, References
@`- 4G2IU} >_ T-u<E 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
,w4V?>l 4.1 Theory
j'"J%e] 4.1.1 General
>!1-lfa8 4.1.2 Core-Line Shape
tFOhL9T 4.1.3 Intrinsic Plasmons
Btn]}8K 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
Z,Dl` w 4.1.5 The Total Photoelectron Spectrum
1K50Z.o&@ 4.2 Experimental Results
`7V]y- 4.2.1 The Core Line Without Plasmons
.Vvx,>>D 4.2.2 Core-Level Spectra Including Plasmoas
Ean5b>\ 4.2.3 Valence-Band Spectra of the Simple Metals
],Do6
@M- 4.2.4 Simple Metals: A General Comment
Cjlk 4.3 The Background Correction
Z o(rTCZX References
jasy<IqT!{ l}A93jSL 5. Valence Orbitals in Simple Molecules and Insulating Solids
@Qt{jI! 5.1 UPS Spectra of Monatomic Gases
6q.Uhe_B 5.2 Photoelectron Spectra of Diatomic Molecules
_
*Pf 5.3 Binding Energy of the H2 Molecule
i2SR{e8:GF 5.4 Hydrides Isoelectronic with Noble Gases
u>a5GkG. Neon (Ne)
z[qDkL Hydrogen Fluoride (HF)
oV78Hq6 Water (H2O)
$c(nF01 Ammonia (NH3)
wgGl[_) Methane (CH4)
G
mA<
g 5.5 Spectra of the Alkali HMides
TJXT-\Vk 5.6 Transition Metal Dihalides
&E5g3lf 5.7 Hydrocarbons
7a<DKB 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
ZyFjFHe+ 5.7.2 Linear Polymers
@?]RBX?a 5.8 Insulating Solids with Valence d Electrons
k!'a,R: 5.8.1 The NiO Problem
D_zZXbNc 5.8.2 Mort Insulation
$X,D( 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
8XE7]&)]; 5.8.4Band Structures of Transition Metal Compounds
_L=h0H l 5.9 High—Temperature Superconductors
YNsJZnGr8# 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
Jij*x>K>y 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
8VXH+5's 5.9.3 The Superconducting Gap
' %o#q6O 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
>(t6.= 5.9.5 Core—Level Shifts
or}[h09qA 5.10 The Fermi Liquid and the Luttinger Liquid
sdw(R#GE 5.11 Adsorbed Molecules
!%%6dB@%t 5.11.1 Outline
m^;f(IK5 5.11.2 CO on Metal Surfaces
"oO%`:pb References
3AN/
H WCixKYq 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
s|r3Gv|G 6.1 Theory of Photoemission:A Summary of the Three-Step Model
PALc;"]O 6.2 Discussion of the Photocurrent
GC}==^1 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
uJ v-4H 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
&6nWzF 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
[S!/E4>[' 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
Z4
=GMXj 6.3.1 Band Structure Regime
B:'US&6Lf' 6.3.2 XPS Regime
.U]-j\ 6.3.3 Surface Emission
^s"R$?;h 6.3.4 One-Step Calculations
ji0@P'^; 6.4 Thermal Effects
v mk2{f,g 6.5 Dipole Selection Rules for Direct Optical Transitions
ye5&)d"fa( References
.eVG:tl\ >tW#/\x{ 7.Band Structtire and Angular-Resolved Photoelectron Spectra
k\?Ii<m 7.1 Free-Electron Final—State Model
Qq|57X)P* 7.2 Methods Employing Calculated Band Structures
k~nBiV 7.3 Methods for the Absolute Determination of the Crystal Momentum
X45%e! 7.3.1 Triangulation or Energy Coincidence Method
h(EhkCf 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
m!HJj>GEo 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
vUM4S26"NT 7.3.4 The Surface Emission Method and Electron Damping
Wvf
^N( 7.3.5 The Very-Low-Energy Electron Diffraction Method
Mb~F%_ 7.3.6 The Fermi Surface Method
cSV aI 7.3.7 Intensities and Their Use in Band-Structure Determinations
Lw>N rY(Y 7.3.8 Summary
;uP:"k 7.4 Experimental Band Structures
3)ywX&4"L 7.4.1 One- and Two-Dimensional Systems
?.BC#S)q1 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
Uz]|N6` 7..4.3UPS Band Structures and XPS Density of States
H9e<v4c 7.5 A Comment
;NITc References
97!;.f- /IMFO:c 8.Surface States, Surface Effects
_I5Y"o 8.1 Theoretical Considerations
pFjK}JOF 8.2 Experimental Results on Surface States
o?\?@H 8.3 Quantum-Well States
%1+4_g9 8.4 Surface Core-Level Shifts
II,8O References
Qzw;i8n{ qlPT Ll 9.Inverse Photoelectron Spectroscopy
9XB 8VKu8 9.1 Surface States
}0Ed] 9.2 Bulk Band Structures
>~0Z& d 9.3 Adsorbed Molecules
(n_/`dP References
`<d }V2rdz X=&KayD 10. Spin-Polarized Photoelectron Spectroscopy
13x p_j 10.1 General Description
>fQMXfoY 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
h<<v^+m 10.3 Magnetic Dichroism
^^ixa1H< References
8YSAf+{FtK ab?aQ*$+ 11. Photoelectron Diffraction
4BpZJ~(p 11.1 Examples
AFwdJte9e 11.2 Substrate Photoelectron Diffraction
+mT_QsLEv 11.3 Adsorbate Photoelectron Diffraction
AH~E )S 11.4 Fermi Surface Scans
O?#7N[7 References
]Zh%DQ SXP]%{@R/ Appendix
+ami?#Sz*; A.1 Table of Binding Energies
$/Uq0U A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
H0vfUF53l A.3 Compilation of Work Functions
67FWa References
$6R-5oQ Index