光电子谱技术是研究原子、分子、固体和表面电子
结构的一种非常有效的手段。本书全面
系统地介绍了
光电子谱技术的
原理和应用,并简明讨论了逆光发射、自旋极化光发射和
光电子衍射等现象。本书是一本非常实用的光电子谱技术的专著,内容几乎覆盖了光电子研究的所有领域。其特点是紧密联系实验,并利用理论详细解释实验结果,达到理论和应用的有机结合。书中还收集了大量的实际
材料的光电子谱分析,同时给出了大量的实验数据,以便于读者的查阅。总之,该书既是一本很有价值的参考书,又可作为初学者的入门教材。
r|\5'ZMx /^z/]!JG:V 作者在该领域做出了杰出的贡献。在第3版中,作者介绍了大量最新研究成果,并对光电子谱技术很多方面给出了有深刻见解的讨论。
R<y Nv dr,B\.|jC 读者对象:适用于凝聚态
物理学、材料物理学和光电子学等专业的高年级本科生、研究生和相关专业的科研人员。
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DqurHQ z)m [0% yJH 目录
f7_\).T 1. Introduction and Basic Principles
<?>I\ 1.1 Historical Development
PSP1>-7)w 1.2 The Electron Mean Free Path
Njy9 JX 1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
B&%L`v2[ 1.4 Experimental Aspects
AND7jEn 1.5 Very High Resolution
=1{H
Sf 1.6 The Theory of Photoemission
,-cpsN 1.6.1 Core-Level Photoemission
vI
pO/m.3 1.6.2 Valence-State Photoemission
;1{iF2jZ: 1.6.3 Three-Step and One-Step Considerations
~h>rskJ_ 1.7 Deviations from the Simple Theory of Photoemission
EFa{O`_@U References
RlI
W&y P;)2*:--) 2. Core Levels and Final States
S\!
a"0$ 2.1 Core-Level Binding Energies in Atoms and Molecules
{+@ms$z 2.1.1 The Equivalent-Core Approximation
i63`B+L{ 2.1.2 Chemical Shifts
ESC 2.2 Core-Level Binding Energies in Solids
6pM"h5hA 2.2.1 The Born-Haber Cycle in Insulators
F9m 2C'U 2.2.2 Theory of Binding Energies
[<en1 2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
1?D8|< 2.3 Core Polarization
'\ph`Run 2.4 Final-State Multiplets in Rare-Earth Valence Bands
O_r^oH 2.5 Vibrational Side Bands
t/v@vJ`vSH 2.6 Core Levels of Adsorbed Molecules
iN:G/ss4O 2.7 Quantitative Chemical Analysis from Core-Level Intensities
]iz_w`I\ References
FSW3' cwH,l$ 3. Charge-Excitation Final States: Satellites
SBCL1aM 3.1 Copper Dihalides; 3d Transition Metal Compounds
(,- 5(fW 3.1.1 Characterization of a Satellite
R7E]*:0} 3.1.2 Analysis of Charge-Transfer Satellites
c0!Te'? 3.1.3 Non-local Screening
q*HAIw[<y 3.2 The 6-eV Satellite in Nickel
96.IuwL*.s 3.2.1 Resonance Photoemission
uuI3NAi~ 3.2.2 Satellites in Other Metals
89*S?C1 3.3 The Gunnarsson-Sch6nhammer Theory
#t"9TP 3.4 Photoemission Signals and Narrow Bands in Metals
/`7 I K References
T5K-gz7A #@nZ4=/z 4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
L/qZ ; { 4.1 Theory
RtW4n:c 4.1.1 General
r :fwrC 4.1.2 Core-Line Shape
&M0o&C-1/ 4.1.3 Intrinsic Plasmons
EsT0"{ 4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
keT?,YI 4.1.5 The Total Photoelectron Spectrum
7ZF}0K$^B 4.2 Experimental Results
}U2[? 4.2.1 The Core Line Without Plasmons
'4J&Gp x 4.2.2 Core-Level Spectra Including Plasmoas
fswZM\@ 4.2.3 Valence-Band Spectra of the Simple Metals
kA1RfSS 4.2.4 Simple Metals: A General Comment
z`\#$ 4.3 The Background Correction
,3G$` References
i0ILb/LS X tJswxw`K 5. Valence Orbitals in Simple Molecules and Insulating Solids
"F&Tnhh4 5.1 UPS Spectra of Monatomic Gases
6tOP}X 5.2 Photoelectron Spectra of Diatomic Molecules
V8-4>H}Cb/ 5.3 Binding Energy of the H2 Molecule
Rb{+Ki 5.4 Hydrides Isoelectronic with Noble Gases
qsI{ b<n Neon (Ne)
FpP\-+Sl Hydrogen Fluoride (HF)
V^j3y`K Water (H2O)
S/a/1n$ U Ammonia (NH3)
cge-'/8w% Methane (CH4)
=Ov9Kf 5.5 Spectra of the Alkali HMides
^it4z gx@ 5.6 Transition Metal Dihalides
OZ eiHX! 5.7 Hydrocarbons
V78Mq:7d 5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
2}D,df'W4 5.7.2 Linear Polymers
[vE$R@TZ0! 5.8 Insulating Solids with Valence d Electrons
Xfj)gPt} 5.8.1 The NiO Problem
7^c2e*S 5.8.2 Mort Insulation
g+:$X- r 5.8.3 The Metal-Insulator Transition;the Ratio of the Correlation Energy and the Bandwidth;Doping
OlIT|bzkb 5.8.4Band Structures of Transition Metal Compounds
l#b:^3 5.9 High—Temperature Superconductors
?A|zRj{ 5.9.1valence-Band Electronic Structure;Polycrystalline Samples
H!p!sn 5.9.2 Dispersion Relations in High Temperature Superconductors;Single Crystals
J =b* 5.9.3 The Superconducting Gap
#]"/{Z 5.9.4 Symmetry of the Order Parameter in the High-Temperature SuDerconductors
k"t>He 5.9.5 Core—Level Shifts
O\%j56Bf 5.10 The Fermi Liquid and the Luttinger Liquid
4"LPJX)Q 5.11 Adsorbed Molecules
;9K[~ 5.11.1 Outline
4\v~HFsv 5.11.2 CO on Metal Surfaces
_\p`4-.V References
sc<kiL 2K
Pqu:lv 6.Photoemission of Valence Electrons froill Metallic Solids in the OHe-Electron Approximation
\{kHSV%z 6.1 Theory of Photoemission:A Summary of the Three-Step Model
Xz8$Xz,O 6.2 Discussion of the Photocurrent
4 uShM0qa 6.2.1 Kinematics of Internal Photoemission in a Polycrystalline Sample
,KT<4 6.2.2 Primary and Secondary Cones in the Photoemission from a Real Solid
:g&>D#{ 6.2.3 Angle-Integrated and Angle-Resolved Data Collection
VcP:}a< B\ 6.3 Photoemission from the Semi—infinite Crystal:The Inverse LEED Formalism
yj>){NcX 6.3.1 Band Structure Regime
m^z,,t9 6.3.2 XPS Regime
e "_&z#
2_ 6.3.3 Surface Emission
V!mWn|lf 6.3.4 One-Step Calculations
ma3Qi/ 6.4 Thermal Effects
~M*7N@D 6.5 Dipole Selection Rules for Direct Optical Transitions
Ks|gL#)*Ku References
\Ph]*% q{/*n]K 7.Band Structtire and Angular-Resolved Photoelectron Spectra
EVWA\RO'\ 7.1 Free-Electron Final—State Model
g/x_m. 7.2 Methods Employing Calculated Band Structures
S3; lKr 7.3 Methods for the Absolute Determination of the Crystal Momentum
*}7U`Aa 7.3.1 Triangulation or Energy Coincidence Method
%z=`JhE"Q 7.3.2 Bragg Plane Method: Variation of External Emission Angle at Fixed Photon Frequency (Disappearance/Appearance Angle Method
CK=ARh#|
7.3.3 Bragg Plane Method: Variation of Photon Energy at Fixed Emission Angle (Symmetry Method)
f;R>Pr;rD 7.3.4 The Surface Emission Method and Electron Damping
P7'M],!9w 7.3.5 The Very-Low-Energy Electron Diffraction Method
Ohc^d"[7 7.3.6 The Fermi Surface Method
#iiwD| 7.3.7 Intensities and Their Use in Band-Structure Determinations
8*vFdoE_oO 7.3.8 Summary
O
/vWd" 7.4 Experimental Band Structures
#T[%6(QW 7.4.1 One- and Two-Dimensional Systems
f KHse$?_ 7.4.2 Three-Dimensional Solids: Metals and Semiconductors
-E:(w<]; 7..4.3UPS Band Structures and XPS Density of States
-7&?@M,u 7.5 A Comment
<H!O:Mf_p References
Trpgx nVNs][ 8.Surface States, Surface Effects
'w:bs! 8.1 Theoretical Considerations
$<:'!#% 8.2 Experimental Results on Surface States
Jlz9E|*qV 8.3 Quantum-Well States
ZH!;z-R 8.4 Surface Core-Level Shifts
!F-sA: xq References
_OLI%o
PaNeu1cO 9.Inverse Photoelectron Spectroscopy
W|0My0y 9.1 Surface States
|ebvx?\ 9.2 Bulk Band Structures
L(;.n>/ 9.3 Adsorbed Molecules
2HSb.&7-G References
E_]k>bf\ b1H7 10. Spin-Polarized Photoelectron Spectroscopy
gXF.on4B 10.1 General Description
A4}#U=3tI 10.2 Examples of Spin-Polarized Photoelectron Spectroscopy
j|k@MfA 10.3 Magnetic Dichroism
h>| g2h References
db'K!M) IEc>.J|T& 11. Photoelectron Diffraction
1b8c67j[ 11.1 Examples
,b4g.CV 11.2 Substrate Photoelectron Diffraction
;KL9oV!<f 11.3 Adsorbate Photoelectron Diffraction
;sCU[4 11.4 Fermi Surface Scans
sLZ>v References
g[AA,@p+ zPHy2H$28 Appendix
vn ``0!FX A.1 Table of Binding Energies
JS PW>W" A.2 Surface and Bulk Brillouin Zones of the Three Low-Index Faces of a Face—Centered Cubic(fcc)Crystal Face
0lBat_<8 A.3 Compilation of Work Functions
M.S
s:ttj References
%Sul4: D# Index