光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
|4s`;4c& uk~4R@=&H 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
r*!sA5 RuHMD" 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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:}Tw+S5 1wpeYn7>W 目录
$MEKt}S 1. Introduction and Basic Principles
d
M&BnI 1.1 Historical Development
007SA6xq 1.2 The Electron Mean Free Path
0=r.I}x 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
\e/'d~F 1.4 Experimental Aspects
4S]`S\w 1.5 Very High Resolution
;O2r+n 1.6 The Theory of Photoemission
e'c~;Z\A 1.6.1 Core-Level Photoemission
#Pz},!7 1.6.2 Valence-State Photoemission
,afh]# 1.6.3 Three-Step and One-Step Considerations
3P!Jw7e 1.7 Deviations from the Simple Theory of Photoemission
5]&vs!wH References
qd B@P O0{M3- 2. Core Levels and Final States
|"Js iT 2.1 Core-Level Binding Energies in Atoms and Molecules
~$N%UQn?b# 2.1.1 The Equivalent-Core Approximation
D 5q Cn^R 2.1.2 Chemical Shifts
c D+IMlT 2.2 Core-Level Binding Energies in Solids
!S[8w9q 2.2.1 The Born-Haber Cycle in Insulators
%/:{x()G
2.2.2 Theory of Binding Energies
J@y1L]: 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
T6|zT}cb 2.3 Core Polarization
!TRJsL8 2.4 Final-State Multiplets in Rare-Earth Valence Bands
Uu9\;f 2.5 Vibrational Side Bands
V=}b>Jo2j 2.6 Core Levels of Adsorbed Molecules
`um#}ify# 2.7 Quantitative Chemical Analysis from Core-Level Intensities
PX3rHKK{ References
dE*n!@ X$zlR)Re 3. Charge-Excitation Final States: Satellites
Nkt(1?:-' 3.1 Copper Dihalides; 3d Transition Metal Compounds
Ch`XwLY9 3.1.1 Characterization of a Satellite
)~<8j 3.1.2 Analysis of Charge-Transfer Satellites
'Pudy\Ab 3.1.3 Non-local Screening
iNR6BP
W 3.2 The 6-eV Satellite in Nickel
i6zfr|`@ 3.2.1 Resonance Photoemission
)z9)oM\ 3.2.2 Satellites in Other Metals
A-O@e
e 3.3 The Gunnarsson-Sch6nhammer Theory
Ctxs]S tU% 3.4 Photoemission Signals and Narrow Bands in Metals
c,1Yxg]| References
M$z.S0" <@}~Fp@ 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
(z0S5#g
,x 4.1 Theory
0+0+%#? 4.1.1 General
DKCPi 0 4.1.2 Core-Line Shape
s% "MaDz 4.1.3 Intrinsic Plasmons
A
e&t#,) 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
E8WOXoP( 4.1.5 The Total Photoelectron Spectrum
yVm~5Y&Z 4.2 Experimental Results
rS>JzbWa 4.2.1 The Core Line Without Plasmons
\cdNyVY 4.2.2 Core-Level Spectra Including Plasmoas
)eNR4nF 4.2.3 Valence-Band Spectra of the Simple Metals
y88FT#hR|5 4.2.4 Simple Metals: A General Comment
^o]ZDc 4.3 The Background Correction
T^8t<S@` References
{T
Z7>k wAxXK94#3 5. Valence Orbitals in Simple Molecules and Insulating Solids
f0fN1 5.1 UPS Spectra of Monatomic Gases
z!5^UD8"W 5.2 Photoelectron Spectra of Diatomic Molecules
vBUx)l 5.3 Binding Energy of the H2 Molecule
{Q[{H'Oa 5.4 Hydrides Isoelectronic with Noble Gases
u=feR0|8 Neon (Ne)
>[=q9k Hydrogen Fluoride (HF)
G}CzeLw Water (H2O)
ow*) 1eo Ammonia (NH3)
w{Wz^=';
Methane (CH4)
6)m}e?D> 5.5 Spectra of the Alkali HMides
w1/pwzn 5.6 Transition Metal Dihalides
h8oG5|Y 5.7 Hydrocarbons
!CROc} 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
l [?o du4 5.7.2 Linear Polymers
j0!Z 20 5.8 Insulating Solids with Valence d Electrons
[Z|R-{" 5.8.1 The NiO Problem
gvO}u 2.: 5.8.2 Mort Insulation
v`MCV29!} 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
*D1^Se 5.8.4Band Structures of Transition Metal Compounds
_rXTHo7P 5.9 High—Temperature Superconductors
Mxn>WCPo 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
}3F8[Td.~N 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
wp`a:QZ8N 5.9.3 The Superconducting Gap
kt.z,<w5O 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
+~\1Zgw 5.9.5 Core—Level Shifts
^ElUU ?rX 5.10 The Fermi Liquid and the Luttinger Liquid
Mo|[Muj8b 5.11 Adsorbed Molecules
d0~F|j\# 5.11.1 Outline
W[[3'J TF 5.11.2 CO on Metal Surfaces
sPn[FuT>+s References
'5.n28W> "qUUH4mR` 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
|GtTz& 6.1 Theory of Photoemission:A Summary of the Three-Step Model
t\E#8 6.2 Discussion of the Photocurrent
x):cirwkl 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
jKZJ0`06q 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
uPc}a3'? 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
r7/y'Y]O 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
-l<b|`s=w. 6.3.1 Band Structure Regime
C
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C1^=se 6.3.3 Surface Emission
e )l<D) 6.3.4 One-Step Calculations
tM]~^U 6.4 Thermal Effects
qc\]~]H]r 6.5 Dipole Selection Rules for Direct Optical Transitions
okJ+Yl.[?7 References
m!5P5U
x z=B*s!G 7.Band Structtire and Angular-Resolved Photoelectron Spectra
.ml24SeC 7.1 Free-Electron Final—State Model
S\K;h/;V 7.2 Methods Employing Calculated Band Structures
m8;;
O 7.3 Methods for the Absolute Determination of the Crystal Momentum
-hw^3Af 7.3.1 Triangulation or Energy Coincidence Method
MW8GM }Ho[ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
9 o6ig>C 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
nS)U+q-x&o 7.3.4 The Surface Emission Method and Electron Damping
JsI`# 7.3.5 The Very-Low-Energy Electron Diffraction Method
6/Y3#d 7.3.6 The Fermi Surface Method
HtB>#`' 7.3.7 Intensities and Their Use in Band-Structure Determinations
Hj't.lg+j 7.3.8 Summary
p9Zi}!
7.4 Experimental Band Structures
)WavG1 7.4.1 One- and Two-Dimensional Systems
;rYL\`6L 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
/"?yB$s 7..4.3UPS Band Structures and XPS Density of States
}.ZX.qYX 7.5 A Comment
#qY`xH'> References
UXwnE@`F 9`Bmop 8.Surface States, Surface Effects
.6aC2A]es 8.1 Theoretical Considerations
@igr~hJ 8.2 Experimental Results on Surface States
<dl:';@a- 8.3 Quantum-Well States
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