光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
iY'hkr w $)7f%II 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
U1|4vd9 gwz _b 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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,h`D(,?X nW%=k!'' 目录
U`p<lxRgQ 1. Introduction and Basic Principles
>~>[}d;glw 1.1 Historical Development
2b,TkG8K 1.2 The Electron Mean Free Path
>,Bu^] C 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
7%!KAtc 1.4 Experimental Aspects
Kcdd=2 [T 1.5 Very High Resolution
6ch[B`[h, 1.6 The Theory of Photoemission
KdpJ[[Ug/ 1.6.1 Core-Level Photoemission
'|?r&-5 h 1.6.2 Valence-State Photoemission
km^+
mK 1.6.3 Three-Step and One-Step Considerations
,VsCRp 1.7 Deviations from the Simple Theory of Photoemission
BD#;3?| References
L^s;kkB +`3ZH9 2. Core Levels and Final States
~(]DNXB8I` 2.1 Core-Level Binding Energies in Atoms and Molecules
IEf^.Z 2.1.1 The Equivalent-Core Approximation
(
+hI 2.1.2 Chemical Shifts
G.e\#_RR? 2.2 Core-Level Binding Energies in Solids
vkgL"([_ 2.2.1 The Born-Haber Cycle in Insulators
*bSG48W(" 2.2.2 Theory of Binding Energies
[E7@W[xr 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
*{s[$}uQ 2.3 Core Polarization
B[X6AQj}d 2.4 Final-State Multiplets in Rare-Earth Valence Bands
s7}
)4.vO 2.5 Vibrational Side Bands
'Pu;]sC 2.6 Core Levels of Adsorbed Molecules
MA6%g} o 2.7 Quantitative Chemical Analysis from Core-Level Intensities
K(<P" g( References
2Hwf:S' 8!>pFVNJf 3. Charge-Excitation Final States: Satellites
R\amcQ
9 3.1 Copper Dihalides; 3d Transition Metal Compounds
xyz86r ^u 3.1.1 Characterization of a Satellite
^D[;JV 3.1.2 Analysis of Charge-Transfer Satellites
*60)Vo.= 3.1.3 Non-local Screening
<);u]0 3.2 The 6-eV Satellite in Nickel
r1atyK 3.2.1 Resonance Photoemission
9ksrr{tW 3.2.2 Satellites in Other Metals
lGhUfhk 3.3 The Gunnarsson-Sch6nhammer Theory
K_3ZJ 3.4 Photoemission Signals and Narrow Bands in Metals
2]ljm]\l References
?%ntO] qJj5J;k 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
)~(_[=' 4.1 Theory
P@?CQvMx 4.1.1 General
`BD`pa7.% 4.1.2 Core-Line Shape
kyB]fmS 4.1.3 Intrinsic Plasmons
?0Zw ^a 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
mIodD)?{ 4.1.5 The Total Photoelectron Spectrum
{'kL]qLg 4.2 Experimental Results
i`L66uV 4.2.1 The Core Line Without Plasmons
i( HhL& 4.2.2 Core-Level Spectra Including Plasmoas
Cz)D3Df^ 4.2.3 Valence-Band Spectra of the Simple Metals
Y))sk- 4.2.4 Simple Metals: A General Comment
.R5z>:A 4.3 The Background Correction
+ETw:i9!? References
xRN$cZC V485Yn!$( 5. Valence Orbitals in Simple Molecules and Insulating Solids
S5TT 5.1 UPS Spectra of Monatomic Gases
JN)t'm[kyE 5.2 Photoelectron Spectra of Diatomic Molecules
'L/TaP/3 5.3 Binding Energy of the H2 Molecule
-<=<T@, 5.4 Hydrides Isoelectronic with Noble Gases
N> Y3[G+ Neon (Ne)
PQr
N";+ Hydrogen Fluoride (HF)
-NeF6 Water (H2O)
UUq9UV-h Ammonia (NH3)
+%v4Ci"%y Methane (CH4)
c 3dZ1v 5.5 Spectra of the Alkali HMides
qW^l2Jff 5.6 Transition Metal Dihalides
hd-ds~ve 5.7 Hydrocarbons
0=&]!WRT 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
H(s^le:! 5.7.2 Linear Polymers
Qafg/JU 5.8 Insulating Solids with Valence d Electrons
N0PX<$y 5.8.1 The NiO Problem
*
=l9gv& 5.8.2 Mort Insulation
[^f`D%8o 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
r%i{a 5.8.4Band Structures of Transition Metal Compounds
[bXZPIz;j 5.9 High—Temperature Superconductors
LlJvuQ 28 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
WAbhBA 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
jtwO\6 t& 5.9.3 The Superconducting Gap
NQ!F` 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
o++Hdvai 5.9.5 Core—Level Shifts
Op{Mc$5a 5.10 The Fermi Liquid and the Luttinger Liquid
=fPO0Ot; 5.11 Adsorbed Molecules
oP6G2@3P/ 5.11.1 Outline
IYPLitT 5.11.2 CO on Metal Surfaces
-(EqBr@_ References
{w++)N2sh O{V"'o 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
-j,o:ng0 6.1 Theory of Photoemission:A Summary of the Three-Step Model
f
WXzK< 6.2 Discussion of the Photocurrent
y6oDbwke 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
_?"J.i 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
Y'T#
6.2.3 Angle-Integrated and Angle-Resolved Data Collection
5Fl|=G+3@g 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
y(A"g3^= 6.3.1 Band Structure Regime
W +E2({ 6.3.2 XPS Regime
5`Bb0=j 6.3.3 Surface Emission
p:jrqjLp 6.3.4 One-Step Calculations
`g~-5Z~J 6.4 Thermal Effects
ZSNg^)cN 6.5 Dipole Selection Rules for Direct Optical Transitions
<#-ERQw References
I
f(_$> By9/tB 7.Band Structtire and Angular-Resolved Photoelectron Spectra
Sy_M!`B 7.1 Free-Electron Final—State Model
*QX$Mo^E 7.2 Methods Employing Calculated Band Structures
?kSs7e> 7.3 Methods for the Absolute Determination of the Crystal Momentum
]{hfM 7.3.1 Triangulation or Energy Coincidence Method
xjYFTb}! 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
?m6E@.{ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
EA\~m*k 7.3.4 The Surface Emission Method and Electron Damping
w'!gLta 7.3.5 The Very-Low-Energy Electron Diffraction Method
fu/c)D6u*m 7.3.6 The Fermi Surface Method
yT4|eHl 7.3.7 Intensities and Their Use in Band-Structure Determinations
!`gg$9 7.3.8 Summary
! [X<> 7.4 Experimental Band Structures
oaHBz_pg 7.4.1 One- and Two-Dimensional Systems
`W9_LROD 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
=ZQIpc 7..4.3UPS Band Structures and XPS Density of States
rZEu@63 7.5 A Comment
.o>QBYpTw/ References
'&Ku Ba Z&%61jGK 8.Surface States, Surface Effects
])`F$S 8.1 Theoretical Considerations
5>HI/QG 8.2 Experimental Results on Surface States
FD<~?- 8.3 Quantum-Well States
d={}a,3? 8.4 Surface Core-Level Shifts
Z+?j8(:n References
G4i&:0 M@8(h= 9.Inverse Photoelectron Spectroscopy
}7V/(K 9.1 Surface States
Buo1o&& 9.2 Bulk Band Structures
Q7C'O @ 9.3 Adsorbed Molecules
__QTlj
References
nT>?}/S ~LVa# 10. Spin-Polarized Photoelectron Spectroscopy
3eB2=_V` 10.1 General Description
y&
)z\8 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
C}!|K0t? 10.3 Magnetic Dichroism
7G/"!ePW6` References
-+L1Hid.7 4&\m!s
11. Photoelectron Diffraction
#&2mu 11.1 Examples
*/1z=
11.2 Substrate Photoelectron Diffraction
4l|Am3vzX 11.3 Adsorbate Photoelectron Diffraction
V{n pK( 11.4 Fermi Surface Scans
+RbCa
c References
gnv4.f: u*M*WpY Appendix
~&pk</Dl A.1 Table of Binding Energies
a}wB7B;,g A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
yY1&hop A.3 Compilation of Work Functions
3Ry?{m^ References
I=1tf;Bsi Index