光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
_/w-gL{ q-)_Qco 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
a_fW{;}[ ;cHI3V 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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{zN_l! S/:QVs 目录
.nY6[2am 1. Introduction and Basic Principles
5qB=@O]|G; 1.1 Historical Development
I!0+RP( 1.2 The Electron Mean Free Path
}c#/1J7 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
vgp%;-p( 1.4 Experimental Aspects
/F9lW}pd 1.5 Very High Resolution
U\GZ
1.6 The Theory of Photoemission
%[CM;|?B4 1.6.1 Core-Level Photoemission
*t*&Q /W 1.6.2 Valence-State Photoemission
< 3+&DV-<N 1.6.3 Three-Step and One-Step Considerations
DT]p14@t9 1.7 Deviations from the Simple Theory of Photoemission
|Ie`L(" References
m-FDCiN> 2}C>{*}yQ 2. Core Levels and Final States
->9xw 2.1 Core-Level Binding Energies in Atoms and Molecules
1Moh` 2.1.1 The Equivalent-Core Approximation
*xVAm7_v 2.1.2 Chemical Shifts
x{o5Ha{ 2.2 Core-Level Binding Energies in Solids
(eE}W~Z 2.2.1 The Born-Haber Cycle in Insulators
cZT.vA# 2.2.2 Theory of Binding Energies
/<(ik&%N 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
U jzz`!mz 2.3 Core Polarization
yQ&%* ?J 2.4 Final-State Multiplets in Rare-Earth Valence Bands
ffd3QQ 2.5 Vibrational Side Bands
u`2k6.- 2.6 Core Levels of Adsorbed Molecules
VIdoT2 2.7 Quantitative Chemical Analysis from Core-Level Intensities
O7*i;$!R References
Vxs`w z(68^-V=: 3. Charge-Excitation Final States: Satellites
xyWdzc](p 3.1 Copper Dihalides; 3d Transition Metal Compounds
U+M?<4J)" 3.1.1 Characterization of a Satellite
QNwAuH T 3.1.2 Analysis of Charge-Transfer Satellites
jz:c)C&/ 3.1.3 Non-local Screening
t? Ja q 3.2 The 6-eV Satellite in Nickel
oT{yttSNo 3.2.1 Resonance Photoemission
O!Cu.9} 3.2.2 Satellites in Other Metals
GlD'?Mk1 3.3 The Gunnarsson-Sch6nhammer Theory
d+ko"F| 3.4 Photoemission Signals and Narrow Bands in Metals
`bF;Ew; References
}@6
%yR R*C+Yk)Tkt 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
"
CoR?[,x 4.1 Theory
5FKd{V' 4.1.1 General
g}KZL-p4\m 4.1.2 Core-Line Shape
xmx;tq 4.1.3 Intrinsic Plasmons
g$LwXfg 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
@&yj7-] 4.1.5 The Total Photoelectron Spectrum
B;_3IHMO 4.2 Experimental Results
Mwk_SCy 4.2.1 The Core Line Without Plasmons
#vwXx r 4.2.2 Core-Level Spectra Including Plasmoas
HN@)/5BY 4.2.3 Valence-Band Spectra of the Simple Metals
0Ch._~Q+20 4.2.4 Simple Metals: A General Comment
FWN%JCOj@ 4.3 The Background Correction
8QBL:7< References
Z"T(8>c;g Ls*=mh~IY 5. Valence Orbitals in Simple Molecules and Insulating Solids
aC 0Jfo 5.1 UPS Spectra of Monatomic Gases
b<7qmg3 5.2 Photoelectron Spectra of Diatomic Molecules
=(\!,S' 5.3 Binding Energy of the H2 Molecule
AE
_~DZ:%c 5.4 Hydrides Isoelectronic with Noble Gases
+[`%b3N k Neon (Ne)
0E1)&f Hydrogen Fluoride (HF)
>L4$DKO Water (H2O)
]~ UkD*Ct Ammonia (NH3)
_3[BS9 Methane (CH4)
tpK4 gjf 5.5 Spectra of the Alkali HMides
+,>bpp1 5.6 Transition Metal Dihalides
zSCPp6 5.7 Hydrocarbons
OG`Oi^2 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
Jl ?Q}SB 5.7.2 Linear Polymers
"ukbqdKD 5.8 Insulating Solids with Valence d Electrons
fTgN2U 5.8.1 The NiO Problem
Ts6X:D4, 5.8.2 Mort Insulation
)>p6h]]a 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
(B#|3o 5.8.4Band Structures of Transition Metal Compounds
T,>e\ 5.9 High—Temperature Superconductors
sAlgp2- 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
_AHVMsz@ 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
*JXJ
2 5.9.3 The Superconducting Gap
`<d>C}9 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
UMaKvr-C& 5.9.5 Core—Level Shifts
=p6xc}N 5.10 The Fermi Liquid and the Luttinger Liquid
:g";p.~= 5.11 Adsorbed Molecules
rgY~8PY" 5.11.1 Outline
RoZV6U~ 5.11.2 CO on Metal Surfaces
zPYa@0I
References
{{,%p#/b ]"6<"1) 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
bHnQLJ 6.1 Theory of Photoemission:A Summary of the Three-Step Model
IIZsN*^ 6.2 Discussion of the Photocurrent
lR!$+atW 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
YSif`W! 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
5WYU&8+]{: 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
p3' +"sFU 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
p2K9R4 6.3.1 Band Structure Regime
}dM^6
Kd% 6.3.2 XPS Regime
a{W-+t 6.3.3 Surface Emission
6wgOmyJx 6.3.4 One-Step Calculations
KK6YA 6.4 Thermal Effects
lOui{QU 6.5 Dipole Selection Rules for Direct Optical Transitions
L')zuI References
Y')+/<Q2E nabN.Ly 7.Band Structtire and Angular-Resolved Photoelectron Spectra
D~:fn|/Brp 7.1 Free-Electron Final—State Model
rGWTpN 7.2 Methods Employing Calculated Band Structures
/slML~$t< 7.3 Methods for the Absolute Determination of the Crystal Momentum
4Q5v8k= 7.3.1 Triangulation or Energy Coincidence Method
-,&Xp>u\ 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
T_WQzEL^ 7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
}UrtDXhA 7.3.4 The Surface Emission Method and Electron Damping
|.A>0-']M 7.3.5 The Very-Low-Energy Electron Diffraction Method
d,)L, J 7.3.6 The Fermi Surface Method
E_oe1C: 7.3.7 Intensities and Their Use in Band-Structure Determinations
51vK> 7.3.8 Summary
C0RwW??t 7.4 Experimental Band Structures
:-)[B^0 7.4.1 One- and Two-Dimensional Systems
!MC Wt 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
q}jf&xUWzH 7..4.3UPS Band Structures and XPS Density of States
X#y l8k_ 7.5 A Comment
\<} nn?~n References
Ar==@777j K^bn4Nr 8.Surface States, Surface Effects
fVM%.` 8.1 Theoretical Considerations
d\v _!7 8.2 Experimental Results on Surface States
t>xV]W< 8.3 Quantum-Well States
FyEl@ }W 8.4 Surface Core-Level Shifts
uOQ5.S+ References
5
Jhl4p}w |1D`v9 9.Inverse Photoelectron Spectroscopy
vF,l?cU~ 9.1 Surface States
`4CRpz 9.2 Bulk Band Structures
;IT^SHym 9.3 Adsorbed Molecules
RjDFc:bB References
yrjm0BM# j*5VJ: 10. Spin-Polarized Photoelectron Spectroscopy
oZ}e
w!V 10.1 General Description
}5k"aCno 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
vXF\PMf 10.3 Magnetic Dichroism
61'7b`:(hi References
v>XE]c_ Ssj'1[% 11. Photoelectron Diffraction
jK =[ 11.1 Examples
gJ])A7O 11.2 Substrate Photoelectron Diffraction
j!s&yHE1 11.3 Adsorbate Photoelectron Diffraction
? _W*7< 11.4 Fermi Surface Scans
)nY/ RO References
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