光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
B0 q![ I2j;9Qcz 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
Di *+Cz;gK y%TR2CvT 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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W%Rh2l 4C01=,6ye 目录
-#gb {vj 1. Introduction and Basic Principles
8ZG'?A+{ 1.1 Historical Development
o,\%c"mC 1.2 The Electron Mean Free Path
O|y-nAZgU 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
P60 3P 1.4 Experimental Aspects
CM5A-R90 1.5 Very High Resolution
s7xRry 1.6 The Theory of Photoemission
Q=PaTh
1.6.1 Core-Level Photoemission
&p;};n 1.6.2 Valence-State Photoemission
Z(as@gjH 1.6.3 Three-Step and One-Step Considerations
D<++6HN 1.7 Deviations from the Simple Theory of Photoemission
fy_'K}i3k References
kOdS^- QwT]|
6> 2. Core Levels and Final States
5)$U<^uy 2.1 Core-Level Binding Energies in Atoms and Molecules
@/$mZ]|T 2.1.1 The Equivalent-Core Approximation
z(\H.P# 2.1.2 Chemical Shifts
MqoQs{x 2.2 Core-Level Binding Energies in Solids
<*(~x esPS 2.2.1 The Born-Haber Cycle in Insulators
/mD KQ< 2.2.2 Theory of Binding Energies
n;Iey[7_E` 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
RTY$oUqlZ 2.3 Core Polarization
!+hX$_RT 2.4 Final-State Multiplets in Rare-Earth Valence Bands
]NFDE-Jz] 2.5 Vibrational Side Bands
LG<lZ9+y 2.6 Core Levels of Adsorbed Molecules
B. P64"w 2.7 Quantitative Chemical Analysis from Core-Level Intensities
-|)[s[T~m References
qsk71L IB!Wrnj? 3. Charge-Excitation Final States: Satellites
Z,4=<;PF 3.1 Copper Dihalides; 3d Transition Metal Compounds
!@YYi[Gk 3.1.1 Characterization of a Satellite
#[KwR\b{:+ 3.1.2 Analysis of Charge-Transfer Satellites
A+F-r_]}db 3.1.3 Non-local Screening
~ml\| 3.2 The 6-eV Satellite in Nickel
gA[M 3.2.1 Resonance Photoemission
e0$mu?wd- 3.2.2 Satellites in Other Metals
xrX("ili 3.3 The Gunnarsson-Sch6nhammer Theory
so8-e 3.4 Photoemission Signals and Narrow Bands in Metals
.<NXk"\!y References
"V^jAPDXb XdS<51 C 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
YKx0Zs 4.1 Theory
H~G=0_S 4.1.1 General
F_r eBPx 4.1.2 Core-Line Shape
kcOpO<oE 4.1.3 Intrinsic Plasmons
^|K*lI/ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
ffB]4 4.1.5 The Total Photoelectron Spectrum
GecXM Aa:2 4.2 Experimental Results
&&y@/<t 4.2.1 The Core Line Without Plasmons
>b$<lo 4.2.2 Core-Level Spectra Including Plasmoas
dY|jV}%T 4.2.3 Valence-Band Spectra of the Simple Metals
&qpA<F@7 4.2.4 Simple Metals: A General Comment
KJ#c(yb9zR 4.3 The Background Correction
|n|2)hC References
VuBp$H(U 785iY865 5. Valence Orbitals in Simple Molecules and Insulating Solids
-qEr-[z 5.1 UPS Spectra of Monatomic Gases
l2v}PALs 5.2 Photoelectron Spectra of Diatomic Molecules
C`#N
Q*O 5.3 Binding Energy of the H2 Molecule
6,h<0j{ 5.4 Hydrides Isoelectronic with Noble Gases
/vV 0$vg Neon (Ne)
B~ez>/H^ Hydrogen Fluoride (HF)
.F6#s Water (H2O)
5;Z~+$1 Ammonia (NH3)
}dR*bG Methane (CH4)
ri^yal<' 5.5 Spectra of the Alkali HMides
LgnGqIlx 5.6 Transition Metal Dihalides
~k%\ LZ3s 5.7 Hydrocarbons
0x &^{P~ 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
PaZYs~EO
5.7.2 Linear Polymers
Iymz2 5.8 Insulating Solids with Valence d Electrons
#Nd+X@j 5.8.1 The NiO Problem
C,]Ec2 5.8.2 Mort Insulation
'
#mC4\<W8 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
z[rB/|2 5.8.4Band Structures of Transition Metal Compounds
(BGipX4 5.9 High—Temperature Superconductors
lm\u(3_$ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
,]Ma, 2 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
yh)q96m-V= 5.9.3 The Superconducting Gap
\'KzSkC8 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
? c+; 5.9.5 Core—Level Shifts
6GN'rVr!Z 5.10 The Fermi Liquid and the Luttinger Liquid
')aYkO{%sb 5.11 Adsorbed Molecules
{HU48v"W 5.11.1 Outline
=3:ltI.'*I 5.11.2 CO on Metal Surfaces
PA/6l"-`3 References
1%+^SR72 DI RCP=5 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
!v`=EF. 6.1 Theory of Photoemission:A Summary of the Three-Step Model
IviWS84 6.2 Discussion of the Photocurrent
LQjqwsuN{ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
)/JC.d# 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
;1 fM L,8 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
'yNp J' 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
pDLo`F}A 6.3.1 Band Structure Regime
9T1G/0k- 6.3.2 XPS Regime
}VGiT~2$ 6.3.3 Surface Emission
1}pR')YL[ 6.3.4 One-Step Calculations
.<B1i 6.4 Thermal Effects
qrkT7f 6.5 Dipole Selection Rules for Direct Optical Transitions
i&$uG[&P References
8f.La
ZS+2.)A 7.Band Structtire and Angular-Resolved Photoelectron Spectra
1rEP)66N 7.1 Free-Electron Final—State Model
{V8Pn2mlo 7.2 Methods Employing Calculated Band Structures
?2TH("hV$ 7.3 Methods for the Absolute Determination of the Crystal Momentum
bqO"k t 7.3.1 Triangulation or Energy Coincidence Method
SD&[K
8-i2 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
t/Fe"T[,V 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
"ir*;| 7.3.4 The Surface Emission Method and Electron Damping
D|o@(V 7.3.5 The Very-Low-Energy Electron Diffraction Method
NP8TF*5V 7.3.6 The Fermi Surface Method
PwW @I~@> 7.3.7 Intensities and Their Use in Band-Structure Determinations
qAS^5|(b[ 7.3.8 Summary
1N+#(<x@, 7.4 Experimental Band Structures
m
C Ge*V} 7.4.1 One- and Two-Dimensional Systems
Nz;;X\GI 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
YYHm0pc 7..4.3UPS Band Structures and XPS Density of States
Q\76jD`m\ 7.5 A Comment
P]B#i1 References
ho1F8TG= w%;'uN_ 8.Surface States, Surface Effects
>gl.(b25C 8.1 Theoretical Considerations
(4LLTf0 8.2 Experimental Results on Surface States
Pcs@`&}7r 8.3 Quantum-Well States
V1.F`3h~ 8.4 Surface Core-Level Shifts
B]7jg9/ References
jGn^<T\ ^&iV