光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
'd|!Hr<2 ,c-*/{3 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
A0Q`Aqs >& 4) : 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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&Z3%UOY 目录
4x<H=CJC 1. Introduction and Basic Principles
q{_ f" 1.1 Historical Development
=''WA:,=h 1.2 The Electron Mean Free Path
c&P/v#U_ 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
k&uh 1.4 Experimental Aspects
5rf Dm 1.5 Very High Resolution
5}Id[%.x 1.6 The Theory of Photoemission
*~YdL7f)J 1.6.1 Core-Level Photoemission
\#]C !JQ 1.6.2 Valence-State Photoemission
<Y6zJ#BD 1.6.3 Three-Step and One-Step Considerations
$P#x>#+[A 1.7 Deviations from the Simple Theory of Photoemission
$f _C~O References
4JU 2x 1Jdx#K 2. Core Levels and Final States
~-[!>1!% 2.1 Core-Level Binding Energies in Atoms and Molecules
F:d2; 2.1.1 The Equivalent-Core Approximation
,(Ol]W} 2.1.2 Chemical Shifts
UmvnVmnv 2.2 Core-Level Binding Energies in Solids
gaxM# 2.2.1 The Born-Haber Cycle in Insulators
xJAQ'ANr 2.2.2 Theory of Binding Energies
XI|k,Ko< 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
8V}|(b# 2.3 Core Polarization
$U.| 2.4 Final-State Multiplets in Rare-Earth Valence Bands
D/Ok 2.5 Vibrational Side Bands
.%)uCLZr$ 2.6 Core Levels of Adsorbed Molecules
@87Y/_l 2.7 Quantitative Chemical Analysis from Core-Level Intensities
\q*-9_M References
7y3WV95Z\ \+nV~Pi"A 3. Charge-Excitation Final States: Satellites
$./aKJ1B 3.1 Copper Dihalides; 3d Transition Metal Compounds
/V{UTMSz 3.1.1 Characterization of a Satellite
[|YvVA 3.1.2 Analysis of Charge-Transfer Satellites
M]p-<R\ 3.1.3 Non-local Screening
PVH Or^ 3.2 The 6-eV Satellite in Nickel
c_S~{a44Ud 3.2.1 Resonance Photoemission
|U;O HS 3.2.2 Satellites in Other Metals
{Q37a=;, 3.3 The Gunnarsson-Sch6nhammer Theory
j5Da53c#^ 3.4 Photoemission Signals and Narrow Bands in Metals
9PA<g3z References
7l$
u.[ LEeA ,Y 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
49M1^nMvoo 4.1 Theory
~-6_-Y| 4.1.1 General
SepwMB4@ 4.1.2 Core-Line Shape
n[gE[kw 4.1.3 Intrinsic Plasmons
EpNN!s=Q 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
,b&hLht 4.1.5 The Total Photoelectron Spectrum
$/C1s"C@O 4.2 Experimental Results
.MG83Si 4.2.1 The Core Line Without Plasmons
&z1U0uk 4.2.2 Core-Level Spectra Including Plasmoas
[tof+0Y6 4.2.3 Valence-Band Spectra of the Simple Metals
5 ,-8oEUL 4.2.4 Simple Metals: A General Comment
O^=+"O] 4.3 The Background Correction
D-LOjMe References
hHmm(~5gR tm5)x^7 5. Valence Orbitals in Simple Molecules and Insulating Solids
\u{4=-C. 5.1 UPS Spectra of Monatomic Gases
.l_Nf9= 5.2 Photoelectron Spectra of Diatomic Molecules
xl`AiO `K 5.3 Binding Energy of the H2 Molecule
]"HaE-`% 5.4 Hydrides Isoelectronic with Noble Gases
wpYk`Lr Neon (Ne)
,>rvl P Hydrogen Fluoride (HF)
; veD?| Water (H2O)
7`;f<QNo Ammonia (NH3)
mN}szW, Methane (CH4)
j\IdB:}j 5.5 Spectra of the Alkali HMides
nOL.% 5.6 Transition Metal Dihalides
cZ?$_;= 5.7 Hydrocarbons
{Ba& 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
PIa!NPy 5.7.2 Linear Polymers
V=*^C+6s 5.8 Insulating Solids with Valence d Electrons
<^Vj1s 5.8.1 The NiO Problem
Znb7OF^#" 5.8.2 Mort Insulation
|xcI~ X7Q 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
GW;%~qH[, 5.8.4Band Structures of Transition Metal Compounds
PjEJC@n 5.9 High—Temperature Superconductors
G2kU_ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
[Cv./hEQi 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
rX?ZUw?u& 5.9.3 The Superconducting Gap
g?v(>#i 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
#l4T/`u'9! 5.9.5 Core—Level Shifts
$~.YB\3 5.10 The Fermi Liquid and the Luttinger Liquid
9D1WUUa 5.11 Adsorbed Molecules
|K Rt$t 5.11.1 Outline
C$6FI`J 5.11.2 CO on Metal Surfaces
T9Q3I References
aqI"4v]~b T8z?_ *k 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
w'(/dr 6.1 Theory of Photoemission:A Summary of the Three-Step Model
/9G72AD! 6.2 Discussion of the Photocurrent
!Yb !Au[ 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
f;
|fS~ 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
{:uv}4 Z 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
I*
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|{YN3"qN 6.3.1 Band Structure Regime
D;V[9E=g/ 6.3.2 XPS Regime
1B2#uhT]r 6.3.3 Surface Emission
ZAgXz{!H( 6.3.4 One-Step Calculations
$!.>)n 6.4 Thermal Effects
@!f4>iUy 6.5 Dipole Selection Rules for Direct Optical Transitions
hOAZvrfQ4 References
YkWHI(p @h{|tP%" 7.Band Structtire and Angular-Resolved Photoelectron Spectra
(4L/I 7.1 Free-Electron Final—State Model
|cma7q}p 7.2 Methods Employing Calculated Band Structures
zW%Em81Wd 7.3 Methods for the Absolute Determination of the Crystal Momentum
0wv#AT 7.3.1 Triangulation or Energy Coincidence Method
Z*co\ pW 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
[UzD3VPg 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
VjM3M<!g>M 7.3.4 The Surface Emission Method and Electron Damping
'/.Dxib 7.3.5 The Very-Low-Energy Electron Diffraction Method
):! =XhQ 7.3.6 The Fermi Surface Method
v&YeQC> 7.3.7 Intensities and Their Use in Band-Structure Determinations
]WDmx$"&e 7.3.8 Summary
>5~#BrpwG 7.4 Experimental Band Structures
$gBQ5Wd 7.4.1 One- and Two-Dimensional Systems
?ZRF]\dP] 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
+;q\7* 7..4.3UPS Band Structures and XPS Density of States
#_ |B6!D! 7.5 A Comment
4@?0wV References
#,d~t sg
$db62> 8.Surface States, Surface Effects
E?XaU~cpc 8.1 Theoretical Considerations
Q[j| 2U 8.2 Experimental Results on Surface States
I$xZV?d. 8.3 Quantum-Well States
f)/Z7*Z 8.4 Surface Core-Level Shifts
neI7VbH4 References
9Lb96K?=> ~:z.Xu5m 9.Inverse Photoelectron Spectroscopy
|NfFe*q0;8 9.1 Surface States
'V:Q : 9.2 Bulk Band Structures
y d97ys 9.3 Adsorbed Molecules
-XV,r<'' References
^ F]hW u-TT;k' 10. Spin-Polarized Photoelectron Spectroscopy
j~qm$ 'H 10.1 General Description
o]e,5] 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
wGArR7r 10.3 Magnetic Dichroism
|RiJ>/MK\ References
;?2)[a 6ZQ |L=Ytp 11. Photoelectron Diffraction
fc9;ZX7 11.1 Examples
O^@8Drgc 11.2 Substrate Photoelectron Diffraction
p'/\eBhG]= 11.3 Adsorbate Photoelectron Diffraction
Y.viOHL 11.4 Fermi Surface Scans
C Bkoky9& References
Zo3!Hs ZA ANhtz1Fl Appendix
]nTeTW A.1 Table of Binding Energies
h&<"jCjL A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
MgJ6{xzz A.3 Compilation of Work Functions
U6]#RxH References
XNYA\%:5S Index