光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
"MeVE#O "69s)~ 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
dRYqr}!%n Q3'llOx 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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4Z3su^XR }:zE< bK 目录
g _9C* 1. Introduction and Basic Principles
}RF(CwZr( 1.1 Historical Development
\
#F 1.2 The Electron Mean Free Path
hgG9m[?K 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
^^sE: 1.4 Experimental Aspects
G[ PtkPSJ 1.5 Very High Resolution
L(6d&t'|-R 1.6 The Theory of Photoemission
AYBns]! 1.6.1 Core-Level Photoemission
}rUN_.n4z 1.6.2 Valence-State Photoemission
)_90UwWpj 1.6.3 Three-Step and One-Step Considerations
~12EQacOT 1.7 Deviations from the Simple Theory of Photoemission
^dWa;m]l References
qz_7%c]K[ B`)BZ,#p 2. Core Levels and Final States
mY|)KJ 2.1 Core-Level Binding Energies in Atoms and Molecules
K-)]
1BG 2.1.1 The Equivalent-Core Approximation
0D.Mke ) 2.1.2 Chemical Shifts
uh0VFL*@ 2.2 Core-Level Binding Energies in Solids
,Zx0%#6 2.2.1 The Born-Haber Cycle in Insulators
l\H=m3Bg 2.2.2 Theory of Binding Energies
$S6`}3 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
RMV/&85?y 2.3 Core Polarization
ktXM|# 2.4 Final-State Multiplets in Rare-Earth Valence Bands
XX TL.. 2.5 Vibrational Side Bands
{lzWrUGO 2.6 Core Levels of Adsorbed Molecules
EU 6 oQ 2.7 Quantitative Chemical Analysis from Core-Level Intensities
Wtd/=gmiI References
&&8x%Pml Pbn*_/H 3. Charge-Excitation Final States: Satellites
%A/0 ' 3.1 Copper Dihalides; 3d Transition Metal Compounds
d'gfQlDny 3.1.1 Characterization of a Satellite
HVCe;eI 3.1.2 Analysis of Charge-Transfer Satellites
/U*C\ xMm 3.1.3 Non-local Screening
!?jrf ]
A@ 3.2 The 6-eV Satellite in Nickel
Dj?> <@ 3.2.1 Resonance Photoemission
O`kl\K*R7 3.2.2 Satellites in Other Metals
t>RY7C;PuS 3.3 The Gunnarsson-Sch6nhammer Theory
net@j#}j- 3.4 Photoemission Signals and Narrow Bands in Metals
Xu'&ynID References
jRlYU`? BwEN~2u6 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
u~:y\/Y6 4.1 Theory
y14;%aQN 4.1.1 General
|^I0dR/w: 4.1.2 Core-Line Shape
H|<[YYk 4.1.3 Intrinsic Plasmons
&ywPuTt 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
Ta0|+IYk< 4.1.5 The Total Photoelectron Spectrum
,-LwtePJ0 4.2 Experimental Results
(,\+tr8r8 4.2.1 The Core Line Without Plasmons
DPxM'7 4.2.2 Core-Level Spectra Including Plasmoas
Xl{P8L 4.2.3 Valence-Band Spectra of the Simple Metals
UhWNl]Z 4.2.4 Simple Metals: A General Comment
ZQsJL\x[UK 4.3 The Background Correction
-Cpl?Io`r5 References
x+:UN'"r \)904W5R 5. Valence Orbitals in Simple Molecules and Insulating Solids
IPKbMlV#d 5.1 UPS Spectra of Monatomic Gases
9&2O9Nz6 5.2 Photoelectron Spectra of Diatomic Molecules
]cWUZ{puRB 5.3 Binding Energy of the H2 Molecule
gfd"v 5.4 Hydrides Isoelectronic with Noble Gases
dL 1tl Neon (Ne)
u%KTNa0 Hydrogen Fluoride (HF)
~H_/zK6e Water (H2O)
ZF8 yw(z Ammonia (NH3)
}eU*(
}<^
Methane (CH4)
z,
)6"/; 5.5 Spectra of the Alkali HMides
\ZFGw&yN 5.6 Transition Metal Dihalides
<c-=3}=U\ 5.7 Hydrocarbons
jD]~ AwRJ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
H5B:;g@ 5.7.2 Linear Polymers
<?6|.\& 5.8 Insulating Solids with Valence d Electrons
wu!59pL 5.8.1 The NiO Problem
YUD`!C 5.8.2 Mort Insulation
h 8S. x) 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
6 7.+
.2 5.8.4Band Structures of Transition Metal Compounds
8 +/rlHp 5.9 High—Temperature Superconductors
bdrg(d6 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
%D34/=(X 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
[wOn|)&
& 5.9.3 The Superconducting Gap
9';JXf$ 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
ItVWO:x&v 5.9.5 Core—Level Shifts
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